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Synthesis of High Molecular Weight Poly(vinyl alcohol) by Low Temperature Polymerization of Vinyl Acetate in Tertiary Butyl Alcohol and the Following Saponification (아세트산비닐의 삼차부틸알코올계 저온 중합 및 비누화에 의한 고분자량 폴리비닐알코올의 합성)

  • 류원석;한성수;최진현;유상우;홍성일
    • Polymer(Korea)
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    • v.24 no.5
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    • pp.610-620
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    • 2000
  • Vinyl acetate (VAc) was polymerized at 30, 40, and 5$0^{\circ}C$ using 2,2'-azobis (2,4-dimethylvaleronitrile) (ADMVN) and tertiary butyl alcohol (TBA) as the initiator and the solvent, respectively. High molecular weight (HMW) atactic poly(vinyl alcohol) (PVA) was prepared by saponifying the poly(vinyl acetate) (PVAc) synthesized. The effect of polymerization conditions were investigated in terms of conversion, degree of branching for acetyl group of PVAc, and molecular weight of both PVAc and PVA. The polymerization rate of VAc in TBA was proportional to the 0.49th power of ADMVN concentration in good accordance with the theoretical value of 0.5. HMW-PVA with high yield could be obtained successfully, probably due to lower polymerization temperature and decreased chain transfer reaction rate which was achieved by adopting ADMVN and TBA. PYAc having average degree of polymerization (P$_{n}$) of 10000~13000 was obtained at the conversion of 35~70%. Saponification of so prepared PVAc yielded PVA having P$_{n}$ of 2400~6100. The syndiotactic diad content increased with decreasing polymerization temperature and increasing VAc concentration due to a steric hindrance effect of TBA during polymerization.

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A Study on Quadcopter Consisting of Dual Li-Po Battery Charging by Solar Cell in the Engineering Education Completed a Senier Project Work at the University (공학교육 이수체계에서 대학 졸업 작품용 이중 Li-Po 전원 사용 태양전지 충전 쿼드콥터 구성에 관한 연구)

  • Yoon, Seong-Geun;Kim, Kyung-Bin;Chang, Eun-Young
    • Journal of Practical Engineering Education
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    • v.8 no.1
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    • pp.9-14
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    • 2016
  • Depending on the college graduation project and graduation thesis regulations for the certification and graduation requirements, the quadcopter acting as a Li-Po battery that charges by solar energy are proposed a design method and improvements in theory. Quadcopter posture is balanced and confirmed by the position sensor, through a PID (Proportional Integral Differential) control. Battery switching circuit is composed of two Li-Po battery. Driving the quadcopter as one battery, and does not use other battery is charged by solar energy. A battery switching circuit is fabricated in a manner that uses two types of relays. Even if completely not charged to the battery is being driven a certain switch by the battery charging voltage from time to time, it proposes a method for increasing the endurance time and range.

Experimental Study on Failure Characteristics of Riprap Revetments in Meandering Channel (만곡부 흐름특성을 고려한 사석호안공 붕괴 수리실험 연구)

  • Bae, Deok-Won;Kim, Hyung-Jun;Yoon, Kwang-Seok
    • Proceedings of the Korea Water Resources Association Conference
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    • 2012.05a
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    • pp.696-696
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    • 2012
  • 호안은 유수의 침입으로부터 제방 및 하안의 침식 피해를 방지하기 위해 제방에 설치되는 구조물이다. 침식에 의한 제방 및 호안의 대표적인 붕괴특성 중에는 만곡부, 하천 급경사, 지형의 간섭효과 등이 있다. 특히, 만곡부는 원심력, 2차류 등에 의한 수위상승 및 유속증가로 제체에 응력 집중이 발생되어 안정성 저하를 유발할 수 있다. 또한, 만곡부의 흐름 방향전환 현상은 하도내 통수능 저하를 발생시켜 홍수피해를 가중시킬 수 있다. 따라서 하천특성상 만곡부에 의해 발생할 수 있는 홍수피해 요소를 저감시킬 수 있도록 적합한 피해저감대책을 마련할 필요가 있다. 제방의 보강대책으로서 활용되고 있는 호안은 역학적인 측면에서 외력과 저항력의 크기에 따라 안정성이 평가되어야 하며 지역여건 등에 따른 만곡부의 수위상승 및 제방 침식 등을 고려한 설계가 수행되어야 한다. 국내 실무에서 적용되고 있는 호안설계방법은 하천설계기준 해설(2009)을 참고하고 있는데, 흐름현상 및 만곡부 특성 등에 대하여 경험과 이론의 양면을 고려한 설계를 수행하도록 제안하고 있다. 이는 호안 안정성에 대한 역학적 검토 방법의 한계로 비합리적 설계가 될 우려가 있다. 따라서 만곡부에 의한 유속 및 소류력 등 흐름특성을 고려한 정량적인 평가기법이 요구되는 상황이다. 본 연구에서는 수리실험을 통해 만곡에 의한 흐름영향과 수리학적 거동 및 설계요소를 파악하고자 만곡부에 사석호안공을 설치하여 흐름전환 및 유속변화에 따른 사석호안공의 이탈현상을 재현하였다. 실험수로는 곡률반경( )이 4.5 m인 만곡부가 3개소 발생하는 폭 2.3 m, 길이 25 m의 다중 사행수로 형태이다. 실험수로 우안의 1V:2H 경사면에 10, 20, 30, 40, 50 mm 사석을 크기별로 설치하여 만곡에 의한 유속변화 등 흐름현상과 호안공 이탈을 관찰하였다. 수리실험은 고정상으로 수행되었으며 정상류 흐름조건에서 공급유량별 하류단 수위 조절을 통해 만곡부내 호안 공 이탈을 발생시키는 설계인자를 도출하고자 유속과 수심을 측정하였다. 실험결과를 바탕으로 사석호안공 설계시 1차원 접근유속에 만곡 영향을 고려하여 대표유속으로 적용하는 방법의 특성을 파악하고, 사석호안공의 이탈유속과 만곡에 의한 흐름특성간의 상관관계를 분석하여 제원결정기법을 제안하였다.

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Theoretical Background and Practice of Anti-dumping Policy in EU (EU 반덤핑정책의 이론적 배경과 실제)

  • Lee, Kab-Soo
    • International Area Studies Review
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    • v.16 no.3
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    • pp.269-291
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    • 2012
  • Analyzing EU trade laws and institutional systems, the trade policy of EU has been founded, undoubtedly, on common interests for EU members. EU trade policy leaves room for 'Collective Protectionism' by permitting legal persona or interesting group to raise anti-dumping procedures. The anti-dumping policy of EU has shown a protectionism itself and has been affected by political motives. Investigation against anti-dumping can easily open and also there exists a wide range of political involvements. Furthermore, anti-dumping policy could be misused for protecting declining industries, which lost comparative advantage in global market. Economic theories show that anti-dumping measures divert import from outsider into insider members, which finally results in increasing intra-production of EU. This is exactly the reason why the anti-dumping policy has become attractive trade policy.

A Study on the Mobilization Simulation Mode of Government Exercise for Emergency (비상대비 정부연습의 동원 시뮬레이션 모형에 관한 연구)

  • Joo, Choong-Geun;Lee, Sung-Lyong
    • The Journal of the Korea Contents Association
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    • v.21 no.10
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    • pp.476-493
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    • 2021
  • This study is on the simulation conditions of the tentative 'mobilization simulation mode'(MOBSM) and the setting option of major simulation elements. The MOBSM is a training module that practices mobilization of various institutions through a simulation computer similar to actual situations. So far, mobilization exercise(Mob-Ex) is a message simulation method, so it is necessary to convert into a MOBSM because many problems such as fragmentary and practice only by some institutions are raised. Therefore, the theoretical background and previous studies on Mob-Ex and simulation were reviewed to derive the requirements and simulated elements of the MOBSM to meet the purpose of government level exercise and to suggest the critical concepts and the direction of application. The basic requirement is to simulate the main mobilization practices by institution and provide information on the mobilization execution in a nationwide scope. The simulation elements are simulated events and flow charts by mobilization type, simulated range and level by object, simulated contents of material mobilization by institution, key simulated items, DB application, and simulated period, etc. This study will be useful for policy establishment and follow-up research for technology development of MOBSM in the future, and will accelerate the transition to practical mobilization exercise by MOBSM.

Characterizing Human Behavior in Emergency Situations (비상상황에서의 인간 행동 특성화 연구)

  • Lee, Jun;Yook, Donghyung
    • Journal of the Society of Disaster Information
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    • v.18 no.3
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    • pp.495-506
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    • 2022
  • Purpose: When a serious disaster occurred in East Japan on March 11, 2011, some evacuees in shock failed to avoid danger to the best of their ability. Why did they hesitate and waste their time? And why didn't they choose correct escaping routes? This study attempts to classify human behavior through psychological point of view and cognitive science and to interpret behavioral patterns based on animal behaviors from the field of biology. Method: This study first conceptually categorized walking behavior into intellectualization, automaticity and instinct based on the existing literature and matched these with empirical data. Result: The actual walking patterns observed failed to be compatible with these categories and consequently, this study suggests the following five categories: normal, busy, fast & straight, freezing and tizzy. This new classification of walking behavior is based on speed, variation of speed and change of direction. Conclusion: The method used in this study and the results can be applied to simulations of walking behavior and analysis of behavior in emergency situations.

The Music Listener's Experience of Listening to Music Changed by the COVID-19 Pandemic (코로나19 팬데믹이 변화시킨 음악 수용자의 음악 청취 경험)

  • Choe, Hee-Jin
    • The Journal of the Korea Contents Association
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    • v.21 no.11
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    • pp.281-293
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    • 2021
  • The purpose of this study is to analyze how Corona daily life has changed the music listeners' music listening experience and what meaning the music listeners are discovering in their music listening experience. This study considered the sociology of music, and music as a medium of perception and consciousness from a theoretical perspective. After that, the purpose of this study was to extract the meaning of subjective interpretations of music listening tendencies and music listening experiences for college students who took music-related classes from 20 to 24 years old. The research methods were written interview and free discussion analysis. As a result of the study, 76% of those interviewed in writing answered that their tendency to select music in daily life had changed. The main reasons were: First, finding a utopia in 'home' with music, second, finding and listening to new music with increasing time, third, getting out of 'corona blue' with music. College students were discovering new meanings in physical isolation through listening to music. They were discovering the meaning of 'self-healing' in listening to music, and they were changing the direction of their desired consciousness and emotions through music.

The Effect of Virtual Tour Experience on Actual Travel Intention -Focusing on the Moderating Effect of Happiness (가상관광체험이 현장여행의도에 미치는 영향 -행복의 조절효과를 중심으로)

  • Weijia Li;Yuejun Wang;Ziyang Liu
    • Journal of Intelligence and Information Systems
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    • v.29 no.1
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    • pp.65-78
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    • 2023
  • This study is based on place attachment theory, explores how to transform tourists' virtual experience into on-site tourism willingness through virtual attachment, And explores the moderating role of happiness in it. A real travel intention model is constructed for people who work in tourism or have the ability to travel alone. Analyzed through analysis tools such as SPSS and AMOS, We hope to explore if the virtual experience can be transformed into a willingness to travel on the ground, and how happiness moderates virtual attachment to virtual tourism experiences. The result shows, the relationship between Virtual Travel Experience and Virtual Attachment is moderated by Happiness, Virtual Attachment is positively related to Place Attachment (Place dependence & Place identity), Place Attachment is positively related to Real Travel Intention. The relationship between tourists and tourist destinations is explored in depth through this study to provide references and suggestions for tourism development.

The Performance of Grant-type Government R&D Project: Focusing on SME's R&D (자유공모형 국가연구개발 과제의 특성 및 효과성 분석 : 중소기업 R&D를 중심으로)

  • Seulki Hong;Sung Joo Bae
    • Journal of Technology Innovation
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    • v.30 no.4
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    • pp.57-82
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    • 2022
  • As the strategy to support SMEs' innovation has shifted to induce market-oriented innovation, the Korean government increasingly invests in grant-type R&D projects proposed by SME firms. This study reveals the characteristics of grant-type R&D projects proposed by SME firms through a transition of national R&D strategy and demand-pull innovation perspectives. This study also examines the differences between grant-type R&D projects proposed by firms and R&D projects led by the government through logit-analysis and propensity score matching methods. As a result, we found that a national R&D project for SMEs yields better innovation performance when the project is proposed by a company than led by the government.

Allocating CO2 Emission by Sector: A Claims Problem Approach (Claims problem을 활용한 부문별 온실가스 감축목표 분석)

  • Yunji Her
    • Environmental and Resource Economics Review
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    • v.31 no.4
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    • pp.733-753
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    • 2022
  • Korean government established the Nationally Determined Contribution (NDC) in 2015. After revising in 2019, the government updated an enhanced target at the end of last year. When the NDC is addressed, the emission targets of each sector, such as power generation, industry, and buildings, are also set. This paper analyzes the emission target of each sector by applying a claims problem or bankruptcy problem developed from cooperative game theory. The five allocation rules from a claims problem are introduced and the properties of each rule are considered axiomatically. This study applies the five rules on allocating carbon emission by sector under the NDC target and compares the results with the announced government target. For the power generation sector, the government target is set lower than the emissions allocated by the five rules. On the other hand, the government target for the industry sector is higher than the results of the five rules. In other sectors, the government's targets are similar to the results of the rule that allocates emissions in proportion to each claim.