• Proceedings of the Korean Institute of Resources Recycling Conference
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• 2006.05a
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• pp.150-155
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• 2006

제강공정에서 발생되는 $CaO-Al_{2}O_{3}-SiO_{2}$계 조성을 갖는 2 차 정련슬래그 (래들 슬래그)를 이용하여 하수슬러지용 고화재개발 및 하수슬러지 고화체의 물성에 관한 연구를 수행하였다. 래들슬래그는 냉각과정에서 분화되는 성질이 있어 냉각후 분말상의 슬래그가 만들어진다. 분말상 슬래그의 주 결정상은 $12CaO{\cdot}7Al_{2}O_{3}$ 및 $2CaO{\cdot}SiO_{2}$로 구성되어 있다. $12CaO{\cdot}7Al_{2}O_{3}$ 상은 속경성 시멘트의 특징이 있다. 또한 $CaSO_{4}$와 혼합사용시 ettringite 상을 형성시켜 하수슬러지의 함수율 저감효과 및 강도발현 효과가 우수한 결과를 얻었다. $Cl^{-}$ 이온의 고정화면에서는 고화재중 래들슬래그의 혼합비가 높을수록 고화체 구조내에 $Cl^{-}$ 이온이 고정화되어 용출량은 감소하였다. 고화재로서 제강부산물을 사용하기 때문에 경제성이 있으며, $Cl^{-}$ 이온 함량이 높은 하수슬러지 고화재로서의 재활용이 기대된다.

• Journal of Korea Soil Environment Society
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• v.3 no.2
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• pp.89-99
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• 1998

Sorption of the aqueous cyanide onto steel mill sludge and steel mill slag, both of which are the by-products from the converter furnace, was studied. In the study, the influence of temperature, activation energy, concentration and pH on sorption of cyanide was investigated. Three different temperature($25^{\circ}C$ > $37^{\circ}C$> $50^{\circ}C$) was chosen to represent that of landfill leachate. Initial concentration was 1 mg/$\ell$ 5 mg/$\ell$, 10 mg/$\ell$, and 20 mg/$\ell$. In addition, pH was set to three different level, that is, 3, 7, and 11 respectively. As the result of batch mode experiment for cyanide adsorption, the removal rate was found to be proportional to the initial concentration of cyanide. The order of removal rate was 20 mg/$\ell$> 10 mg/$\ell$> 5 mg/$\ell$> 1 mg/$\ell$. Similarly the influence of pH was proportional because of the change in solubility of cyanide. The order of removal rate was pH 11 > pH 7 > pH 3. As the temperature increased, so did the removal rate. The reaction was endothermic and the value of activation energy(Ea) was 127.93 J/mole and 59.44 J/mole respectively at 1 mg/ιand 20 mg/ιof initial concentration. From the experiment, it can be postulated that the capability of steel mill by-products to attenuate aqueous cyanide is enough to be used as substitute for clay liner of landfill site in the aspect of pollutant removal.

• Environmental engineer
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• s.131
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• pp.34-39
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• 1997

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 1997.05a
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• pp.1-3
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• 1997

질산염(NO$_3$)은 음전하를 띠고 있기 때문에 지하에서 제거되기 어려운 물질 중 하나이다. 특히, 매립지로부터 침출수로 유출될 경우 통제하기가 곤란하다. 본 연구에서는 제철폐기물로서 다량 발생하는 제강슬러지와 제강슬래그를 매립지 복토/차수재로 이용시 NO$_3$흡착 제거 가능성을 알아보기 위해 온도, pH, 초기농도를 변화시키는 회분식방법의 실험을 실시하였다. 온도와 PH는 낮을 때. 초기농도는 높을 때 높은 흡착제거 효율을 나타내었다.

• Resources Recycling
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• v.26 no.6
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• pp.45-49
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• 2017

Most Waste slurry is produced in the process of silicon manufacturing for semiconductor industry, containing silicon (Si) and silicon carbide (SiC). Waste slurry is simply stored with solidifying by cement or buried. On the other hand, it was suggested in this study that the waste slurry should be used for heating source as supplementary material in steel making process. The waste slurry was refined and pulverized, which was recycled into SiC-based sludge briquette. Chemical composition for SiC-based sludge briquette was analyzed and the feature of heating source was observed in accordance with the injection time and input amount. As a result, SiC-based sludge briquette in terms of low cost and high efficiency had an effect on increasing liquid steel temperature in steel making plants.

• Resources Recycling
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• v.23 no.5
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• pp.3-11
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• 2014

Calcium ferrite is more effective binder for making sintered ore and flux for steel making because of it's low melting temperature. In this Study, calcium ferrite was made by calcinating method in the cement manufacturing process in order to reduce manufacturing costs and increase productivity. Limestone and calcination sludge were used as CaO source, steelmaking sludge, blast furnace dust and iron ore were used as Fe-bearing raw materials. The sintering temperature of specimens is in the range of $950{\sim}1170^{\circ}C$. For Calcium ferrite can be used 'binder for making sintered ore' or 'flux for converter/electric furnace' with a low melting point properties, the raw material characteristics and sintering properties were investigated.

• Proceedings of the Korean Environmental Sciences Society Conference
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• 2006.05a
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• pp.423-427
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• 2006

1) 바실러스는 불리한 환경조건에서 포자를 형성하며 포자는 균체가 죽어도 살아 남고, 외부 환경이 좋아지면 다시 발아하여 영양형 균체를 형성하게 된다. 본 연구에서 바실러스를 우점화와 포자의 활성화를 위해 열처리(80$^{\circ}C$, 10min)를 한다 울산분뇨처리장 슬러지 Cake를 배양하여 포자화 전 후 상태의 미생물의 EPS 추출결과 RCF법을 적용하였을 때 Carbohydrate물질이 다른 추출법에 비해 가장 많이 추출되었고, Steaming extraction법을 적용하였을 때 Protein이 가장 많이 추출되는 것으로 나타났으며, 포자화 전 보다 포자화 후의 EPS 양이 더 많이 추출될 것이라는 가설을 가지고 실험한 결과 포자화 전보다 포자화 후의 EPS 양이 더 많이 추출되었다. 울산분뇨처리장의 슬러지 Cake를 배양하여 포자화 전 후의 Cu의 제거정도를 비교한 결과 포자화 후의 EPS물질이 포자화 전의 EPS물질보다 Cu를 더 많이 제거하는 것으로 나타났으며 EPS 물질이 중금속 제거능력이 탁월하다고 할 수 있겠다. 2) 용인분뇨처리장과 천안하수처리장의 MLSS의 중금속 제거능력을 알아보기 위해 미생물량을 고려했을 경우와 미생물량을 고려하지 않은 경우로 나누어서 실험을 하였는데 울산분뇨처리장의 슬러지 Cake를 가지고 실험한 결과와 마찬가지로 Bacillus의 EPS물질이 중금속 제거에 탁월하다는 것을 알 수 있다. 3) Baillus를 사용하는 김천 식품폐수 처리장과 활성슬러지를 사용하는 천안하수처리장과의 EPS 함량을 비교한 결과 김천 식품폐수 처리장의 EPS 물질중 Protein과 Carbohydrate가 천안하수처리장의 활성슬러지보다 더 많은 것으로 나타났다.TEX>, DIN/DIP비 표층수 $23.91\pm3.42$, 저층수 $23.43\pm3.38$이었으며, 전반적으로 해역별 수질기준 I등급 내지는 II등급을 유지하고 있었고, 공간적으로는 외해측으로 갈수록 외해수와 혼합 확산되어 양호한 수질을 나타내었다. 장기적인 변동특성은 세그룹으로 구분되어진다.기 실험결과 용출용매로 증류수와 해수를 이용했을 때, 제강 슬래그에서 용출되는 납, 구리, 카드뮴, 수은의 용출 경향의 차이를 확인할 수 있었고 이에 따라서, 납, 구리, 카드뮴의 용출 유해성은 낮기 때문에 해양구조물로의 제강슬래그 유효이용은 적합할 것으로 판단되었다.im80%$로 계산되었다. 열형광선량계로 측정된 방사선량은 각각 1.8, 1.2, 0.8, 1.2, 0.8 (70 cm 거리) cGy로 측정되었으며, 환자의 복부 표면에서의 서베이메터를 이용한 측정량은 10.9 mR/h였다. 차폐구조물의 사용 시 전체 치료 동안에 태아선량은 약 1 cGy 정도로 평가되었다. 결론 : AAPM Report No.50의 자료에 따르면, 임산부의 방사선 치료 시 태아의 방사선 피폭선량은 5 cGy 이하일 경우에 방사선 피폭에 따른 태아의 위험이 거의 없는 것으로 제시되고 있다. 본원에서 차폐 구조물을 설치하였을 경우에 측정된 태아선량은 약 1 cGy로 측정되었고, 고안된 차폐구조물은 태아에 도달하는 방사선량을 감소시키기에 적합한 설계임이 입증되었다. 아니라 일반종합병원에서도 CTX-M형 ESBL 생성 E. coli와 K. pneumoniae가 존재하며 확산 중임을 시사한다. 앞으로 CTX-M형 ESBL의 만연과 변종 CTX-M형 ESBL의 출연을 감시하기 위한 정기적인 연구와 조사가 필

• Resources Recycling
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• v.15 no.2 s.70
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• pp.18-23
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• 2006

Foaming of slag is a thermodynamically unstable phenomenon and has significant effects in iron and steelmaking processes. For better recycling method of pulp sludge, the application as an defoaming agent during steelmaking process was adopted and tested. The forming machine has been modified in order to produce the briquettes, which are made of pulp sludge and slag with different weight ratio. Influencing factors on the foaming phenomena have been studied and tested for better understanding of foaming phenomena. Experiments were carried out with $CaO-FeO-SiO_2$ based slags with Ar gas injection and addition of coke particles. The slag basicity and (%FeO) contents adapted as major factors to treasure foaming tendency of the slag system. It was found that foam index (${\Sigma}$) gradually decreased as both the basicity and the (FeO) content increase. Four kinds of antifoaming agent such as aluminium dross, cokes, rice bran and pulp sludge with steelmaking slag have been tested in actual process. Aluminium dross was the most effective, and pulp sludge with steelmaking slag also showed the desired results.

• Journal of Korean Society of Environmental Engineers
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• v.28 no.3
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• pp.329-336
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• 2006

Iron manufacturing process involves production of various by-product including slag, sludge, sintering and EAF(Electric Arc furnace dust). Some of the by-products such as EAF and sintering dust are disposed of as waste due to their high heavy metal contents. It has been notice for many years that the EAF dust also contain about 65% of Fe(0) and Fe(II) and then the possible utilization of the iron. One possibility is to apply the EAF as a lining material in conjunction with clay or HDPE liners, in waste landfill. The probable reaction between the leachate containing toxic elements such as TCE, PCE dioxine and $Cr^{6+}$ is reduction of the toxic materials in corresponding to the oxidation of the reduced iron and therefore diminishing the toxicity of the leachate. It is, however, prerequisite to evaluate the leaching characteristics of the EAF dust before application. Amelioration of the leachate would be archived only when the level of toxic elements in the treated leachate is less than that of in the untreated leachate. Several leaching techniques were selected to cover different conditions and variable environments including time, pH and contact method. The testing methods include availability test, pH-stat test and continuous column test. Cr and Zn are potentially leachable elements among the trace metals. The pH of the EAF dust is highly alkaline, recording around 12 and Zn is unlikely to be leached under the condition. On the contrary Cr is more leachable under alkaline environment. However, the released Cr should be reduced to $Cr^{3+}$ and then removed as $Cr(OH)_3$. Removal of the Cr is observed in the column test and further study on the specific reaction of Cr and EAF dust is underway.

• Economic and Environmental Geology
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• v.52 no.1
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• pp.29-35
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• 2019

The purpose of this study was to assess the applicability of acid mine drainage sludge (AMDS) pellets for the arsenic (As) stabilization and to suggest an evaluation method for arsenic stabilization efficiency in soil around abandoned coal mines. The soil samples were collected from the agricultural field around Ham-Tae, Dong-Won, Dong-Hae, and Ok-Dong coal mine. The As concentration in soil was exceeding the criteria of soil pollution level, except for Ham-Tae coal mine. The AMDS pellets are more appropriate to use by reducing dust occurrence during the transport and application process than AMDS powder. In addition, AMDS pellets were maintained the As stabilization efficiency. The application of AMDS pellets for the As stabilization in soil was assessed by column experiments. The AMDS pellets were more effective than limestone and steel slag, which used as the conventional additives for the stabilization process. The As extraction by $0.43M\;HNO_3$ or $1M\;NaH_2PO_4$ solution were appropriate evaluation methods for evaluation of As stabilization efficiency in the soil.