• Title/Summary/Keyword: 차이니즘

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High Temperature Combustion Behavior of Carbon/Carbon Composites Coated with SiC (탄화규소로 도포된 탄소/탄소 복합재의 고온 연소거동)

  • Choi, Don-Mook;Kim, Joung-Il
    • Journal of the Korean Society of Hazard Mitigation
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    • v.1 no.1 s.1
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    • pp.127-138
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    • 2001
  • Although Carbon/Carbon Composites(CFRCs) have excellent mechanical properties at high temperature, the disadvantage of combustion in air restricts their applications. Thus a lot of investments have been studied to improve the drawback of CFRCs. In this study, SiC used as a thermal protective coating material possesses almost the same expansion coefficient compared to that of carbon, so SiC was coated on 4D (directional) CFRCs by Pack-Cementation process. For the 4D CFRCs coated with SiC, optical microscopy observations were performed to estimate the coating mechanism involved and TGA tests were also performed to evaluate the improvement of combustion resistance. And their high temperature combustion properties were investigated by the arc torch plasma test. From the results, it is found that the mechanical properties and high temperature combustion properties of the 4D(directional) CFRCs coated with SiC were much better than bare 4D CFRCs.

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Redox Property of Transition Metal Oxides in Catalytic Oxidation (TPR/TPO 실험기법을 이용한 전이금속산화물의 산화-환원 특성 연구)

  • Kim, Young-Ho;Lee, Ho-In
    • Applied Chemistry for Engineering
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    • v.10 no.8
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    • pp.1161-1168
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    • 1999
  • The redox property of oxide materials of the 3rd period transition metals(Cr~Zn), V, Mo, and W was studied with temperature-programmed reduction/temperature-programmed oxidation(TPR/TPO) experiment. The peak temperatures of TPO spectra were equal to or lower than those of TPR spectra. And the peak shapes of TPO spectra were broader than those of TPR ones. The activation energies of TPR/TPO for the oxides of the 3rd period transition metals showed in the range of 33~149 kJ/mol, while for the oxides of V, Mo, and W, they showed relatively higher values. The change of activation energies of TPR/TPO with various metal oxides showed a similar trend to the change of their metal-oxygen bond strengths. The change of activation energies of o-xylene oxidation for various metal oxides was proportional to the difference (${\Delta}E_a$) between the activation energy of TPR and that of TPO. From these results, we concluded that the oxidation of o-xylene over various metal oxide catalysts follows the Mars-van Krevelen mechanism including the surface reduction-oxidation of the metal oxide itself.

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The Shear Resistance of Rc Deep Beam with Web Opening Repaired and Reinforced by Fiber Sheets After Shear Failure (깊이가 큰 철근콘크리트 유공보의 보수·보강 전후의 내력에 관한 연구)

  • Yang, Chang-Jin
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.8 no.3
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    • pp.149-158
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    • 2004
  • In this study, deep beam specimens are designed to have the effective shear span to depth ratio 1.0 and web opening within effective shear region. The purpose of this study is to investigate experimentally the shear strengthening effect between before failure and after failure upon using fiber sheets for RC deep beam with opening in web. The results can be summarized as follows; 1)When deep beams with web opening were failed in shear, their initial diagonal crack load and crack width were not influenced by their types of the arranged steel bars. 2)Deep beam with the horizontal reinforced bar was effective in the ultimate load of deep beam with web opening in shear failure 3)There were the approximate values between the experimental values and the analysis of finite element method. 4)The ultimate failure strengths of the repaired and strengthened specimens were increased about 34.4%~83.8% in comparison with specimens not to be strengthened.

Behavior Characteristics of Railway Roadbed Retained by Geosynthetic Reinforced Segmental Wall Under Train Load (열차 하중 작용 시 블록식 보강토 옹벽으로 지지된 철도 노반의 거동)

  • Lee, Seong Hyeok;Choi, Chan Yong;Lee, Jin Wook
    • Journal of the Korean Society for Railway
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    • v.15 no.5
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    • pp.467-475
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    • 2012
  • Static and dynamic train load tests were conducted to evaluate the train load transfer mechanism in the roadbed which was retained by two types (fully and partially) of segmental retaining walls reinforced by geogrid. The test roadbed was 2.6m high, 5m wide, and 6m long. A combination of earth pressure gages, displacement transducers, and strain gages were placed in specific locations to measure the responses. Test results showed that the wall displacement pattern as well as the earth pressure for the fully reinforced retaining wall was different from those for the partially reinforced retaining wall. In the dynamic train load test, the strain in the upper part of the wall tended to decrease, and both the residual deformation and the rate of the deformation were significantly lower than those in the current design standard.

Electrochemical Studies of Light Lantanide Complexes (Part 1) (가벼운 란탄족 원소 착물의 전기화학적 연구 (제 1 보))

  • Kang Sam-Woo;Park Chong-Min;Chang Choo-Hawn;Do Lee-Mi;Suh Moo-Yul
    • Journal of the Korean Chemical Society
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    • v.37 no.1
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    • pp.83-91
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    • 1993
  • The eletrochemical behavior of light lanthanide complexes has been investigated by several electrochemical techniques in alkaline solutions. The composition of the complexes was determined by spectrophotometric method to be 1 : 1 and reduction mechanism was two steps 1 electron transfer reaction. The half wave potential of first peak depended on pH and cathodic current showed remarkably adsorptive properties. The results of DC and CV investigation demonstrated the quise-reversible nature of the electron transfer. The anion radical formed after first one electron reduction process, dimerizes to form dimer. The apparent irreversible behavior of the second wave is a result of the existence of a fast protonation following the second electron transfer. An exhaustive electrolysis was carried out at controlled potential of -1.80 V, deep blue color of the solution became progressively weaker, and then the solution became colorless solution. The final product of an exhaustive electrolysis is electro-inactive. The appearance of four steps may be explained by the fact the reduction of Ln-OCP elucidated ECEC mechanism.

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Reversed Cyclic Latcral Load Test of A 2-Bay 2-Story Reinforced Concrete Frame With Seismic Detail (내진상세를 가진 2경간 2층 철근콘크리트 골조의 반복횡하중 실험)

  • Lee, Han-Seon;Woo, Sung-Woo
    • Magazine of the Korea Concrete Institute
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    • v.8 no.6
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    • pp.183-193
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    • 1996
  • The objective of this study is to investigate the characteristics of elastic and inelastic bekavior of ductile momenting-resisting reinforced concrete frame subjected to reversed lateral loading such as earthquake excitations. For this purpose, a 2-bay 2-story reinforced concrete plane frame with seismic detail was designed and one 1/2.5-scale subassemblage was manufactured according to the required similitude law. Then, the reversed load test under the displacement control was performed statically to this subassemblage. Finally, the results of this test were analysed regarding to (1) the design load vs actual strength, (2) degradation in stiffness and strength. (3) failure mode or energy dissipation. (4) local deformations.

Tectonic Movement in the Korean Peninsula (II): A Geomorphological Interpretation of the Spatial Distribution of Earthquakes (한반도의 지반운동 (II): 한반도 지진분포의 지형학적 해석)

  • Park, Soo-Jin
    • Journal of the Korean Geographical Society
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    • v.42 no.4
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    • pp.488-505
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    • 2007
  • The purposes of this research are twofold; 1) to verify spatial differences of tectonic movement using the spatial distribution of earthquakes, and 2) to infer mechanisms that generate spatial accumulation patterns of earthquakes in the Korean Peninsula. The first part of this sequential paper (Park, 2007) argues that the Korean Peninsula consists of four geostructural regions in which tectonic deformation and consequent geomorphological development patterns are different from each other Since this conclusion has been made by terrain analyses alone, it is necessary to verify this suggestion using other independent geophysical data. Because earthquakes are results of movement and deformation of land masses moving in different directions, the distribution of earthquake epicenters may be used to identify the direction and rates of land mass movement. This paper first analysed the spatial distribution of earthquakes using spatial statistics, and then results were compared with the spatial arrangement of geostructural regions. The spatial distribution of earthquakes in the Korean Peninsula can be summarized as the followings; firstly, the intensity of earthquakes shows only weak spatial dependency, and shows large difference even at adjacent regions. Secondly, the epicenter distribution has a clear spatial accumulation pattern, even though the intensity of earthquake shows a random pattern. Thirdly, the high density area of earthquakes shows a clear 'L' shape, passing through Pyeongannam-do, centered at Pyeongyang, and Hwanghae-do, Seosan and Pohang. The correlation coefficient between the density of earthquakes and distance from geostructral region boundaries is much higher than those between the density of fault lines and distance from tectonic division boundaries. Since fault lines and tectonic divisions in the Korean Peninsula are the results of long-term geological development, there is an apparent scale discrepancy to find significant correlations with earthquakes. This result verifies the research hypothesis that the Korean Peninsula is divided into four geostructral regions in which each has its own moving direction and spatial deformation characteristics. The existence of geostructural regions is also supported by the movement parrerns of land masses estimated from the GPS measurements. This conclusion is expected to provide a new perspective to understand the geomorphological developments and the earthquake occurrences in the Korean Peninsula.

Uplift Testing and Load-transfer Characteristics of Model Drilled Shafts in Compacted Weathered Granite Soils (화강풍화토 지반에 타설된 소형 현장 타설 말뚝의 인발시험 및 하중 전이 특성)

  • 임유진;서석현
    • Journal of the Korean Geotechnical Society
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    • v.18 no.4
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    • pp.105-117
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    • 2002
  • In the design of foundations for the super-structures such as transmission towers and oil-platforms, the foundations must be considered as a medium to resist cyclic tensile forces. In this study, the uplift capacity of the drilled shaft used as the medium resisting to this pattern of forces is investigated by performing cyclic uplift test of a small model-drilled shaft constructed in compacted granite soil in a steel chamber. In this test, the behavioral difference between a pile loaded on the top of the pile and a pile loaded at the bottom of the pile was investigated intensively. The load transfer curves obtained from the test were investigated by changing the confining pressure in the chamber. The load tests also included creep test and cyclic test. It is found from the tests that uplift capacity of the shaft loaded at the bottom is greater than that of the shaft loaded on the top of the pile. It is found also from the creep test that the pile loaded at the bottom was more stable than the shaft loaded on the top. If a pile loaded at the bottom is pre-tensioned, the pile will be most effective to the creep displacement. It is found also from the cyclic tests that apparent secant modulus obtained in a cycle of the load increases with the number of cycles.

Behavioral Analysis of Silt Protectors in Seawater Using the Mass-Spring Model (질량-스프링 모델을 이용한 해수 중 오탁방지막 거동해석)

  • Lee, Choon-Woo;Kim, Ok-Sam;Shin, Hyun-Chool;Hwang, Doo-Jin
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.23 no.2
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    • pp.194-199
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    • 2017
  • When sea tide and wave velocity change, the behavior of silt protectors underwater changes, and a hydraulic force exceeding the anchor wave force is applied. In this study, the movement mechanism of a silt protector has been analyzed using the mass-spring method. The initial position of the silt protector was in the Jindo area near Gwangpo Port (742-1, Gyupori, Chongdo-myeon, Jindo-gun, Jeonnam, Korea). The tension required to exceed the holding power of the anchor was 0.05 m/s at 318 sec., 0.15 m/s at 77 sec., 0.25 m/s at 43 sec., and 0.3 m/s at 37 sec.. As the anchor started to move from the sea floor and the tide speed increased to 0.01 m/s, anchor movement start time shortened by an average of 11.2 sec.. Compared with when tide was the only affecting factor, the silt protector and anchor were found to have moved 19.7 % at 0.1 m/s, 7.6 % at 0.15 m/s, 5.8 % at 0.2 m/s, 4.3 % at 0.25 m/s and 2.8 % at 0.3 m/s, showing an increase. When wave effect was added to the tide, anchor movement started when the flow rate was slow 7.6 % of the time. With a high flow velocity, anchor movement started without any significant difference less than 4.3 % of the time. When tide speed exceeded 0.13 m/s and the direction of the waves matched, the silt protector was not able to perform due to collisions with surrounding sea structures. When installing a silt protector, the fluid flow situation and the silt protector situation must be carefully analyzed using the mass-spring method to apply the result found in this study.

Effects of Probiotic Extracts of Kimchi on Immune Function in NC/Nga Mice (김치 추출 프로바이오틱스 섭취가 아토피 동물모델 NC/Nga mice에서 면역 지표에 미치는 영향)

  • Lee, In-Hoe;Lee, Sun-Hee;Lee, In-Seok;Park, Yoo-Kyoung;Chung, Dae-Kyun;Choue, Ryo-Won
    • Korean Journal of Food Science and Technology
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    • v.40 no.1
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    • pp.82-87
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    • 2008
  • Atopic dermatitis (AD) is characterized by chronic relapsing inflammation and is associated with hyper-production of immunoglobulin E (IgE). Recent studies have suggested that one of the treatments to alleviate symptoms of AD could be a supplementation of probiotics, Lactobacillus, Rhamnosus, Bifidus, etc. The purpose of this study was to evaluate the effects of probiotics on immune parameters in NC/Nga mice treated with 1-chloro-2,4-dinitro-benzene (DNCB). To induce atopic dermatitis, DNCB was treated to the back of mice for 2 weeks. Then, NC/Nga mice were divided into the four experimental groups randomly. Probiotics fragment, probiotics with other complex (Lactobacillus rhamnosus GG, Bifidobacterium lactis Bb-12LbL, L. plantarum K8, L. plantarum K8 fragment, ${\gamma}$-linolenic acid), antihistamine, and distilled water were administrated orally to the NC/Nga mouse for 4 weeks of experimental period. The groups were probiotics fragment group (DPF), probiotics with other complex group (DPOC), antihistamine group (DAH) and distilled water group (DDW) as a control group. The levels of serum IgE, interlukin-4 (IL-4), interlukin-5 (IL-5), interferon-gamma (IFN-${\gamma}$) and spleenocyte IgE were measured. The levels of serum IgE were significantly different among the four experimental groups. Before the treatment, there was no differences among the groups. However, from the first through the third week of the treatments, the levels of serum IgE in the probiotics (DPF, DPOC) and antihistamine (DAH) groups were lower than those of control group (p < 0.05). The levels of serum IL-4 of DPOC group was significantly lower than that of control group (p < 0.05) and serum IL-5 levels of DPF, DPOC, and DAH groups were significantly lower than that of control group. The levels of serum IFN-${\gamma}$ were not different among the four experimental groups. The levels of serum IgE in supernatant of spleen lymphocytes were not significantly different among the groups. These results suggest that probiotics supplementation showed partial effectiveness in the DNCB treated NC/Nga mice via modulation of IgE level and IL-4, IL-5 production. Based on these findings, probiotics exhibited the inhibitory effect via IL-4 production thereby inhibited the production of IgE in atopic animal model NC/Nga mice.