• Applied Chemistry for Engineering
• /
• v.21 no.4
• /
• pp.377-384
• /
• 2010

We perform a comparative study to investigate the properties of the new energetic chain extender (AzPD). A series of poly(glycidyl azide)/poly(tetramethylene oxide)-based energetic segmented polyurethane (GAP/PTMG ESPU) with different chain extender, which is 3-azidopropane-1,2-diol (AzPD), 1,4-butane diol (1,4-BD), or 1,5 pentane diol (1,5-PD), was synthesized by solution polymerization in dimethyl formamide (DMF) and their phase behaviors were investigated. The ESPUs were characterized with Fourier transform infrared-attenuated total reflection spectroscopy (ATR FT-IR), differential scanning calorimetry (DSC), and dynamic mechanical analysis (DMA). The results of the ATR FT-IR analysis of the urethane carbonyl group region showed that the 'free' C=O fraction was higher in GAP/PTMG AzESPU (0.5) than GAP/PTMG BDESPU (0.44) and GAP/PTMG PDESPU (0.41) for 7 days samples after preparation and that it was similar in the range of 0.26~0.29 for three 60 days ESPU samples. DMA curves of the GAP/PTMG AzESPU for 7 days samples showed amorphous polymers, but GAP/PTMG BDESPU and GAP/PTMG PDESPU showed viscoelastic behaviors with rubbery plateau and the flow region. However, DMA curves of the GAP/PTMG AzESPU for 60 days samples showed viscoelastic behaviors with rubbery plateau and the flow region like GAP/PTMG PDESPU, but GAP/PTMG BDESPU did not show the flow region. From phase behaviors with ATR FT-IR, DSC and DMA analysis, GAP/PTMG AzESPU showed good phase-mixing between components. However, it represented viscoelastic behavior of TPE similar to GAP/PTMG PDESPM according to phase equilibrium progress with aging time.

• Journal of the Korean Society of Propulsion Engineers
• /
• v.19 no.6
• /
• pp.26-32
• /
• 2015

In this study, it is evaluated for fracture toughness to analyze crack resistance properties of particulate reinforced composite propellant. Fracture toughness test using WST specimen is conducted by temperature conditions from $50^{\circ}C$ to $-60^{\circ}C$. Evaluation method for fracture toughness calculated using an equation suggested by ASTM E399 with linear elastic fracture mechanics. From these result, splitting loads and stress intensity factors of propellant increase according to decrease of test temperature. Also, the strain fields of specimen surface using digital image correlation increase as temperature decreased from $50^{\circ}C$ to $-40^{\circ}C$, but it sharply decreases at $-60^{\circ}C$ because of brittle behavior.

• Transactions of the Korean Society of Mechanical Engineers A
• /
• v.36 no.12
• /
• pp.1585-1590
• /
• 2012

Engineering plastics are used in instrument panels, interior trim, and other vehicle applications, and the thermomechanical behaviors of plastic materials are strongly influenced by many environmental factors such as temperature, sunlight, and rain. As the material properties change, the mechanical parts create unexpected noise. In this study, the dynamic mechanical property changes of plastics used in automobiles are measured to investigate the temperature effects. Viscoelastic properties such as the glass transition temperature and storage modulus and loss factor under temperature and frequency sweeps were measured. The data were compared with the original ones before aging to analyze the behavior changes. It was found that as the temperature increased, the storage modulus decreased and the loss factor increased slightly.

• Applied Chemistry for Engineering
• /
• v.24 no.1
• /
• pp.24-30
• /
• 2013

The adsorption characteristics of cationic starches and starch-oligomers were investigated using the quartz crystal microbalance with dissipation monitoring (QCM-D). The adsorbed amount of modified starches was higher than that of cationic surfactants such as $C_{12{\sim}16}$ trimethylammonium bromide. Cationic starches did not show the tendency depending on the degree of cationic substitution and molecular weight. On the other hand, the softness of the adsorption layer increased with the molecular weight of cationic starches in a viscoelasticity terms. During the adsorption/desorption steps, the amount of adsorbed cationic surfactants was 4~9 times. On the other hand, the difference in the amount of adsorption of all the $C_1$ grafted cationic starches was just 0~50%. In addition, the rigidity of the adsorption layer of cationic surfactant in the desorption step decreased, while, that of cationic starches increased at the same condition.

• Korean journal of food and cookery science
• /
• v.7 no.3
• /
• pp.7-12
• /
• 1991

Castera is a favorite food which is well known to the general public made by egg, sugar and wheat flour. This study is carried out in order to investigate to the physical properties of eastern. The results are summarized as follows: 1) As a result of the sensory evaluation for eastern with 19 kinds of material in Kyushu on the market, it could be classified into 3 types: A) high grade (Castera), C) low grade (Sponge cake), and B) midium grade (Something middle of those). 2) In the texturometer measurement for eastern, hardness of A type was highest, B and C are 22∼35% lower than A type, while cohesiveness and springiness are not significantly different. 3) In the creep test, 3 types are all the S-element Voigt model, consisting of Hookean body, Newtonian body and two sets of Voigt body. Eo of A type is 13∼36% higher than other types, it tends to the same result of hardness. The parts of retardation strain of A type are 21∼41% lower than B type, 8∼l3% higher than C type, respectively. 4) About the day change of eastern of A type, mechanical model is not changed.

• Elastomers and Composites
• /
• v.47 no.3
• /
• pp.231-237
• /
• 2012

This study measured the mechanical and damping properties of EPDM compounds including fillers. Semi-reinforcing furnace black (SRF), high abrasion furnace black (HAF) and acetylene black were used as fillers. Dicumyl peroxide (DCP) were used as curing agents. The measurements were conducted using a moving die rheometer (MDR), durometer, universal testing machine (UTM), compression set and dynamic mechanical analysis (DMA). The tensile strength and elongation at break increased with increasing SRF contents in EPDM compounds. However, they decreased with increasing the amount of acetylene black. In the inspecting temperature range, EPDM compound filled acetylene black had stable storage modulus. Furthermore, the tan ${\delta}$ of the EPDM compounds obtained was enhanced by compounding with acetylene black.

• Elastomers and Composites
• /
• v.36 no.3
• /
• pp.188-194
• /
• 2001

Thermoplastic elastomers based on dynamically vulcanized NR/TOR/PP (rubber/PP=70/30) blends were prepared in a Haake banbury mixer. Effect of TOR content on the mechanical, dynamic mechanical and thermal stability of the rubber/plastic blends was characterized by UTM, DMTA, and TGA. On the addition of trans-polyoctylene rubber(TOR) to the rubber phase, there was a decrease in compression set and increase in tensile properties, hardness and dynamic properties as well as thermal stability or the elastomeric blends. Improvements in the properties were believed to be due to an increase in crosslink density of the rubber phase and increase in homogeneity of the blends.

• Korean Chemical Engineering Research
• /
• v.46 no.1
• /
• pp.124-130
• /
• 2008

In order to fabricate a modified poly (lactic acid) (PLA) for applications requiring high melt strength, a PLA has been irradiated in the presence of functional monomer of glycidyl methacrylate (GMA). Samples were prepared with various contents of GMA and irradiation dosages, and were characterized by observing their thermal and melt viscoelastic properties and gel faction. The complex viscosity and storage modulus of the modified PLA without GMA were lower than those of the original PLA. Those of the modified PLA decreased with increasing dosage. In the case of the modified PLA containing 0.1 phr or 0.3 phr of GMA, their changing tendency with dosage was similar to the irradiated PLA without GMA. However, the 5 kGy irradiated PLA containing 0.5 phr of GMA showed the greatly enhanced complex viscosity and storage modulus, which were about 3 and 10 times higher than those of the original PLA at a frequency of 0.1 rad/s, respectively.

• Elastomers and Composites
• /
• v.39 no.1
• /
• pp.51-60
• /
• 2004

The cure, viscoelastic and mechanical characteristics of organoclay filled NR/BR blends were studied and compared with the properties of carbon black and silica filled NR/BR blends. The nanocomposites with extensive exfoliation state can be fabricated by a solution mixing method. In the composites, the amount of filler content was fixed to 10 phr. Degree of intercalation and exfoliation was characterized by X-ray diffraction (XRD). XRD results indicated exfoliation of the silicate layers into the rubber matrix. While the degree or intercalation and exfoliation is lowered by the conventional mixing method, extensive exfoliation can be obtained by the solution mixing method. It was found that the clay filled NR/BR compound showed better viscoelastic (tan ${\delta}$) and mechanical properties than the carbon black or silica filled NR/BR compounds.

• Elastomers and Composites
• /
• v.45 no.4
• /
• pp.309-315
• /
• 2010

The CIIR blends, which is use for shoes outsole, with SSBR, XNBR and KBR were prepared with various mixing ratio. The viscoelastic properties of these blends, such as tensile modulus, rebound resilience, storage modulus, tan${\delta}$, and creep properties were measured. In the rebound resilience measurement, KBR showed the highest value, which means the lowest energy absorption to stress. As SSBR, XNBR and KBR blends with CIIR, the rebound resilience of the mixtures showed tendency to increase in arithmetic average. In the creep measurement, CIIR showed the highest visconse strain to stress, SSBR and KBR showed lower visconse strain. Maximum tan${\delta}$ peak of CIIR, SSBR and XNBR appeared at $-30^{\circ}C$, $5^{\circ}C$ and $0^{\circ}C$ respectively.