• Title/Summary/Keyword: 천연 접착제

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Effects of Ozonized Soybean Oil to Changes of Chemical Structures and Bond Strength of pMD (오존산화 처리한 콩기름을 이용한 변성 pMDI 접착제의 화학 구조 및 접착력 변화)

  • You, Young Sam;Lee, Hyun Jong;Lee, Taek Jun;Park, Heon
    • Journal of the Korean Wood Science and Technology
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    • v.36 no.4
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    • pp.37-43
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    • 2008
  • The research attempted to develop an eco-friendly wood adhesive based on vegetable oil (soybean oil), the renewable and sustainable natural resources, using ozonification technology for the chemical structure modification. The soybean oils (SBO) were reacted with $O_3$ at the rate of 7.13 g/h for different times, 15 minutes, 30 minutes, 60 minutes, and 120 minutes. Modified chemical structure of the ozonized SBOs were examined by Fourier transform Infrared (FT-IR) spectrum. The FT-IR spectrum of SBO had an absorbance peak at $3010cm^{-1}$ that is the characteristic peak of the unsaturated double bonds. As ozone treatment time increased, the peak of the double bond was disappeared and aldehyde or carboxyl peak appeared at $1700cm^{-1}$. The dry, wet, and cyclic boiling bond strengths of the ozonized SBO mixed with polymeric diphenylmethane-4, 4-diisocyanate (pMDI) were also investigated. In the dry shear test, all strengths met constantly the standard requirement of $7.0kgf/cm^2$ (KS F3101 2006). The bond strengths gradually increased with increasing ozone treatment time. The highest strength showed at 60 minutes ozone treatment and decreased values at 120 minutes. In the cyclic boiling shear test, 30, 60 and 120 minutes exceeded the standard requirement.

Study on Qualitative Analysis for Lacquer Mixed with Some Additives by Pyrolysis‐Gas Chromatography/Mass Spectrometry (Py-GC/MS 분석법을 이용한 첨가물 혼합 옻칠 접착제의 정성분석)

  • Kim, Ji Eun;Yu, Ji A;Chung, Yong Jae
    • Journal of Conservation Science
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    • v.33 no.1
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    • pp.51-59
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    • 2017
  • Lacquer has been used as a natural paint or adhesive in Korea since 2nd century B.C. It has been found to have been used as an adhesive as mentioned in old records and as seen in excavated relics, It was also mixed with flour, animal glue, or fish glue to produce lacquer adhesives. Qualitative analysis and evaluation of the applicability of lacquer and additives was performed in this study. The results of EGA analysis for lacquer additives confirmed that the pyrolysis temperature of lacquer, glucose glue, and animal glue. On the basis of this result, raw lacquer sample was checked that pyrolysis product that originated from urushiol side chain (R group). Components originating from glucose and amino acid were detected in glutinous rice paste and animal glue samples. In this study, the optimum pyrolysis temperature for each lacquer and additive mixture was determined from basic qualitative analysis data. By performing the qualitative analysis of each mixture, the applicability of this technique for analyzing real relics was evaluated.

Study About Filling-Material for Clay Layer Restoration of Seated Amitabha Triad at Muwisa Temple (Treasure No. 1312) (보물 제1312호 무위사 아미타여래삼존좌상 소조층 보수 충전제에 관한 연구)

  • Lee, Su Yea
    • Journal of Conservation Science
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    • v.31 no.1
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    • pp.1-11
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    • 2015
  • Seated Amitabha Triad at Muwisa Temple (Treasure No. 1312) had been known as wooden Buddha statue, but a precise safety inspection revealed that the statue is terracotta Buddha statue made with clay. The clay layer of Amitabha Triad was conserved due to its severe damage. In this study, experiments were conducted to produce the most appropriate filler for the conservation treatment of the seated Amitabha Triad. Mixed clay samples with various ratios were produced and surface hardening state, crack, color change, and shrinkage of the samples during dry process were measured. Loess, fine sand powder, and cotton were used to produce the mixed clay for the filler with six different ratios and then 12 different concentration glues made with glutinous rice glue, Pachymeniopsis Elliptica glue, and animal glue were added as adhesives. Total 72 types of samples were prepared and comparative study was conducted. As a result, when the mixed clay contains 2.5% cotton compared to the weight per cent of loess and fine sand powder and also loess and fine sand in the mixed clay have a 15:1 ratio, the mixed clay had the lowest shrinkage. Animal glue is considered as an appropriate glue since it had small color change, low physical property change and shringkage. Therefore, mixed clay (loess:fine sand=15:1) mixed with 15ml animal glue is likely to be a suitable filler for conservation treatment of the seated amitabha triad at the Muwisa Temple.

브롬화 부틸고무에 대하여 [제 2 부 응용(應用)]

  • Choe, Jun-Chul
    • Elastomers and Composites
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    • v.12 no.1
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    • pp.43-46
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    • 1977
  • 브롬화 부틸고무는 새로운 연속적(連續的)인 방법(方法)에 의해 제품(製品)의 질(質)이 균일(均一)하고 안정(安定)한 제품(製品)을 얻을 수 있는 바 이것은 소위(所謂) 상품명(商品名)으로 Folysar Bromobutyl X2라 한다. 이 고무는 일반(一般) 부틸고무와는 달리 여러가지 장점(長點)을 지니고 있다. 다시 말하면 일반(一般) 부틸고무에 비(比)해 첫째 가황속도(加黃速度)가 빠르며, 둘째 천연(天然)고무 또는 SBR과 같은 불포화(不飽化) 고무들과 혼합사용(混合使用)이 가능(可能)하며, 셋째 이러한 고무들과의 혼합사용시(混合使用時) 접착력(接着力)도 우수(優秀)하며 마지막으로 글로로프렌이나 EPDM과도 혼합(混合)이 가능(可能)하기 때문에 여러가지 용도(用途)로 사용(使用)할 수 있다. 이러한 점(點)을 참작(參酌)하여 브롬화 부틸고무의 이용도(利用度)는 (1) 타이어중, tubeless 타이어의 inner liner, white side wall, sidewall coverstrip 그러고 라디얼 타이어에 이용(利用)될 수 있고, (2) 내열성(耐熱性)이 요구(要求)되는 고속용(高速用) 또는 heavy-duty 타이어의 튜우브, 자동차(自動車) 부품(部品) 예(例)컨대 mount등(等)에 이용(利用)할 수 있을 뿐만 아니라 행크 라인닝, 고무 호오스, 콘베어 고무벨트, 의료용 병마개, 접착제등(等)에 광범위(廣範圍)하게 이용(利用)할 수 있다.

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Study on the filling material for the painting wall layer of the temple wall painting using a natural adhesive (천연 접착제를 활용한 사찰벽화 화벽층의 충전 재료연구)

  • Kim, Soon-Kwan;Jeong, Hye-Young
    • 보존과학연구
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    • s.29
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    • pp.255-278
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    • 2008
  • Considering the physical quality of the wall body in this study we tried to select a replenishing that is proper for filling the cracked part of the painting wall layer and apply the natural adhesives that have traditionally been used, investigating whether it is possible to substitute those for the chemical adhesive which is used at present time. The result of this study showed the red algae adhesive was, in a weathering environment, as safe as the synthetic resin originated from the polyvinyl acetate which is used generally on the present spot, and it was concluded that although the starch adhesive displayed its superiority in enhancing the strength of the earth mortar and its work disposition, it seemed proper for it to be used as a filling adhesive for the first or midterm layer because it showed a surface hardening phenomenon. And also the glue and fish glue were judged they were not qualified as a filling adhesive due to mold occurring in a environment of high moisture that is a biological problem, showing at same time a weak physical feature in a weathering environment. Therefore it would be possible to use the red algae adhesive or starch one substituting them for the original one sold on the present market, if among natural adhesives the weak points of the them were to be corrected.

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Direct Analysis of Organic Additives in Cured Rubber by Pyrolysis-Gas Chromatography/Mass Spectrometry (열분해-가스크로마토그래피/질량분석법에 의한 가황고무중의 유기첨가제의 직접분석)

  • Kim, Seung Wook;Heo, Gwi Suk;Lee, Gae Ho
    • Journal of the Korean Chemical Society
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    • v.41 no.10
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    • pp.524-534
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    • 1997
  • Analysis of additives in cured rubber is often a difficult task for analytical chemists because of a wide variety of complex components. Conventional analyses of additives and rubbers have been done in multistep, off-line processes with large sample size and extensive sample preparations. The coumarone-indene resin, resorcinol-formaldehyde resin, and prevulcanization inhibitor have been characterized by their pyrolysis pathways and mass spectra of characteristic pyrolyzates. Pyrolysis Gas Chromatography/Mass Spectrometry (Py-GC/MS) was used in the identification of additives without any sample pretreatment. This result shows that several organic additives in cured rubber can be directly analyzed.

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A Study on the Bonding Strength, Reactivity and Thermal Properties of Epoxy Resin Mixed with ESBO (에폭시수지-ESBO 혼용 비율에 따른 목재접착제의 접착력, 반응성 및 열분석에 관한 연구)

  • Choi, Jin Lim;Park, Heon
    • Journal of the Korean Wood Science and Technology
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    • v.35 no.3
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    • pp.36-44
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    • 2007
  • The purpose of this study was to investigate thermal stability, reactivity, and bonding strength of existing epoxy resin mixed with the epoxidized soybean oil (ESBO) in order to use soybean oil economically. In the dry shear test, the marked strengths showed $30.5kgf/cm^2$ at the ratio of ESBO to epoxy resin 9 : 1 and $6.2kgf/cm^2$ at the ratio 8 : 2. The bonding strengths of the others, except mixing ratios 2 : 8 and 1 : 9, exceeded the requirement of Korean plywood standard of $7.0kgf/cm^2$. In the wet shear test, the result was $5.8kgf/cm^2$ at the ratio 9 : 1. There were no thickness swelling and moisture absorption in the water resistance of the film. The value of activation energy, Tg (${\Delta}E$), by DSC analysis showed between $110^{\circ}C$ and $120^{\circ}C$ through all ratios. Epoxy in the epoxy resin fully reacted with the hardener (TETA), but it is difficult to decide that epoxys in the ESBO were reacted directly with the hardener from FT-IR analysis. As the mixing ratio of ESBO increased, the thermal stabilities dropped from TGA analysis. From the comprehensive view on the results of above experiments, it could be confirmed through experiments that the ESBO in the mixed adhesive of epoxy resin/ESBO played a role as an extending agent level of epoxy adhesive, and we were able to know that in order to utilize ESBO as an adhesive, a study should be performed on the condition of hardening, inducible of the hardening reaction.

The Variation of Indoor Air Quality in Nursing Home

  • Ji, Dong-Ha;Choi, Mi-Suk
    • Journal of the Korea Society of Computer and Information
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    • v.25 no.1
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    • pp.117-124
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    • 2020
  • In this paper, we proposed a plan to maintain comfortable indoor air quality in nursing homes by suggesting ways to reduce items temporarily exceeding the reference values through real-time concentration variation analysis of indoor air quality. Five items including PM10, CO2, CO, VOC, and Radon are measured at nursing homes in spring (April) and autumn (September) was carried out and all of the measured items were analyzed to satisfy the criteria set by the Indoor Air Quality Control Act. As a result of the analysis of the real-time concentration change, the concentration of CO2 was close to the reference value based on the number of occupants in the sick room. Due to the disinfectant (alcohol) used to disinfect and the auxiliary tools (adhesive) used in the operation of the program such as making and coloring, it was analyzed to temporarily exceed the standard value in the hall. In conclusion, it is possible to provide pleasant indoor air quality and contribute to securing the nursing home's competitiveness if periodic ventilation, natural disinfectant and eco-friendly product are used in consideration of the thermal environment.

Scientific Conservation and Analysis of Octagonal Green Glass Bottle Excavated from Tomb Hwayu princess (화유옹주묘 출토 녹유리장경각병-보존과 분석)

  • Gang, Hyeong-Tae;Yang, Pil-Seung;Heo, U-Yeong;Jo, Nam-Cheol
    • KOMUNHWA
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    • no.70
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    • pp.5-15
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    • 2007
  • Octagonal green glass bottle with long neck(녹유리장경각병) was found in the tomb of the princess Hwayu who was King Youngjo's daughter by a concubine while the tomb was exhumed and buried in another place around Bucheon City, Gyeonggi-do. This octagonal glass bottle is dark green. It was made in AD 1736-A1795 because it was cngraved an inscription of "건륭년제" the bottom. This glass bottle was taken an X-ray radiography and tested adhesives and restoration materials for the conservation. Loctite 401 was suitable as considering the translucency of the glass bottle, good adhesive property and reversibility of the adhesive so it was chosen. A minute piece of the glass was analyzed the composition and lead isotope ratio. Major chemical composition of the glass bottle consisted of SiO2, K2O, and PbO system and the ratio was 68: 18.5:5.7. Green color of glass bottle was due to Fe2O3 and CuO. When the glass bottle was made, quartz as raw material of silica and K2O as natural saltpeter(KNO3) were utilized. As a result of lead isotope ratio analysis, it was suggested that the galena as raw material of lead for glass making came from the southern part of China. These results are expected to become useful data in background of glass culture and circulation study of old glass.

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Performance Measurement of The Hybrid Sheet with Dual Function of Electromagnetic-Shielding and Heat-Dissipating (전자파차폐 및 방열 기능을 가지는 하이브리드시트 성능측정)

  • Ahn, Sung-Su
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.22 no.5
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    • pp.530-536
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    • 2021
  • This paper presents the performance measurement results of a hybrid sheet with both shielding and heat dissipation functions developed by laminating copper mesh sheets and natural graphite sheets, which are used widely as electromagnetic shielding and heat-dissipating materials in electronic devices, without a pressure-sensitive adhesive (PSA). The results were compared by measuring the vertical and horizontal thermal conductivity with two other products to confirm the heat dissipation performance. A radiation emission test confirmed the electromagnetic shielding performance using a 3m electromagnetic anechoic chamber according to the CISPR 11 standard. In the case of vertical thermal conductivity, the proposed hybrid sheet was approximately 8.63 times higher than that of an aluminum sheet with heat dissipation coating and 18.7 times higher than that of a copper sheet laminated with artificial graphite with PSA. The proposed hybrid sheet was approximately 0.64 times that of the sheet, and approximately 1.76 times that of the heat-dissipated aluminum sheet in case of horizontal thermal conductivity. Measurements after applying each sheet in the same heat source revealed the proposed hybrid sheet to have the best heat dissipation performance. The radiation emission test showed that significantly radiation noise had been removed.