• Title/Summary/Keyword: 채색층

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Physical Properties Testing and Practical Applications of Restoration Materials Made with Extra Hard Stone and Metakaolin (초경석고와 메타카올린 혼합재료의 물성실험 및 적용)

  • Kim, Hyunsuk;Lee, Haesoon
    • Conservation Science in Museum
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    • v.17
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    • pp.101-116
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    • 2016
  • Ceramic cultural artifacts restored with gypsum-based materials are prone to decay over time due to gypsum's natural absorption and release of atmospheric moisture, often leading to distortion and peeling of painted layers. This study proposes a new restoration material which utilizes extra hard stone, significantly superior in strength to regular gypsum. In order to enhance its physical properties and make it suitable for restoration of ceramics, extra hard stone is mixed with metakaolin. This mixture far surpasses regular gypsum in compressive strength(119MPa vs. 26MPa) while also maintaining a much lower wear rate(0.88% vs. 2.53%). Furthermore, the water absorption rate(2.9%) of the mixed material is over five times lower than that of regular gypsum(17.2%). When examined using a SEM(Scanning Electron Microscope), this mixture also proved superior to extra hard stone in terms of hardened density. The addition of metakaolin increases the mixture's strength and water resistance over that of extra hard stone and also improves its surface density, making it ideal for the restoration of ceramics. It has already been used to repair ceramic objects in the Museum's collection: Clay basin(sinan 18892), Buncheong ware bottle with incised peony design(jubsu 2034), Buncheong ware bowl with chrysanthemum(jubsu 1730). Results thus far have shown the mixture to be easy to inject and layer as well as harden into an even surface, which allows for smooth application of paint for color matching.

The Analytical Study of Pigments on Fourguardian Statues in Song-gwang Buddhist Temple in Suncheon - Focusing on Pigments of Virupaksha - (순천 송광사 소조사천왕상 채색안료의 자연과학적 분석 - 서방광목천왕상 채색안료를 중심으로 -)

  • Lee, Han Hyoung;Park, Ji Hee;Hong, Jong Ouk;Han, Min Su;Seo, Min Suck;Heo, Jun Su
    • Korean Journal of Heritage: History & Science
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    • v.45 no.1
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    • pp.122-147
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    • 2012
  • The Four-guardian statues in Song-gwang buddhist temple, Suncheon, Korea, have been remade in AD 1628 and have been repaired and repainted over several times since then. Therefore, the study of the pigments applied on the statues can provide good chance for investigation about pigments used in the late Chosun Period. Pigments on fragments from Gwang-mok(Virupaksha), one of the Four-guardian statues, have been analyzed by optical microscope, SEM-EDX and XRD in order to identify the components and compounds. Six types of materials were found from the fragments, which are soil layer with brown clay band, soil layer containing a lot of fibers, Korean paper with loose texture, Korean paper with dense texture, silk, and hemp textile. Presumably, the soil layer which have brown clay band is basis layer and the other layers are repaired layers. From comparative study for the components of the pigments, applied on upper and lower parts of the repaired layers, we have concluded that those repaired layers had been applied on the statue by the following order; basis layer ${\rightarrow}$ Korean paper with loose texture ${\rightarrow}$ soil containing a lot of fibers ${\rightarrow}$ silk ${\rightarrow}$ hemp textile and Korean paper with dense texture. In addition, the years that those materials were applied on the statue have been estimated as 1720~1891, 1926, 1946 and 1976, respectively. The distinct features of each age are as the following; lead white and copper chloride hydroxide are major white and green pigments before 1891, zinc white, barium white, emerald green, and ultramarine blue appear after 1926 and titanium white uprises around 1976. Our result presented here, study on pigments applied on traditional statues over several different periods, will provide good database for future study on pigments used for traditional painting in Buddist temples and Dancheong.

Study on the Manufacturing Technology of Mural Tomb in Goa-dong of Daegaya Period (대가야 고아동 고분벽화 제작기술에 관한 연구)

  • Lee, Hwa Soo;Lee, Han Hyeong;Lee, Kyeong Min;Han, Kyeong Soon
    • Journal of Conservation Science
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    • v.30 no.4
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    • pp.457-466
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    • 2014
  • Rigorous analysis was performed to identify the structure and materials of the murals to study techniques used on mural tombs of ancient Daegaya era(6th century). The murals were painted by applying mortar on the walls and the ceiling after building a stone chamber and creating ground layers on mortar layers. Mud was applied on most of the mortar layers on four sides of the walls except the ceiling. Sand was not used in mortar but was made of materials with pure calcium substances. In addition, shells in irregular sizes with incomplete calcination were mixed; and the mortar's white powder was inferred as lime obtained by calcination of oyster shells. Kaolinite($Al_2Si_2O_5(OH)_4$) was used in the ground layer, Cinnabar(HgS) was used for red pigment, Malachite($Cu_2CO_3(OH)_2$) for green and Lead white($PbCO_3{\cdot}Pb(OH)_2$) for white. Mud plaster was applied on the mortar and was composed thinly and densely using clayey of particle size smaller than that of medium sand. It was assumed that the finishing was for repair after long time had passed since the mortar layer came off. Using lime made with oyster shells as mortar is unprecedented in ancient Korean mural tombs and its durability was very poor, suggesting that Gaya's mortar production technique was relatively behind compared to that of Koguryo's in the same era.

A Study of Weather Resistance on Dancheong Ground Treatment of Tranditional Wooden Building in Korea (한국 목조건축물 단청 바탕처리에 대한 내후성 연구)

  • Kim, Young Kyun;Han, Kyeong Soon
    • Journal of Conservation Science
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    • v.35 no.5
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    • pp.480-493
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    • 2019
  • In this study, the method for processing glue and glue-alum sizing from the dancheong ground treatment was evaluated with respect to weather resistance, and its effect on the conservation of dancheong was analyzed. Viscosity and pH of the glue and glue-alum specimen were measured and classified into three categories(none layer, glue layer, and glue-alum layer), which were further classified according to low concentration(four times for 2%) and high concentration(once for 10%). The base layer formation was subsequently classified into three categories based on pigment adoption, namely, Noerok(celadonite), Seokganju(terra rossa), and Jangdan(red lead). The completed specimen was subjected to a changing-environment experiment for evaluating weather resistance and observing the surface. Color variations were analyzed before and after the experiment. The results indicate that glue-alum sizing comprising 5% alum or 7% alum has strong acidity that can affect the life of dancheong, and the high level of 7% alum makes it difficult to create a solid coating layer. After ultraviolet irradiation, the specimen with 7% alum changes its color to yellow. Furthermore, after moisture absorption and drying, cracks can be observed on the entire specimen surface that corroborate the physical change. Additionally, gas-based corrosion causes marginal surface changes. Hence, the formation of a stable coating layer can be achieved by incorporating a low concentration glue solution that is almost neutral, and the application of glue-alum sizing having 2% concentration can aid in the conservation of dancheong.

Characteristics Evaluation of Hobun Pigments according to Shell Types and Calcination (패각의 종류 및 소성 여부에 따른 호분안료의 특성 평가)

  • Ju Hyun Park;Sun Myung Lee;Myoung Nam Kim;Jin Young Hong
    • Economic and Environmental Geology
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    • v.56 no.6
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    • pp.899-909
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    • 2023
  • In this study, the material scientific characteristics of Hobun pigments used as white inorganic pigment for traditional cultural heritage were identified according to the type of shell and calcination and evaluated the stability of the preservation environment. For the purpose of this, we collected 2 different types of Hobun pigments made by oyster and clam shell and its calcined products(at 1,150℃). Hobun pigments before calcined identified calcium carbonate such as calcite, aragonite but calcination derived changing main composition to portlandite and calcite. Results of FE-SEM showed characteristics microstructure for each shell but pigments after calcined observed porous structure. Porous granule highly caused oil adsorption according to increase specific surface area of pigments. In addition, the whiteness improved after calcined pigments compared to non-calcined pigments, and the color improvement rate of Hobun pigment (CS) which made of clam shell was higher. As a result of the accelerated weathering test, the Hobun pigment-colored specimen had a color difference value of less than 2 after the test, which was difficult to recognize with the naked eye. In particular, the color stability has improved as the color difference value of the Hobun pigment is smaller after calcined compared to before non-calcined pigment. However, it was confirmed that the stability of the painting layer was lower in the specimen after calcined pigment. For antifungal activity test, Aspergillus niger, Tyromyces palustris and Trametes versicolor were used as test fungi, and all pigments were found to have preventive and protective effects against fungi. Especially, the antifungal effect of the calcined pigment was excellent, which is due to the stronger basicity of the pigment.

Assessment of Durability of Stone Monument Using Specimens from Old Stone Quarry (고대 채석장 부지의 시료를 이용한 석조문화재 내구성 평가)

  • Park, Hyeong Dong;Shin, Gi Hye;Aboushook, M.
    • 한국문화재보존과학회:학술대회논문집
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    • 2001.11a
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    • pp.19-24
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    • 2001
  • This study mainly reports preliminary results from site investigation of the Great Pyramids and Sphinx in Egypt and sampling works where conducted in the same limestone beds in Mokattam quarry in Cairo. Analyses of composition of samples showed similar result to those of limestone in Giza and thus such samples can be easily used for further experimental work without disturbing real monuments. Future work will be concentrated on the change of engineering properties of samples before and after artificial weathering and the change of digital image acquired from the colored surface of monuments.

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Pigment Analysis for Wall Paintings According to Verification of Penetration Depth for X-ray: Ssanggyesa Daeungjeon (Main Hall of Ssanggyesa Temple) in Nonsan (X-선 투과깊이 검증에 따른 벽화 안료의 정밀분석: 논산 쌍계사 대웅전)

  • Chun, Yu-Gun;Lee, Chan-Hee
    • Journal of Conservation Science
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    • v.27 no.3
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    • pp.269-276
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    • 2011
  • We have suggested effective P-XRF analysis method for pigment painting layer by calculating penetration depth of X-ray. This experiment calculated that X-ray generated from P-XRF was possible penetration until 1.17mm deep in the pigment painting. Based on the experimental results, analysis for eight color pigments on wall paintings in Ssanggyesa Main Hall, most pigments were painted traditional pigments. However pigments on recently restorated wall painting were used synthetic modern pigments.

The Study on Removing Paraloid B-72 from Painting Layer on Mural of Mireukjeon Hall at Geunsansa Temple (금산사 미륵전 벽화 채색층의 Paraloid b-72 제거방법과 안정성에 관한 연구)

  • Jin, Byung-Hyuk;Cho, Jae-Yeon;Park, Jin-Yeon;Han, Sung-Hee;Kim, Yong-Sun
    • Korean Journal of Heritage: History & Science
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    • v.50 no.3
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    • pp.88-109
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    • 2017
  • As the technique to remove Paraloid B-72, which is known as an irreversible material, the method using organic solvent and heating, though the ways vary depending on the kind of material to be removed, has been usually used, but it has yet to apply to mud mural because of the technical limit in processing and the potential risk of damage and, moreover, the removal efficiency which also remains unproven. Thus, in a bid to seek the way to safely remove Paraloid B-72 contained in mural, the test was conducted in a way of applying a compress method, which is deemed most efficient. The solvents which are proven to be Paraloid B-72 were applied to the absorbents such as active carbon fiber and methyl cellulose and then were eluted to the surface of mud mural sample which was prepared in the same size and condition for a certain time before evaluating the stability and removal efficiency. Such test was intended to identify the applicability to the mural of Mireukjeon Hall at Geunsansa Temple, which had been treated with Paraloid B-72 for preservation in the past. As a result, the way of mixing the absorbent such as active carbon fiber and Xylene alone or with other quick vaporable solvents proved to be most efficient in removing Paraloid B-72 from mud mural and particularly Acetone:Xylene(1:1wt%) was found to be the most stable among others. Such a test outcome is expected to be a useful data for removing Paraloid B-72 from the mural of Mireukjeon Hall at Geunsansa Temple as well as for restoring other mural cultural assets in the coming days.

Study of Condition Analysis and Diagnosis on Oil Paintings with Terahertz Imaging (테라헤르츠 이미징기법을 이용한 유화의 상태분석 및 진단)

  • Baek, Na Yeon;Song, You Na;Kim, Moon Jeong;Chung, Yong Jae;Lee, Han Hyoung
    • Journal of Conservation Science
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    • v.35 no.3
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    • pp.237-244
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    • 2019
  • In this study, we applied terahertz imaging technology to three Korean modern oil paintings ('Boy,' 'Girl,' and 'Hyehwadong Landscape'); investigated the types of inner layer information in the pictures that can be extracted with terahertz imaging technology; and analyzed the conditions for extracting them. The biggest problem in the terahertz imaging analysis we encountered was the image distortion caused by the change of the distance between the target surface and the terahertz detector, depending on the surface curvature of the target paintings. We then developed a 'working distance maintaining device' to solve this problem. As a result, the terahertz imaging technique was used to identify the base material characteristics and any patterns of damage inside, and presented the optimal conditions for identifying each characteristic. In addition, it was useful to employ the terahertz frequency-division image to check the characteristics of the background materials. To confirm coloring techniques such as brush strokes, it is effective to compare the maximum reflection peak image with the cross-section image; and to detect damage information inside the paintings that cannot be observed on the surface, to compare the cross-section image with the frequency-division image. On the other hand, according to the terahertz imaging analysis of the oil paintings, the internal structural damage marks of 'Boy' and 'Girl' were confirmed, and the artist's painting style was confirmed in 'Hyehwadong Landscape.' The above results are expected to be useful for the analysis and diagnosis of Korean modern oil paintings for their preservation.

Occurrence and Forming Process of the Reddish Bed at Hwangto Cave, Ulleung Island, Korea (울릉도 황토굴 적색층의 산출특징과 형성기작)

  • Woo, Hyeon Dong;Jang, Yun Deuk
    • Journal of the Mineralogical Society of Korea
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    • v.29 no.4
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    • pp.239-254
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    • 2016
  • The Hwangto cave is a sea cave which is located near shore in the Taeha-ri, Ulleung Island, being composed of the reddish tuff wall rock, the topic of this study, and the trachyte ceiling rock. The chemical compositions of the red tuff layer are 49.81-63.63% of $SiO_2$, 13.05-24.91% of $Al_2O_3$, 2.67-5.82% of $Fe_2O_3$, 2.87-6.92% of $Na_2O$, 2.37-3.85% of $K_2O$, 0.55-0.81% of $TiO_2$, 0-0.53% of MnO, 0.39-1.75% of MgO, and 0.60-1.40% of CaO with a pH ranging from 4.5 to 8. The reddish tuff are composed of 23.7-39.4% of anorthoclase, 16.9-33.3% of sanidine, 15.8-26.1% of illite, 5.1-9.0% of hematite, 0-3.7% of goethite, 6.9-9.9% of titanium oxide, and 0.9-9.5% of halite in mineral composition. Although it only includes anorthoclase, sanidine, and illite as major minerals, there can be additional vitric minerals that could not detected by the XRD. The mineralogy and textures of the tuff layer indicate that it became reddish due to the formation of amorphous palagonite and the oxidation of the iron as a heat from the trachytic lava affects the underlying tuff to altered. This iron oxides are enriched in the palagonite, or form microcrystalline or amorphous minerals. We thus suggest that the red tuff layer was generated by the combination of the thermal oxidation involved in the trachytic lava flow on the tuff layer, the palagonitization of the matrix of the tuff, and the oxidation of iron-bearing minerals.