• Title/Summary/Keyword: 중금속 분석

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Contents of Inorganic Elements in Shellfish and Geochemical Characteristics of Surface sediments on the West Coast of Korea (서해연안 패류의 성분원소 함량 및 퇴적물의 지화학적 특성)

  • Choi, Yoon Seok;Park, Kwang Jae;Song, Jae Hee;Yoon, Sang Pil;Chung, Sang Ok;An, Kyoung Ho
    • The Korean Journal of Malacology
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    • v.28 no.3
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    • pp.225-232
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    • 2012
  • In order to evaluate the relationship of between the contents of inorganic elements in shellfish and surface sediments, we measured the concentration of inorganic elements (As, Ca, Cd, Cr, Fe, Hg, Li, Mn, Ni, P, Pb, Zn) in various shellfish and surface sediments of research area. The enrichment factor (EF) and the index of accumulation rate (Igeo) of the metals showed that the research areas can be classified as moderately polluted, or unpolluted. And also we measured the geochemical characteristics of surface sediments(grain size, chemical oxygen demand (COD), ignition loss (IL) and acid volatile sulfide (AVS). The grain sizes for research areas of surface sediment were similar the ratio of silt and clay in comparison with other sites. The COD and IL in surface sediment ranged from 5.41 to 14.06 mg/g. d.w. (mean $8.78{\pm}3.16$ mg/g d.w.) and from 0.92 to 3.17% (mean $2.08{\pm}0.86%$), respectively. Siginificant differences in metal concentrations also were determinated in the shellfish tissue among the different sites. However, except for metals(Mn, Zn), which showed some elevation of concentrations, the variations in the shellfish tissue were not related to variations in the sediment.

A Study on the Damage Degree of Hair Dye Treatments and the Impact of Heavy Metals (트리트먼트(Treatment)를 이용한 모발 염색이 손상도와 중금속 함량에 미치는 영향)

  • Lee, Tae-Sook;Kim, Younghee
    • Journal of Digital Convergence
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    • v.15 no.10
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    • pp.551-557
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    • 2017
  • Hair beauty treatments that can express individuality have increased and diversified. However, their repetitive use has also brought about hair damage. To reduce such damage, the importance of hair treatments when receiving chemotherapy has magnified greatly. In this study, the hair (normal hair, NH) of 5 people in their 20s has been collected and observed with SEM before dyeing (NH), after dyeing (DH) and after dyed and treated (DTH) to measure the hair's morphological damage and mineral content. SEM observation results revealed that, in DTH, a cuticle-like arrangement appears almost uniformly, the hair settles, the lines are smooth, and the damage degree is low. Regarding mineral content, the concentration of minerals was generally balanced. However, in the observation of toxic minerals and minerals found in large amounts, the concentration of Ba, Na, Ca, and Mg was higher than the balance range in NH, DH, and DTH.

A Biogeochemical Study on the Heavy Metal Leaching from Coal Fly Ash Disposed by Dangjin Fire Plant in the Coastal Environment (당진화력발전소의 석탄회 연안매립과 중금속 원소의 용출에 대한 생지화학적 연구)

  • Cho, Kyu-Seong;Roh, Yul;Chung, Duk-Ho
    • Journal of the Korean earth science society
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    • v.28 no.1
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    • pp.112-122
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    • 2007
  • It is known that coal-derived fly ashes have the unique chemical composition and mineralogical characteristics. Since iron oxides in coal fly ash are enriched with heavy metals, the subsurface media including soils, underground water, and sea water are highly likely contaminated with heavy metals when the heavy metals are leached from fly ashes by water-fly ash interactions. The purpose of this study was to investigate how indigenous bacteria affect heavy metal leaching and mineralogy in fly ash slurry during the fly ash-seawater interactions in the ash pond located in Dangjin seashore, Korea. The average pH of ash pond seawater was 8.97 in nature. Geochemical data showed that microbial activity sharply increased after the 7th day of the 60-day course batch experiments. Compared with other samples including autoclaved and natural samples, ${SO_4}^{2-}$ was likely to decrease considerably in the fly ash slurry samples when glucose was added to stimulate the microbial activity. Geochemical data including Eh/pH, alkalinity, and major and trace elements showed that the bacteria not only immobilize metals from the ash pond by facilitating the chemical reaction with Mn, Fe, and Zn but may also be able to play an important role in sequestration of carbon dioxide by carbonate mineral precipitation.

Oceanographic Conditions in Relation to Laver Production in Kwangyang Bay, Korea (광양만의 김 생산과 양식장환경과의 관계에 대하여)

  • HONG Jae-Sang;SONG Choon Bok;KIM Nam-Gil;KIM Jong Man;HUH Hyung Tack
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.20 no.3
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    • pp.237-247
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    • 1987
  • The present study deals with the physico-chemical and meteorological conditions in Porphyra-cultivation ground to determine the relationship between laver production and its environmental factors in Kwangyang Bay from January to April in 1986. As a result, major environmental factors which are thought to have a great influence upon the poor harvest during the cultivation period are as follows; 1) the excessive rainfall in the beginning of cultivation period 2) the accumulation of suspended matters on the thallus of laver 3) the decrease of current velocity and the stagnation of the water in the cultivation ground.

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Stabilization of Heavy Metals-contaminated Soils Around the Abandoned Mine area Using Phosphate (인산염을 이용한 휴.폐광산 주변 중금속 오염토양의 안정화처리에 관한 연구)

  • Lee, Eun-Gi;Choi, Sang-Il
    • Journal of Soil and Groundwater Environment
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    • v.12 no.6
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    • pp.100-106
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    • 2007
  • The objective of this study was to evaluate the efficiency of $(NH_4)_2HPO_4$, $Na_2HPO_4{\cdot}12H_2O$, $CaHPO_4{\cdot}2H_2O$, $Ca(H_2PO_4)_2{\cdot}H_2O$ and $H_3PO_4$ for the stabilization of soils contaminated with multi-metals containing Pb, Cd and As. The application rate of stabilizers to soils was determined based on $PO_4/Pb_{total}$ molar ratio of 0.5, 1, 2, 4. The results of Korea Standard Test and TCLP (EPA Method 1311) showed the reduction of metal leachabilities below the regulatory limits for Pb and Cd when $H_3PO_4$ and $Ca(H_2PO_4)_2{\cdot}H_2O$ were applied. However, stabilization efficiency for Cd was low and in case of As leaching concentration increased rather. It is considered that $PO_4$ reacted effectively $Pb^{2+}$ due to leaching Pb under low pH condition created by adding $H_3PO_4$. Accordingly Pb was stabilized by dissolution and precipitation of hydroxypyromorphite. From the change of metals fraction using sequential extraction procedure when $H_3PO_4$ applied as a stabilizer, we confirmed that residual fraction increased more than 60% and this result was accorded with XRD analysis that detected only hydroxypyromorphite peak in $H_3PO_4$.

Seasonal Variations in the Nutritional Compositions and Heavy Metals in Two Demersal Fish, Liparis tessellatus (Cubed Snailfish) and Hemitripterus villosus (Shaggy Sea Raven) (동해안 저서어 곰치와 풍덕구이의 영양성분 및 중금속의 계절적 변화)

  • Lee, Byung-Yong;Surh, Jeong-Hee
    • Korean Journal of Food Science and Technology
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    • v.43 no.3
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    • pp.282-290
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    • 2011
  • Two species of demersal fish, Liparis tessellates (cubed snailfish) and Hemitripterus villosus (shaggy sea raven), were investigated in relation to seasonal chemical composition. Total fat contents of the two fish were very low and were not appreciably different throughout the year, whereas their fatty acid compositions were significantly different depending on season. Noticeable changes in the moisture and protein contents in the two fishes were observed before and after spawning. Cubed snailfish showed relatively high amounts of total amino acids and free amino acids during summer months, whereas the levels of those in shaggy sea raven remained relatively unchanged throughout the year. Regardless of season, the major fatty acid of the two fishes was palmitic acid and most of polyunsaturated fatty acids (PUFAs) were n-3 PUFAs. Lead was over the legislative limit in some samples of the two fishes.

Heavy Metals Contens and Organochlorine Pestieide Residues in Commercial Salted and Fermented Sea Foods (시판 젓갈중의 중금속 및 유기염소 잔유농약의 함량)

  • Ryu, Beung-Ho;Ha, Mi-Suck;Kim, Dong-Seuk;Sin, Dong-Bun;Hur, Ho-Jang;Jung, Jong-Soon
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.15 no.3
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    • pp.207-212
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    • 1986
  • Heavy metal contents and residues level of organochlorine pesticides were analyzed for commercial salted and fermented sea-food which bought from pusan area. Heavy metal contents ranged from 0.11 to 0.46 ppm of mercury, trace to 1.1 ppm of lead, 0.01 to 0.34 ppm of cadmium, 0.4 to 5.98 ppm of cupper, 0.16 to 4.5 ppm of zinc, trace to 0.49 ppm of manganese and trace to 1.35 ppm of arsenic. Residue level of organochlorine pesticides in salted and fermented sea-foods ranged from 0.3 ppb to 1.825 ppb of total BHC Organochlorine pesticides of DDE, dieldrine, pp'-DDD and pp'-DDT were detected a small amount from Ge jeot and Myeol-Chi jeot. In conclusion. the heavy metal and levels of organochlorine pesticides residues were safety to eat the salted and fermented sea foods.

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Heavy Metal Contents and Antioxidant Activity and Cytotoxic Effect of Red Sea Bream (Pagrus major): Comparative Studies in Domestic and Imported Red Sea Bream (Pagrus major) (국내산 및 수입산 참돔의 중금속 함량 및 항산화 활성과 세포독성 효과 비교)

  • Hwang, Seong Yeon;Bae, Jin Han;Lim, Sun-Young
    • Journal of Life Science
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    • v.25 no.4
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    • pp.450-455
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    • 2015
  • This study compared the heavy metal contents and the effects of extracts from domestic and imported red sea bream on the antioxidant activity and cytotoxicity of human cancer cell lines. The antioxidant activity was measured using the fluorescently sensitive dye, 2’-7’ dichlorofluorescein-diacetate (DCFH-DA), and antiproliferative activity against AGS human gastric adenocarcinoma and HT-29 human colon cancer cell lines, which was determined by the 3-(4,5-dimethylthiazol-2-yl)-2,5-diphenyltetrazolium bromide (MTT) assay. Domestic red sea bream had a higher mercury content when compared to imported red sea bream, but there was no significant difference in the lead content. Treatments with acetone/methylene chloride (A+M) and methanol (MeOH) extracts from domestic and imported red sea bream dose-dependently decreased the H2O2 induced ROS production, compared to the control. The cell viability showed that treatments with the A+M and MeOH extracts had cytotoxicity in the growth of AGS and HT-29 cancer cells. In the case of AGS, the extracts from the domestic red sea bream were higher in inhibiting cancer cell growth, compared to imported red sea bream. Our results demonstrate that the heavy metal contents of domestic and imported red sea bream were below the limit of the Food Code of Korea. The results of the biological activities indicate that the antioxidant activity of extracts from imported red sea bream was more effective, while the extracts from the domestic red sea bream were stronger in cytotoxic activity.

A Study on the Constituents of the Pollen of Pinus densiflora Siebol et Zuccarini and Pinus rigida Miller -Proximate Composition, Mineral, Heavy Metal, Vitamin and Free Sugar Contents- (적송화분과 리기다송화분의 성분 조성에 관한 연구 -일반성분, 무기질, 중금속, 비타민, 유리당의 함량-)

  • 김혜자
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.21 no.2
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    • pp.201-206
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    • 1992
  • Pinus pollen is used as the chief ingredient for Song-wha-dashik (Korea's traditional pattern-pressed candy). It has been the food stuff indispensable especially on the occasion of performing ancestral rites and holding a banquet since Shilla and Koryo Dynasty. In this paper, therefore, a new examination is made of the nutritive ingredients of the very Pinus pollen. Analysis has been made of the proximate composition, minerals, heavy metals, vitamins and free sugars of the Pollen of both Pinus densinora Siebol et Zuccarini and Pinus rigida Miller. In the proximate composition, Pinus rigida Miller is high except in free sugar ; crude ash (4.0%), crude protein (15.0%), crude fat (2.5%), crude fiber (17.5%). A lot of minerals have been found in both the samples. They contain Mg, Cl, Ca, Fe, Mn, Na, Zn, etc. In heavy metals, both the samples contain the same quantity of Cd(0.3 ppm) and the contents of Pb, Cu, and As are lower than the maximal limit permitted for food stuff. The contents of vitamin B$_1$, B$_2$, vitamin C are a little higher in Pinus rigida Miller : in vitamin E, on the contrary, Pinus densiflora Siebol et Zucarini (1.6 mg) doubles Pinus rigida Miller (0.8 mg). In free sugars, the results is as follows : 6.6%/6.9% in sucrose : 0.2% in fructose : 2.1% /2.9% in glucose respectively.

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Applicability of Natural Zeolite with Different Cation Exchange Capacity as In-situ Capping Materials for Adsorbing Heavy Metals (중금속 흡착을 위한 원위치 피복소재로서 천연제올라이트의 양이온교환용량에 따른 적용성 평가)

  • Kang, Ku;Shin, Weon-Ho;Hong, Seong-Gu;Kim, Young-Kee;Park, Seong-Jik
    • Journal of Korean Society of Environmental Engineers
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    • v.39 no.2
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    • pp.51-58
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    • 2017
  • We investigated the efficiency of natural zeolite with different cation exchange capacity (CEC) as capping material for the remediation of marine sediments contaminated with heavy metals. Three different zeolite with high CEC (HCzeo, 163.74 cmolc/kg), medium CEC (MCzeo, 127.20 cmolc/kg), and low CEC (LCzeo, 70.62 cmolc/kg) were used. The surface area of the zeolite was in decreasing order: HCzeo ($59.43m^2/g$) > MCzeo ($52.10m^2/g$) > LCzeo ($10.12m^2/g$). The results of mineralogical composition obtained from X-ray diffraction (XRD) show that LCzeo was mainly composed of quartz and albite. In the XRD result of MCzeo and HCzeo, the peaks of clinoptilolite, heulandite, and mordenite were also observed along with that of quartz and albite. Sorption equilibrium onto the HCzeo, MCzeo, and LCzeo was reached in 6 h at initial concentration of 10 mg/L and 100 mg/L. Higher adsorption of Cd and Zn onto the zeolite with higher CEC were achieved but adsorption of Cu and Ni were not dependent on the CEC of zeolite. It can be concluded that the zeolite with high cation exchange ability is recommended for the contaminated sediments with Cd and Zn but the inexpensive zeolite with low CEC for Cu and Ni.