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Phase Behavior of Poly(ethylene-co-vinyl alcohol)-Solvent System at High Pressure (고압에서 폴리(에틸렌/비닐 알코올) 공중합체-용매계의 상거동에 관한 연구)

  • Byun, Hun-Soo;Kim, Chong-Bae
    • Applied Chemistry for Engineering
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    • v.9 no.3
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    • pp.424-429
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    • 1998
  • Cloud-point data at $230^{\circ}C$ and 1,800 bar are presented for two poly(ethylene-co-vinyl alcohol)(PEVA) copolymers[9.9mol% and 17.8mol% vinyl alcohol(VA)] in ethylene, propane, propylene, n-butane, 1-butene, dimethyl ether(DME), and chlorodifluromethane(CDFM). The static type experimental apparatus with a view cell has been used for the experiment at the high pressure and temperature. The pressure-temperature (P-T) loops of PEVA(9.9mol% VA) copolymer-DME mixtures are presented at copolymer concentrations of 1.4wt% to 20.0wt%. Also, we presented the phase behavior of PEVA(17.8mol% VA) copolymer-DME system at copolymer concentration of 1.9wt% to 6.8wt%. The cloud-point curves for the PEVA copolymers in dimethyl ether showed single phase above 480 bar as a result of the hydrogen bonding between the vinyl alcohol unit and dimethyl ether. The pressure-concentration(P-x) isotherm loops of PEVA(9.9mol% and 17.8mol% VA)-DME system are obtained. The cloud-point curves for PEVA(9.9mol% and 17.8 mol% VA) copolymers andthe ethylene, propane, propylene, n-butane, 1-butene, and CDFM all show negative slopes of phase behavior and are located at pressures below 1,800 bar. For PEVA copolymer-DME system(9.9mol% VA), cloud-point curves show positive slopes that decrease in pressures with decrease in temperature in the temperature range of $80^{\circ}C$ to $160^{\circ}C$.

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A Study on Frost Occurrence Estimation Model in Main Production Areas of Vegetables (채소 주산지에 대한 서리발생예측 연구)

  • Kim, Yongseok;Hur, Jina;Shim, Kyo-Moon;Kang, Kee-Kyung
    • Journal of the Korean earth science society
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    • v.40 no.6
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    • pp.606-612
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    • 2019
  • In this study, to estimate the occurrence of frost that has a negative effect on th growth of crops, we constructed to the statistical model. We factored such various meteorological elements as the minimum temperature, temperature at 18:00, temperature at 21:00, temperature at 24:00, average wind speed, wind speed at 18:00, wind speed at 21:00, amount of cloud, amount of precipitation within 5 days, amount of precipitation within 3 days, relative humidity, dew point temperature, minimum grass temperature and ground temperature. Among the diverse variables, the several weather factors were selected for frost occurrence estimation model using statistical methods: T-test, Variable importance plot of Random Forest, Multicollinearity test, Akaike Informaiton Criteria, and Wilk's Lambda values. As a result, the selected meteorological factors were the amount of cloud, temperature at 24:00, dew point temperature, wind speed at 21:00. The accuracy of the frost occurrence estimation model using Random Forest was 70.6%. When it applied to the main production areas of vegetables, a estimation accuracy of the model was 65.2 and 78.6%.

Phase Behavior of Simvastatin Drug in Mixtures of Dichloromethane and Supercritical Carbon Dioxide and Microparticle Formation of Simvastatin Drug Usins Supercritical Anti-Solvent Process (디클로로메탄과 초임계 이산화탄소의 혼합용매에서 Simvastatin 약물의 상거동과 초임계 역용매 공정을 이용한 Simvastatin 약물 미세입자의 제조)

  • Oh, Dong-Joon;Lee, Byung-Chul
    • Clean Technology
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    • v.13 no.1 s.36
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    • pp.34-45
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    • 2007
  • Phase behavior of the ternary systems of water-insoluble simvastatin drug, which is well known to be effective drugs for hypercholesterolemia therapy, in solvent mixtures of dichloromethane and supercritical carbon dioxide was investigated to present a guideline of establishing operating conditions in the particle formation of the drugs by a supercritical anti-solvent recrystallization process utilizing dichloromethane as a solvent and carbon dioxide as an anti-solvent. The solubilities of simvastatin in the mixtures of dichloromethane and carbon dioxide were determined as functions of temperature, pressure and solvent composition by measuring the cloud points of the ternary mixtures at various conditions using a high-pressure phase equilibrium apparatus equipped with a variable-volume view cell. The solubility of the drug increased as the dichloromethane composition in solution and the system pressure increases at a fixed temperature. A lower solubility of the drug was obtained at a higher temperature. The second half of this work is focused on the particle formation of the simvastatin drug by a supercritical anti-solvent recrystallization process in a cylindrical high-pressure vessel equipped with an impeller. Microparticles of the simvastatin drug were prepared as functions of pressure (8 MPa to 12 MPa), temperature (303.15 K, 313,15 K), feed flow rate of carbon dioxide, and stirring speed (up to 3000 rpm), in order to observe the effect of those process parameters on the size and shape of the drug microparticles recrystallized.

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Types and Characteristics of Fabrics of Bokjang Objects Enshrined within Wooden Buddha Statues at the National Museum of Korea (국립중앙박물관 소장 목조불상 복장직물의 종류와 특성)

  • Hwang, Jinyoung;Park, Seungwon
    • Conservation Science in Museum
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    • v.18
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    • pp.35-50
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    • 2017
  • As part of the NMK's research project on wooden Buddha statues, four items which contained fabric among their bokjang objects(腹藏物) were investigated. Firstly, when classified by the method of weaving, two items made of ra (羅, a four-end complex gauze) silk and five of neung(綾, twill damask) silk from the Goryeo era were identified, and the satin fabrics showing characteristics of the Joseon period were classified as either dan(緞, satin damask) or sa(紗, simple gauze). In particular, the fabric of the bokjang objects enshrined within the gilt-bronze Avalokiteshvara Bodhisattva(Deoksu 801) feature both early and late Joseon characteristics, suggesting that two enshrinements were performed(once in the fifteenth century and another in the seventeenth). Secondly, the patterns on the fabrics included flowers, treasures, fruits, plants with animals, and landscapes with clouds. Thirdly, patches of fabric were found that are assumed to be related with all cardinal directions according to their arrangement, albeit in small quantities.

A Stusy on the Coupled Vibration of Train Wheel and Pail - Dynamic Characteristics of Train Wheel with the Stepped Thickness - (車輪과 鐵路의 連成振動에 관한 硏究)

  • 김광식;박민태
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.11 no.1
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    • pp.63-73
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    • 1987
  • This study is a part of the research on the coupled vibration of train wheel with the stepped thickness and rail. The research was conducted for the purpose of examining the dynamic characteristics of train wheel at the running state and preventing the vibrations of the high speed railway. The stress at the boundary surface of web and rim, .sigma.$_{c}$, was analyzed in consideration of the uniform In-plane compressive stress depending on the conditions of rolling and the In-plane compressive stress depending on the rotation of train wheel. Then the equation of transverse vibration of the annular plate with the stepped thickness was analyzed by Rayleigh-Ritz's method. As a result of study, it was known that the rotational speed increase the natural frequency slightly and the acceleration level highly while the reaction force between train wheel and rail decrease the natural frequency linearly and the critical buckling is generated at n=1.

Lubrication of Contact Area in Ball Reducer with Waved Grooves (파형 구름볼 감속기의 접촉점에서의 윤활특성 해석)

  • Jang, Si-Youl;Park, Kyoung-Kuhn;Kim, Wan-Doo
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 2002.05a
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    • pp.143-149
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    • 2002
  • Ball reducer with waved grooves has many advantages over other reducers for the high-reduction ratios, low noise and low energy loss, etc. The mechanism of force transmission is very similar to that of cam and follower in automobile valve train system especially in the contact geometry. In this study, we have investigated the traces of contact between ball and outer race and the working behaviors with a certain reduction ratio. In order to verify the contact behaviors between ball and outer race, which determines the critical endurance life the contact velocity and load are computed for a cycle. During some period of a cycle, the contact velocity reverses its direction very suddenly, which causes undesirable endurance performance of this machinery. From the computational investigation in this work, we hope to predict similar contact damages in other machinery due to this kind of contact behaviors, which is very common in many contact phenomena.

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Quality Control of Pluvio Snowfall Data Using Parsivel (광학우적계를 이용한 무게식 우량계 적설 자료 품질 관리)

  • Ro, Yonghun;Chung, Gunhui
    • Proceedings of the Korea Water Resources Association Conference
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    • 2018.05a
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    • pp.80-80
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    • 2018
  • 겨울철 대설 현상에 따른 도로 결빙과 항공기 운항 지연, 비닐하우스 및 가건물 붕괴와 같은 피해가 증가함에 따라 대처방안을 마련하는 일이 중요시 되고 있다. 이를 위해 정확한 적설 정보가 근본적으로 필요하지만, 문제는 적설량을 정량적으로 관측하는 일이 간단하지 않다는 점이다. 최근에는 무게식 우량계를 이용한 적설 관측이 수행되고 있지만, 강설량이 많을 경우 우량계가 눈에 덮이는 캐핑(capping) 현상으로 인해 제대로 관측하기 어려운 문제가 있다. 본 연구에서는 무게식 우량계의 이러한 한계를 보완하고 자료의 활용성을 높이기 위해 광학우적계(Parsivel)로 관측된 강설입자정보를 이용하여 적설량을 보정하는 방법을 제안하였다. 무게식 우량계 자료는 대관령 구름물리선도센터에 설치되어 있는 플루비오(Pluvio)의 적설 관측 자료를 이용하였다. 먼저, 관측된 플루비오 자료에서 단위 시간동안의 신적설을 산정한 후 과도한 관측값과 같은 노이즈를 제거하였다. 또한 플루비오와 동일 기간에 관측된 광학우적계 자료에 대해 강설 입자가 $10/m^3$ 초과로 나타나는 사상을 강수 기간으로 결정하고 두 자료가 모두 '0'인 경우 무강수로 나타냈다. 그 결과 강수 입자가 관측된 적설 기간에 플루비오가 우수하게 강설 사상을 관측하고 있음을 확인하였고, 부적합한 자료를 보정할 수 있었다. 이러한 방법으로 적설 자료를 개선할 경우 향후 레이더를 이용한 공간적 강설 추정의 정확도를 크게 개선할 수 있을 것으로 판단된다.

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Development of 3D Point Cloud Mapping System Using 2D LiDAR and Commercial Visual-inertial Odometry Sensor (2차원 라이다와 상업용 영상-관성 기반 주행 거리 기록계를 이용한 3차원 점 구름 지도 작성 시스템 개발)

  • Moon, Jongsik;Lee, Byung-Yoon
    • IEMEK Journal of Embedded Systems and Applications
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    • v.16 no.3
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    • pp.107-111
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    • 2021
  • A 3D point cloud map is an essential elements in various fields, including precise autonomous navigation system. However, generating a 3D point cloud map using a single sensor has limitations due to the price of expensive sensor. In order to solve this problem, we propose a precise 3D mapping system using low-cost sensor fusion. Generating a point cloud map requires the process of estimating the current position and attitude, and describing the surrounding environment. In this paper, we utilized a commercial visual-inertial odometry sensor to estimate the current position and attitude states. Based on the state value, the 2D LiDAR measurement values describe the surrounding environment to create a point cloud map. To analyze the performance of the proposed algorithm, we compared the performance of the proposed algorithm and the 3D LiDAR-based SLAM (simultaneous localization and mapping) algorithm. As a result, it was confirmed that a precise 3D point cloud map can be generated with the low-cost sensor fusion system proposed in this paper.

The Characteristics of Winter Lightning Observed in the Mid-western Part of Japan (일본 중서부지방에서 발생하는 동계 뇌 방전의 특징)

  • Lee, Jong-Ho;Kawasaki, Z.;Ryu, Chan-Su
    • Journal of the Korean earth science society
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    • v.24 no.3
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    • pp.181-189
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    • 2003
  • This study analyzes the results of thunderstorm data observed in the mid-western part of Japan during the winter of 1996-1997. There were 35 instances of thunderstorms with 4,426 instances of lightning detected during the observation period. This study estimates the frequency of lightning occurrence through classification of detected lightning into two types, and analyzes the relationship between lightning types and synoptic pattern. According to the analyzed results, cloud-to-cloud discharge and positive polarity occupied 78% and 42.3% of total discharge, respectively. It is rare for lightning to occur in the winter season, usually occuring during the night (midnight to 5 a.m.). Lightning frequently occurs when there is a prevailing synoptic wind from the norhwest. According to the analyzed results of multiplicity and multi-point lightning, the mean values of multiplicity and multi-point lightning are 1.4 and 1.2, respectively.

Approaching Method for Detecting Vessels in the Korean Waters using the Panchromatic Imagery of IRS-1C Satellite (Panchromatic 위성 자료를 이용한 선박 확인의 접근 기법)

  • Suh, Young-Sang;Choi, Chul-Uong;Lee, Na-Kyung;Kim, Bok-Kee;Jang, Lee-Hyun
    • Journal of the Korean Association of Geographic Information Studies
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    • v.5 no.4
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    • pp.86-92
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    • 2002
  • The feasibility of counting number of small vessels and position in Korean waters using the panchromatic imageries derived from the IRS-1C was tested. The parameters for interpretation of satellite's imageries of small vessels were location(position), size, shape, shadow, tone, texture and pattern, height and depth, situation and association with other vessels. The position of small vessels in the sea without GCP(ground control point) was considered to be inclusive in the satellite imagery with 35 km semi-diameter, denoting rough geographical position of the vessel. The size of vessel was measured by length from stem to stern of the vessel, distinguished by following wave on the surface water. Offshore fishing vessels were separated from merchant ships by their length smaller than 100 m. The shape of vessels on panchromatic imagery of IRS-1C appeared just streamline. In case of clouds which were similar to the shape of small vessels, we were able to distinguish between vessel and cloud by shadow of cloud in the water surface. The tone of sea surface was dark black while small vessel appeared bright white. Small vessel was distinguished from the rough texture of the sea surface and the regular pattern of the waves with white capes when weather was not so good. The situation of the fishing activity was estimated by information of fishing method related to the fishing boat such as the pair trawl in the Yellow Sea.

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