• Economic and Environmental Geology
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• v.41 no.4
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• pp.393-403
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• 2008

Hydrogeochemistry of groundwater was studied in order to identify the influence of cow manure, distributed to a farmland as organic fertilizer, on nitrate concentrations in shallow groundwater and its spatio-temporal variations. From monitoring wells, water levels were measured using automatic data loggers, and water samples collected and analyzed in Feb., April, June and Oct. 2007. The average electric conductivity and concentration of nitrate in the groundwater show the highest levels in April and decline in subsequent sampling times. Decreases in dissolved oxygen(DO) and nitrate concentrations from April to Oct. and corresponding increases in $HCO_3$ concentrations indicate denitrification processes by microorganisms. Spatial variation of nitrate concentration appeared to be affected by the redox conditions of groundwater controlled by geochemical reactions of Mn, Fe and DOC contents.

• Economic and Environmental Geology
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• v.34 no.2
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• pp.175-192
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• 2001

We have collected hydrogeochemical data of shallow groundwaters in the Uljin area located at eastern coastal area of Korea. Geostatistical analysis (ANOVA test, cluster analysis, and factor analysis) of the collected data sets was pert'onned, in order to evaluate both the spatial and/or temporal variation of water quality data and the groundwater contamination, as weJl as the principal reactions occurring in the aquifer. Results of the ANOVA test show that regional water chemistry are not significantly changed spatially in eight watersheds. However, some ions such as $Ca^{2+}$, $HCO_{3}^{-}$ and $SO_{4}^{2-}$ show a meaningful watershed variation. Water chemistry variation according to sampling time (season) is not shown, except for $SO_{4}^{2-}$. The cluster analysis shows that significant water chemistry variation is eXplained by the distance from the coast. Factor analysis indicates that the water chemistry is changed according to various factors as follows: in the order of decreasing importance, water-rock interaction (mainly, carbonate dissolution), sea-salt spraying, and then contamination by fertilizers and agrochemicals.

• Journal of the Korean Society of Groundwater Environment
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• v.7 no.1
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• pp.32-46
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• 2000

Hydrogeochemical and isotope ($\delta$$^{18}$ O, $\delta$D, $^3$H, $\delta$$^{13}$ C, $\delta$$^{34}$ S, $^{87}$ Sr/$^{86}$ Sr) studies of various kinds of waters (thermal groundwater, deep groundwater, shallow groundwater, and surface water) from the Yusung area were carried out in order to elucidate their geochemical characteristics such as distribution and behaviour of major/minor elements, geochemical evolution, reservoir temperature, and water-rock interaction of the thermal groundwater. Thermal groundwater of the Yusung area is formed by heating at depth during deep circlulation of groundwater and is evolved into Na-HCO$_3$type water by hydrolysis of silicate minerals with calcite precipitation and mixing of shallow groundwater. High NO$_3$contents of many thermal and deep groundwater samples indicate that the thermal or deep groundwaters were mixed with contaminated shallow groundwater and/or surface water. $\delta$$^{18}$ O and $\delta$D are plotted around the global meteoric water line and there are no differences between the various types of water. Tritium contents of shallow groundwater, deep groundwater and thermal groundwater are quite different, but show that the thermal groundwater was mixed with surface water and/or shallow groundwater during uprising to surface after being heated at depths. $\delta$$^{13}$ C values of all water samples are very low (average -16.3$\textperthousand$%o). Such low $\delta$$^{13}$ C values indicate that the source of carbon is organic material and all waters from the Yusung area were affected by $CO_2$ gas originated from near surface environment. $\delta$$^{34}$ S values show mixing properties of thermal groundwater and shallow groundwater. Based on $^{87}$ Sr/$^{86}$ Sr values, Ca is thought to be originated from the dissolution of plagioclase. Reservoir temperature at depth is estimated to be 100~1$25^{\circ}C$ by calculation of equilibrium method of multiphase system. Therefore, the thermal groundwaters from the Yusung area were formed by heating at depths and evolved by water-rock interaction and mixing with shallow groundwater.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2001.09a
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• pp.83-87
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• 2001

토양이나 천부 지하수 온도의 장기 관측 자료를 이용하여 함양량 또는 증발산량을 산정하는 온도추적자법의 원리를 소개하였으며, 국가 지하수 관측망의 장기 관측 자료에 본 방법을 적용하여 관측소 주변에서의 수직적인 물의 흐름(flux)을 추정하였다. 20개 충적층 관정의 수온 관측 자료를 분석한 결과, 15개 지역에서는 증발산에 의한 상향(upward) 흐름이, 5개 지역에서는 지하수 함양에 의한 하향(downward) 흐름이 우세하게 발생하는 것으로 나타났다. 본 방법은 수직적인 물의 흐름을 시간 독립적인 정류 상태로 가정하므로 우기에 지하수 함양이 주로 발생하는 국내의 수리지질학적 조건에 잘 부합하지 않지만 함양 지역을 판단하는 방법으로 유용하게 이용될 수 있다.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.10 no.3
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• pp.189-197
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• 2012

Geochemical composition of fracture filling minerals and groundwater was investigated to characterize geochemical characteristics of groundwater system at the KURT site. Minerals such as calcite, illite, laumontite, chlorite, epidote, montmorillonite, and kaolinite, as well as I/S mixed layer minerals were detected in the minerals extracted from the fracture surfaces of the core samples. The groundwater from the DB-1, YS-1 and YS-4 boreholes showed alkaline conditions with pH of higher than 8. The electrical conductivity (EC) values of the groundwater samples were around $200{\mu}S/cm$, except for the YS-1 borehole. Dissolved oxygen was almost zero in the DB-1 borehole indicating highly reduced conditions. The Cl- concentration was estimated around 5 mg/L and showed homogeneous distribution along depths at the KURT site. It might indicate the mixing between shallow groundwater and deep groundwater. The shallow groundwater from boreholes showed $Ca-HCO_3$ type, whereas deep groundwater below 300 m from the surface indicated $Na-HCO_3$ type. The isotopic values observed in the groundwater ranged from -10.4 to -8.2‰ for ${\delta}^{18}O$ and from -71.3 to -55.0‰for ${\delta}D$. In addition, the isotope-depleted water contained higher fluoride concentration. The oxygen and hydrogen isotopic values of deep groundwater were more depleted compared to the shallow groundwater. The results from age dating analysis using $^{14}C$ indicated relatively younger (2000~6000yr old) groundwater compared to other european granitic groundwaters such as Stripa (Sweden).

• Proceedings of the KSEEG Conference
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• 2002.04a
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• pp.463-465
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• 2002

연구지역은 좁은 면적에 비하여 800m 이상의 지형기복을 보이며, 계곡과 하천 충적층을 따라 마을이 발달된 전형적인 수계 상류의 농촌지역이다. 주요 상수원은 천부지하수이며, 농업용으로는 하천수를 이용한다. 지표수는 연구지역의 소유역(A, B)간 계절별 수질차이를 보이나, 지하수의 경우 유역간 및 계절별 변동이 상대적으로 작게 나타난다. B 소유역의 하류부에서는 지질매체의 영향으로 보이는 Fe, Mn, Zn 농도의 부화현상이 나타났으며, 이는 방이리층과 길왕리층을 기반암으로 하는 지역에 대한 전체적인 지하수질 조사가 필요함을 지시한다. 국지적인 수질오염원으로 과거에 개발되었던 폐금광이 존재하며, 이로 인한 산성수의 발생도 인지되었다.

• Journal of the Korean earth science society
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• v.41 no.6
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• pp.630-646
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• 2020

In rural areas, nitrate-nitrogen (NO3-N) pollution caused by agricultural activities is a major obstacle to the use of shallow groundwater as domestic water or drinking water. In this study, the water quality characteristics of shallow groundwater in Hyogyo-ri agricultural area of Yesan-gun, Chungcheongnam-do province was studied in connection with land use and chemical composition of soil layer. The average NO3-N concentration in groundwater exceeds the domestic and agricultural standard water qualities of Korea and is caused by anthropogenic sources such as fertilizer, livestock wastewater, and domestic sewage. The groundwater type mainly belongs to Ca(Na)-Cl type, unlike Ca-HCO3 type, a general type of shallow groundwater. The average NO3-N concentration (7.7 mg L-1) in groundwater in rice paddy/other (upstream, ranch, and residential) area is lower than the average concentration (22.8 mg L-1) in farm field area, due to a lower permeability in paddy area than that in farm field area. According to the trend analysis by the Mann-Kendall and Sen tests, the NO3-N concentration in the shallow groundwater shows a very weak decreasing trend with ~0.011 mg L-1yr-1 with indicating almost equilibrium state. Meanwhile, SO42- and HCO3- concentrations display annual decreasing trend by 15.48 and 13.15%, respectively. At a zone of 0 to 5 m below the surface, the average hydraulic conductivity is 1.86×10-5 cm s-1, with a greater value (1.03×10-4cm s-1) in sand layer and a smaller value (2.50×10-8 cm s-1) in silt layer.

• The Journal of Engineering Geology
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• v.20 no.1
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• pp.25-33
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• 2010

Most of contaminated groundwater in the study area was contaminated by $NO_3-N$ due to inflow of contaminated shallow surface groundwater inflow into groundwater well. Poor grouting and teared screen have increased contaminated shallow surface groundwater inflow into groundwater well. Contaminated shallow surface groundwater was inflowed into groundwater well throughout faults, joints and fracture zone of ESE-WNW, NNW, NW-SE and NS direction. The objective of this paper is to evaluate an improvement of water quality for contaminated groundwater by $NO_3-N$ using compression packer. For this study groundwater samples collected from 46 groundwater wells were analyzed to clarify $NO_3-N$ contents. Groundwater wells over 10 mg/L in $NO_3-N$ content is 9 wells showing 20% among total samples. $NO_3-N$ contents after compression packer installation showed 26~81% low value compared with before compression packer.

• The Journal of Engineering Geology
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• v.2 no.2
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• pp.113-130
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• 1992

Groundwater in crystalline basement is controlled primarily by tectonic fractures. It is evident that the delineation of the heavily faulted area and/or fractures deeply developped should be considerable value in deep-seated low enthalphy geothermal water. Electrical and electromagnetic methods have effectively been employed to map hydraulic faults and shear zones for groundwater exploration. In this study VLi; dipoledipole resistivity, controlled source audio~frequency magneto-telluric(CSAMT) and magnetic methods were applied in the Bomun resort area, adjacent to Kyongju city, southeastern part of Korea. The integrated geophysical tools employed in this experiment can be manifested themselves as: 1. Magnetic high for granite intrusions which is more favorable for geothermal gradient increase in depth. 2. VLF cross-over trends for mapping linear shallow conductive fractures and shear zones. 3. Dipole-dipole resistivity distributions for the deep-seated(less than 500m in depth) fractures and shear zones. The dipole-dipole resistivity field data were inverted to the true resistivity distribution with two-dimensional automatic inversion program based on the finite-difference method. 4. CSAMT provides an efficient way of delineating fractures and fault zones if the depth is greater than about 500m.

• Economic and Environmental Geology
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• v.42 no.6
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• pp.541-548
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• 2009

The Dongrae thermal water area located at the southeastern marginal part of the Korean Peninsula is one of the oldest hot springs in Korea. The Dongrae thermal water shows Na-Cl type of water chemistry, whereas the shallow cold groundwater is Ca(-Na)-$HCO_3$ type. In this paper, we discuss the age of the Dongrae hot spring, i.e. groundwater cycle among meteoric water-surface water-shallow groundwater-hot spring water. The $^{87}Sr/^{86}Sr$ ratios of the thermal water in Dongrae area range from 0.705663 to 0.705688 and are lower than those of groundwater, surface water and rain water as well as aquifer bearing granite. These Sr isotopic signatures in the Dongrae thermal water indicate that the circulation rate between thermal water and current meteoric water including groundwater, surface water and rain water in the Dongrae area should be very slow. The $^{14}C$ age of the Dongrae hot spring water range from $1,271{\pm}36$ BP(before present) to $2,467{\pm}36$ BP whereas that of the shallow groundwater is $-495{\pm}33$ BP. This suggests that the period of groundwater cycle among meteoric water, surface water, shallow groundwater and hot spring should be more than 1,270 years. Then, it also indicates that the present Dongrae hot spring may be a mixed water between the old thermal water heated for at least 1,270 years and the present shallow cold groundwater.