• Proceedings of the Korea Water Resources Association Conference
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• 한국수자원학회 2018년도 학술발표회
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• pp.288-288
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• 2018

점착성 유사는 응집 현상을 겪는 유사로, 응집 현상(Flocculation Process)는 응집 과정(Aggregation Process)와 파괴 과정(Breakup Process)의 경쟁으로 이루어진다고 여겨진다. 응집 현상을 통해 점착성 유사는 물과 점착성을 띠는 작은 입자들의 덩어리인 플럭(Floc)을 형성하여 흐름 내에서는 대부분이 플럭의 형태로 이동한다. 점착성 유사의 응집 모형 중 하나인 플럭 성장모형(Floc Growth Model, FGM)은 상미분 방정식으로 시간에 따른 플럭의 크기를 계산하는 모형이다. 응집과 파괴의 평형 상태에서 평균 입경을 얻는다. 이러한 FGM은 낮은 수치 계산 비용으로 합리적인 계산 결과를 얻을 수 있으며, 유사 이동 모형 혹은 흐름 모형과의 결합이 수월한 장점을 가진다. 또한, 닫힌 계(Closed System)에서 질량이 보존되는 특징이 있다. 반면, 결정론적인 특성을 띠면서 특정 플럭 크기만을 계산하기 때문에 점착성 유사의 입도 분포에 대한 정보를 얻을 수 없다. 결정론적 특성을 띠는 FGM에 추계학적 방법을 적용함으로써 특정 확률 분포형을 가지는 플럭의 입도 분포를 얻을 수 있다. 본 연구에서는 기 개발된 추계학적 FGM과 유사 이동 모형의 결합을 통해 변화하는 유수동역학적 조건에서 플럭의 입도 분포를 산정하고자 한다. 이전의 많은 실험실 실험 결과들은 부유가 발생한 상태를 유지하면서 수행되는 것으로, 특정 난류 특성(난류 소산 매개변수)와 특정 유사 농도 조건에서의 입도 분포를 얻는다. 그러나 하구부 및 하천의 하류는 조류의 영향을 받는 구간으로, 점착성 유사의 특성을 분석하기 위해서는 변화하는 유수동역학적 특성에 관한 고려가 필수적이라 할 수 있다. 결합된 점착성 유사 입도 분포 모형은 플럭의 침강과 재부유를 고려할 수 있는 특징을 가지며, 실측자료와의 비교를 통해 입도 분포를 합리적으로 모의하는 것으로 나타난다. 본 연구에서 개발된 점착성 유사 입도 분포 모형은 나아가 비점착성 유사의 입도 분포 모형과의 결합을 통해 두 종류의 유사가 혼재하는 구간에서도 합리적인 입도분포와 유사의 이동을 모의할 수 있을 것으로 예측된다.

• Journal of the Korean Society of Propulsion Engineers
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• 제19권3호
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• pp.47-53
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• 2015

Design parameters required for Methane/oxygen bipropellant small-rocket-engine were derived through a theoretical performance analysis. The theoretical performance of the rocket engine was analyzed by using CEA and optimal propellant mixture ratio, characteristic length, and optimal expansion ratio were calculated by assuming chemical equilibrium. A coaxial-type swirl injector was chosen because of its outstanding atomization performance and high combustion efficiency compared to other types of injector and also a bell nozzle with 80% of its full length was designed. The rocket engine configuration with 1.72 MPa of chamber pressure, 0.18 kg/s in total propellant mass flow, and O/F ratio of 2.7 was proposed as a ground-firing test model.

• Plant Journal
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• 제13권4호
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• pp.48-50
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• 2017

A program for analyzing the transient behaviors of industrial gas turbines was developed. Each component (compressor, combustor, turbine and ducts)of gas turbine is modeled as a fully module to enhance the expandability of the program. We used object-oriented programing for this purpose. The mass and energy balance equations are solved numerically by Multivariable Newton Raphson method. The characteristic maps for the compressor and turbine were used for predicting the performance of a gas turbine engine. Combustion in the combustor is assumed to be complete combustion. PID control is used to maintain constant rotational speed and turbine exhaust temperature by the control of the fuel flow rate and the changing of the compressor inlet guide vane angle at the same time. It was confirmed that stable control of the gas turbine was possible, even for a rapid load change.

• Journal of the Korean Society of Groundwater Environment
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• 제7권3호
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• pp.103-115
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• 2000

The formation of brown-colored precipitates is one of the serious problems frequently encountered in the development and supply of groundwater in Korea, because by it the water exceeds the drinking water standard in terms of color. taste. turbidity and dissolved iron concentration and of often results in scaling problem within the water supplying system. In groundwaters from the Pajoo area, brown precipitates are typically formed in a few hours after pumping-out. In this paper we examine the process of the brown precipitates' formation using the equilibrium thermodynamic and kinetic approaches, in order to understand the origin and geochemical pathway of the generation of turbidity in groundwater. The results of this study are used to suggest not only the proper pumping technique to minimize the formation of precipitates but also the optimal design of water treatment methods to improve the water quality. The bed-rock groundwater in the Pajoo area belongs to the Ca-$HCO_3$type that was evolved through water/rock (gneiss) interaction. Based on SEM-EDS and XRD analyses, the precipitates are identified as an amorphous, Fe-bearing oxides or hydroxides. By the use of multi-step filtration with pore sizes of 6, 4, 1, 0.45 and 0.2 $\mu\textrm{m}$, the precipitates mostly fall in the colloidal size (1 to 0.45 $\mu\textrm{m}$) but are concentrated (about 81%) in the range of 1 to 6 $\mu\textrm{m}$in teams of mass (weight) distribution. Large amounts of dissolved iron were possibly originated from dissolution of clinochlore in cataclasite which contains high amounts of Fe (up to 3 wt.%). The calculation of saturation index (using a computer code PHREEQC), as well as the examination of pH-Eh stability relations, also indicate that the final precipitates are Fe-oxy-hydroxide that is formed by the change of water chemistry (mainly, oxidation) due to the exposure to oxygen during the pumping-out of Fe(II)-bearing, reduced groundwater. After pumping-out, the groundwater shows the progressive decreases of pH, DO and alkalinity with elapsed time. However, turbidity increases and then decreases with time. The decrease of dissolved Fe concentration as a function of elapsed time after pumping-out is expressed as a regression equation Fe(II)=10.l exp(-0.0009t). The oxidation reaction due to the influx of free oxygen during the pumping and storage of groundwater results in the formation of brown precipitates, which is dependent on time, $Po_2$and pH. In order to obtain drinkable water quality, therefore, the precipitates should be removed by filtering after the stepwise storage and aeration in tanks with sufficient volume for sufficient time. Particle size distribution data also suggest that step-wise filtration would be cost-effective. To minimize the scaling within wells, the continued (if possible) pumping within the optimum pumping rate is recommended because this technique will be most effective for minimizing the mixing between deep Fe(II)-rich water and shallow $O_2$-rich water. The simultaneous pumping of shallow $O_2$-rich water in different wells is also recommended.

• Journal of Korean Society of Environmental Engineers
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• 제34권8호
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• pp.566-573
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• 2012

This study examined the removal rate of heavy metals from synthetic control water using red mud and lime stone. Overall, the percent of absorption obtained in this study for the red mud treatment was 94.0% ($Pb^{2+}$), 67.1% ($As^{3+}$), 37.5% ($Cu^{2+}$), and 36.6% ($Cr^{6+}$), while that of lime stone was $Pb^{2+}$ (30.8%), $Cu^{2+}$ (16.5%), $Cr^{6+}$ (11.5%), and $As^{3+}$ (8.9%). The kinetic data presented that the slow course of adsorption follows the Pseudo first and second order models, the equilibriuim adsorption of $Cr^{6+}$ and $Pb^{2+}$ obeys Freundlich isotherm model, while the adsorption of $Cu^{2+}$ obeys only Langmuir model. The results also showed that adsorption rate slightly increased with increasing pH from 5 to 9. Interestingly, this trend is similar to results obtained as function of loading amount of red mud. Meanwhile, an unit adsorption rate was slightly decreased. For lime stone, it did not much change in adsorption as function of treatment amount. Consequently, it was concluded that the absorbents can be successfully used the removal of the heavy metals from the aqueous solutions.

• Journal of Korean Society of Environmental Engineers
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• 제30권11호
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• pp.1146-1153
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• 2008

Numerical simulation was carried out to study the trichloroethylene (TCE) degradation by permeable reactive barrier (PRB), and revealed the effect of concentration of TCE, iron medium mass, and concentration of iron-reducing bacteria (IRB). Newly developed model was based on axial dispersion reactor model with chemical and biological reaction terms and was implemented using MATLAB ver R2006A for the numerical solutions of dispersion, convection, and reactions over column length and elapsed time. The reaction terms include reactions of TCE degradation by zero-valent iron (ZVI, Fe$^0$) and ferrous iron (Fe$^{2+}$). TCE concentration in the column inlet was maintained as 10 mg/L. Equation for Fe$^0$ degradation includes only TCE reaction term, while one for Fe$^{2+}$ has chemical and biological reaction terms with TCE and IRB, respectively. Two coupled equations eventually modeled the change of TCE concentration in a column. At Fe$^0$ column, TCE degradation rate was found to be more than 99% from 60 hours to 235 hours, and declined to less than 1% in 1,365 hours. At the Fe$^{2+}$ and IRB mixed column, TCE degradation rate was equilibrated at 85.3% after 210 hours and kept it constant. These results imply that the ferrous iron produced by IRB has lowered the TCE degradation efficiency than ZVI but it can have higher longevity.http://kci.go.kr/kciportal/ci/contents/ciConnReprerSearchPopup.kci#

• Journal of the Korean Society of Groundwater Environment
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• 제4권4호
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• pp.199-211
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• 1997

As a part of study on geological disposal of radioactive waste, hydrogeochemical characteristics of deep granitic groundwater in Korea were investigated through the construction of a large geochemical dataset of natural water, the examination on the behaviour of dissolved constituents, and the consideration of phase stability based on thermodynamic approach. In granitic region, the contents of total dissolved solids increase progressively from surface waters to deep groundwaters, which indicates the presence of more concentrated waters at depth due to water-rock interaction. The chemical composition of groundwater evolves from initial $Ca^{2＋}$－(C $l^{－}$＋S $O_4$$^{2-}$) or $Ca^{2＋}$-HC $O_3$$^{－}$ type to final N $a^{＋}$-HC $O_3$$^{－}$ or N $a^{＋}$－(C $l^{－}$＋S $O_4$$^{2-}$) type, via $Ca^{2＋}$-HC $O_3$$^{－}$ type. Three main mechanisms seem to control the chemical composition of groundwater in the granitic region; 1) congruent dissolution of calcite at shallower depth, 2) calcite precipitation and incongruent dissolution of plagioclase at deeper depth, and 3) kaolinite-smectite or/and kaolinite-illite reaction at equilibrium at deeper depth. The behaviour of dissolved major cations (C $a^{2＋}$, $K^{＋}$, $Mg^{2＋}$, M $a^{＋}$) and silica is likely to be controlled by these reactions.

• Korean Chemical Engineering Research
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• 제47권4호
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• pp.453-458
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• 2009

Recently, new methods to synthesize and process polymers without toxic organic solvents are needed in order to solve environmental problems. The use of supercritical carbon dioxide as a solvent for the polymer synthesis is attractive since it is non-toxic, non-flammable, naturally abundant, and the product may be easily separated from the solvent. In this study, we developed the method using super critical $CO_2$ to prepare P(MAA-co-EGMA) hydrogel nanoparticles as an intelligent drug delivery carrier. The effects of concentrations of PtBuMA-PEO as a dispersion stabilizer and AIBN as an initiator on the particle synthesis were investigated. When PtBuMA-PEO concentration increased, the particle size decreased. However, there was no significant difference in the particle size according to the AIBN concentration. There was a drastic change of the equilibrium weight swelling ratio of P(MAA-co-EGMA) hydrogel nanoparticles at a pH of around 5, which is the $pK_a$ of PMAA. At a pH below 5, the hydrogels were in a relatively collapsed state but at a pH higher than 5, the hydrogels swelled to a high degree. In release experiments using Rh-B as a model solute, the P(MAA-co-EGMA) hydrogel nanoparticles showed a pH-sensitive release behavior. At low pH(pH 4.0) a small amount of Rh-B was released while at high pH(pH 6.0) a relatively large amount of Rh-B was released from the hydrogels.

• Journal of the Korean Chemical Society
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• 제56권5호
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• pp.583-590
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• 2012

The HF (Hollow fiber) extraction method was optimized to analysis seven species of pesticides in aqueous sample and analyzing samples by GC/MS. Hollow fiber extraction showed good efficiency when it was conducted under these conditions: organic solvent was toluene and agitation speed was 1200 rpm. The 15% concentration of NaCl was optimized when it was experimented between 5% and 25%. The equilibrium time was determined at 15 minutes. The pH 5 showed the best effect on the extraction efficiency. The linearities of calibration curves of seven species were good with correlation of regression ($r^2$) over 0.995 when they were experimented over a concentration range of $5{\mu}g/L$ to $50{\mu}g/L$. The analytical data exhibited the detection of limits (LODs) range of $0.37{\mu}g/L$ to $1.23{\mu}g/L$ and the limit of quantification (LOQs) range of $1.19{\mu}g/L$ to $3.91{\mu}g/L$. The optimized HF-LPME extraction method provides a simple and effective preparation and requires small amount of organic solvents and samples compared to conventional pre-treatment methods.

• Journal of Korea Soil Environment Society
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• 제1권1호
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• pp.89-102
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• 1996

An integrated model is presented to describe underground flow and mass transport, using a multicomponent multiphase approach. The comprehensive governing equation is derived considering mass and force balances of chemical species over four phases(water, oil, air, and soil) in a schematic elementary volume. Compact and systemati notations of relevant variables and equations are introduced to facilitate the inclusion of complex migration and transformation processes, and variable spatial dimensions. The resulting nonlinear system is solved by a multidimensional finite element code. The developed code with dynamic array allocation, is sufficiently flexible to work across a wide spectrum of computers, including an IBM ES 9000/900 vector facility, SP2 cluster machine, Unix workstations and PCs, for one-, two and three-dimensional problems. To reduce the computation time and storage requirements, the system equations are decoupled and solved using a banded global matrix solver, with the vector and parallel processing on the IBM 9000. To avoide the numerical oscillations of the nonlinear problems in the case of convective dominant transport, the techniques of upstream weighting, mass lumping, and elementary-wise parameter evaluation are applied. The instability and convergence criteria of the nonlinear problems are studied for the one-dimensional analogue of FEM and FDM. Modeling capacity is presented in the simulation of three dimensional composite multiphase TCE migration. Comprehesive simulation feature of the code is presented in a companion paper of this issue for the specific groundwater or flow and contamination problems.