• Title/Summary/Keyword: 질소산화율

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Effect of Mn Oxides on the Magnetic properties of Mn-Zn Ferrite (가수가 다른 Mn 산화물이 Mn-Zn 페라이트의 자기특성에 미처는 영향)

  • 박천제;권오홍;배철수
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 1999.11a
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    • pp.516-519
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    • 1999
  • 스위칭 전원에 사용되는 Mn-Zn 페라이트에 대항하는 고성능화의 요구에 부응하기 위해 그 중요한 요인이 되는 기수가 다른 Mn 산화물에 착목하여 그것들을 이용 제작한 Mn-Zn 페라이트의 자기특성 및 결정구조를 정밀하게 조사함과 동시에 그것들의 상관성을 검토하였다. Mn-Zn 페라이트의 소성 분위기의 변경방식은 소성개시에서 종료시까지 질소 분위기, 냉각시부터 질소분위기로 변경, 소성 개시에서 종료시까지 대기중 소성 세가지를 실험하였고, 소성 온도는 115$0^{\circ}C$, 120$0^{\circ}C$, 125$0^{\circ}C$ 130$0^{\circ}C$ 135$0^{\circ}C$ 및 140$0^{\circ}C$의 6종류의 시료를 제작하였다. 이 결과는 Mn-Zn 페라이트의 소성 분위기 및 온도 최적화는 승온 및 온도 유지 단계에서는 대기중으로, 냉각단계에서는 질소가스 분위기로 치환한 것과 소성 온도는 120$0^{\circ}C$ 이다. 이 분위기에서 Mn-Zn 페라이트를 가수를 다르게 하여 시료의 투자율 및 주파수 특성, 코아로스 주파수 의존성, 코아로스 주파수로 나눈값의 주파수 의존성, 스피넬 구조(311)의 면에서의 회절픽, 자화의 온도 의존성을 분석하였다. 이 결과는 Mn$_3$O$_4$를 출발원료로 사용한 Mn-Zn 페라이트가 투자율 및 한계 주파수 모두 뛰어난 특성을 나타내었다.

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Properties of $SiO_2$Deposited by Remote Plasma Chemical Vapor Deposition(RPCVD) (원거리 플라즈마 화학증착법으로 증착된 이산화규소박막의 물성)

  • Park, Yeong Bae;Gang, Jin Gyu;Lee, Si U
    • Korean Journal of Materials Research
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    • v.5 no.6
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    • pp.709-709
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    • 1995
  • 원거리 플라즈마 화학증착법을 이용하여 저온에서 이산화규소박막을 제조하였다. 본 연구 에서는 공정변수인 기판의 온도, 반응기체의 조성 및 분압과 플라즈마 전력에 따른 산화막의 재료적인 물성을 평가하였다. XPS결과에서 산화막은 양론비(O/Si=2)보다 약간 적어 실리콘이 많이 함유된 막으로 나타났다. 이 경우 굴절율과 ESR분석에 의해 미결합된 실리콘의 양이 증가함을 알 수 있었다. SIMS분석에 의해 미량의 질소성분이 계면에 존재하는 것과 실리콘 미결함을 관찰하였다. FT-IR로부터 막내 수소량을 정량화하였으며 결합각 분포는 200℃이상에서 열산화막과 비슷한 값을 얻었다. 하지만 열산화막에 비해 높은 식각율을 보여 계면 스트레스에 의해 막내의 결합력이 약해진 것으로 생각된다.

Removal of Ammonia and Nitrite in Water by Bacillus sp. A8-8 (Bacillus sp. A8-8에 의한 수질 중의 암모니아 및 아질산성 질소 제거)

  • 이용석;유주순;정수열;최용락
    • Journal of Life Science
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    • v.13 no.1
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    • pp.47-53
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    • 2003
  • The purpose of this study is to improve the system for biological nitrogen oxidizing process in sewage and wastewater. A bacterium having high abilities to oxidize of nitrogen was one of the possessed on Lab. The strain was identified to Bacillus sp. A8-8, based on the physiological and biochemical properties. And the strain has ability degradation crude oil. In comparison with oxidizing rates with changing initial pH and temperature, the strain Bacillus sp. A8-8 was nitrogen oxidizing ability and growth rate on the various of pH, temperature. oxidizing rates of the strain in sewage and wastewater were about 48% and 62%, respectively. The nitrogen oxidizing rate was increased in proportion to the initial concentration of glucose. The microorganism, Bacillus sp. A8-8, immobilized in ceramic carrier were evaluated for the oxidation of ammonia in culture media.

A Study on the Effect of Chemical Pretreatment for Livestock Wastewater on the Linked Treatment of Sewage (축산폐수 처리 시 화학적 전처리가 연계처리에 미치는 영향 연구)

  • Han, Jun-Suk;Han, Gee-Bong
    • Journal of the Korea Organic Resources Recycling Association
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    • v.18 no.1
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    • pp.89-97
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    • 2010
  • In this study, to investigate the effect of chemical pretreatment for livestock wastewater, laboratory scale test for ozonation and linked treatment of sewage were conducted. and the results were obtained as follows. The ozonation of livestock wastewater showed the COD removal rate per hour to be 17%, 78% and 62% at each pH 4, 7 and 10, respectively. With transformation of NBDCOD to biodegradable BDCOD by ozonation, the ratio of SCODcr/TCODcr was increased from 26% to 38%. Accordingly, pretreatment of livestock wastewater affected to the biological post treatment process to elevate removal efficiency by transformation of nonbiodegradable mass to biodegradable mass. As the results of linked treatment of pre-ozonated livestock wastewater and sewage in the MLE process, the treatment efficiencies of TCODcr 93.8%, T-N 74.3%, T-P 89.7%, SS 97.5% were earned at 100% of internal recycle rate. When the internal recycle rate was increased to 150%, the treatment efficiencies of TCODcr 94.5%, T-N 54.5%, T-P 70.8%, SS 98.5% were earned. Also the removal efficiencies of TCODcr 92.6%, T-N 83.1%, T-P 81.9%, SS 98.5% were earned as the internal recycle rate was increased to 200%. Especially, nitrogen removal efficiency in the linked treatment showed 74.3%, 54.5%, 83.1% at 100%, 150% and 200% of internal recycle ratio, respectively, which revealed the tendency of higher removal efficiency than that of sewage treatment.

Biofilm airlift 반응기를 이용한 선택적 질산화의 연구

  • Yun, Ho-Jun;Jang, Jae-Seon;Kim, Dong-Jin
    • 한국생물공학회:학술대회논문집
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    • 2000.11a
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    • pp.457-460
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    • 2000
  • A biofilm airlift reactor filled with biomass-covered carriers (sand) were used to remove ammonium by selective nitrification (ammonium to nitrite). The effects of experimental conditions (ammonium load, pH, dissolved oxygen) on nitrification and nitrite accumulation were investigated. The reactor showed more than 90% nitrification efficiencies at 2.5 kg $NH_4\;^+-N/m^3/d$ and $NO_2\;^--N$ could be accumulated between 75% and 90% in the effluent. It is likely that nitratation (nitrite oxidizer) was inhibited by low dissolved oxygen concentration while nitritation (ammonium oxidizer) was kept stable.

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Oxidation Reaction of silicon Oxids fabricated by Rapid Thermal Process in $N_2$O ambient ($N_2$O 분위기에서 RTP로 제조한 실리콘 산화막의 산화 반응)

  • Park, Jin-Seong;Lee, U-Seong;Sim, Tae-Eon
    • Korean Journal of Materials Research
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    • v.3 no.1
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    • pp.7-11
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    • 1993
  • Abstract Oxidation kinetics of silicon oxide films formed by rapid thermal oxidizing Si substrate in $N_2$O ambient studied. The data on $N_2$0 oxidation shows that the interfacial nitrogen-rich layers results in oxide growth in the parabolic regime by impeding oxidant diffusion to the Si$O_2$-Si interface even for ultrathin oxides. The activation energy of parablic rate constant, B, is about 1.5 eV, and the energy increses with oxide thickness.

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Endogenous Nitric Oxide Strengthens Doxorubicin-induced Apoptosis in Human Colorectal Cell Lines (Doxorubicin에 의한 내인성 산화질소가 인간 대장암 세포주에서의 세포사멸에 미치는 효과)

  • Im, Soon Jae;Kim, Ji Hye;Kim, Min Young
    • Journal of Life Science
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    • v.24 no.10
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    • pp.1137-1143
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    • 2014
  • Doxorubicin is a general chemotherapy drug widely used for a number of cancers. However, the correlation between endogenous nitric oxide ($NO^{\bullet}$) levels and chemoresistance to doxorubicin remains unclear. In this study, we investigated the effect of endogenous $NO^{\bullet}$ on the anticancer activity of doxorubicin in human colon cancer cell lines HCT116 and HT29 with different p53 status. The cells were treated with either doxorubicin alone or in combination with the $NO^{\bullet}$ synthase (NOS) inhibitor $N^G$-monomethyl-L-arginine (NMA). Doxorubicin differentially inhibited the growth of both the HCT116 (p53-WT) and HT29 (p53-MUT) cells, which was mitigated by cotreatment with NMA. Further studies revealed that inhibition of endogenous $NO^{\bullet}$ mitigated doxorubicin-induced apoptosis in the HCT116 and HT29 cells, as evidenced by apoptotic DNA fragmentation and the sub-G1 peak of apoptotic markers. Apoptosis was delayed in the HT29 cells, and its magnitude was greatly reduced, underscoring the importance of the modulation of p53 in the response. RT-PCR analysis revealed that doxorubicin down-regulated levels of inhibitors of the apoptosis family (cellular IAP-1 and-2). Collectively, these data show that induction of apoptosis by doxorubicin in human colon cancer cells is possibly related to modulation of endogenous $NO^{\bullet}$, the expression of the IAP family of genes, and the status of p53. The underlying mechanisms may represent potential targets for adjuvant strategies to improve the efficacy of chemotherapy for colon cancer.

Optimization for Removal of Nitrogen Using Non-consumable Anode Electrodes (비소모성 Anode(산화전극)을 이용한 질소 제거 최적화)

  • Hyunsang, Kim;Younghee, Kim
    • Clean Technology
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    • v.28 no.4
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    • pp.309-315
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    • 2022
  • Research was conducted to derive the optimal operation conditions and the optimal cathode for using a DSA electrode as an anode to minimize electrode consumption during the removal of nitrogen from wastewater by the electro-chemical method. Of the various electrodes tested as cathodes, brass was determined to be the optimal electrode. It had the highest NO3-N removal rate and the lowest concentration of residual NH3-N, a by-product when Cl is present in the solution. Investigating the effect of current density found that when the initial concentration of NO3-N was 50 mg L-1, the optimal current density was 15 mA cm-2. In addition, current densities above 15 mA cm-2 did not significantly affect the NO3-N removal rate. The effect of electrolytes on removing NO3-N and minimizing NH3-N was investigated by using Na2SO4 and NaCl as electrolytes and varying the reaction times. When Na2SO4 and NaCl are mixed at a ratio of 1.0 g L-1 to 0.5 g L-1 and reacted for 90 min at a current density of 15 mA cm-2 and an initial NO3-N concentration of 50 mg L-1, the removal rate of NO3-N was about 48% and there was no residual NH3-N. On the other hand, when using only 1.5 g L-1 of NaCl as an electrolyte, the removal rate of NO3-N was the highest at about 55% and there was no residual NH3-N.

$HfO_2$ 박막과 Si 기판사이에 다양한 산화제로 증착한 $Al_{2}O_{3}$ 방지막을 사용한 경우에 대한 고찰

  • 조문주;박홍배;박재후;이석우;황철성;정재학
    • Proceedings of the Korean Society Of Semiconductor Equipment Technology
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    • 2003.12a
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    • pp.42-44
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    • 2003
  • 최근 logic 소자의 gate oxide로 기존의 $SiO_2$, SiON보다 고유전, 작은 누설전류를 가지는 물질의 개발이 중요한 이슈가 되고 있다. 본 실험실에서는 Si 기판위에 $HfO_2$ 를 바로 증착하는 경우, 기판의 Si 이박막내로 확산하여 유전율이 저하되는 문제점을 인식하고, 기판과 $HfO_2$ 사이에 $AlO_x$를 방지막으로 사용하였다. 이 때, $AlO_x$의 Al precursor 는 TMA 로 고정하고, 산화제로는 $H_2O, O_2$-plasma, O_3$ 를 각각 사용하였다. 모든 $AlO_x/HfO_y$ 박막에서 매우 우수한 누설전류특성을 얻을 수 있었는데, 특히 $O_3$ 를 산화제로 사용한 $AlO_x$ 방지막의 경우 가장 우수한 특성을 보였다. 또한 질소 분위기에서 $800^{\circ}C$ 10 분간 열처리한 후, 방지막을 사용한 모든 경우에서 보다 향상된 열적 안정성을 관찰할 수 있었다.

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Reduction of the Nitrogen in the Secondary Effluent by the Hybrid Sequential Aerobic-Anoxic Natural System (자연현상을 이용한 질산화-탈질공정에 의한 하수처리장 유출수의 질소제거)

  • Kim, Young-Chul;Chung, Paul-Gene;An, Ik-Sung
    • Journal of Korean Society of Environmental Engineers
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    • v.27 no.3
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    • pp.323-329
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    • 2005
  • In this paper, performance of a hybrid sequential aerobic-anaerobic natural system was investigated. Continuous aerobic and anoxic conditions were created by alternatively placing waste stabilization pond (WSP) and wale. hyacinth pond (WHP). Two pilot-scale treatment lines were built and operated; The first consists of WSP integrated with WHP and the second of WSP connected with Dark Pond(DP), namely control system ponds which were used to examine the effects of water hyacinth on nitrification and de-nitrification. The overall performance in nitrogen was 86% reduction in WSP-WHP and 36% in WSP-control pond system. Nitrogen was mostly removed by nitrification and de-nitrification which simultaneously occurred in the same water hyacinth ponds. For the de-nitrification, benthic layer was found out to be adequate support as a carbon source. In addition, WSP-WHP system was very effective in reducing phosphorus. Overall P removal efficiency in WSP-WHP is 81%, while it is only 16% in WSP-control. difference in phosphorus reduction between those two systems is thought to be caused by the plants and probably their roots producing extra-cellular materials, but these aspects need to be further studied.