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Study on the Physicochemical Properties of Crosslinked Poly(Styrene-Butadiene-Styrene) Block Copolymers Prepared by Radiation (방사선으로 제조된 가교 구조의 Poly(Styrene-Butadiene-Styrene) 블록 공중합체 특성에 관한 연구)

  • Lee, Sun-Young;Song, Ju-Myung;Sohn, Joon-Yong;Shin, Junhwa
    • Journal of Radiation Industry
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    • v.6 no.2
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    • pp.171-176
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    • 2012
  • In this study, a crosslinked poly(styrene-butadiene-styrene) [SBS] block copolymers were prepared by using gamma ray irradiation method. The effects of various radiation doses on the degree of crosslinking, thermo property, and morphology of crosslinked SBS block copolymer were investigated. The degree of crosslinking of crosslinked SBS block copolymers were measured by gel-fraction and FT-IR. It was found that the degree of crosslinking of crosslinked SBS block copolymers increases with increase of the irradiation dose while the TGA result shows that the initial degradation temperature of irradiated SBS block copolymer was shifted to lower temperature with increasing irradiation dose. These results indicate that degradation reaction also occurs when SBS block copolymer is exposed to gamma ray irradiation for crosslinking reaction. The SAXS and FE-SEM results indicate that the phase separation of the styrene block and butadiene block was reduced with increasing irradiation dose.

Study on Diminution of Pesticide Residues in Citrus Fruits by γ-Irradiation (감마선 조사에 의한 감귤의 잔류농약 저감화 연구)

  • Yang, Hee Sun;Park, Yong Dae;Jin, Chang Hyun;Choi, Dae Seong;Jeong, Il Yun
    • Journal of Radiation Industry
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    • v.3 no.1
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    • pp.19-24
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    • 2009
  • The citrus fruits were irradiated at different doses (25~200 kGy) to remove pesticides such as diuron, dichlorbenil, trifluralin, dimetoate, chlorothalonil, fenitrothion, bromacil, phenthoate and norflurazon, and the rates of degradation were detected by using gas chromatography electron capture detector (GC-ECD). The limit of detection (LOD) was in the range of 0.007~0.105 ppm. The limit of quantification (LOQ) was in the range of 0.024~0.352 ppm, and the recoveries of 9 pesticides were in the range of 71.5~106.5%. The results demonstrated that the ${\gamma}$-irradiation was effective method to remove pesticides such as diuron, dichlorbenil, trifluralin, dimetoate, chlorothalonil, fenitrothion, and norflurazon. However, the bromacil and phenthoate showed lower removal rates in the rate of 40.5 and 54.8%, respectively, at 200 kGy irradiation.

Effect of Persulfate on Disinfection of Escherichia coli K12 by Gamma Radiation (감마선을 이용한 Escherichia coli K12의 살균에서 persulfate의 효과)

  • Lee, O Mi;Kim, Tae Hun;Yu, Seungho;Jung, Inha;Lee, Myun Joo
    • Journal of Radiation Industry
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    • v.5 no.1
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    • pp.63-67
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    • 2011
  • A comparative experiment was conducted to compare the effects of persulfate with gamma radiation on the disinfection efficiencies against Escherichia coli K12. The microorganism used for the disinfection experiments were prepared by transferring a bacterial stock culture into a 50 ml nutrient broth an incubating for 24 hrs at $37^{\circ}C$. The initial concentration of the harvested culture was approximately $10^7$ to $10^9CFU\;ml^{-1}$. The culture solution was irradiated at different absorbed doses of 0.1, 0.2, 0.3, 0.4, 0.5, 0.7, and 1 kGy, respectively. The disinfection efficiency of persulfate with gamma radiation of 0.3 kGy against Escherichia coli K12 was 97.2% and while the gamma radiation only was 90.01% at 0.3 kGy. Therefore, it could be thought that addition of persulfate in the disinfection of Escherichia coli K12 can enhance the disinfection efficiency when it is used together with gamma radiation.

Anti-inflammatory Activity of Herbal Extracts through Inhibition of TNF-α, IL-6 and IL-8 (TNF-α, IL-6, IL-8 저해를 통한 천연약용식물 추출물의 항염증 특성)

  • Kim, Yong-Soo;Gwon, Hui-Jeong;Park, Jong-Seok;Lim, Youn-Mook;Nho, Young-Chang
    • Journal of Radiation Industry
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    • v.5 no.3
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    • pp.273-277
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    • 2011
  • This study evaluated the cytotoxicity and anti-inflammatory activities of natural herbal extracts including Houttuynia cordata and Eucommia ulmoides against human mast cell (HMC-1). Houttuynia cordata (HC) and Eucommia ulmoides(EU) were extracted with distilled water (at $75^{\circ}C$) and then freeze-dried for 5 days. Finally, the mixture of HC and EU were sterilized by ${\gamma}$-rays irradiation. Cytotoxicity of the mixture against HMC-1 cell was measured using cell counting kit-8 (CCK-8) assay. In addition, inflammatory mediator cytokines such as TNF-${\alpha}$, IL-6 and IL-8 were evaluated by ELISA kit on the HMC-1 cells with calcimycin A23187 and phorbol 12-myristate 13-acetate (PMA). The results showed that mixture of HC and EU had no cytoxicity and reduced TNF-${\alpha}$, IL-6, IL-8 response on HMC-1 cells.

Genotoxicological Safety of Undaria pinnatifida Gamma-irradiated after Harvest (감마선 조사된 채취 미역의 유전독성학적 안전성 평가)

  • Choi, Jong-il;Kim, Jae-Hun;Song, Beom-Seok;Kim, Jaekyung;Lee, Ju-Woon;Chun, Byung-Soo;Ahn, Dong-Hyun;Byun, Myung-Woo;Park, Kyung-Sook
    • Journal of Radiation Industry
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    • v.5 no.1
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    • pp.81-86
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    • 2011
  • This study was conducted to evaluate the genotoxcity of gamma-irradiated Undaria pinnadifida after harvest for enhancing the storage and microbial safety during drying process. The harvested seaweed was irradiated with the doses of 1 and 10 kGy. The genotoxicity was evaluated by Ames test (Salmonella typhimurium reversion assay) and SOS chromotest. The results from all samples were negative in the bacterial reversion assay with S. typhimurium TA98 and TA100. No mutagenicity was detected in the assay, at both with and without metabolic activation. The SOS chromotest also indicated that the gamma-irradiated U. pinnadifida did not show any mutagenicity. Therefore, this study indicated that gamma irradiation could be used for extending the shelf-life of U. pinnadifida.

Sensory Evaluation of Korean Seaweed Soup, Miyukgook, with Gamma-irradiated Undaria pinnatifida (감마선 조사된 미역으로 제조한 미역국의 관능 연구)

  • Choi, Jong-il;Kim, Jae-Hun;Song, Beom-Seok;Kim, Jaekyung;Lee, Ju-Woon;Chun, Byung-Soo;Ahn, Dong-Hyun;Byun, Myung-Woo;Park, Kyung-Sook
    • Journal of Radiation Industry
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    • v.5 no.1
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    • pp.21-24
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    • 2011
  • This study was conducted to evaluated the sensory properties of Miyukgook, Korean seaweed soup, with gamma-irradiated Undaria pinnadifida for enhancing the storage of the harvested seaweed. The harvested seaweed was irradiated at the doses of 1, 3, 5, and 10 kGy. The Miyukgook was made by following the general recipe. The values of pH and acidity of the Miyukgook were not changed by the irradiation of harvested Undaria. The sensory evaluation result showed that the preference scores in all the sensory properties was a little decreased when it was irradiated, but sensory score of less than 5 kGy samples was similar in all terms. Therefore, it was considered that gamma irradiation with less than 5 kGy was effective for improvement of the storage stability of U. pinnatifida without the changes in the sensory of its major cooked food, Miyukgook.

Preparation and Characterization of Gelatin Scaffold Containing Microorganism Fermented Cellulose (미생물 발효 셀룰로오스와 젤라틴을 함유한 조직공학적 세포지지체의 제조 및 특성)

  • Lim, Youn-Mook;Kim, Mi-Yeong;Gwon, Hui-Jeong;Park, Jong-Seok;Nho, Young-Chang;Lee, Byeon-Heon;Lee, Jong-Dae;Song, Sung-Gi;Kim, Sung-Ho;Choi, Young-Hun;Lee, Sun-Yi
    • Journal of Radiation Industry
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    • v.4 no.4
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    • pp.373-379
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    • 2010
  • Cellulose, chitin, chitosan and hyaluronic acid are well known as polysaccharides. These polysaccharides have many effects on cell growth and differentiation. Cell activation increases with increasing the polysaccharides concentration. In this study, gelatin scaffold containing microorganism fermented cellulose, citrus gel were prepared by using irradiation technique. Physical properties of the scaffolds were investigated as a function of the concentrations of gelatin and citrus gel and the cell attachment, cell morphology and inflammation of the scaffolds also were characterized for regeneration of skin tissue.

Volatile Analysis and Preference Measurement of Korean Black Raspberry Wines from Different Regions (주요 산지별 제조 복분자주의 기호도 및 휘발성분 분석)

  • Lee, Seung-Joo;Lee, Kwang-Geun
    • Food Engineering Progress
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    • v.13 no.4
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    • pp.302-307
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    • 2009
  • In this study, four Korean black raspberry wines were developed from different regions in Korea; Gochang (G), Heongsung (H), Jeongup (J), and Sungchang (S). Their flavor profiles were determined using a combination of volatile analysis and sensory evaluation. From the volatile analysis of the developed wines, 8 acids, 17 alcohols, 12 esters, 9 terpenes, 3 aldehydes and ketones, and 4 miscellaneous compounds were identified. Preferences of appearance, aroma, full-body, and overall acceptability in the developed wines were determined using 9-point hedonic scale by 43 panelists, compared with one commercial black raspberry wine (Sunw). The sweetness, sourness, astringency levels were also evaluated using 9-point just-about-right (JAR) scale. The mean overall acceptability score of Sunw (5.58) was the highest among the tested wines, followed by G (4.81), S (4.44), H (4.41), and J (4.13) (p<0.05). Sweetness levels in the developed wines were overall lower than JAR level, while sourness and astringency levels were overall higher than JAR level.

Effects of Electron Beam Irradiation on the Dielectric Properties of Polyimide Films (전자선 조사에 따른 폴리이미드 필름의 유전특성 변화)

  • Kim, Hyun Bin;Jeun, Joon Pyo;Kang, Phil Hyun
    • Journal of Radiation Industry
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    • v.4 no.3
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    • pp.285-288
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    • 2010
  • Polyimide films have excellent thermal stability, reliable mechanical properties and low dielectric constant. Therefore, this material is widely used in many industrial fields such as microelectronics, flexible circuits, semiconductor products and aerospace materials. In space applications, earth-orbiting hardware operates in environments that generally include neutral particles, charged particles such as trapped protons and electrons, solar protons, and cosmic rays. Under these conditions, polyimide films were changed in the optical, electrical and mechanical properties. Therefore, in this study, we evaluated the effects of electron beam irradiation on polyimide. The O-H functional groups were created on the polyimide film surface in the results of FT-IR spectra. And it was found that the dielectric constants were changed as a function of electron beam dose.

Influence of Quaternary Ammonium Anion Exchange Moieties onto Mechanical Properties of Radiation-grafting Anion Exchange Membranes (방사선그라프팅 음이온교환막의 기계적 물성에 대한 4차 암모늄 음이온교환기의 영향)

  • Ko, Beom-Seok;Sohn, Joon-Yong;Shin, Junhwa
    • Journal of Radiation Industry
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    • v.6 no.1
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    • pp.49-54
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    • 2012
  • Various anion exchange membranes were prepared by radiation graft copolymerization of vinylbenzyl chloride onto fluorinated films and subsequent quaternization with various tertiary amines such as trimethylamine, N,N-dimethylbuthylamine, N,N-dimethylaniline, and N-methylpiperidine. The quaternizations of the anion exchange membranes were confirmed by measuring of the ion exchange capacities of the membranes. The mechanical properties and the water uptakes were also measured. The elongation at break was found to be largely dependent on the fluorinated film, the quateranry ammonium, and the degree of grafting. The results indicate that the poly (ethylene-alt-tetrafluoroethylene) with quaternized trimethylamine moiety exhibits higher flexible property compared to the other prepared anion exchange membranes.