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Influence of Eu3+ Doping Content on Photoluminescence of GdVO4 Red Phosphors

  • Lee, Jae-Hui;Jo, Sin-Ho
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.08a
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    • pp.314-315
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    • 2011
  • 최근에 $Eu^{3+}$ 이온이 첨가된 적색 형광체에 대한 연구가 활발히 진행되고 있다. 현재 상업적으로 이용 가능한 적색 형광체와 비교하여 $GdVO_4$를 모체로 갖는 적색 형광체는 우수한 열적 안정성과 광학적 특성을 나타낸다. 본 연구에서는 고효율의 적색 형광체를 개발하기 위하여 고상 반응법을 사용하여 $Gd_{1-x}VO_4$ : $Eu_x^{3+}$ 형광체를 합성하였다. $Gd_{1-x}VO_4$ : $Eu_x^{3+}$ 형광체 분말 시료는 활성체인 $Eu^{3+}$의 함량을 0, 0.05, 0.10, 0.15, 0.20 mol로 변화시키며, 초기 물질 $Gd_2O_3$ (99.99%), $H_3BO_3$ (99.99%), $Eu_2O_3$ (99.9%)를 화학 적량으로 준비하였다. 분말은 볼밀과 건조 작업을 거친 후, 500$^{\circ}C$ 전기로에서 5시간 동안 하소 공정, 1,100$^{\circ}C$에서 6시간 동안 소성시켰다. 합성된 형광체 분말의 XRD 측정한 결과에 의하면, $Eu^{3+}$의 함량비에 관계없이 모든 분말 시료들에서 주 피크는 24.7$^{\circ}$와 33.2$^{\circ}$에 최대값을 갖는 (200)와 (112)면의 회절 신호들이 관측되었고, 상대적으로 약한 회절 세기를 갖는 (101), (211), (301), (103), (312)와 (420)면의 회절 신호들은 각각 18.6$^{\circ}$, 31.1$^{\circ}$, 40.1$^{\circ}$, 44.6$^{\circ}$, 49.2$^{\circ}$와 57.1$^{\circ}$에서 나타났다(Fig. 1). 이결과를 JCPDS(86-0996)와 비교함으로써, 합성된 형광체 분말의 결정 구조는 정방정계임을 확인할 수 있었다. $Eu^{3+}$의 함량비가 0.05 mol에서 0.15 mol로 증가함에 따라 주 피크인 (200)면의 회절 신호의 세기는 증가한 반면, 0.20 mol에서는 급격하게 감소하였으며, 이 경우에 반치폭의 크기는 0.16$^{\circ}$이었다. 결정 입자의 크기를 결정하기 위하여 (200)면의 회절 피크에 대한 정보를 잘 알려진 Scherrer의 식에 대입하여 계산한 결과, $Eu^{3+}$의 함량비가 0 mol인 경우에, 평균 크기는 48 nm이었다. $Eu^{3+}$ 함량비를 증가함에 따라 결정 입자의 크기도 비례하여 증가하였으며, 0.15 mol에서 최대값을 나타내었으나, 농도 억제 효과로 인하여 0.20 mol 에서는 현저히 감소하였다. 표면 형상의 변화를 관측한 SEM 측정 결과에 의하면, $Eu^{3+}$의 함량비가 0 mol에서 0.15 mol로 증가함에 따라 결정 입자의 모양은 사다리꼴 형태에서 모서리가 둥글게 깎인 구형으로 변형되는 것을 관측할 수 있었으며 평균 크기는 500 nm이었다(Fig. 2). $Eu^{3+}$의 함량이 0.20 mol인 경우에 결정 입자의 형상은 더욱 구형에 접근하였으나, 평균 크기는 최소값을 나타내었다. 실험 결과로부터, 적절한 함량비를 갖는 $Eu^{3+}$ 이온을 첨가함으로써 적색 형광체 $Gd_{1-x}VO_4$ : $Eu^{3+}$ 분말의 결정 크기와 발광 세기를 제어할 수 있음을 제안한다.

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A study on taxation of foreign corporation's Permanent Establishment (고정사업장의 과세에 관한 연구: 플랜트 건설.판매기업의 사례를 중심으로)

  • Suh, Jung-Rog
    • Management & Information Systems Review
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    • v.29 no.3
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    • pp.71-96
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    • 2010
  • This article firstly reviewed Permanent Established(PE) concept of OECD and UN model tax treaty and compared it with that of Korean Corporate Income Tax Law(CITL). The various factors regarding profit like ways of deciding the local source profit, scope and calculation method which will be imputed to PE were also reviewed. Based on above, standard PE judgement basis and calculation method of local source profit were also studied by using actual cases in foreign corporation which performs plant construction & sales in Korea. Accordingly to properly solve the conflict regarding international tax and to protect the tax authority against the foreign corporation in Korea, by standing on equality, I now propose followings for the better concept of PE in Korea. Firstly, the article that a building site or construction or installation project constitutes a PE only if it lasts more than 6 months should be modified to reflect OECD model convention's criteria of 12 months. Second, the scope of 'subordinate attorney' which is regarded as PE under CITL is now including 'holding-delivery attorney', 'order attorney', and 'assurance attorney' as well as 'contract attorney'. This is overly limit the activities of foreign corporation. It had better be loosened only to include 'contract attorney' as OECD provisions. Third, the CITL limits the cases of preparatory and/or auxiliary place which is not regarded as PE, thus limit the foreign corporations' business by expanding the concept of PE. This had better be eased. Fourth, in deciding the amount of local source profits, the CITL stipulates to split the profits by the relevant contribution of transaction parties through 'profit split method'. To solve the conflict, the ways of profit split must be better clarified through providing object and detailed standard and basis.

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The Effect of Salesperson's Adaptive Selling Tactics on Shopping Value, Commitment, and Product Satisfaction - Focused on Small and Medium Enterprises' product - (판매원의 적응적 판매전략이 쇼핑가치, 관계 결속, 및 제품 만족도에 미치는 영향 - 중소기업 제품을 중심으로 -)

  • Kim, Jae-Hun;Shin, Jong-Kuk
    • Management & Information Systems Review
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    • v.38 no.4
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    • pp.41-60
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    • 2019
  • The purpose of this study is to investigate the effect of salesperson's adaptive selling tactics on consumers who purchase Small and Medium Enterprises' product with the help of salespeople in the store. Specifically, we examine whether salesperson's adaptive selling tactics affect consumers hedonic shopping value and utilitarian shopping value. Furthermore, we try to figure out the effect of shopping value on the salesperson relationship commitment and consumer product satisfaction. The subjects of this study have surveyed the consumers with experience in purchasing SME's products through salespeople in the Gyeongnam area. As data process, SPSS 21.0 was used as the analysis tool and AMOS 21.0 was used to analyze the structural equation model. The implications of these findings are as follows. First, the salesperson's role has a positive effect on the consumer's product satisfaction. Second, it can be suggested that the salesperson's adaptive selling tactics are an important variable affecting the consumer's shopping value. Third, the results on the consumers who have hedonic shopping value have a strong positive influence rather than the consumers who have the utilitarian shopping value. The adaptive selling tactics of the salesperson should be encouraged to increase sales performance. In order to generate more performance in a competitive market environment, it is necessary to continuously strive to increase contact between the salesperson and the consumer in order to improve the quality of the relationship.

A New Approach to Improve Knowledge Sharing Activities at the Organizational Level by Rearranging Members of Current CoPs (실행공동체 멤버 재구성을 통한 조직차원에서의 지식공유 활동 개선 방안 연구)

  • Lee, Su-Chul;Suh, Eui-Ho;Hong, Dae-Geun
    • Information Systems Review
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    • v.13 no.2
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    • pp.1-16
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    • 2011
  • Recently, many companies have started to manage and support CoPs formally at the organizational level because of strategic usability of CoP. These companies are also seeking ways to motivate CoP members to actively participate in their groups. Accordingly, this paper proposes one way of increasing CoP activities by rearranging CoP members. In practice, active CoP members often lead their groups. Therefore, rearranging members can, eventually, be one method to motivate more individuals to participate in CoP activities. This paper first suggests a new approach in order to improve knowledge sharing activities at the organizational level based on rearranging members of current CoPs. Second, a mathematical model is presented which maximizes total BLS (Balanced Level Score) of company A with several constraints. Then a real world problem is changed to a popular problem, VRP to solve this problem. Third, the solution program was developed to find a meaningful solution.

A Study on Developmental Plan of In-Flight Security Officer in Korea - Focused on U.S. Federal Air Marshal Service - (항공기내보안요원제도의 발전 방안에 관한 연구 - 미국 연방 Air Marshal 제도를 중심으로-)

  • Park, Hee-Kyun;Moon, Jun-Seob
    • Korean Security Journal
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    • no.53
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    • pp.83-105
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    • 2017
  • The purpose of this study is to identify the problems of In-Flight Security Officer responsible for the security of the aircraft in the situation where Acts of Unlawful Interference in Aircraft shows an increasing tendency and the aircraft security is threatened by the terror threat of IS(Daesh) and to suggests its policy implications. Based on the problems of In-Flight Security Officer system found in the media reports and laws, the US Air Marshal system and the domestic similar system were presented to the In-Flight Security Officer developmental implications. First, it is necessary to revise the "Operational Guidelines for Airline Operators' In-Flight security officer" and the related qualifications to the "National Technical Qualifications" system. Second, the plan to change the national civil servants of In-Flight Security Officer in the aircraft, Third, it is a plan to use the registered security guard system in the aircraft. Although this study has limitations the accessibility of information related to aviation security. But, contributions of this study is that the government's efforts to create the public sector jobs, the "strengthening of public services in the country", "the establishment of national accountability for safety accident prevention and disaster safety management" in the "A five-year plan for Government Operation" that it has a timeliness in that it is together. In addition, since there are not many researches related to In-Flight Security Officer, this study also has another contribution as a basic study of the researchers in the aviation security aircraft in the future.

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A Study on the Direction of the Third Phase New Town Development in Seoul Metropolitan Area through expert survey method (전문가 설문조사를 통한 3기 신도시의 계획지표 및 개발방향설정 연구)

  • Yoon, Jeong Joong
    • Land and Housing Review
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    • v.10 no.3
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    • pp.43-55
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    • 2019
  • The purpose of this study is to derive indicators and development directions to be considered when planning new towns in the Seoul metropolitan area as new towns are planned to be built. To this end, the following implications were derived after analyzing the survey data of experts in each field using Frequency Analysis and Analysis of Variance(ANOVA) technique. First, the assessment results of the existing first and second phase new towns showed that there were many negative assessments of citizen participation and information sharing, smart technologies and services, social and cultural diversity and inclusion. Regarding the third phase new town, experts said that the most important indicators are accessibility and convenience of transportation, environmental comfort, quality and service of residence. In addition, experts cited the superiority of landscape/design, jobs/self-sufficiency and social/cultural diversity as important indicators. Second, after examining whether the perceptions and assessments of experts differ depending on individual characteristics such as gender, age, occupation, and professional field, the first and second phase new towns showed significant differences only in "gender", and the third phase new town had significant differences in "gender" and "professional field". Third, experts thought that changes in population structure, industry and jobs, quality of life and diversity, environment and climate change, and social and residential welfare should be considered important in the planning of third phase new town. In addition, experts considered expanding park and self-sufficient land as important in the land use plan, and ranked eco-city as a desirable type of the city, and public transportation facilities, park areas and education facilities as the most important living infrastructure.

Preliminary Study on Developing Protocol for Music Therapy Assessment for Cognitive and Emotional-Behavioral Domain using Rhythm (MACED-Rhythm) (인지 및 정서행동 영역에서의 음악치료 사정을 위한 리듬 프로토콜(MACED-Rhythm) 개발 예비 연구)

  • Duerksen, George;Chong, Hyun Ju
    • Journal of Music and Human Behavior
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    • v.10 no.1
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    • pp.67-83
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    • 2013
  • Assessment in music therapy is a vital part for both the therapist and client in the process of therapy. Based on what is assessed, objectives are identified to formulate specific action procedures and strategies. The existing assessment tools involve lists of skills and behaviors in developmental domains without the music assessment protocol. In this study, the authors attempted to develop an assessment protocol using rhythm production for assessing skills in cognitive and emotional-behavior domain, namely Music Therapy Assessment for Cognitive and Emotional Behaviors (MACEB). The test items of the MACEB-Rhythm were developed using rhythmic patterns varying in terms of item difficulty, which are based on the various degree of clarity in the grouping/gestalt, saliency in part-whole relationship, and complexity in repetition vs. variability. Also the developed tool purported to examine one's level of emotional behavior trait by analyzing performance of musical parameters such as tempo, pacing, and loudness in the reproduced output. In order to verify the logical sequencing of test items, firstly 61 subjects participated in verifying the item difficulty for the selected 15 pilot items. The test items were revised and re-sequenced based on the gathered scores of item difficulty. In the second procedure, seven experts in the fields of music education, music therapy and music psychology whose research interest lie in music cognition revised the developed rhythm protocol items focusing on learning sequence, cognitive process and feasibility for skills assessment. The study attempted to provide foundations for using rhythm as an assessment protocol prior to its verification of assessment validity and reliability.

Design and Implementation of an Analysis System for Diseases and Protein Based on Components (컴포넌트 기반의 질병 및 단백질 분석 시스템의 설계 및 구현)

  • Park, Jun-Ho;Yeo, Myung-Ho;Lee, Ji-Hee;He, Li;Kang, Gwang-Goo;Kwon, Hyun-Ho;Lee, Jin-Ju;Lee, Hyo-Joon;Lim, Jong-Tae;Jang, Yong-Jin;WeiWei, Bao;Kim, Mi-Kyoung;Ryu, Jae-Woon;Kang, Tae-Ho;Kim, Hak-Yong;Yoo, Jae-Soo
    • The Journal of the Korea Contents Association
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    • v.10 no.12
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    • pp.59-69
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    • 2010
  • The research on protein for the diseases analysis and the new medicines development is one of the most important themes in biotechnology. Since the analysis on diseases and protein needs to handle a large scale of data, we don't use the way to approach it by the experiments anymore. In recent, we have accelerated the research on diseases and protein analysis by sharing and connecting the various experimental data by combining the biotechnology with the IT technology. However, many biotechnology researchers have difficulty in handling the protein analysis tools based on the IT knowledge. In order to solve such problems, data analysis tools through the cooperation between IT researchers and biologists have been developed. However, the existing data analysis tools still have the problems that it is very hard for biologists to extend their functions and to use them. In this paper, we design and implement an effective analysis system for diseases and protein based on components that alleviates the problems of the existing data analysis systems.

Analysis of Network Dynamics from Annals of the Chosun Dynasty (조선왕조실록 네트워크의 동적 변화 분석)

  • Kim, Hak Yong;Kim, Hak Bong
    • The Journal of the Korea Contents Association
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    • v.14 no.9
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    • pp.529-537
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    • 2014
  • To establish a foundation to objectively interpret Chosun history, we construct people network of the Chosun dynasty. The network shows scale free network properties as if most social networks do. The people network is composed of 1,379 nodes and 3,874 links and its diameter is 14. To analysis of the network dynamics, whole network that is composed of 27 king networks were constructed by adding the first king, Taejo network to the second king, Jeongjong network and then continuously adding the next king networks. Interestingly, betweenness and closeness centralities were gradually decreased but stress centrality was drastically increased. These results indicate that information flow is gradually slowing and hub node position is more centrally oriented as growing the network. To elucidate key persons from the network, k-core and MCODE algorithms that can extract core or module structures from whole network were employed. It is a possible to obtain new insight and hidden information by analyzing network dynamics. Due to lack of the dynamic interacting data, there is a limit for network dynamic research. In spite of using concise data, this research provides us a possibility that annals of the Chosun dynasty are very useful historical data for analyzing network dynamics.

Mismatch of Perception and Data: Air Pollution, Medical Expenses, and Consumption in South Korea (관측 자료와 인지의 불일치: 대기 오염에 따른 의료 비용 및 소비 지출에 관한 분석)

  • Yun, Seong Do;Kim, Seung Gyu
    • Environmental and Resource Economics Review
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    • v.29 no.2
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    • pp.113-144
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    • 2020
  • Throughout various data sources, it is widely observed that air quality in South Korea has become improved. Koreans, however, insist that their health status and economic burden due to worsened air quality get degenerated. This study aims to explain the mismatch between perception and measured data, air pollution-led medical expenses, and consumption behaviors in the economics perspectives. First, we demonstrated data-driven evidence of mismatch in the perceived severity of air pollution and its enhancement in measured data. Second, using the health demand model, we theoretically derived and empirically showed a co-rising relation between air pollution severity and medical expenses. Last, we analyzed that the perception led to increased defensive expenditures in consumption. This result implies the possibility of overestimation in air pollution impacts on socioeconomic losses and its possible reverse interpretation from increased social benefit after improved air quality. Our results recommend policy consideration to strengthen air quality standards, to support socially vulnerable groups regarding defensive expenditures, and to improve the accessibility and credibility of air pollution information.