• Polymer(Korea)
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• v.34 no.3
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• pp.226-236
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• 2010

UV irradiated acrylic pressure sensitive adhesives(PSAs) are prepared to be used for thermal pad in plasma display panel(PDP). The effect of the chemical structure of side-chain in comonomer and of crosslinking agent on wet-out property of acrylic PSAs in wide temperature range were investigated. The correlationship between viscoelastic behavior and adhesion properties, such as tack and peel strength, was also studied. The experimental results supported that wet-out and adhesion properties of acrylic PSAs were enhanced inversely proportional to side-chain length of comonomer in wide temperature range. The peel energy clearly increased in acrylic PSAs prepared by using di(ethylene glycol) dimethylacrylate (DEGDMA) for crosslinking agent. The results might be due to the difference in the glass transition temperature and viscoelastic behavior of acrylic PSAs.

• Polymer(Korea)
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• v.38 no.2
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• pp.199-204
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• 2014

To prepare acrylic pressure sensitive adhesives (PSAs), quaternary copolymer syrups were photopolymerized from 2-ethylhexyl acrylate and 2-hydroxyethyl acrylate as default constituents and isobornyl acrylate and tetrahydrofurfuryl acrylate (THFA) as variable constituents. After polymerization, 1,6-hexanediol diacrylate and photoinitiator were added and then crosslinked by UV-irradiation to prepare the PSAs. The characteristics of the syrup such as viscosity, molecular weight, and solid content were investigated. As increasing THFA contents, the relationship between molecular weight and solid content of the syrup was reciprocal. Also, the relationship between peel strength and surface energy of the PSAs showed the same tendency. All the PSA samples showed high transmittance (more than 92%), low haze (less than 1.0%) and low color-difference (less than 1.0).

• Journal of Adhesion and Interface
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• v.20 no.4
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• pp.135-139
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• 2019

In this work, flame retardant acrylic emulsion pressure sensitive adhesives were newly polymerized combining phosphorous flame retardant monomer and acrylic monomer like butyl acrylate, 2-ethylhexyl acrylate, methyl methacrylate, acrylic acid, and 2-hydroxyethyl methacrylate. The process of polymerization showed 100% of conversion at solid content of 65%, and viscosity of acrylic emulsion was increased up to 5500 cps when phosphorous flame retardant monomer was added into acrylic emulsion. The structure of flame retardant acrylic emulsion was identified using FT-IR and thermal properties like glass transition temperature (Tg) were checked by differential scanning calorimeter (DSC). Acrylic emulsion without phosphorous flame retardant monomer had Tg of -44.1℃ and peel strength of 2,100gf/inch, however, flame retardant acrylic emulsion showed maximum Tg (-31.4℃) and peel strength of 200gf/inch when 15 part of phosphorous flame retardant monomer was added. Flammability test was also conducted to confirm the application of flame retardant acrylic emulsion as the flame retardant addtive.

• Journal of the Korean Society for Marine Environment & Energy
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• v.5 no.1
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• pp.3-10
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• 2002

Quantifying the settling velocities of fine-cohesive sediments is very essential in the study of ocean pollutions as well as sedimentations. Settling properties of fine-cohesive sediments are influenced largely by aggregation which occurs as a consequence of interparticle collision and cohesion of particles. Since the degree of cohesion of fine-cohesive sediments depends on physico-chemical properties such as grain size distribution, percentage of organic materials, and mineralogical compositions, and these physico-chemical properties varies regionally, the settling velocities of fine-cohesive sediments for a specific site should be determined through field or laboratory experiment. Recently, settling velocities of fine-cohesive sediments in Saemankeum coasts and Kunsan Estuary have been measured through laboratory experiments. Using these data, the previously proposed well-known settling velocity equations for fine-cohesive sediments are examined and a new equation is developed for better representation of the measured data in this study. The newly developed settling velocity equation is simpler in the form and easier in determining the related coefficients than the previous well-known equations.

• Proceedings of the Korea Water Resources Association Conference
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• 2008.05a
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• pp.909-914
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• 2008

미세-점착성 퇴적물로 구성되는 퇴적저면의 침식특성을 해석하기 위해, 고령토 퇴적저면에 대한 침식실험이 환형수조를 이용하여 수행되었다. 현재, 퇴적저면의 침식특성 연구에 대한 국내사례는 전무한 실정으로, 본 연구는 퇴적저면에 대한 침식실험 방법 및 결과의 타당성 검증을 목적으로 한다. 이를 위하여, 본 연구에서는 압밀시간 조건에 따라 4가지의 서로 다른 퇴적저면이 조성되었고, 각 저면별로 저면깊이에 따른 저면밀도의 변화가 우선적으로 정밀 측정되었다. 각 퇴적저면별 침식실험으로부터는, 바닥전단응력(${\tau}_b$)의 변화에 따른 저면 침식깊이(즉, 수층 부유사 농도)의 변화 측정을 통하여, 저면깊이에 따른 저면전단강도(즉, 침식한계전단응력, ${\tau}_S$)의 변화 값들이 정량적으로 분석되었으며, 최종적으로 잉여전단응력(${\tau}_b-{\tau}_S$)과 침식률 간의 관계식이 산정되었다. 퇴적저면 침식특성에 관한 과거 해외 연구 결과와의 비교 검토를 통하여, 본 연구에서 사용 혹은 적용된 실험장치, 실험 방법 및 실험결과가 타당성이 있음이 확인되었다.

• Tunnel and Underground Space
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• v.13 no.5
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• pp.362-372
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• 2003

Since the occurrence of Portland cement, a great number of concrete structures were constructed. But the concrete structures have their own life times, which inevitably demand repairing treatments, especially on their surface parts. Currently many various methods have been developed and are being applied fer this purpose. In this study, a newly developed method using pneumatic chipping machine and anchor pin was adopted far repair of old concrete structure and the mechanical characteristics of cementing plane between existing and new concrete were tested. Comparing the removal methods for the decrepit part of existing concrete using pneumatic chipping machine and hydraulic breaker, the peak cohesion was higher when using chipping machine at the cementing plane. On the other hand, the residual cohesion was higher for the case of breaker. Step shaped chipping on the cementing plane was effective in increasing peak cohesion, which results 14% increase in the case of 30 mm step height and 22% in 50 mm height when compared with planar chipping plane. The use of anchor pin increased the residual cohesion, which restricted shear slip on the cementing plane after peak shear stress and the tensile strength of 32% compared with that of non-anchored case. According to the combined effect of step shaped chipping of 30 mm and anchor pin with an interval of 15 cm, the peak cohesion reached up to 77% and the residual cohesion showed 180% of the ones of the fresh concrete, respectively.

• Tunnel and Underground Space
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• v.28 no.6
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• pp.584-595
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• 2018

This study conducted direct shear test on about 290 sorts of materials such as sandy soil, clayey soil and gravely soil to present proper standard on shear strength of soil. Shear strength of soil in large scale tends to show that angle of internal friction increases as sand contents grow and it ranges $23.5^{\circ}{\sim}34.9^{\circ}C$ with cohesion of 2.0 kPa~15.7 kPa. Elastic modulus was visibly distinct by load, and which increased approximately 80% as vertical load grows. Angle of internal friction arranging $15.0^{\circ}{\sim}28.6^{\circ}$ on clayey soil decreased as clay contents rises and cohesion increase in regular scale. Elastic modulus tends to increase initial elastic modulus with almost same growing rate. While angle of internal friction on gravely soil indicates $29.9^{\circ}{\sim}36.7^{\circ}$ which hardly shows distinctive features. According to test in detail, cohesion of SW (well-graded sand), SP (poorly-graded sand), SC (clayey sand) and SM (silty sand) indicates value by 94%, 78% and 59% comparing to SC, SW and SP respectively. Angle of internal friction of ML (low-liquid limit silt) and CL (low-liquid limit clay) appears almost same features, and MH (high-liquid limit silt) despite of 88% value of ML. Cohesion among them varies with similar growing rate.

• Proceedings of the KSR Conference
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• 2010.06a
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• pp.656-663
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• 2010

본 연구에서는 K.Terzaghi의 유효응력이론을 인용하여 압밀기반의 안전하중 산출 과정과 결과를 제시하였다. 일반적인 강도를 평가하기 위하여 이용된 J.I.Solovyov의 순간강도 이론에 기초를 두어, 제시한 방법은 포화된 연약점토지반에서 도로의 유지보수 뿐 아니라 축조 과정에 안전하중의 계산 적용이 가능하다. 실제로 편리한 표준 압밀 drain test에서 정의된 점착력, 내부 마찰각과 같은 강도정수를 가진 유효응력은 실제적 적용을 고려하기 위하여 산출된다.

• Proceedings of the KSEG Conference
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• 2005.04a
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• pp.235-242
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• 2005

본 연구에서는 퇴적암의 시험 관련자료 2,000 여건을 사암(역암 포함), 셰일 및 석회암으로 구분하여 흡수율, 단위중량, 일축압축강도, 점착력, 내부마찰각, 인장강도, 탄성계수, P파속도 및 S파속도 등의 특성치 분포도와 상관성을 분석하였다. 이러한 암석 특성치는 지하공간개발시 안전하고 경제적인 설계와 시공에 참고자료로 활용될 수 있는데 퇴적암의 강도특성 분석결과 사암과 석회암이 셰일 보다 전반적으로 양호하여 대규모 지하공간개발에 유리한 것으로 평가하였으며, 또 84% 신뢰도를 만족하는 범위에서 퇴적암의 암종별 공학적 특성치의 상관관계식을 유도하였다.

• Journal of the Korean GEO-environmental Society
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• v.11 no.3
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• pp.23-32
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• 2010

In this study, Generally sandbag was used to reinforce slope or restore levee by using the in-situ material. To increase shear strength of sandbag, the Velcro system was effective for geosynthetic interface and make up for the weakness of shear strength between sandbag to sandbag. In this study, shear properties of geosynthetic-geosynthetic and geosynthetic-soil were evaluated from large scale direct shear tests. The cohesion and the angle of internal friction of each interface was evaluated. And laboratory model tests were performed to compare strength of reinforcement with strength of none reinforcement. As a result of this study, the cohesion and the angle of internal friction of each interface was increased, especially the cohesion was increased more than the angle of internal friction. Also according to the result of model test, the bearing capacity was increased by 20%.