• Title/Summary/Keyword: 중금속 흡착

Search Result 524, Processing Time 0.025 seconds

The Removal of Nutrients and Heavy Metals Using Household Rain garden (가정용 빗물정원을 이용한 지붕빗물내 영양소 및 중금속 제거)

  • Pak, Gijung;Park, Heesoo;Cho, Yunchul;Kim, Sungpyo
    • Journal of Wetlands Research
    • /
    • v.17 no.1
    • /
    • pp.38-44
    • /
    • 2015
  • In Korea, most rainfall events occur during summer which then leads to an increasing concern regarding high influx of non-point source pollutants since the pollutant loadings from these non-point sources are very significant. In particular, the first flush of roof-harvested rainfall is said to contain the most highest concentration of nutrients and heavy metals. Accordingly, it is important to develope the possible water quality management options in treating the contaminants and considering reclaimed water reuse. The rain garden could be one of suitable alternatives in addressing this issue. In this study, the development of an effective adsorption media and its application to a lab-scale rain garden was tested to evaluate the removal rate of various nutrient and organic matter (TN, TP, CODcr), and heavy metals (Cu, Cd, Pb). Results showed that carbonized peatmoss produced at higher temperature have better adsorption capacity as compared to the one produced at a lower temperature. When the carbonized peatmoss was applied as rain garden media, the highest removal of TN, TP, and CODcr was observed compared to no carbonized peatmoss applied rain garden. Therefore, this study showed that the carbonized peatmoss would be effectively applied to the rain garden for removing nutrients and heavy metals from roof-harvested rainwater.

Synthesis and Characterization of Chelating Resins Containing Thiol Croups (티올기를 함유하는 킬레이트 수지의 합성 및 특성)

  • 박인환;방영길;김경만;주혁종
    • Polymer(Korea)
    • /
    • v.27 no.4
    • /
    • pp.330-339
    • /
    • 2003
  • Three kinds of macro-reticular bead-typed chelating resins having thiol groups were obtained from basic resins like poly(strene-co-divinylbenzene) (PSD) and poly(styrene-co-methyl methacrylate-co-divinylbenzene) (PSMD): the chelating resin (I) was prepared by chloromethylation of phenyl rings of PSD followed by thiolation using thiourea. The chelating resin (ll) was designed to provide enough space to chelate heavy metal ions; one chloromethyl group was obtained by chlorination of hydroxymethyl group provided by reduction of carboxylic ester group of PSMD and another chloromethyl group was obtained by direct chloromethylation of pendent phenyl group using chloromethyl methyl ether. Both of chloromethyl groups were thiolated by using thiourea. The chelating resin (III) was prepared by chlorosulfonation of phenyl rings of PSD followed by thiolation using sodium hydrosulfide. The adsorbtivity toward heavy metal ions was evaluated. The hydrophobic chelating resin (I) with thiol groups showed highly selective adsorption capacity f3r mercury ions. However, the chelating resin (II) with thiol groups showed mere effective adsorption capacity toward mercury ions than chelating resin (I) with thiol groups, and showed some adsorption capacity for other heavy metal ions like Cu$\^$2+/, Pb$\^$2+/, Cd$\^$2+/ and Cr$\^$3+/. On the other hand, the chelating resin (III) which have hydrophilic thiosulfonic acid groups was found to be effective adsorbents for some heavy metal ions such as Hg$\^$2+/, Cu$\^$2+/, Ni$\^$2+/, Co$\^$2+/, Cr$\^$3+/ and especially Cd$\^$2+/ and Pb$\^$2+/.

Removal/Recovery of Heavy Metals Using Biopolymer (생물고분자를 이용한 중금속 제거/회수에 관한 연구)

  • 안대희;정윤철
    • KSBB Journal
    • /
    • v.8 no.4
    • /
    • pp.336-340
    • /
    • 1993
  • Zoogloea ramigera 115, well known type of bacteria to produce slime in sewage plants, was selected for biopolymer production. The extracted biopolymer showed high uptake capacity of metals such as cadmium and zinc. Especially the fermentor broth itself showed high adsorption of metal and could be used a biosorbent without an additional separation process. Biopolymer was immobilized into beads of calcium alginate and used in a packed bed reactor for the purpose of valued metals recovery. The biopolymer showed high removal efficiencies of 80% or greater for Cu, Cd, Mn and Zn, and high stability in sorption-desorption-resorption experiments. The immobilized biopolymer systems were found to be comparable to other metal removal systems such as ion exchange resins and to be of potential industrial application value.

  • PDF

Preparations and characteristics of the ceramic balls for heavy metals absorption and antibacterial activities in the drinking water (음용수중의 중금속흡착과 항균성용 세라믹 볼의 제조 및 특성평가)

  • Park, Chun-Won;Park, Ra-Young;Park, Sun-Min
    • Journal of the Korean Crystal Growth and Crystal Technology
    • /
    • v.15 no.6
    • /
    • pp.263-268
    • /
    • 2005
  • The ceramic balls impregnated with $20{\sim}40nm$ sized Ag colloid were examined for heavy metals absorption and antibacterial activities in the drinking water. The preparation conditions of ceramic ball that the porosity was excellent were as follows: starting material: 85 wt% $Ca_{10}(PO_4)_6(OH)_2$, binder: 5 wt% PVA and 15 wt% ${\alpha}-Ca_3(PO_4)_2$, heating temperature: $1000^{\circ}C$, duration: 3 hrs. The ceramic balls obtained under these conditions showed specific surface area of $110m^2/g$, pore size of $120{\mu}m$ and porosity of 80%. Also, as the results of a performance test on a rate of adsorbing and removing heavy metals in the drinking water by using the.AAS, heavy metals such as Zn, Mn, Fe and Cu were removed to the extent that their content became 0.03mg/l or lower after 1 day and they showed an excellent bactericidal activity that all coliforms were killed after 3 hrs.