• Polymer(Korea)
• /
• v.36 no.5
• /
• pp.651-655
• /
• 2012

Considerable effort has been directed toward the use of silk fibroin as a biotechnological material in biomedical applications on account of its excellent biodegradability, biocompatibility, and unique mechanical properties. For use in tissue engineering, it is very important to design and control the pore architecture of polymeric scaffolds, which provide the vital framework for seeded cells to organize into functioning tissue. In the present study, a silk fibroin scaffold with controlled interconnectivity and pore size was prepared using an electrospinning method with poly(ethylene oxide).

• Proceedings of the KAIS Fall Conference
• /
• 2010.05b
• /
• pp.1086-1088
• /
• 2010

본 연구는 지하 구조물의 내벽에서 발생하는 습윤(濕潤) 및 결로를 방지하는 내벽체에 관한 것으로, 사방으로 연결조립 가능한 벽체판넬의 한쪽을 수직 지지프레임에 끼움 조립한 상태에서 타카핀으로 벽체판넬 및 수직 지지프레임을 동시 관통하여 내벽에 고정한 후 상기 수직프레임에 다른 벽체판넬의 일측을 중첩되게 조립하는 방법으로 지하 구조물에 내벽체를 편리하게 시공할 뿐만 아니라 공기를 단축하며, 상기 내벽체의 구성부품이 매우 간소하면서 가격이 저렴하여 공사비를 대폭 절감할 수 있는 시공이 편리한 지하 구조물용 내벽체의 개발에 관한 것이다.

• Korean Chemical Engineering Research
• /
• v.52 no.2
• /
• pp.214-218
• /
• 2014

In this study, nanoporous $Cu_3(BTC)_2$ membranes were synthesized on macroporous alumina tube supports by solvothermal method. It is very difficult to prepare uniform and crack-free $Cu_3(BTC)_2$ layer on macroporous alumina support by in situ solvothermal method. In this study, continuous and crack-free $Cu_3(BTC)_2$ tubular membranes could be obtained by in situ solvothermal process after surface modification of alumina support. The surface modification was conducted by spraying Cu precursor solution on the alumina support heated at $200^{\circ}C$. The prepared $Cu_3(BTC)_2$ tubular membranes were characterized by XRD, FE-SEM and gas permeation experiments. $H_2$ permeance through $5{\mu}m$ thick $Cu_3(BTC)_2$ tubular membrane was calculated to be $7.8{\times}10^{-7}mol/s{\cdot}m^2{\cdot}Pa$ by single gas permeation test, with the ideal selectivities of $H_2/N_2=11.94$, and $H_2/CO_2=12.82$.

• Journal of Korean Tunnelling and Underground Space Association
• /
• v.22 no.5
• /
• pp.543-561
• /
• 2020

This paper is the result of the study on the effect of the support structure of the tunnel steel rib. In tunnel excavation, the top and bottom half excavation methods result in subsidence of steel rib reinforcement due to insufficient support of steel rib reinforcement when the ground is poor after excavation. The foundation of the steel rib installed in the upper half excavates the bottom part of the base, causing the subsidence to occur due to various effects such as internal load and lateral pressure. As a result, the tunnel is difficult to maintain and its safety is problematic. To solve these problems, steel rib support structures have been developed. For the purpose of verification, the behavior of the supporting structure is verified by model experiments reduced to shotcrete and steel rib material similarity, the numerical analysis of ΔP and ΔP generated by bottom excavation by Terzaghi theoretical equation. As a result, it was found that the support structure of 20.100~198.423 kN is required for the 10~40 m section of the depth for each soil of weathered soil~soft rock. In addition, as a result of the reduced model experiment, a fixed level of 50% steel rib deposit of steel rib support structure was installed. The study shows that the installation of steel rib support structures will compensate for uncertainties and various problems during construction. It is also thought that the installation of steel rib support structure will have many effects such as stability, economy, and air reduction.

• Polymer(Korea)
• /
• v.32 no.6
• /
• pp.529-536
• /
• 2008

We manufactured poly (L-lactide-co-glycolide) (PLGA) scaffolds impregnated demineralized bone particle (DBP) and hyaluronic acid (HA) by ice-particle leaching method and tested their ability of sustained release of brain derived neurotrophic factor (BDNF). BDNF (50 and 200 ng) mixed with PLGA, DBP/PLGA, HA/PLGA and DBP/HA/PLGA scaffold. The release profiles of BDNF from BDNF loaded scaffolds were assayed using ELISA. Morphological changes of scaffolds by BDNF release were also observed by SEM. BDNF stably and sustainedly released from DBP/HNPLGA than from PLGA and DBP/PLGA scaffolds. DBP/HA/PLGA scaffolds showed the great structural changes, which demonstrated BDNF release amount from DBP/HA/PLGA scaffolds were highest in all groups. We suggest that BDNF loaded DBP/HNPLGA scaffold would be very useful for nerve regeneration.

• Journal of the Korean Chemical Society
• /
• v.41 no.12
• /
• pp.653-660
• /
• 1997

Silicone rubber-matrix membranes doped with tetradecyltrimethylammonium chloride (TDTMACl) are used to enhance electrode performance for chloride measurements in physiological samples. The optimized membrane formulation incorporates 95.4 wt% silicone rubber and 4.6 wt% TDTMACl, and its pH response is negligible in the range of pH 6-10. The TDTMACl-doped silicone rubber membrane exhibits sub-Nernstian response to chloride from 10 to 300 mM (-37.5 mV/decade), but its selectivities for chloride over other anions are remarkably enhanced: KpotCl,NO3=1.3, KpotCl,I=2.0, KpotCl,Sal=0.8, KpotCl,SCN=2.0 and KpotCl,ClO4=0.8. Furthermore, since the silicone rubber-matrix membrane exhibits better adhesion to the solid surface than do PVC membranes, the lifetime of the coated-wire type membrane electrode is greatly improved. The response properties toward chloride and salicylate for solid-state sensor are not significantly changed after at least 35 days of use.

• Journal of the Korean GEO-environmental Society
• /
• v.18 no.2
• /
• pp.5-19
• /
• 2017

Underground excavation for building construction in Korea is changing from conventional support method (Strut, Ground anchor) to inside permanent support method by stability, economic, circumstances around excavation and etc. This study was selected the sites of Top-down, New Top-down, S.P.S, S.T.D and B.R.D in general use. This study was compared and analyzed a construction cost and period between aforementioned methods and conventional support method. Also, this study was confirmed the stability of temporary retaining wall by analysis for measurement data under construction. As a result, this study can grasp that most improved permanent support method is excellent in economic and constructability than conventional support method in case of deep excavation and rapid appearance of bedrock.

• Journal of Energy Engineering
• /
• v.12 no.4
• /
• pp.302-308
• /
• 2003

The peformence tests of zinc-based desulfurization sorbents using the yellow earth as support for the hot gas clean up were carried out. The zinc-based sorbent with 25 wt％ yellow earth was prepared, and their properties such as the reaction rate, the sulfur capacity and the attrition resistance, were investigated. The reactivity tests for hot gas desulfurization was performed at middle temperatures (sulfidation/regeneration：480$^{\circ}C$/580$^{\circ}C$). During multi-cyclic desulfurization, the deactivation of zinc-based sorbent was decreased by the addition of yellow earth, and their efficiency was enhanced. The ZnO/yellow earth sorbent had high reactivity, good regenerability, long-term durability (about 19 gS/100 g sorbent for 10-cycles) and high attrition resistance (AI=19.1％). It was concluded that the peroperties of zinc-based sorbent were improved by metal oxides (Fe$_2$O$_3$, Na$_2$O, MnO$_2$, etc) in the yellow earth. From these results, it was confirmed that the desulfurization properties of zinc-based sorbents at middle temperatures could be improved by the yellow earth using as support.

• Polymer(Korea)
• /
• v.38 no.2
• /
• pp.150-155
• /
• 2014

Polycaprolactone (PCL) is a synthetic biodegradable polymer with excellent mechanical properties. $TiO_2$ (titanium dioxide) has a hydrophilic, high density and excellent biocompatibility. In this work, we produced three-dimensional porous scaffolds with PCL and $TiO_2$ nanoparticles using a salt-leaching method. Physical properties of the scaffolds were analyzed by FE-SEM, FTIR, TGA and compressive strength. Interestingly, the addition of $TiO_2$ nanoparticles decreased the water absorption and swelling ratio of the porous scaffolds. However, the compressive strength was increased by $TiO_2$. CCK-8 assay, which is generally used for the analysis of cell growth, shows that $TiO_2$ nanoparticles have no cytotoxicity. Taken together, we suggest that the PLC/$TiO_2$-scaffold can be used for biomedical applications.

• Clean Technology
• /
• v.17 no.3
• /
• pp.225-230
• /
• 2011

Characteristics of hydrocarbon selective catalytic reduction of NOx using various noble metal catalysts were investigated. The best active metal is Pt, supports are $CeO_2$ and $TiO_2$ by strong interactions between active metals, and 55% of conversion rate of NOx is shown. Pd, Rh and Ag catalysts presented a conversion of less than 20% as active metals, and supports also showed the poor activity compared to $SiO_2$ and $ZrO_2$. Experiments were performed with different types of reducing agents, amount, concentration of oxygen and space velocity in order to investigate the performance of catalysts according to operating conditions. The results confirm that the methane is better than propane as a reducing agent, and as the ratio of methane/nitrogen oxide increases, the catalytic activity increased, as the concentration of oxygen increases and space velocity decreases, the performance of catalysts increased.