• Title/Summary/Keyword: 진동 패턴

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Equilibrium Fractionation of Clumped Isotopes in H2O Molecule: Insights from Quantum Chemical Calculations (양자화학 계산을 이용한 H2O 분자의 Clumped 동위원소 분배특성 분석)

  • Sehyeong Roh;Sung Keun Lee
    • Korean Journal of Mineralogy and Petrology
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    • v.36 no.4
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    • pp.355-363
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    • 2023
  • In this study, we explore the nature of clumped isotopes of H2O molecule using quantum chemical calculations. Particularly, we estimated the relative clumping strength between diverse isotopologues, consisting of oxygen (16O, 17O, and 18O) and hydrogen (hydrogen, deuterium, and tritium) isotopes and quantify the effect of temperature on the extent of isotope clumping. The optimized equilibrium bond lengths and the bond angles of the molecules are 0.9631-0.9633 Å and 104.59-104.62°, respectively, and show a negligible variation among the isotopologues. The calculated frequencies of the modes of H2O molecules decrease as isotope mass number increases, and show a more prominent change with varying hydrogen isotopes over those with oxygen isotopes. The equilibrium constants of isotope substitution reactions involving these isotopologues reveal a greater effect of hydrogen mass number than oxygen mass number. The calculated equilibrium constants of clumping reaction for four heavy isotopologues showed a strong correlation; particularly, the relative clumping strength of three isotopologues was 1.86 times (HT18O), 1.16 times (HT17O), and 0.703 times (HD17O) relative to HD18O, respectively. The relative clumping strength decreases with increasing temperature, and therefore, has potential for a novel paleo-temperature proxy. The current calculation results highlight the first theoretical study to establish the nature of clumped isotope fractions in H2O including 17O and tritium. The current results help to account for diverse geochemical processes in earth's surface environments. Future efforts include the calculations of isotope fractionations among various phases of H2O isotopologues with a full consideration of the effect of anharmonicity in molecular vibration.

A Study on the Women's Bodysuit Sleeve Block Construction Using Stretch fabrics (Stretch 소재를 사용한 여성용 Bodysuit Sleeve 원형 설계에 관한 연구)

  • Park Gin-Ah
    • Journal of the Korean Society of Clothing and Textiles
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    • v.29 no.12 s.148
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    • pp.1535-1545
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    • 2005
  • The study aimed firstly, to develop the women's bodysuit sleeve block construction method adopting the appropriate pattern reduction rates according to the fabric stretch property. Secondly, the details applied to the bodysuit sleeve block drafting (Dr the educational and industrial usage were proposed. For these, several distinguishing bodysuit sleeve pattern making methods(i.e. Joseph-Armstrong: T1, Shoben & Ward: T2, Esmod: T3 and Mixed Joseph-Armstrong: T4) were analyzed and divided into two categories that adopt 1) the equally (i.e., T1) and 2) the differently(i.e., T2, T3 & T4) distributed front and back armhole length measurements. Women's sleeve samples were made for the research using the same stretch fabric($50\%\;and\; 70\%$ in wale and course each) to the previous research. A group comprising 5 relevant experts evaluated the fit and comfort features of the samples. Experiments analyzed the appearance of sleeve samples focused on total 13 evaluation parts(including the front/side/back fit tolerance, sleeve centre line, sleeve length, appropriateness of the sleeve appearance balanced with the bodysuit and etc.): and performed the comfort test evaluating three kinds(vertical-front/vertical-side/ horizontal) of arm movements. The most appropriate bodysuit sleeve to fulfil the original aims of the study was suggested. The findings and suggestions throughout the study were: 1) the measurements and required reduction rates for the bodysuit sleeve block developed: outer sleeve length (with 1.0 RR), crown height(with 0.7 RR), front and back armhole lengths measured on the bodysuit blocks ($0\%$ ease amount), elbow width(0.9/0.95 RR), wrist girth measurements(from $12\%\;to\;18\%$ tolerances can be given to): and 2) the differently distributed front and back armhole length measurements resulted in the better fit and comfort through the research.

A Study on the Characteristics of Tropical Cyclone Passage Frequency over the Western North Pacific using Empirical Orthogonal Function (경험적 직교함수를 이용한 북서태평양 열대저기압의 이동빈도 특성에 관한 연구)

  • Choi, Ki-Seon;Kang, Ki-Ryong;Kim, Do-Woo;Hwang, Ho-Seong;Lee, Sang-Ryong
    • Journal of the Korean earth science society
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    • v.30 no.6
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    • pp.721-733
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    • 2009
  • A pattern of tropical cyclone (TC) movement in the western North Pacific area was studied using the empirical orthogonal function (EOF) and the best track data from 1951 to 2007. The independent variable used in this study was defined as the frequency of tropical cyclone passage in 5 by 5 degree grid. The $1^{st}$, $2^{nd}$ and $3^{rd}$ modes were the east-west, north-south and diagonal variation patterns. Based on the time series of each component, the signs of first and second mode changed in 1997 and 1991, respectively, which seems to be related to the fact that the passage frequency was higher in the South China Sea for 20 years before 1990s, and recent 20 years in the East Asian area. When the eigen vectors were negative values in the first and second modes and TC moves into the western North Pacific, TC was formed mainly at the east side relatively compared to the case of the positive eigen vectors. The first mode seems to relate to the pressure pattern at the south of Lake Baikal, the second mode the variation pattern around $30^{\circ}N$, and the third mode the pressure pattern around Japan. The first mode was also closely related to the ENSO and negatively related to the $Ni\tilde{n}o$-3.4 index in the correlation analysis with SST anomalies.

A Study on Depth Data Extraction for Object Based on Camera Calibration of Known Patterns (기지 패턴의 카메라 Calibration에 기반한 물체의 깊이 데이터 추출에 관한 연구)

  • 조현우;서경호;김태효
    • Proceedings of the Korea Institute of Convergence Signal Processing
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    • 2001.06a
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    • pp.173-176
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    • 2001
  • In this thesis, a new measurement system is implemented for depth data extraction based on the camera calibration of the known pattern. The relation between 3D world coordinate and 2D image coordinate is analyzed. A new camera calibration algorithm is established from the analysis and then, the internal variables and external variables of the CCD camera are obtained. Suppose that the measurement plane is horizontal plane, from the 2D plane equation and coordinate transformation equation the approximation values corresponding minimum values using Newton-Rabbson method is obtained and they are stored into the look-up table for real time processing . A slit laser light is projected onto the object, and a 2D image obtained on the x-z plane in the measurement system. A 3D shape image can be obtained as the 2D (x-z)images are continuously acquired, during the object is moving to the y direction. The 3D shape images are displayed on computer monitor by use of OpenGL software. In a measuremental result, we found that the resolution of pixels have $\pm$ 1% of error in depth data. It seems that the error components are due to the vibration of mechanic and optical system. We expect that the measurement system need some of mechanic stability and precision optical system in order to improve the system.

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Identification of Dynamic Characteristics Using Vibration Measurement Data of Saemangeum Mangyeong Offshore Observation Tower and Numerical Model Updating by Pattern Search Method (새만금 만경해상관측타워의 진동계측자료를 이용한 동특성 분석과 패턴서치 방법에 의한 수치해석모델 개선)

  • Park, Sangmin;Yi, Jin-Hak;Cho, Cheol-Ho;Park, Jin-Soon
    • Journal of Korean Society of Coastal and Ocean Engineers
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    • v.32 no.5
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    • pp.285-295
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    • 2020
  • In the case of small observation towers located at sea, it is necessary to confirm the change in dynamic characteristics due to the influence of environmental loads. In this study, the dynamic characteristics were analyzed and the numerical analysis model was designed through field dynamic response measurement on the Mangyeong Offshore Observation Tower (Mangyeong Tower) located near the Saemangeum Embankment. As a result of the measurement, the natural frequency was found to increase slowly as the tide level is lowered. In addition, it was confirmed that the same mode has two frequencies, which was judged to be a phenomenon in which the natural frequency was partially increased when the pile and the ground contacted by scouring. For numerical analysis, the upper mass, artificial fixity point, scour depth and fluid influences are reflected in the structural characteristics of the Mangyeong Tower. In addition, the model updating from the estimated natural frequency and pattern search algorithm was performed. From the model updating, it is expected that it can be applied to future studies on stability of Mangyeong Tower.

Baseline Model Updating and Damage Estimation Techniques for Tripod Substructure (트라이포드 하부구조물의 기저모델개선 및 결함추정 기법)

  • Lee, Jong-Won
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.21 no.6
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    • pp.218-226
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    • 2020
  • An experimental study was conducted on baseline model updating and damage estimation techniques for the health monitoring of offshore wind turbine tripod substructures. First, a procedure for substructure health monitoring was proposed. An initial baseline model for a scaled model of a tripod substructure was established. A baseline model was updated based on the natural frequencies and the mode shapes measured in the healthy state. A training pattern was then generated using the updated baseline model, and the damage was estimated by inputting the modal parameters measured in the damaged state into the trained neural network. The baseline model could be updated reasonably using the effective fixity model. The damage tests were performed, and the damage locations could be estimated reasonably. In addition, the estimated damage severity also increased as the actual damage severity increased. On the other hand, when the damage severity was relatively small, the corresponding damage location was detected, but it was more difficult to identify than the other cases. Further studies on small damage estimation and stiffness reduction quantification will be needed before the presented method can be used effectively for the health monitoring of tripod substructures.

Current and Future Changes in the Type of Wintertime Precipitation in South Korea (현재와 미래 우리나라 겨울철 강수형태 변화)

  • Choi, Gwang-Yong;Kwon, Won-Tae
    • Journal of the Korean Geographical Society
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    • v.43 no.1
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    • pp.1-19
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    • 2008
  • This study intends to clarify the characteristics and causes of current changes in wintertime precipitation in Korea and to predict the future directions based on surface observational $(1973/04\sim2006/07)$ and modeled (GFDL 2.1) climate data. Analyses of surface observation data demonstrate that without changes in the total amount of precipitation, snowfall in winter (November-April) has reduced by 4.3cm/decade over the $1973\sim2007$ period. Moreover, the frequency and intensity of snowfall have decreased; the duration of snow season has shortened; and the snow-to-rain day ratio (STDR) has decreased. These patterns indicate that the type of wintertime precipitation has changed from snow to rain in recent decades. The snow-to-rain change in winter is associated with the increases of air temperature (AT) over South Korea. Analyses of synoptic charts reveal that the warming pattern is associated with the formation of a positive pressure anomaly core over northeast Asia by a hemispheric positive winter Arctic Oscillation (AO) mode. Moreover, the differentiated warming of AT versus sea surface temperature (SST) under the high pressure anomaly core reduces the air-sea temperature gradient, and subsequently it increases the atmospheric stability above oceans, which is associated with less formation of snow cloud. Comparisons of modeled data between torrent $(1981\sim2000)$ and future $(2081\sim2100)$ periods suggest that the intensified warming with larger anthropogenic greenhouse gas emission in the $21^{st}$ century will amplify the magnitude of these changes. More reduction of snow impossible days as well as more abbreviation of snow seasons is predicted in the $21^{st}$ century.

Utilization of Pigments and Tunic Components of Ascidian as an Improved Feed Aids for Aquaculture 2. Chemical Properties of Sulfated Polysaccharides in Ascidian (Halocynthia roretzi) Tunic (우렁쉥이 껍질성분 및 색소를 이용한 양식소재 개발 2. 우렁쉥이 껍질 중 부분정제한 황산다당의 화학적 특성)

  • HONG Byeong-Il;JUNG Byung-Chun;JUNG Woo-Jin;RUCK Ji-Hee;CHOI Byeong-Dae;LEE Kang-Ho
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.34 no.6
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    • pp.632-637
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    • 2001
  • Components of polysaccharides isolated from ascidian tunic were measuerd by gel filtration, electrophoresis and chemical analyses. The sulfated polysaccharides consisted in sulfate, protein, uronic acid and amino sugars. Hexosamines were composed of arabinose, xylose, glucose, galactose, glucuronic acid, N-acetylgalactosamine and N-acetylglucosamine by gas chromatography analysis. The galactose was predominant hexose after autoclave and nutrase digestion followed by DEAE-cellulose ion exchange chromatography and gel-permeation chromatography on Sephadex G-100 and G-25. FT-IR spectra of isolated polysaccharides from ascidian tunic and standard chondroitin sulfates have similar functional groups of the type of vibration and frequency. Molecular weight of isolated polysaccharides by autoclave represented more than 40 kDa by polyacrylamide gel electrophoresis. But the neutrase treatment group divided into three band. The highest molecular band group was shown more than 100 kDa, and the two low molecular band group were shown about 22 kDa and 5 kDa, respectively, compare to standard materials.

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Development of High Precision Fastening torque performance Nut-runner System (고정밀 체결토크 성능 너트런너 시스템 개발)

  • Kim, Youn-Hyun;Kim, Sol
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.20 no.4
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    • pp.35-42
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    • 2019
  • Nut fasteners that require ultra-precise control are required in the overall manufacturing industry including electronic products that are currently developing with the automobile industry. Important performance factors when tightening nuts include loosening due to insufficient fastening force, breakage due to excessive fastening, Tightening torque and angle are required to maintain and improve the assembling quality and ensure the life of the product. Nut fasteners, which are now marketed under the name Nut Runner, require high torque and precision torque control, precision angle control, and high speed operation for increased production, and are required for sophisticated torque control dedicated to high output BLDC motors and nut fasteners. It is demanded to develop a high-precision torque control driver and a high-speed, low-speed, high-response precision speed control system, but it does not satisfy the high precision, high torque and high speed operation characteristics required by customers. Therefore, in this paper, we propose a control technique of BLDC motor variable speed control and nut runner based on vector control and torque control based on coordinate transformation of d axis and q axis that can realize low vibration and low noise even at accurate tightening torque and high speed rotation. The performance results were analyzed to confirm that the proposed control satisfies the nut runner performance. In addition, it is confirmed that the pattern is programmed by One-Stage operation clamping method and it is tightened to the target torque exactly after 10,000 [rpm] high speed operation. The problem of tightening torque detection by torque ripple is also solved by using disturbance observer Respectively.

The Fault Diagnosis Model of Ship Fuel System Equipment Reflecting Time Dependency in Conv1D Algorithm Based on the Convolution Network (합성곱 네트워크 기반의 Conv1D 알고리즘에서 시간 종속성을 반영한 선박 연료계통 장비의 고장 진단 모델)

  • Kim, Hyung-Jin;Kim, Kwang-Sik;Hwang, Se-Yun;Lee, Jang Hyun
    • Journal of Navigation and Port Research
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    • v.46 no.4
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    • pp.367-374
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    • 2022
  • The purpose of this study was to propose a deep learning algorithm that applies to the fault diagnosis of fuel pumps and purifiers of autonomous ships. A deep learning algorithm reflecting the time dependence of the measured signal was configured, and the failure pattern was trained using the vibration signal, measured in the equipment's regular operation and failure state. Considering the sequential time-dependence of deterioration implied in the vibration signal, this study adopts Conv1D with sliding window computation for fault detection. The time dependence was also reflected, by transferring the measured signal from two-dimensional to three-dimensional. Additionally, the optimal values of the hyper-parameters of the Conv1D model were determined, using the grid search technique. Finally, the results show that the proposed data preprocessing method as well as the Conv1D model, can reflect the sequential dependency between the fault and its effect on the measured signal, and appropriately perform anomaly as well as failure detection, of the equipment chosen for application.