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Application of Rare Earth Compounds for the Treatment of Phosphate and Fluoride in Wastewater (인산염 및 불소폐수 처리제로서의 희토류 화합물 적용에 관한 연구)

  • Kim, Jin-Wha;Shin, Sung-Hye;Song, Hye-Won;Kim, Dong-Su;Woo, Sang-Mo;Kwon, Young-Shik
    • Journal of Korean Society of Environmental Engineers
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    • v.22 no.6
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    • pp.1127-1137
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    • 2000
  • Applications of lanthanum ion and crude rare earth chloride to the phosphate wastewater and fluorine wastewater, respectively, as treatment agents were studied. For the investigation of phosphate removal characteristics according to the amount of lanthanum ion, initial phosphate content was decreased by about 50% when molar ratio of [$La^{3+}$]:[$PO_4{^{3-}}-P$] was 0.25 and nearly all of phosphate was removed when the molar ratio of [$La^{3+}$]:[$PO_4{^{3-}}-P$] to be doubled. The removal of phosphate by $La^{3+}$ appeared to reach equilibrium state rapidly, and it was exothermic reaction since the removed amount of phosphate was diminished somewhat when the reaction temperature was increased. The zeta potential of combined particulate compound of lanthanum ion and phosphate was located for its isoelectric point at pH 5.5 and the turbidity of treated wastewater was found to vary according to the pH in a similar manner as the absolute value of zeta potential of the combined particulate compound did. For the treatment of fluorine wastewater by crude rare earth chloride, the remaining fluorine content after treatment decreased as the dosage of crude rare earth chloride increased. Whereas, the turbidity of treated wastewater and the amount of sludge generated were shown to increase as more crude rare earth chloride was added. The remaining fluorine content and the turbidity of treated wastewater were decreased and the amount of sludge generated was observed to increase according the increase of coagulant dosage under the condition of constant input of crude rare earth chloride.

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Formation and Crystallization of Calcium Carbonate in $C_2H_5OH-Ca(OH)_2-CO_2$ System by Ceramic Bubble Plate Reactor. (Ceramic Bubble Plate를 이용한 $C_2H_5OH-Ca(OH)_2-CO_2$계의 탄산칼슘 생성 및 결정화 연구)

  • Ahn, Ji-Whan;Park, Chan-Hoon
    • Resources Recycling
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    • v.5 no.3
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    • pp.56-64
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    • 1996
  • C,H,OH system is widely used for producing synthetic beverages and pharmaceuticals. Calcium hydroxide suspension was used to callhol the morphology of calcium carbonate, and the charactenstics of the formahan and crystsllizatian of calcium cilrbonate by adding ethylenc glycol were determined A reaclor was made with attaching a ceramic bubble plate, and lhe eleclrical conductivity was continously monitored during the rcaction with CO, gas. A part of the suspension was separated and powdered at the transition point. XRD and electron microscopic observation showed that the intermedmte and final products were vilterite, ;~r;lganite and calcite. In this study, the volumc of the ethylene glycol added to CH,OH was fixed a1 10 vol\ulcornerh. The valumc of the suspension was 500 ml, and the changes oi characteristics were shdied along with variims cnntents(l0-50 g) of calcium hydroxide. Except m the case of 10 g of calcium hydroxide at the crystallization stagc, all of products showed gelation. Tne marc the calcium hydroxide the shorter the formation time. Alsa. the farmalion of spherical valcrile ivas obsemcd when 30 g Ca(OH), was added. Tne vaterite(a compound material) can bc synthesised under alnbienl pressure and lempcmhre m a C,H,OH system by morphology control. Even though the vateritc was meta-stable phasc and could bc changed to calcitc easily, the stable and spherical vateritc was observed by using G5 glass fillers and vacuum dricrs.

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Field Variability and Variable Rate Fertilization of Nitrogen in a Direct Seeding Paddy for Precision Agriculture (정밀 농업을 위한 직파 벼 재배 논에서 포장 변이성 조사와 질소의 변량 시비)

  • Jung, Yeong-Sang;Lee, Ho Jin;Chung, Ji-Hoon;Park, Jeong-Geun;Kang, Chang-Sik
    • Korean Journal of Soil Science and Fertilizer
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    • v.38 no.4
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    • pp.202-210
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    • 2005
  • Since understanding on spatial variability of a field is essential to pursue precision agricultural technology, a field study for field variability and variable rate fertilization of nitrogen in a direct seeding paddy was attempted. Variable rate application of nitrogen was designed with soil test, and field application was tested in a direct seeding paddy in the Kimje, Jeonbuk, Korea. The grid samples of soil was collected from the field of which unit size was 35 m by 112 m on February before irrigating of the field. Soil organic matter, available phosphate and silicate, and extractable potassium were analyzed. Variable rate fertilizer recommendation maps of nitrogen for high yielding, HY, and low input sustainable agriculture, LISA, were derived based on the soil analysis. Direct seeding of rice was performed for variable rate treatment, VRT, for the experimental plot in 2001 and 2002, and so did for three volunteer farmers' field in 2003. Yield mapping was performed by harvesting. Economic feasibility of direct seeding of rice by variable rate fertilization was evaluated. Though increased yield of variable rate application and benefit of reducing fertilizer use and environmental impact, the cost for soil test exceeded the total reduced fertilizer cost.

Study on No-tillage Silage Corn Production with Legume Hairy Vetch (Vicia villosa Roth) Cover II. Changes of yield and nitrogen upake of corn by N fertilizer and hairy vetch cover (헤어리베치 피복을 이용한 옥수수 무경운 재배에 관한 연구 II. 질소시비 및 헤어리베치 피복에 의한 옥수수의 수량 및 질소 흡수량의 변화)

  • 서종호;이호진
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.18 no.2
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    • pp.123-128
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    • 1998
  • Legume winter cover crop hairy vetch(Vicia villosa Roth, HV) can supply mineral nitrogen for silage corn by HV cover killed. The purphose of this study was to understand changes of soil mineral N, yield and N uptake of silage corn by N level (0, 135kgFN/ha) and cover cmp(no cover crop: NCC, hairy vetch cover crop: HVC) at field of Crop Experiment Station in 1996. HV growth decreased soil mineral N concentration before seeding corn, but killed HV cover increased concentration of soil mineral N at surface soil (0~7.5cm) at six-leaf stage of corn. Total dry matter(DM) and N uptake of corn averaged over N level was more decreased in HVC than in NCC at silk stage, but N uptake of corn after silk was more increased in HVC than in NCC by N mineralized fiom HV killed, especially in OkgFNJha. N fertilization increased total DM and and N uptake of corn averaged over cover crop, especially more increased the DM and N uptake before silk stage. Early application of N fertilizer was recommendable in netillage silage corn using hairy vetch cover crop.

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Distributed Trust Management for Fog Based IoT Environment (포그 기반 IoT 환경의 분산 신뢰 관리 시스템)

  • Oh, Jungmin;Kim, Seungjoo
    • Journal of the Korea Institute of Information Security & Cryptology
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    • v.31 no.4
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    • pp.731-751
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    • 2021
  • The Internet of Things is a huge group of devices communicating each other and the interconnection of objects in the network is a basic requirement. Choosing a reliable device is critical because malicious devices can compromise networks and services. However, it is difficult to create a trust management model due to the mobility and resource constraints of IoT devices. For the centralized approach, there are issues of single point of failure and resource expansion and for the distributed approach, it allows to expand network without additional equipment by interconnecting each other, but it has limitations in data exchange and storage with limited resources and is difficult to ensure consistency. Recently, trust management models using fog nodes and blockchain have been proposed. However, blockchain has problems of low throughput and delay. Therefore, in this paper, a trust management model for selecting reliable devices in a fog-based IoT environment is proposed by applying IOTA, a blockchain technology for the Internet of Things. In this model, Directed Acyclic Graph-based ledger structure manages trust data without falsification and improves the low throughput and scalability problems of blockchain.

The Changes of the Heart Rate, Hand Function, and Health related Quality of Life of the People with Intellectual Disability through the Increase of the Auditory Stimulation (청각자극 증가에 따른 지적장애인의 심박수와 손 기능, 건강관련 삶의 질의 변화)

  • Son, Sung-Min;Kang, Jin-Ho;Bak, Ah-Ream
    • Journal of Korea Entertainment Industry Association
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    • v.14 no.5
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    • pp.217-227
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    • 2020
  • The purpose of the study is to analyze the changes of the heart rate, hand function, and health related quality of life of the people with intellectual disability through the increase of the auditory stimulation. The subjects were 16 people with intellectual disability. The increase of the auditory stimulation was modulated through the music sound and the intensity was consisted of 60dB, 65dB and 70dB. The wist heart rate and blood pressure monitor was used to measure the heart rate during the application of the auditory stimulation increase. The hand function of right and left hand was measured by the Purdue pegboard. Health related of quality of life was measured by the short form-8 health survey. As the results, the increase of the heart rate was showed by the increase of the auditory stimulation and the decrease of the hand function and health related quality of life was showed. For these, the increase of the auditory stimulation acts as a psychological distress, thereby the increase of the heart rate and the reduction of the hand function and health relate quality of life showed. Thus, to decrease of the heart rate and increase the hand function and the health related quality of life of the people with intellectual disability, the intensity of the auditory stimulation should be considered in the environmental stimulation.

A Study on the Co-branding Determine FactorsBetween Franchise Restaurant and Hotel F&B Department in Korea (프랜차이즈 레스토랑과 국내 호텔 식음료부문 브랜드제휴 결정요인에 관한 연구)

  • Choo, Seung Woo;Lee, Sang Youn
    • The Korean Journal of Franchise Management
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    • v.2 no.1
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    • pp.134-151
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    • 2011
  • The strategy for brand alliance is a new type of franchise to iron out the problems like the hotel restaurant's structural contradiction and decreasing profits caused by keen competition with external restaurants. This study is purposed to present the decisive factors for the brand alliance throughexamining the correlations between the brand restaurant designation standards and the expected effects from local low- and mid-priced hotel's brand alliance. The questionnaires were distributed to instructors and professors who have experience in teaching the food and beverage sections at college's hotel and tourism departments and 100 specialists at managerial level of a hotel's food and beverage parts.This survey was conducted for 20 days from December 2 to 22, 2004 and analyzed by independent t-test and canonical correlation analysis. The findings of this survey are as follows.Firstly, the service of the expected effect factors of the brand alliance was recognized relatively high by the specialists in hotel industry, while the sales effect factor of restaurant designation standards was recognized higher by the academic experts.The specialists of the hotel industry recognized the factors of menu and corporate culture higher than the academic experts. Secondly, the entire factors of the brand restaurant designation standards showed a correlation with the whole factors of the restaurant designation standards.In particular, the 'menu' factor presented the most influential to the expected effects of brand alliance.The factors of 'risk reduction' and 'synergy effect' exerted the strongest effect on the restaurant designation standards, which indicated the mutual correlation between the expected effect of brand alliance and the restaurant designation standards. Based on this study, the correlation between the expected effect of brand alliance and brand restaurant designation standards may play a primary role to choose a partner for the brand alliance, a decisive factor for the success.The execution of the brand alliance or the method to designate the alliance partner may vary from the hotel's desirable effects when the brand alliance is determined.In other words, the partner designation standards should be corresponding to the expected effects from the brand alliance between hotel and brand restaurant, and the academic and industrial experts' perceived differences in the expected effects of brand alliance and restaurant designation standards should be clarified to display the direction of decision-making and find the potential risks.

Developing a hydrological model for evaluating the future flood risks in rural areas (농촌지역 미래 홍수 위험도 평가를 위한 수문 모델 개발)

  • Adeyi, Qudus;Ahmad, Mirza Junaid;Adelodun, Bashir;Odey, Golden;Akinsoji, Adisa Hammed;Salau, Rahmon Abiodun;Choi, Kyung Sook
    • Journal of Korea Water Resources Association
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    • v.56 no.12
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    • pp.955-967
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    • 2023
  • Climate change is expected to amplify the future flooding risks in rural areas which could have devastating implications for the sustainability of the agricultural sector and food security in South Korea. In this study, spatially disaggregated and statistically bias-corrected outputs from three global circulation models (GCMs) archived in the Coupled Model Intercomparison Project Phases 5 and 6 (CMIP5 and 6) were used to project the future climate by 2100 under medium and extreme scenarios. A hydrological model was developed to simulate the flood phenomena at the Shindae experimental site located in the Chungcheongbuk Province, South Korea. Hourly rainfall, inundation depth, and discharge data collected during the two extreme events that occurred in 2021 and 2022 were used to calibrate and validate the hydrological model. Probability analysis of extreme rainfall data suggested a higher likelihood of intense and unprecedented extreme rainfall events, which would be particularly notable during 2051-2100. Consequently, the flooded area under an inundation depth of >700 mm increased by 13-36%, 54-74%, and 71-90% during 2015-2030, 2031-2050, and 2051-2100, respectively. Severe flooding probability was notably higher under extreme CMIP6 scenarios than under their CMIP5 counterparts.

Effects of Lime and NPK Application Rates on the Soil Charateristics after a 10-year Experiment in Oversown Hilly Pasture of Mixed Grass-Clover Sward III. Change in the mutural ratios of exchaegeable cations by the soil depth, and the visible characteristics of soil conservation (겉뿌림 산지초지에서 석회 및 3요소 시용수준이 10년후 토양특성에 미치는 영향 III. 토심별 염기간 상호비율 및 가시적 토양보존의 특성변화)

  • 정연규;이혁호
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.18 no.3
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    • pp.223-232
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    • 1998
  • The main experiment related to this report was undertaken to assess the effects of two rates of $Ca(OH)_2$ (0, 250 kg/10a only at establishment) and five rates of $N-P_20_5-K_20$ (0-0-0, 0-10-10, 6-15-15, 12-20-20, 24-25-20 kg/10a/year) on the pasture establishment, forage yield and quality, and vegetation etc. After this 10-year main e experiment pasture had been used to assess the effects of the above treaments on the soil characteristics in oversown hilly pasture of a grass-clover sward. soil properties of mutual ratios of exchangeable cations at d different soil depth, and the visible characteristics of soil conservation obtained are summarized as follows; 1. Compared with the properties of soil fertility and the level for the likelihood grass tetany, the mutual ratios of exchangeable cations in soils; Ca:Mg:K(% of CEC), Ca:Mg:K(K=I), $K/\sqrt{Ca+Mg}$, Mg/K, K/Mg, and Ca/Mg, were discussed at different soil depth. Before and after experiment, these ratios were generally unbalance and unsuitable, and were rather worsened in the order of Mg>Ca>K under the conditions of liming and NPK fertilization without Mg. 2. The ratios of Ca and Ca/Mg were increaby liming, whereas it of $K/\sqrt{Ca+Mg}$ was redused. The ratios of K and $K/\sqrt{Ca+Mg}$ in control and the heavy fertillization of NPK(especially N) were rather lowered than those in the low and medium fertilizations of NPK. 3. The prperties of consevation were closely related with the forage productivity/vegetation rates, as affected by liming and the application rates of NPK. In control of NPK, It was shown to be the worst soil conservation; severly eroded(3rd grade), exporsure of subsoil, redish brown in soil colour, and 18.8% of cobble and stony in covering rate. 4. The improvement of soil conservation was greatly enhanced by increasing the NPK rate. In the medium and heavy fertilizations of NPK, it was shown to be the favorable improvement of soil conservation; slightly eroded(lst grade), covered with humus layer/grass residues in surface soil, dark brown in surface soil colour, under 1% of cobble and stony in covering rate. The increasing of legume yield/vegetation rate by liming rather enhanced the soil conservation of grassland.

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Sequential Pituitary Hormone Responses to Electroconvulsive Therapy (전기경련요법후 뇌하수체 호르몬의 순차적인 분비 반응)

  • Kim, Doh Kwan;Kim, Soo Jeong;Choi, Do Sun;Bok, Hae-Sook;Kim, Seungtai Peter
    • Korean Journal of Biological Psychiatry
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    • v.3 no.2
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    • pp.288-294
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    • 1996
  • Background : Most studies of the pituitary hormonal responses to electroconvulsive therapy(ECT) have used limited blood sampling schedules. Little is known about the precise sequence of neuroendocrine events immediately following en ECT application. or about the regulation of the hormonal responses. Methods : Blood was sampled at three minute intervals from eleven patients(two schizophrenics and nine affective disorder patients) undergoing ECT. Each sample was immunologically assayed for arginine vasopressin(AVP), adrenocorticotropic hormone(ACTH), prolactin(PRL), and cortisol. Baseline hormone concentrations and several measures of response were determined for each hormone. The temporal and quantitative relationships among the hormonal responses were determined. Correlations were calculated between seizure duration and secretory responses. Results : All four hormones demonstrated significant secretory responses to ECT, with AVP increasing from 1.2 to 33.3pg/ml(P<0.001), ACTH from 5.4 to 32.3fmol/ml(P<0001). PRL from 21.8 to 102.2ng/ml(P<0.005) and cortisol from 20.1 to 31.1ug/dl(P<0.001). The three pituitary hormones showed consistent time courses of secretion with onset of responses by three minutes but clearly differing peak times of 3, 6, and 12-15 minutes for AVP, ACTH, and PRL, respectively. Cortisol began to rise after 6minutes and pecked between 20-30minutes. There ware no significant correlations between seizure duration and any of the secretory response measures. Conclusions : 1) The pituitary hormone response to ECT is sequential rather than synchronous 2) The AVP response was extremely rapid and more massive than those of any other hormones. 3) The ACTH response of this study was more rapid and mare robust than thai revealed by the mast of past studies. 4) The results strongly suggest that the pituitary hormones are released as a result of the seizure rather tho, the electrical stimulus. 5) The sequential pattern of responses suggests that neuroendocine feedback-regulatory mechanisms determine the response profile.

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