• Journal of the Mineralogical Society of Korea
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• v.22 no.2
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• pp.115-127
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• 2009

Mineral quantification was performed on sediments of the Ulleung basin by X-ray powder diffraction and the computer software based on Rietveld quantification method. The sediments are dominated by amorphous opal-A with quartz, feldspars, micas, clays, calcite, and pyrite. The opal-A shows iterative variation in abundance with increasing burial depth. In addition, the relative abundance of opal-A is coincident with abundance of organic carbon contents, indicating that the Ulleung sediment consists mostly of amorphous silica derived from organism in the pelagic environment. Upward increase in the abundance of opal-A is markedly shown in the cores located in the slope region. On the other hand, there is a distinct tendency that the abundance of calcite is inversely proportional to that of opal-A. This indicates that the abundance of opal-A increases during the rise of sea level. Also, the fall of sea level lowers the abundance of opal-A.

• Journal of the Korean Ceramic Society
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• v.40 no.5
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• pp.481-487
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• 2003

A technique for determination of proportions of char, coal ana coke is needed in order to monitor pulverized coal injection performance in operating blast furnace. Quantitative X-ray powder diffraction analysis can be applied to the problem providing that structural information on carbonaceous materials, coal, char, coke and their mixture are known. Chars were prepared from a coal at different temperatures (1000∼1400$^{\circ}C$) and were characterised by X-Ray powder Diffraction (XRD). The XRD result gave crystallite size (height Lc and diameter, La), aromaticity, number of (002) plane in carbon, and d-spacing. As a result, with increasing heat treat temperature of char, Lc$_{(002)}$, La$_{(10)}$ and number of (002) plane in carbon were increased, and d-spacing and FWHM(Full With Half Maximum) were decreased. Result of prediction of amount of char from the mixtures (char, coke and ore) based on the Lc$_{(002)}$ information of two mixtures (coke and char) showed very close values expected.

• Proceedings of the Korean Ceranic Society Conference
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• 2002.10a
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• pp.154.2-154
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• 2002

• Proceedings of the Computational Structural Engineering Institute Conference
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• 2011.04a
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• pp.400-403
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• 2011

본 논문에서는 시차열중량분석법과 X-선 회절분석법을 이용한 원전콘크리트의 탄산화에 의한 열화도 평가를 진행하였으며 두 가지 정성적 분석방법을 이용한 반정량적 평가 방법을 개발하였다. 원자력발전소 건설에 사용된 동일한 콘크리트 배합을 사용한 시편을 촉진 탄산화 시험장치에 28, 56, 91, 180, 365일 기간에 걸쳐 노출시켜 탄산화를 진행하였으며 노출된 시편은 시차열중량분석법, X-선 회절분석법을 이용하여 탄산화에 따라 발생된 열화생성물의 양을 정성적으로 분석하였다. 그 결과, 탄산화로 인해 발생되는 Calcite의 양이 노출기간에 따라 점차적으로 증가되는 것이 확인되었으며, Calcite의 생성을 위해 이산화탄소와 반응하는 Portlandite의 양이 점차적으로 감소되는 것이 확인되었다. 본 논문에서는 위의 언급된 두 방법의 관계성을 통해 열화도 평가를 진행하였다.

• Analytical Science and Technology
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• v.20 no.6
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• pp.502-507
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• 2007

X-ray diffraction method has been widely used for qualitative and quantitative analysis of a mixture of materials since every crystalline material gives a unique X-ray diffraction pattern independently of others, with the intensity of each pattern proportional to that material's concentration in a mixture. For determination of mixing ratios, extracting source spectra correctly is important and crucial. Based on the source spectra extracted, a regression model with non-negativity constraint is applied for determining mixing ratios. In some mixtures, however, X-ray diffraction spectrum has sharp and narrow peaks, which may result in partial negative source spectrum from independent component analysis. We propose several procedures of extracting non-negative source spectra and determining mixing ratios. The proposed method is validated with experimental data on powder mixtures.

• Economic and Environmental Geology
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• v.45 no.2
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• pp.181-188
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• 2012

The 1M and $2M_1$ stacking sequences are the most frequently encountered in the illite species among the possible 6 polytypes. The $1M_d$, derived from the 1M polytype which exhibits a variable degree of disorder in the stacking sequence, is also observed in illite samples. In this paper, the author introduces and reviews the theoretical background of the quantitative analysis method of illite polytypes, and considers the possibility to determine the fault age and its reactivation age using K/Ar age-dating based on the quantification of illite polytypes in the fault system. For the increase of the accuracy and precision of the illite age analysis method, the occurrence, identification, and mineralogical characterization of illite polytypes should be defined in detail. The broadening effect of (hkl) reflections, due to disordering of 1M polytype and the presence of I/S minerals with expandability, are also considered as the main parameters controlling the quantification of illite polytypes using the WILDFIRE(C)simulation.

• Journal of the Mineralogical Society of Korea
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• v.3 no.2
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• pp.98-108
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• 1990

전자현미분석외에 금-은 고용체의 금 또는 은 성분을 결정할 수 있는 간편하고도 신뢰성 높은 측정법 개발은 응용 광물학자들에게 오랜 연구과제가 되어 왔다. 이를 달성하기 위한 방법으로 정량적으로 측정할 수 있는 단위포 상수, 반사도, 비중, 미경도 측정연구를 실시하였다. 이 실험을 위해 순수한 원소 금과 은을 5 at.% 간격으로 혼합하여 시료를 제작한 후 석영관을 사용하여 진공하에서 밀봉하였다. 고온에서 가열하여 용융시킨 후 서냉하여 얻어진 반응물을 각종 현미경, X 선 회절분석기, 전자현미분석기, 반사도측정기, 비중저울, 미경도측정기를 사용하여 분석하였다. 직경이 114.6 nm 인 Debye-Scherrer 카메라를 사용해 얻은 X 선분말회절자료로 계산한 단위포 상수의 크기는 은함량이 증가함에 따라 일정하게 증가한다. 반사도 측정에는 480nm와 546nm 두파장을 사용하였는데 두 파장 모두에 대해 은 함량이 증가할수록 반사도가 증가한다. 또한 480nm를 사용했을 때의 반사도 변화가 현저하므로 유용하다. 비중은 은 함량이 증가할수록 오히려 일정하게 감소한다. 한편, 25g과 50g 추를 사용하여 측정한 미경도 값은 금-은고용체내의 성분변화에 관계없이 불규칙하게 변하여 어떤 경향을 나타내지 않는다.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.10 no.3
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• pp.264-270
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• 2000

Quantitative analysis of iron ore sinter consisting of hematite, magnetite, calcium ferrite and slag was investigated by X-ray internal standard method. After selecting NaF and $SiO_2$as internal standard materials, the calibration curves were determined and were applied to quantitative analysis of the internal standard method. Calcium ferrite was identified as a solid solution of CaO.$2Fe_2$$O_3$with 7 wt% and 3 wt% solubility of $AI_2$$O_3$and $SiO_2$, respectively. The maximum deviation of quantitative analysis of synthetic iron ore was about $\pm$5 wt%. The contents of each mineral calculated in industrial sinter were 27~40 wt% of hematite, 20~30 wt% of magnetite, 22~33 wt% of calcium ferrite and 10~20 wt% of slag.

• Journal of the Korean Geotechnical Society
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• v.16 no.6
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• pp.51-58
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• 2000

울산지역에 널리 분포하고 있는 해성 퇴적토에 대하여 깊이별로 물리, 화학 그리고 광물학적 특성을 파악하였으며, 이 지역에서 채취된 시료에 대하여 깊이별로 퓨준압말시험을 실시하였다. 본 논문을 위하여 울산 해성 퇴적토의 생성과정을 추정하고, X-선 회절 분석, X-선 형광분석 및 에너지분산분광분석을 실시하여 깊이에 따른 변화를 비교하였다. 울산 해성 퇴적토의 점토광물에 대한 정량분석결과, 일라이트, 카올리나이트, 녹니석, 스멕타이트 순으로 많게 나타났음, 화학성분 분석결과, SiO$_2$, $Al_2$O$_3$그리고 Fe$_2$O$_3$가 대부분을 차지하는 것으로 나타났다. 주사전자현미경 관찰결과, 유공충과 규조류가 관찰되었다. 표준압밀시험 결과, 울산지역의 해성 퇴적 점토는 깊이에 따른 변형거동이 화학적, 광물학적 분석결과와 마찬가지로 깊이에 따른 변화를 보이지 않아 같은 시디에 퇴적인 것으로 판단된다.

• Journal of the Korean Recycled Construction Resources Institute
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• v.12 no.1
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• pp.72-81
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• 2024

In this study, DEIPA was used for enhancing cementitious performance of bottom ash replaced cement. By applying the partial or no-known crystal structure method to X-ray diffraction data, the amounts of amorphous bottom ash and calcium silicate hydrate(C-S-H) could be separated and quantified. In the sample without DEIPA, the bottom ash hardly reacted, resulting in low compressive strength. However, the addition of DEIPA not only altered the hydration behavior of the cement but also enhanced the pozzolanic reaction between bottom ash and calcium hydroxide, leading to the generation of additional C-S-H. This resulted in high compressive strength not only in the early stages but also in the later stages. Therefore, with the addition of DEIPA during the pulverization of the bottom ash, the reactivity of the bottom ash was significantly improved. Hence, there is potential in the development of bottom ash replacement cement.