• Journal of the Korean Geosynthetics Society
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• v.13 no.2
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• pp.59-67
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• 2014

The amount of the contaminants that can be adsorbed on the drain was evaluated for the effective remediation of the contaminated soil, and the contaminants adsorptivity of the drain was evaluated by comparing the isothermal adsorption model after carrying out the contaminants adsorption test of the reactants coated on the surface of the drain. The reactant used in the experiment is a natural zeolite, and the contaminants are copper, lead and cadmium. The results that Freundlich and Langmuir adsorption isotherm model are compared to the adsorption amount according to the change of the initial concentration by the contaminants. As a result of the component analysis, because Si, Al and O are contained approximately 28%, 11% and 48%, respectively, it is identified that the material coated on the surface of the drain is the component of the zeolite which is the reactant for the adsorption of the heavy-metal (Cu, Pb, Cd) contaminants. The heavy-metal adsorption kinetic of the zeolite which is the reactant was decreased in order of lead, copper and cadmium. The important factor of the performance evaluation of the adsorbent is the reaction rate, and if zeolite is used as the reactant in the relationship between the maximum amount of adsorption and reaction rate, it can be utilized as the design factor that determine the removal order of the complex heavy-metal. In other words, because the maximum adsorption quantity of lead is smaller compared to copper but the reaction rate is relatively fast, it can be primarily removed, and copper can be removed after removing the lead. It was analyzed that Cadmium can be finally removed after that other heavy-metal is removed.

• Journal of the Korean Geotechnical Society
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• v.26 no.10
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• pp.61-68
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• 2010

A pilot-scale model test was performed to estimate the availability of new material, Fe-loaded zeolite, as the filling material in permeable reactive barrier (PRB) against the contaminated groundwater with both Cd and Cr(VI). Aquifer was simulated by filling up a large scale soil tank with sands, and mobilizing the water flow by the head difference of water level in both ends of the tank. Then, the mixture of concentrated Cd and Cr(VI) solution was injected into the aquifer to form a contaminant plume, and its behavior through Fe-loaded zeolite barrier was monitored. The test results showed that Fe-loaded zeolite barrier successfully treated the contaminant plume containing both Cd and Cr(VI) and that the immobilized contaminants in the barrier were not desorbed or released. The results indicated that the Fe-loaded zeolite could be a promising material in PRBs against the multiple contaminants with different ionic forms like Cr(VI) and Cd.

• Journal of the Korean Geotechnical Society
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• v.27 no.10
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• pp.5-12
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• 2011

This study was focused on the reactivity of furnace slag against cadmium to design the vertical drain method with reactive column for improving contaminated sea shore sediment. The kinetic sorption test was performed by changing the initial concentration and pH. Using pseudo-second-order model, the reactivity of furnace slag was quantitatively analyzed. Equilibrium removal amount ($q_e$) of furnace slag increased and rate constant ($k_2$) decreased with the increase of initial cadmium concentration. With the increase of pH, the equilibrium removal amount ($q_e$) and rate constant ($k_2$) increased in the same initial concentration. Required retention time was related to the inverse of the product of the equilibrium removal amount ($q_e$) multiplied by rate constant ($k_2$). The required retention time could be used to design the length of reactive column.

• Journal of the Korean Geosynthetics Society
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• v.14 no.4
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• pp.139-146
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• 2015

This paper describes a effect of nano-bubble on removal of complex heavy metals, in order to remove pollutants of soil with copper (Cu) and lead (Pb) based on column test. It was conducted column test considering inflow and fine soil contents condition, and then it was analyzed removal effect of nano-bubble on Cu and Cu/Pb. The test result showed that the removal effect of the nano-bubble was higher than that of distilled water regardless of fine soil contents in case of Cu pollutant, and the removal effect of nano-bubble on heavy metals was found to have a significant impact on Pb than Cu in case of Cu/Pb pollutants. It was also analyzed that engineering properties (like a flow path and permeability) of soil due to void ratio has influenced a significant impact the pollutants removal of nano-bubble. The test results determined that nano-bubble can be applied as a flushing agent for priority target pollutant in complex heavy metals.

• Journal of The Korean Society of Agricultural Engineers
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• v.47 no.5
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• pp.63-71
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• 2005

In-situ soil remediation mechanism through the vertical drains (VDs) is analyzed with numerical model as the error and complementary error function. Results from in-situ test and analysis indicate that the contaminant concentration ratio as initial one ( C/$C_0$) increases as the radius ratio ( r/R) increases from the injection well, and also increases as the depth ratio ( z/ H) increases from the top of contaminated area. The elapse time needed to attain $50\%$ and $90\%$ clean up level ($ t_{50},\;t_{90}$) increases as the radius ratio ( r/R) and the depth ratio ( z/ H) increase. As above results, the procedure of soil flushing in contaminated area using vertical drains makes progress from the top of injection well to the bottom of extraction well.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2002.09a
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• pp.175-178
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• 2002

The purpose of this research is to evaluate the effect of microemulsion on the remediation of soil contaminated with organic materials. The laboratory tests were conducted to confirm the ability of microemulsion as remediation agent and compare remediation efficiency in microemulsion process with soil washing. In the test, pyrene was used as organic contaminant and alkylpolyethoxylates(C$_4$E$_1$) was used as surfactant. Microemulsion in the $C_4$E$_1$-water-decane mixture was formed in the range of 22 and 48$_{o}$ C at surfactant contents V=55%. Extraction was completed within 30 min and about 90% pyrene was removed. Seperation of pyrene with oil phase lowering temperature was sufficient for application in a multistep process.s.

• Journal of the Korean GEO-environmental Society
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• v.15 no.5
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• pp.39-46
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• 2014

The objectives of this study were to determine biodegradation and characteristics of BTEX and MTBE under aerovic-anaerobic conditions and evaluate the potential of natural attenuation method in denitrifying condition.. In the single-substrate experiments, all of the BTEX compounds were degraded under all the conditions. but, lower degradation of benzene and p-xylene were observed under aerobic condition due to the lack of oxygen initially supplied. In the mixed-substrate experiments, BTEX degradation was delayed compared to that in the single-substrate experiments due to a competition of the substrates. Biodegradation of MTBE was observed only under denitrifying conditions and we expected that MTBE mineralized to $CO_2$ without the accumulation of TBA. We also conducted to determine the effect of initial nitrate concentration on BTEX and MTBE degradation. At low nitrate concentration (<50 mg/L), BTEX degradations were limited by the lack of electron acceptor and BTEX degradation was inhibited at high nitrate concentration (>200 mg/L). The results in this study indicated that biotransformation could be applied to the gasoline-contaminated region under aerovic-anaerobic.

• Journal of the Korean GEO-environmental Society
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• v.15 no.6
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• pp.17-29
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• 2014

A remedial investigation was conducted at five military training ranges in northern Gyeonggi province to collect information necessary for the design of on-site treatment facilities for the abatement of explosive compounds release to the environment. These information includes (i) identification of dominant explosive compounds in each range, (ii) discharge/migration routes, and (iii) contaminant distribution in particle size fraction and settling velocity of the soils. The results of investigation showed that TNT and RDX are the major contaminants but the extent of contamination varied depending on the types of military training practices and topography of the site. RDX was also detected in the subsurface soil and in the nearby stream within the training ranges, suggesting release of contaminants to streams. The median concentrations of explosives in the surface soil were less than 20 mg/kg despite several 'hot spots' in which explosives concentrations often exceeds several hundred mg/kg. The average clay contents in the soil of target area was less than 5 % compared to 12 % in the control, indicating loss of smaller particles by surface runoff during rainfall due to lack of vegetative land cover. Analysis of explosive compounds and particle size distribution showed that the amount of explosive compounds in soil particles smaller than 0.075 mm was less than 10 % of the total. Settling column tests also revealed that the quantity of explosive compounds in the liquid phase of the effluent was greater than that in the solid phase. Therefore, pre-treatment of particulate matter in surface runoff of shooting range with a simple settling basin and subsequent effluent treatment with planted constructed wetlands as polishing stage for explosives in the aqueous phase would provide the shooting ranges with a self-standing, sustainable, green solution.

• Journal of the Korean Geosynthetics Society
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• v.10 no.1
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• pp.53-61
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• 2011

This study was conducted to confirm the adsorption capacity of CFW(Carbonized Foods Waste), which is produced by the process of recycling waste, in PRB method that Electrokinetic(E/K) method was applied. The batch test was carried out to analyze the adsorption characteristics of CFW for adsorbing the organic compounds. The organic compounds used in the batch test were Phenanthrene and Trichloroethylene(TCE), and the anionic surfactant(SDS) and the nonionic surfactant(Brij$^{(R)}$30) were used for the surfactants. The results of the batch test confirmed that the adsorption efficiency of Phenanthrene was 99% and TCE was 26%. The each compounds compared with the adsorption isotherms, which is calculated by the Langmuir and Freundlich models. The results indicated that Phenanthrene is fitted to the linear Langmuir model, whereas the distribution of TCE is unclear. The results of the batch test used in surfactants confirmed that the adsorption efficiency of CFW using Phenanthrene was reduced to 6~8%. However, the adsorption efficiency of CFW in TCE was increased up to 81% by surfactants. Especially, the nonionic surfactant was excellent in the adsorption of CFW using TCE. Nevertheless, the adsorption efficiency of CFW in Phenanthrene was still higher than TCE. Therefore, the adsorption efficiency of CFW in Phenanthrene was better than in TCE. In PRB method using E/K method, the adsorption of CFW used nonionic surfactant is better to use than the anion surfactants on the organic compounds.

• Journal of Korean Society for Geospatial Information Science
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• v.24 no.4
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• pp.13-19
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• 2016

This study presented the build-up of three-dimensional soil pollution map for precise analysis. To do this, survey on the existing pollutant region on Dongnae-gu, Busan that is the study subject, showed that it tended to produce 0.72 clusters. So, this study suggested to investigate center of $1km{\times}1km $ grid and, as the results of comparing the pollution map that input pollution figure values based on the actually investigation point showed precise results. And, it divided the standard of pollution into 5 levels in surface and underground space and the map was built up using IDW interpolation against the amount of polluted substance. The pollution of ground surface, flow of polluted substance, coefficient of permeability and ground water level that are 504 geotechnical informations were selected as the influential parameters in pollution analysis of underground space, and it calculated that to 0~20 points by dividing the characteristics. It enables the build-up of pollution map of ground surface-underground with depth that considers the characteristics of soil layers and it is considered that it is possible to analyze the general infiltration. And, it was considered that it enables more accurate forecast about influential analysis per depth and pollution of underground water.