• Title/Summary/Keyword: 중금속 분석

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Contents of Arsenic in Some Fisheries Caught in Western Coast (서해안 지역 수산물의 비소함량에 관한 연구)

  • 김애정;김선여;이완주;박미정
    • Journal of Food Hygiene and Safety
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    • v.13 no.3
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    • pp.201-205
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    • 1998
  • In Korea, a small proportion of fishery products are contaminated with a considerable amount of potentially hazardous contaminants. So, there is generally a high risks to consumers. Inorganic contaminants with the greatest potential for toxicity are Sb, As, Cd, Pb, Hg, Se and the Sulfides. As appears to be much more variable than the others. This study was performed to assess the levels of the As in fisheries caught from the waters of the western coast of Korea. The samples included 26 kinds of fishes, 18 kinds of Mollusca, 3 kinds of Crustacea and 7 kinds of salted fishes. The Moisture content of molluscans was significantly higher than that of others (p<0.05). And the As contents of crustaceans were significantly higher than those of fishes, molluscans and salted fishes (p<0.05). The As content of Turban shell was 51.62 ppm, which was the highest among the samples. Also, the As contents of eel, cuttle fish and blue crab were found to be higher than in other fisheries. This variability offers a solution for the reduction of exposure to As through restricting the harvest of aquatic organism from the western coast of Korea.

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Operation of Sewage Sludge Composting Plant(Capacity of 1 ton/day) (1톤/일 처리규모의 하수슬러지 퇴비화 실증운전)

  • Joung, Kyong-Chul;Kwak, No-Hyuk;Park, Sung-Hee;Phae, Jae-Kuen
    • Journal of the Korea Organic Resources Recycling Association
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    • v.8 no.2
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    • pp.77-84
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    • 2000
  • Aim to get operation factors, an In-vessel Composting of Wastewater Sludge was operated. The composting equipment is consisted of three chamber, 1st, 2nd and 3rd consequently. In the results, the temperature of fermentation had shown that 1st fermentation chamber(F/C) temperature was higher than that of 2nd and 3rd fermentation chamber. The temperature was steady in all steps during the sludge being composted, the ranges of each step were $50^{\circ}{\sim}59^{\circ}C$ of 1st F/C, $41^{\circ}{\sim}50^{\circ}C$ of 2nd F/C, and $32^{\circ}{\sim}37^{\circ}C$ of 3rd F/C. Organic material content of the end product was 28% and that of pH was 7.5. Properties of the compost which have been composted on optimized condition, were shown that is acceptable to use as a fertilizer. Even in the winter time, the composting system was working well without any trouble. According to result of investigation, the end-product of the system was satisfied with the standard for a fertilizer usage. HRT(hydraulic retention time) of entire process was appropriated to be 14 days(0.9 days at drying and 3.5, 4.4, 5.2 days at each step of fermentations, respectively).

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Microcosm Studies of Nanomaterials in Water and Soil Ecosystems (수생태 및 토양생태계에서 나노물질의 마이크로코즘 연구)

  • Yoon, Sung-Ji;An, Youn-Joo
    • Journal of Korean Society of Environmental Engineers
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    • v.34 no.4
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    • pp.288-294
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    • 2012
  • The current growth of nano-industries has resulted in released nanoparticles entering into water and soil ecosystems via various direct or indirect routes. Physicochemical properties of nanoparticles differ from bulk materials, and nanomaterials influence the fates of nanoparticles and the interactions of living or non-living things in the environment. Microcosm analysis is a research methodology for revealing natural phenomena by mimicking part of an ecosystem under controlled conditions. Microcosm study allows for the integrated analysis of toxic effects and fates of nanoparticles in the ecosystem. Ecotoxicity studies of nanomaterials are steadily increasing, and microcosm studies of nanomaterials are currently beginning to surface. In this study, microcosm studies of nanomaterials in water and soil ecosystems were extensively investigated based on SCI(E) papers. We found that the microcosm studies have been reported in 12 instances, and mesocosm studies have been reported in only once until now. Advanced research was mostly evaluated at the microorganism level. But integrated analysis of nanotoxicity is required to research the interactions based of various species. Thus, our studies analysed the trend of microcosm studies on nanomaterials in water and soil ecosystems and suggested future directions of microcosm research of nanomaterials.

Effect of Immobilization Method in the Biosorption and Desorption of Lead by Algae, Chlorella pyrenoidosa (Chlorella pyrenoidosa에 의한 납 흡.탈착시 고정화 방법의 영향)

  • Shin, Taek-Soo;Lim, Byung-Seo;Lee, Sang-Woo;Rhu, Kwon-Gul;Jeong, Seon-Ki;Kim, Kwang-Yul
    • Journal of Korean Society of Environmental Engineers
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    • v.31 no.8
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    • pp.663-672
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    • 2009
  • In this studies, the adsorption test using Chlorella pyrenoidosa was conducted to examine the effect of Pb adsorption according to various immobilized methods such as Ca-alginate, K-carrageenan, and Polyacrylamide. From the results, the duration to need to reach adsorption equilibrium was delayed according to the immobilization. And, the higher adsorption capacity of immobilized Chlorella pyrenoidosa was represented in the higher concentration of Pb, the smaller amount of immobilizing agent, and the higher pH of solution. The maximum adsorption capacity of Pb was shown in the adsorption test using Chlorella pyrenoidosa immobilized with Ca-alginate even though it was sensitive pH. The adsorption results properly represented with Freundlich isotherm equations. And, pseudo second-order chemisorption kinetic rate equation was applicable to all the biosorption data over the entire time range. The FT-IR analysis showed that the mechanism involved in biosorption of Pb by Chlorella pyrenoidosa was mainly attributed to Pb binding of carbo-acid and amide group. Adsorbed Pb on immobilized Chlorella prenoidosa was easily desorbed in the higher concentration of desorbents(NTA, HCl, EDTA, $H_2SO_4,\;Na_2CO_3$). Among the several desorbents, NTA showed the maximum desoption capacities of Pb from Chlorella pyrenoidosa immobilized with Ca-alginate and K-carrageenan and EDTA was the most effective in Chlorella pyrenoidosa immobilized with polyacrylamide. The desoprtion efficiency in the optimum condition was 90.0, 83.0, and 80.0%, respectively.

Nondestructive Deterioration Diagnosis for the Former Ore Dressing Plant in the Yongwha Mine of Registered Cultural Property No. 255 (등록문화재 제255호 영양 구 용화광산 선광장의 비파괴 훼손도 진단)

  • Chun, Yu Gun;Lee, Chan Hee
    • Journal of Conservation Science
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    • v.28 no.3
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    • pp.235-245
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    • 2012
  • Nondestructive deterioration diagnosis has been carried out for the former ore dressing plant of the Yongwha mine in Yeongyang (Registered Cultural Property No. 255). Deterioration rates about organic contaminant and soil of the upper part (7 to 13 layer) indicate higher than the lower part (1 to 6 layer) of the ore dressing plants. By contrast, deterioration rates such as crack, break out and discoloration of the lower part indicate very higher than the upper part. It is estimated that the plants of the lower part that mechanical and chemical process had been done for flotation were damaged severely by physicochemical weathering with reaction of concrete and chemical solution. As results of ultrasonic velocity measurement, average p-wave velocity of plants were measured 2,462m/s (compressive strength $529kgf/cm^2$). As for the analytical results of surface contaminants and soil compositions using P-XRF, they were identical with major elements (Cu, Zn, Pb, Fe and As) of ore minerals from the Yongwha mine. Therefore, the ore dressing plant should be treated by phytoremediation with conservation because heavy metals could impinged upon plants and natural environment.

Characteristics of Trace Element Concentrations in Dust by Facilities and Areas in Daegu, Korea (대구지역 축적먼지 중 미량원소성분의 시설별 및 지역별 농도분포)

  • Song, Hee-Bong;Do, Hwa-Seok;Kwak, Jin-Hee;Kim, Jong-Woo;Kang, Jae-Hyoung;Phee, Young-Gyu
    • Journal of Korean Society of Environmental Engineers
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    • v.32 no.3
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    • pp.287-295
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    • 2010
  • Dust samples have been collected from streets, schools, subway stations and households in Daegu metropolitan city. Samples were sieved through a 100 ${\mu}m$ mesh and the concentration of 14 elements have been determined using by ICP after acid extraction. Results showed that Ca, Fe, K, Mg, Mn, Na and V were influenced by natural sources while Cd, Cr, Cu, Ni, Pb and Zn were influenced by anthropogenic sources. The measured values were remarkably higher in components from natural sources than in components from anthropogenic sources. In particular, school dust had higher levels of Ca and Pb and subway station dust had higher levels of Cu and Zn. The percentage composition of chemicals from subway stations, households, and schools were remarkably higher in components from anthropogenic sources than that from streets. It is well recognized that anthropogenic sources were affected by indoor dust. Results of pollution index of hazardous heavy metals indicated that schools, households, and subway stations were more contaminated than streets and urban areas typically had higher pollution index than rural areas. The correlation analysis among trace elements seem to suggest that there were correlations between components of soil/road dust resuspension, and components of waste incineration and fuel combustion.

The geochemical characteristic and quality assessment of surface sediments in Sihwa Lake (시화호 표층퇴적물의 특성과 오염도 평가)

  • Ju, Jae Sik;Son, Moonho;Cho, Hyeon-Seo;Kim, Pyoung-Joong
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.17 no.12
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    • pp.333-338
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    • 2016
  • The purpose of this study was to understand the pollution level of the surface sediment of Sihwa Lake by assessing its geochemical characteristics and investigating the spatial distribution of trace metals and organic matter. In the surface sediment of Sihwa lake, the mean grain size was between 2.94 and 6.35 Ø and the main type of sediment was sandy silt. The concentrations of As, Co, Cr, Ni, V and Li among the metal elements in the surface sediment were correlated with the mean crust concentration (p<0.05). Based on the strong correlation between the metals (Cd, Cu, Pb and Zn) and organic matter (Ignition Loss), the concentrations of these metal elements seem to be controlled by the organic matter dilution effect. The trace metal pollution level, determined by applying the Republic of Korea Marine environmental standard and the US National Oceanic and Atmospheric Administration's sediment quality guidelines, showed the pollution level of As to be either close to or in excess of the above-mentioned standards at almost all levels. The enrichment factor and geoaccumulation index of As showed that there was an incremental increase of pollution by elements other than V, Cr, Co, Fe, Al and Mn. Moreover, the nearby industrial area and dike were more polluted than the other areas, so the surface sediments in Sihwa lake should be monitored by taking into consideration the geological variations.

The Dissolution Characteristics of Metal Compounds in Soil Application Experiment using Sewage Treatment Sludge mixed with Oyster shells (하수슬러지 및 굴껍질의 토지주입시 금속성분의 용출특성에 관한 연구)

  • Kim, Chul;Moon, Jong-Ik;Shin, Nam-Cheol;Ha, Sang-An;Sung, Nak-Chang;Huh, Mock
    • Journal of the Korea Organic Resources Recycling Association
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    • v.9 no.2
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    • pp.71-76
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    • 2001
  • Recently, sludge disposal becomes one of the most serious environmental problems. Because the landfilling and ocean dumping of sludge materials will be prohibited in the near future, the proper treatment?disposal methods should be investigated. Also, oyster shells, piled at the coast, cause adverse effects in coastal fishery, public water surface, natural landscape, public health and so on. Thus, the purpose of this study is to evaluate the dissolution characteristic of metal compounds during soil application experiment using sewage treatment sludge mixed with oyster shells. The dissolution experiment conducted 100days under artificial rainfall and farming soil, mixed with sewage treatment sludge and oyster shells, was put into the pots(approx. 0.5L). The results from dissolution experiment as follows. 1. K, Na was $5{\sim}20mg/{\ell}$, and Ca was less than $90mg/{\ell}$. 2. Heavy metals such as Cd, Cu, As, Pb, Cr, Hg are dissoluted far less than the soil pollution guideline. The application of sewage sludge mixed with oyster shells increases pH(soil acidity)and buffer capacity(CEC) of farming soil, and heavy metals are thought to be attached to soil as insoluble forms.

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The Physico chemical Characteristic of MSW and sludge in west area of Kangwondo (강원도 영서지역 생활폐기물 및 슬러지의 물리·화학적 특성에 관한 연구)

  • Lee, Geon-Joo
    • Journal of the Korea Organic Resources Recycling Association
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    • v.12 no.4
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    • pp.112-120
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    • 2004
  • In this study, the physico chemical characteristic of MSW and sludge in west area of Kangwondo was investigated for database, managing the waste and waste treatment facility. The sampling sites were selected as 6 different MSW generation area and 2 sludge generation area. it is necessary to measure the characteristics of MSW to build the data-base. The year of 2000, 197.4ton/day of MSW which was generated in this area. This MSW was composed of 26.6% food wastes, 24.2% of papers, 22.8% of plastics & vinyls, 9.6% of textiles, 3.80% of wood, 2.8% of rubbers & leathers and others, respectively. Most of MSW are composed of food, paper and plastic waste and combustible waste is more than 89%. The generation of papers and vinyls are almost same for different seasons For 3-components of MSW, moisture is 40.2%, combustible component is 52.1% and ash is 7.7% and for 3-components of sludge, moisture is 83.3%, combustible component is 7.7% and ash is 9%. The chemical element has the high order of carbon(51.6%), oxygen(38.6%), hydrogen(7%) on the dry basis of wastes. And the high heating value of MSW is 4989.4 Kcal/kg sludge is 4428.04 Kcal/kg and low heating value of the MSW which is measured by calorimeter is 2032.88kcal/kg. From the leaching test of wastes, there is no heavy metals.

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Heavy Metal Concentrations in Three Shorebird Species in Saemankeum Mudflat, Korea (대한민국 새만금 갯벌지역에 도래하는 도요류 3종의 중금속 농도)

  • Lee, Hwa-Su;Kim, Jung-Soo;Koo, Tae-Hoe
    • Korean Journal of Environment and Ecology
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    • v.22 no.3
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    • pp.241-248
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    • 2008
  • We studied concentrations of trace elements such as iron, zinc, copper, lead and cadmium in three shorebird species from Saemankeum mudflat, Korea$(1999{\sim}2000)$, and also analysed correlations between elements in livers. Iron(ANOVA, p=0.018), copper(ANOVA, p=0.043), lead(ANOVA, p=<0.001) and cadmium (ANOVA, p=0.016) concentrations significantly differed among shorebird species, but zinc concentrations wasn't different among species. We suggested that iron, zinc, and copper concentrations were within a range for normal and are maintained by normal homeostatic mechanisms for wild birds. Lead concentrations in Great Knots Calidris tenuirostris$(5.76{\pm}2.14{\mu}g/dry\;g)$ were at the background level but Red-necked Stints Calidris ruficollis$(29.4{\pm}10.6{\mu}g/dry\;g)$ and Terek Sandpipers Xenus sinereus$(15.9{\pm}11.9{\mu}g/dry\;g)$ were within the exposed level for wild birds. In particular, Red-necked Stints were nearly poisoned level. Cadmium concentrations in Terek Sandpipers and Great Knots were at the background concentration, but Red-necked Stints were greater than the poisoned level$(3{\mu}g/dry\;g)$. We found significantly correlations between lead and cadmium concentrations, but other elements didn't find.