• Title/Summary/Keyword: 중금속 분석

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Chemical Properties and Heavy Metal Content of Forest Soils around Abandoned Coal Mine Lands in the Mungyeong Area (문경지역 폐탄광지 주변 산림토양의 화학적 성질 및 중금속 함량)

  • Min Jae-Gee;Park Eun-Hee;Moon Hyun-Shik;Kim Jong-Kab
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.7 no.4
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    • pp.265-273
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    • 2005
  • Chemical properties and heavy metal concentrations of forest soils of four abandoned coal mine lands affected by coal mining activities in the Mungyeong area were investigated to provide basic information for revegetation of abandoned coal mine lands. Soil pH in abandoned coal mine lands ranged from 5.30 to 6.76 it in the control site was 5.23. Contents of organic matter and total N in abandoned coal mine lands were $4.46\~7.19\%\;and\;0.07\~0.15\%$, respectively. Available P contents were 6.54 for A (Samchang), 6.52 for B (Bongmyeong),3.94 fur C (Kabjung), 5.45 mg/kg for D (Danbong coal mine land) and 5.25 mg/kg for the control site, which had a positive correlation with soil pH. Contents of exchangeable Ca, Mg, K and Na in abandoned coal mile lands averaged 196.1, 88.7, 88.2 and $10.2cmol^+/kg$, with a range of $132.1\~242.1,\;24.2\~138.\; 64.9\~120.8\;and\;8\~12.2cmol^+/kg$, respectively. Those of the control site were 192.8, 95.8, 104 and $21.2 cmol^+/kg$, respectively. Heavy metals such as Al, As, Cd, Cr, Cu, Fe, Mn, Ni, Pb and Zn of forest soil in abandoned coal mine lands have a larger content than those of the control site. Al, Mn and fb content was especially high in abandoned coal mine lands. The Al content of forest soil in abandoned coal mine lands ranged from 397 to 917 ppm, which was considered to be high enough to inhibit tree growth. Therefore, it is suggested that soils of abandoned coal mine lands contaminated by mining activities need to be properly treated for remediation of environmental problems.

The Effect of Reclaimed Sewage Irrigation on the Rice Cultivation (벼 재배시 생활오수 처리수 관개 효과)

  • Yoon, Chun-Gyeong;Kwun, Soon-Kuk;Chung, Ill-Min;Kwon, Tae-Young
    • Korean Journal of Environmental Agriculture
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    • v.18 no.3
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    • pp.236-244
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    • 1999
  • A feasibility study was performed to examine the agronomic application of treated sewage on paddy rice culture by field experiment. The domestic sewage was treated by the constructed wetland system which was in subsurface flow type and consisted of sand and macrophyte. The effluent of the wetland system was adjusted to maintain the total nitrogen concentration below $25mgL^{-1}$ and used for irrigation water. Four treatments include (1) irrigation of treated sewage after concentration adjusted with conventional fertilization (TWCF), (2) irrigation of treated sewage after concentration adjusted with half of the conventional fertilization (TWHF), (3) irrigation of treated sewage after concentration adjusted without fertilization (TWNF), and (4) irrigation of treated sewage as it was without fertilization (SWNF). These cases were compared to the control case of tap water irrigation with conventional fertilization (Control). Generally, addition of the treated sewage to the irrigation water showed no adverse affect on paddy rice culture, and even improvement was noticed in both growth and yields. TWCF showed the best result and the yields exceed the Control in about 10%. Overall performance of the treatments was TWCF, Control, TWHF, TWNF, and SWNF in decreasing order. From this study, it appears that reuse of treated sewage as a supplemental irrigation water could be feasible and practical alternative for ultimate sewage disposal which often causes water quality problem to the receiving water body. For full scale application, further study is recommended on the specific guidelines of major water quality components and public health.

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Contents of Lead, Cadmium and Zinc in Bone, Muscle and Fin of Carassius carassius from Middle Stream of Nakdong River, Korea (낙동강 본류에 서식하는 붕어에서의 납, 카드뮴과 아연의 함량)

  • Kim, Doo-Hie;Kim, Yong-Gu;Jang, Bong-Ki
    • Journal of Preventive Medicine and Public Health
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    • v.21 no.2 s.24
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    • pp.307-319
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    • 1988
  • In order to determine the contents of lead, cadmium and zinc, the tissues of the crussian carp, Carassius carassius, collected from the middle streams of the Nakdong river were examined. During the dry season from 8 to 15, March, 1987, six loci were selected to sample the fish and river water; five of them were the midstreams of the Nakdong river i. e., the vicinities of the Andong dam, the Nakdong bridge, the Waegwan bridge, Gangjung and Gaepori, the other one was the Kumho river around the Paldal bridge(see Fig. 1). The microanalyses of lead and cadmium contents were undertaken by the atomic absorption spectrophotometer(Model IL-551) connected with CTF-IL 655, while that of Zinc by the flame method with IL551 only. The contents of lead and cadmium in water sampled from Gaepori distant from about 30km downward from the junction with the Kumho river were about 1.5 times higher than those from Gangjung distant about 0.5km upward from the junction, and the content of zinc from Gaepori was slightly higher than that from Gangjung. However, the contents of lead and cadmium in water sampled from Gaepori were three fifth of those from the vicinity of Paldal bridge far about 2km upperward from the junction. In the other words, the contents of lead and cadmium in the samples from the vicinity of the Paldal bridge were about 2.5 to 3 times higher than those from the Gangjung and 5 times higher than those from the Andong dam. The contents of the heavy metals in the tissues of Carassius carassius were relatively consistent to those of the aquatic environments where the fish were collected, with higher contents in the tissues of the crussian carp collected from the vicinity of Gaepori and the Paldal bridge which were so much polluted than in those from other loci in upper stream from the junction. And the contents of lead and cadmium in tissues were positively correlated with the age of the fish, however, that of zinc was not. The contents of lead in bone of crussian carp from the vicinity of the Paldal bridge in the group of 0-1 year old fish were similar to those of 4-5 years old fish from Gaepori, and higher than those of 3-4 years old fish collected from the upper stream of the junction. It is likely that fishing from Gaepori and the paldal bridge is not recommended, and all the industrial producers have to pay intensive attention to the water pollution due to the sewage disposal.

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A Feasibility Study on the Deep Soil Mixing Barrier to Control Contaminated Groundwater (오염지하수의 확산방지를 위한 대체 혼합차수재의 적용에 관한 연구)

  • 김윤희;임동희;이재영
    • Journal of Soil and Groundwater Environment
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    • v.6 no.3
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    • pp.53-59
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    • 2001
  • There is a lot of method to manage the insanitary landfill but vertical cutoff walls have been widespreadly used and were installed into the subsurface to act as a barrier to horizontal groundwater flow, The stabilized material such as specialized cement or mixed soil with additives has been generally applied for the materials of the deep soil mixing barrier in korea. The amount of the stabilized material is dependent on the field conditions, because the mixing ratio of the material and the field soil should achieve a requirement in the coefficient of permeability, lower than 1.0$\times$$10^{7}$cm/sec. This study determined the quantity and optimized function ratio of the stabilized material in the formation process of the mixed barrier that was added with stabilized material on the field soil classified into SW-SC under USCS (Unified Soil Classification System). After that the fly ash and lime were selected as an additives an that could improve the function of the stabilized material and then the method to improve the functional progress in the usage of putting into the stabilized material as an appropriate ratio was studied and reviewed. The author used the flexible-wall permeameter for measuring the permeability and unconfined compressive strength tester for compressive strength, and in the view of environmental engineering the absorption test of heavy metals and leaching test regulated by Korean Waste Management Act were performed. As the results, the suitable mixing ratio of the stabilized material in the deep soil mixing barrier was determined as 13 percent. To make workability easy, the ratio of stabilized material and water was proven to be 1 : 1.5. With the results, the range of the portion of the additives(fly ash : lime= 70 : 30) was proven to be 20-40% for improving the function of the stabilized material, lowering of permeability. In heavy metal absorption assessment of the mixing barrier system with the additives, the result of heavy metal absorption was proved to be almost same with the case of the original stabilized material; high removal efficiency of heavy metals. In addition, the leaching concentration of heavy metals from the leaching test for the environmental hazard assessment showed lower than the regulated criteria.

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Establishments of Lead Standards through Monitoring Heavy Metals in Calcium, Chitosan, and Propolis Health Foods (칼슘, 키토산, 프로폴리스 건강보조식품중 중금속 모니터링을 통한 납기준 제정)

  • Kim, Mee-Hye;Chung, So-Young;Sho, You-Sub;Kim, Myung-Chul;Kim, Chang-Min
    • Korean Journal of Food Science and Technology
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    • v.33 no.5
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    • pp.525-528
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    • 2001
  • This study was conducted to estimate the contents of heavy metals in some health foods available on Korean markets. The samples were digested with microwave system, then analyzed using GF-AAS for the contents of lead (Pb), cadmium (Cd) and arsenic (As). The contents of mercury (Hg) were determined using a mercury analyzer. The average values of Hg, Pb, Cd and As in calcium (Ca) health foods were 0.007, 1.08, 0.02 and 0.48 mg/kg respectively. Those values in chitosan health foods were 0.001, 0.36, 0.01 and 0.03 mg/kg respectively. Those values in propolis health foods were 0.013, 4.96, 0.01 and 0.13 mg/kg, respectively. The health foods that contained cow bone powders had the highest lead contents. Based on the variation in lead contents of those products, it could be possible that they might be contaminated through raw materials and/or manufacuring process. Some propolis products were also very high in lead contents. There could be risks for some population, especially the aged who overtake those health foods, to have heavy intake of lead. Therefore, we established the lead standards of 3.0, 2.0 and 5.0mg/kg less than for Ca, chitosan and propolis health foods respectively, based on the Codex method.

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Spectral Response of Red Lettuce with Zinc Uptake: Pot Experiment in Heavy Metal Contaminated Soil (아연섭취에 따른 적상추의 분광학적 반응: 중금속 오염토양에서의 반응실험)

  • Shin, Ji Hye;Yu, Jaehyung;Kim, Jieun;Koh, Sang-Mo;Lee, Bum Han
    • Economic and Environmental Geology
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    • v.52 no.2
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    • pp.129-139
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    • 2019
  • This study investigates the spectral response of red lettuce (Lactuca sativa var crispa L.) to Zn concentration. The control group and the experimental groups treated with 1 mM(ZnT1), 5 mM(ZnT2), 10 mM(ZnT3), 50 mM(ZnT4), and 100 mM(ZnT5) were prepared for a pot experiment. Then, Zn concentration and spectral reflectance were measured for the different levels of Zn concentration in red lettuce. The Zn concentration of the control group had the range of 134-181 mg/kg, which was within the normal range of Zn concentration in uncontaminated crops. However, Zn concentration in the experimental group gradually increased with an increase in concentration of Zn injection. The spectral reflectance of red lettuce showed high peak in the red band due to anthocyanin, high reflectance in the infrared band due to the scattering effect of the cell structure, and absorption features associated with water. As Zn concentration in red lettuce leaves increased, the reflectance increased in the green and red bands and the reflectance decreased in the infrared band. The correlation analysis between Zn concentration and spectral reflectance showed that the reflectance of 700-1300 nm had a significant negative correlation with Zn concentration. The spectral band is a wavelength region closely related to the cell structure in the leaf, indicating possible cell destruction of leaf structure due to increased Zn concentration. In particular, 700-800 nm reflectance of the infrared band showed the strongest correlation with the Zn concentration. This study could be used to investigate the heavy metal contamination in soil around mining and agriculture area by spectroscopically recognizing heavy metal pollution of plant.

Status of Water Quality and Future Plans in the Philippines (필리핀의 수질현황 및 미래 관리계획)

  • Gorme, Joan B.;Maniquiz, Marla C.;Kim, Lee-Hyung
    • Journal of Wetlands Research
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    • v.11 no.3
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    • pp.89-103
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    • 2009
  • The Philippines is abundant with rich natural resources such as water. Because of rapid urbanization in the country, most of the water bodies are polluted as a result of domestic, agricultural and industrial activities. The Environmental Management Bureau (EMB) is the main government arm responsible for monitoring and inspection of affected water bodies. Only water bodies with at least four sampling events during dry and wet seasons were included in the assessment of water bodies that passed the DAO 90-34 water quality criteria. Water bodies were monitored for dissolved oxygen (DO), biochemical oxygen demand (BOD), total suspended solids (TSS), and total dissolved solids (TDS), heavy metals, fecal coliform contamination and nitrates. High pollutant concentrations from domestic, agricultural, industrial and nonpoint sources were observed from monitoring events due to inadequate sewage services and treatment facilities in the country. The objective of this paper was to present and evaluate the quality of the water bodies in the Philippines.

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Water-well Management Data Modeling using UML 2.0 based in u-GIS Environment (u-GIS 환경에서 UML 2.0을 활용한 지하수 관리 데이터 모델링)

  • Jung, Se-Hoon;Kim, Kyung-Jong;Sim, Chun-Bo
    • The Journal of the Korea institute of electronic communication sciences
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    • v.6 no.4
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    • pp.523-531
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    • 2011
  • Many of the wells which were constructed to use ground water resource are abandoned and not managed efficiently after its use. And a variety of heavy metals and organic compounds are released from the abandoned wells and this can cause ground water pollution. Therefore in this paper implemented to monitor locational information drill holes and underground water sensing information on real time basis using u-GIS environment to combined ubiquitous sensor node and GIS technology to improve these problems. In addition, this system suggests using system by UML 2.0 by analyzing variety requirement of user and between system internal modules interaction and data flow. It provides graphical user interfaces (GUI) to system users to monitor water-well related property information and its managements for each water-well at remote site by variety platform by GIS map and web environment and mobile device based on smart phone.

Preparation and Coating of Red Colored Artificial Pearl by CVD Method (CVD법을 이용한 적색 인조진주 코팅 및 제조)

  • Shin, Cheol-Woo;Choi, Kyoung-Rim;Lee, Dong-Kyu
    • Journal of the Korean Applied Science and Technology
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    • v.35 no.3
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    • pp.857-864
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    • 2018
  • Demand for developing artificial green pearl that meets the needs of modern people has been increasing. In this paper, eco-friendly inorganic pearlescent pigment was used instead of organic pigment and urethane resin was substituted for nitrocellulose which has been used as main materials in previous preparation method, increasing gloss from 73.4% to 86.7%. Urethane was coated on substrate before finishing with CVD, resulting high gloss of 96%. Colorimeteric analysis shows that a* and b* of CIE value was changed from +37.7 and +24.5 to +31.9 and +14.2 respectively because of CVD finishing, obtaining colorful, high gloss and durable artificial pearl. Quality and toxicity of samples was established by chemical resistance, glossiness, colorimeter, surface roughness, wear resistance, content of heavy-metal, and salt water test.

Life Cycle Assessment of Activated Carbon Production System by Using Poplar (포플러를 이용한 활성탄 제조 시스템에 대한 전과정 평가)

  • Kim, Mihyung;Kim, Geonha
    • Journal of Korean Society of Environmental Engineers
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    • v.36 no.11
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    • pp.725-732
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    • 2014
  • Phytoremediation is a technology to mitigate the pollutant concentrations such as metals, pesticides, solvents, oils, or others in contaminated water and soils with plants. The plants absorb contaminants through the root and store them in the root, stems, or leaves. Rapid growth trees such as poplar are used to remove low concentrated contaminants eco-friendly and economically in a wide contaminated region. This study was practiced to evaluate an activated carbon production system by using poplar wood discarded after phytoremediation. Life cycle assessment methodology was used to analyze environmental impacts of the system, and the functional unit was one ton of harvested poplar. It was estimated that the small size rotary kiln for activated carbon production from poplar wood had an environmental benefit in optimized conditions to minimize energy consumptions. The results of an avoided environmental impact analysis show that the system contribute to reduce environmental impacts in comparison with activated carbon production from coconut shell.