• Title/Summary/Keyword: 중금속 분석

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Analysis of Bulking Agent Reduction Effect by using Previously Produced Compost (생산퇴비 재사용을 통한 수분조절재 절감효과 분석)

  • Lee, Min-Ho;Phonsuwan, Malinee;Moon, Byeong-Eun;Wang, Eun-Chul;Kim, Hyeon-Tae
    • Journal of agriculture & life science
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    • v.51 no.4
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    • pp.139-147
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    • 2017
  • This study was carried out in order to reduce the amount of sawdust for recycling the generated manure from livestock farms, and to investigate the effects on the reducing usage of sawdust and quality of produced compost. To do this, a cylindrical horizontal composting device were used in the experiments and compost was analyzed for judging produce compost quality. The experiment was carried out separately under different cases of operational control conditions. The first case was produced by using sawdust and pig manure mixture(Test-1); the second case was produced by using sawdust, pig manure and the previously produced compost(Test-2). In the second case, Except for some heavy metal content, The water content and C/N ratio were found to be suitable for fertilizer process specification of the RDA(Rural Development Administration) and it was found to reduce the sawdust 1.25tons usage.

Assessment of Soil Stabilization forthe Reduction of Environmental Risk of Lead-contaminated Soil Near a Smelter Site (제련소 주변 납 오염 현장토양의 위해성 저감을 위한 토양 안정화 평가)

  • Yeo, In-Hong;Chang, Yoon-Young
    • Journal of Environmental Impact Assessment
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    • v.30 no.4
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    • pp.215-224
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    • 2021
  • In this study, to investigate the effect of stabilization of Pb-contaminated soil near a smelter site for the reduction of environmental risk of Pb leaching, commercial stabilizers were amended with the Pb-contaminated soil and evaluated leaching characteristics of Pb in soil by TCLP and SPLP leaching test. Also, performing sequential extraction procedure speciation of Pb in the amended soil was investigated. Limestone, AC-2 (Amron), Metafix (Peroxychem) that possess stabilization performance towards heavy metal in soil and mass production is available were selected as candidates. AC-2 contained a CaCO3 and MgO crystalline phase, while Metafix had a Fe7S8 crystalline phase, according to XRD studies. Pb content in SPLP extract was lower than the South Korean drinking water standard for Pb in groundwater at 4% AC-2 and Metafix treatment soil, and TCLP-based stabilization effectiveness was more than 90%. The findings of the sequential extraction method of soil treated with Metafix revealed that fractions 1 and 2 of Pb, which correspond to relatively high mobility and bioavailable fractions, were lowered, while the residual fraction (fraction 5) was raised. As a consequence, the order of performance for Pb stabilization in polluted soil was Metafix>AC-2>limestone.

Determination of Heavy Metal Concentration in Herbal Medicines by GF-AAS and Automated Mercury Analyzer

  • Kim, Sang-A;Kim, Young-Jun
    • Journal of Food Hygiene and Safety
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    • v.36 no.4
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    • pp.281-288
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    • 2021
  • This study was conducted to analyze and compare the concentrations of heavy metals in 430 different products of 20 types of herbal medicines available in the domestic market in Korea by Graphite Furnace-Atomic Absorption Spectrometry (GF-AAS) and automated mercury analyzer. The accuracy for lead (Pb), arsenic (As), cadmium (Cd), and mercury (Hg) was in the range 92.67-102.56%, and the precision was 0.21-6.00 relative standard deviation (RSD%), which was in compliance with the Codex acceptable range. Furthermore, the Food Analysis Performance Assessment Scheme (FAPAS) quality control (QC) material showed a recovery range of 96.7-102.0% and 0.33-4.93 RSD%. The average contents (㎍/kg) of Pb, As, Cd, and Hg in herbal medicines were 254.9 (not detected (N.D.)-2,515.2), 171.0 (N.D.-2,465.2), 99.2 (N.D.-797.1), and 6.0 (N.D.-83.6), respectively. Based on the quantitative analysis results, the heavy metal contents of 20 types of herbal medicines distributed in Korea are within the acceptable range according to the standards issued by the Ministry of Food and Drug Safety (MFDS). By using the manufacturer of herbal products as the standard for QC, the Pb, As, Cd, and Hg contents were investigated in the packaging process just before distribution to determine the actual conditions of residual heavy metals in herbal medicines. Thus, these result may contribute to monitoring the QC of herbal medicines distributed in Korea and could provide basic data for supplying safe herbal medicines to the public.

A Experimental Study on the Ready-mixed Shotcrete Using Granulated Blast Furnace Slag (고로슬래그 미분말을 혼입한 레디믹스트 숏크리트의 현장적용성에 관한 실험적 연구)

  • Choi, Hee-Sup;Kim, Dong-Min;Jang, Pil-Sung;Seo, Sin-Seuk
    • Journal of the Korean Geotechnical Society
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    • v.25 no.6
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    • pp.31-45
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    • 2009
  • The aim of this study is to evaluate the applicability of Granulated Blast Furnace Slag to the development of the Powdered Ready-mixed Shotcrete. First of all, after accomplishing SEM analysis and Leaching Test, the laboratory and field experiments for evaluating the utility of Granulated Blast Furnace Slag were performed. As a result of SEM and Leaching test, the environmental stability was confirmed. That is, non-detection of harmful lists and dense shotcrete structure result from mixing Granulated Blast Furnace Slag. As a result of lab. and field test, Blast Furnace Slag is superior to Plain Batch in improving strength and durability. And it will be able to improve to some extent the problem caused by the delayed reaction of existing Granulated Blast Furnace Slag with alkali activated material. Also the proper amount of Granulated Blast Furnace Slag is estimated to be under 30%. Finally, it is possible that Granulated Blast Furnace Slag can apply to economical recycling and development of the Ready-mixed Shotcrete for its price is only about 5% of Silica-finne's price.

Recycling Organic Sludge into Modification Block by Hydrothermal Carbonization (HTC) (열수가압탄화공법을 적용한 유기성 슬러지의 응용 블록 제조에 관한 연구)

  • Hyewon Park;Minah Oh;Seungjin Oh;Woori Cho;Jinman Chang;Jai-young Lee
    • Clean Technology
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    • v.29 no.2
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    • pp.102-108
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    • 2023
  • This study applied a hydrothermal carbonization (HTC) method to carbonize sewage sludge in order to satisfy the criteria of the Waste Management Act for recycled products and to explore the possibility of recycling sludge into modification blocks. Cement was mixed with carbonized sludge generated at the optimal temperature and reaction time during HTC. After that, the compressive strengths of the modification blocks were measured by conducting both a performance and leaching test. The results of the leaching test showed that heavy metals were not detected, and the specific gravity and absorption rates were less than 1.7 and 10%, respectively, indicating that all species satisfied the criteria. The results of the compressive strength test showed that a mixing ratio of 5% and 7% with cement cured for 28 days satisfied the criteria of A, B, and C type blocks but a mixing ratio of 3% with cement did not satisfy the criteria of A type blocks after 28 days. However, after additional curing for 42 days, the mixing ratio of 3% also satisfied the A type block criteria. Therefore, the optimal mixing ratio of carbonized sludge and cement was considered to be between 3% and 5% and confirmed that the modified blocks could be utilized as aggregates.

Investigation of Unintentionally Hazardous Substance in Commercial Herbs for Food and Medicine (유통 식약공용농산물 중 비의도적 유해물질 오염도 조사)

  • Seo, Mi-Young;Kim, Myung-Gil;Kim, Jae-Kwan;Jang, Mi-Kyung;Lee, Yu-Na;Ku, Eun-Jung;Park, Kwang-Hee;Yoon, Mi-Hye
    • Journal of Food Hygiene and Safety
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    • v.33 no.6
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    • pp.453-459
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    • 2018
  • This study was performed to investigate the contamination levels of heavy metals (such as lead, cadmium, arsenic and mercury) and aflatoxin (such as $B_1$, $B_2$, $G_1$ and $G_2$) in commercial herbs for food and medicine. The concentrations of the heavy metals were measured by the ICP-MS and a mercury analyzer. The aflatoxins were analyzed by a HPLC-florescence coupled with photochemical derivatization. The detection ranges of the lead, cadmium, arsenic and mercury were found to be 0.006~4.088 mg/kg, 0.002~2.150 mg/kg, ND~0.610 mg/kg and ND~0.0139 mg/kg respectively. Among the total samples, the 3 samples (2.6%) were not suitable for the specification of cadmium by the MFDS (Ministry of Food and Drug Safety). The 13 samples of the total 117 samples were aflatoxin positive (11.1%). The amount of aflatoxin $G_1$ was $0.7834{\mu}g/kg$ in the Puerariae Radix and aflatoxin $G_2$ were $0.3517{\mu}g/kg$, $0.4881{\mu}g/kg$ in two samples of the Glycyrrhizae Radix et Rhizoma, respectively. The aflatoxins $B_2$ and $G_1$ were simultaneously detected in the 10 Angelicae Gigantis Radix. The detection ranges of aflatoxins $B_2$ and $G_1$ were $0.2324{\sim}1.0358{\mu}g/kg$ and $0.7552{\sim}1.6545{\mu}g/kg$ respectively in Angelicae Gigantis Radix. The results of the current study suggest that continuous monitoring is needed for the proactive management of commercial herbs for food and medicine safety.

Safety and Quality Assessment of Kimchi Made Using Various Salts (소금의 안전성 분석과 김치제조를 통한 품질 평가)

  • Chang, Min-Sun;Cho, Sun-Duk;Bae, Dong-Ho;Kim, Gun-Hee
    • Korean Journal of Food Science and Technology
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    • v.42 no.2
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    • pp.160-164
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    • 2010
  • This study examined the safety of various salts (domestic purified salt, domestic solar salt, imported purified salt, imported solar salt) as well as the effects on the quality of kimchi fermented during 28 days at $4^{\circ}C$. All salts contained DEHP, but ferrocyanide ion and heavy metals (Cd, Pb, As, Hg) were not detected. Following fermentation, the pH of kimchi was decreased during storage, but total acidity and salinity values increased. There was no considerable differences between the various salts. As the fermentation period increased, the lactic acid bacterial counts increased remarkably. Regarding the sensory characteristics of kimchi during storage, the appearance of domestic purified salt was better than that of domestic solar salt following fermentation. Imported salts produced a strong salty taste initially, but domestic refined salt had the highest salty taste at 7 days. Therefore, there were no considerable differences between the various salts.

Manufacturing of Extinguishing Powder of Expanded Glass from Recycling Automotive Glass Powder (자동차 폐유리 분말을 이용한 팽창유리 소화약제의 제조)

  • Duk-Woo, Jeon;Jung-Ho, Park;Yong-Kwon, Lee
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.10 no.4
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    • pp.547-552
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    • 2022
  • In this study, we secured a technology for manufacturing expanded glass of uniform quality by using general tempered glass, that is, window glass, among automotive glass that is scrapped, and verified whether the manufactured expanded glass can be used for lithium battery fire suppression. The process of manufacturing expanded glass using waste glass is generally divided into Crushing → Milling → Granulation → Expansion → Cooling. With several trials a nd errors. It is obtained a yield of 0.5 ø mm to 2 ø mm spherical particles of 80 % or more. By comparing the surface analysis and physical properties, a more suitable sample was selected as a fire extinguishing agent for lithium batteries, and it was confirmed that the result of the adaptability test for lithium battery fire was satisfactory.

The Effects of Physico-Chemical Factors on the Microbial Population in Groundwater (지하수 세균 군집에 미치는 물리화학적 환경요인의 영향)

  • 안영범;김여원;이대영;민병례;최영길
    • Journal of the Korean Society of Groundwater Environment
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    • v.5 no.4
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    • pp.215-222
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    • 1998
  • The objective of this study was to investigate the effects of physico-chemical environmental factors on the changes of bacterial population from two sites used for drinking water and eight sites polluted with various pollutant in Seoul city. In all the stations except for two sites used for drinking water, the concentrations of nitrate- nitrogen and ammonia were in excess of the criteria of groundwater quality by the result of analysis of 40 variations including physicochemical environmental factors, heavy metals, and bacterial populations. The numbers of total bacteria, heterotrophic bacteria and functional groups of bacteria were ranged from 5.1 to 41.4${\times}$10$\^$5/cells/ml and from 0.01 to 29.6${\times}$10$^4$cfu/ml, respectively. The activities of extracellular enzymes showed the ranges of 0.005∼11.3${\mu}$M/l/hr and its order to lipase, phophatase, ${\beta}$-glucosidase, cellulase, chitinase, amylase. The results of correspondence and multidimensional scaling analysis between bacterial populations and its physico-chemical environmental factors were explained the effects of physico-chemical environmental factors according to site characters and separated four group, which is accord with potential pollutants at wells.

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A Study on Mineral Contents of the Underground Vegetables Produced in Korea harvested in different times (국내산 식용 지하 부위 채소의 수확시기에 따른 무기 성분 분석에 관한 연구)

  • 장경미;이미순
    • Korean journal of food and cookery science
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    • v.15 no.5
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    • pp.545-549
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    • 1999
  • This study was performed to estimate mineral contents of some underground vegetables including potatoes, sweet-potatoes, carrots, radishes, onions, garlics, gingers, burdocks, and lotus roots produced in Korea using ICP-AES (Inductively Coupled Plasma-Atomic Emission Spectrometry). According to the measurement, the amounts of Na, Mg, Al, K, Ca, Mn, Fe, Zn, and P in underground vegetables are variable depending upon harvest time and individual plants. It was noticeable that the carrots showed quite higher amounts of Na compared to other underground vegetables. The amounts of Cd, Ba, Sr and Pb appeared to be below hazard levels. In the near future we expect that this study can be used to calculate the mineral intake from underground vegetables.

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