• Title/Summary/Keyword: 전해조

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Achievement of a $10^{-11}$ Torr Ultrahigh Vacuum System ($10^{-11}$Torr의 초고진공 실현)

  • 유운종;이재선;김명길;서성기
    • Journal of the Korean Vacuum Society
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    • v.1 no.1
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    • pp.28-31
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    • 1992
  • 초고진공 시스템을 구성할 때 고려할 요소는 진공용기의 세척과 표면조도, 진공용 기의 재질, 기타 방출기체의 요인이다. 초고진공용기를 전해연마 처리하였으며, 처리한 진공 용기의 표면조도를 표면 조도기(surface profiler)로 측정하였다. 진공용기는 직경 300mm이 고 높이는 720mm로 하였다. 설치한 초냉각 펌프로 18시간 배기후 2.9 $\times$ 10-10Torr를 얻었 으며, 계속해서 초고진공용기를 250에서 60시간 baking 후 최저도달 압력이 3.08 $\times$ 10-11torr에 도달하였다 누드 이온게이지를 이용하여 초고진공용기의 최저도달압력과 누출비 를 측정하였다.

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Secondary Concentration Technology of Brine from Membrane Seawater Desalination Process with Electrodialysis (전기투석을 이용한 분리막 담수화 공정 배출 농축수의 이차 농축기술)

  • Moon, Jeong-Ki;Park, Kwang-Seok;Yoo, Yoon-Ki;Yun, Young-Ki
    • Transactions of the KSME C: Technology and Education
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    • v.1 no.1
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    • pp.69-73
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    • 2013
  • This study is about the secondary concentration technology using electrodialysis process for minimum discharge and maximize recovery ratio from seawater desalination by reverse osmosis process. The experimental method adopted the constant voltage driving method and, concentrated/desalination volume capacity ratio changes, voltage changes and electrolyte types. Multi-ion membrane is used, aiming to derive conditions to minimize the TDS concentration of desalination water, to minimize the volumes of secnodary concentraion water and minimizing the power efficiency. The results of this study are as follows. The optimal ratio of concentraion/desalination volume is 1:5, the final TDS concentration of desalinated water is 5.32g/l, the final secnodary concentrated water salinity is 17.07% and electric energy demands of desalinated water is $16.74kWh/m^3$.

Localization Development of On-Site High Sodium Hypochlorite Generation (고농도 차아염소산나트륨 발생장치 국산화 개발)

  • Kim, Jung Sik;Shin, Hyun Su;Lee, Eun Kyoung;Jung, Bong Ik
    • Transactions of the KSME C: Technology and Education
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    • v.1 no.1
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    • pp.83-90
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    • 2013
  • The purpose of this study is to replace existing liquid chlorine with localization of on-site high (12%) sodium hypochlorite generation system. On-site high (12%) sodium hypochlorite generation system is higher the current efficiency of 38.7%, 54.6% reduction of salt consumption, and 97.3% lower rate of chlorate than on-site low (0.8%) sodium hypochlorite generation system.

Recovery of High Purity Sn by Multi-step Reduction of Sn-Containing Industrial Wastes (건식 환원 공정을 이용한 고순도 주석 회수)

  • Lee, Sang-Ro;Lee, Man-Seung;Kim, Hyun You
    • Resources Recycling
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    • v.24 no.3
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    • pp.11-15
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    • 2015
  • In order to develop a technology for the recovery of pure tin from the Sn containing industrial wastes (SIWs), a process consisted of high temperature reduction and electrorefining was investigated. The tin which exists as oxide in SIWs was successfully reduced by two consecutive high temperature treatments and 92.7% of the tin was recovered. The purity of the tin thus obtained was increased to 99.87% by electrorefining. By applying the results obtained in this work, a commercial process can be developed to produce pure tin metals from domestic spent resources, which can reduce the amount of tin imported from abroad.

Continuous removal of phosphorus in water by physicochemical method using zero valent iron packed column (영가철 충진 컬럼을 이용한 연속적인 물리화학적 수중 인 제거)

  • Jeong, Jooyoung;Ahn, Byungmin;Kim, Jeongjoo;Park, Jooyang
    • Journal of Korean Society of Water and Wastewater
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    • v.27 no.4
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    • pp.439-444
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    • 2013
  • Excessive phosphorus in aquatic systems causes algal bloom resulting in eutrophication, DO depletion, decline in recreational value of water and foul tastes. To treat wastewater containing phosphorus including effluent of wastewater treatment plant, the continuous experiments were performed by using electrochemical way. The spherical ZVI and silica sand which act as physical filter are packed at appropriate volume ratio of 1:2. Electric potential is applied externally which can be changed as per the operational requirement. The results indicate that optimum hydraulic retention time of 36 minutes (10 mL/min at 1 L reactor) was required to meet the effluent standards. Lower concentrations of phosphorus (<10 mg/L as phosphate) were removed by precipitation by contact with iron. Thus, additional electric potential was not required. In order to remove high concentration phosphorus around 150 mg/L as phosphate, external electric potential of 600 V was applied to the reactor.

Recovery of Tin from Tin Oxide Resulted from Glass Manufacturing Process by Pyrometallurgy (유리생산공정 폐주석산화물에서 건식제련에 의한 주석회수기술)

  • Lee, Sang-Ro;Kim, Sang-Yeol;Lee, Man-Seung;Park, Man-Bok
    • Resources Recycling
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    • v.24 no.2
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    • pp.23-28
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    • 2015
  • Most of the domestic need for tin rely on imports. In this work, a pyrometallurgical process was investigated to recover pure tin from the tin oxides in tin bath which results from the production of flat glass and LCD panel. From the results on the effect of reaction temperature, the highest recovery percentage of tin was obtained at $1350^{\circ}C$. The recovery percentage of tin was improved to 88% by employing the first and second smelting step. Electrorefining of the crude tin thus obtained led to pure tin with purity higher than 99.9%.

Developing High-Performance Polymer Electrolyte Membrane Electrolytic Cell for Green Hydrogen Production (그린수소 생산을 위한 고성능 고분자 전해질막 전해조 개발 연구)

  • Choi, Baeck Beom;Jo, Jae Hyeon;Lee, Yae Rin;Kim, Jungsuk;Lee, Taehee;Jeon, Sang-Yun;Yoo, Young-Sung
    • KEPCO Journal on Electric Power and Energy
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    • v.7 no.1
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    • pp.137-143
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    • 2021
  • As an electrochemical water electrolysis for green hydrogen production, both polymer electrolyte membrane (PEM) and alkaline electrolyte are being developed extensively in various countries. The PEM electrolyzer with high current density (above 2 A/cm2) has the advantage of being able to design a simple structure. Also, it is known that it has high response to electrical output fluctuations. However, the cost problem of major components is the most important issue that a PEM electrolyzer must overcome. Instantly, there are platinum group metal (PGM)-based electrocatalysts, fluorine-based polyfluoro sulfuric acid (PFSA) membrane, Ti felt (porous transport layer, PTL) and so on. Another challenging issue is productivity. A securing outstanding productivity brings price benefits of the electrolytic cells. From this point of view, we conducted basic studies on manufacturing electrode and membrane electrode assembly (MEA) for PEM electrolyzer production.

Tidal Variation of Waves in Kyung-Gi Bay (경기만 조석조건에서의 파랑변이)

  • 김지웅
    • Journal of Korean Society of Coastal and Ocean Engineers
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    • v.12 no.2
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    • pp.87-95
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    • 2000
  • Spectral wave models are applied to the area of Kyung-gi bay with two different combinations. One combination assumes a constant tidal elevation over the whole region when applying the wave model to the area. In this case no tidal currents exist in any place. The other combination employs tide model as well as wave model so that tidal condition is defined at every computation time when wave modelling is carried out. Significant wave heights and wave directions are shown for these two cases. With these two different constraints of tidal variation, the results are checked and compared with each other. Both results are found significantly different from each other.

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The PWM Control Which used Microprocessor for Intensity Control of Acid Ion Water (산성이온수 농도제어를 위한 Microprocessor를 이용한 PWM 제어)

  • Kwon, Yunjung;Nam, Sangyep
    • Journal of the Institute of Electronics and Information Engineers
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    • v.50 no.7
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    • pp.269-274
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    • 2013
  • We are used with the alkaline ion water which an application field does to object for drinking water compare with the alkaline ion water which asked ion acid electrolysis so as to be very different. This is used with sterilization disinfection use by residual chlorine in case of strong acidity according to ph intensity, and in case of middle acidity use by washing and face washing, and mix with meal materials in case of weak acidity widely usable in cooking. Acid ion water generates as we electrolyze water. Chlorine gas and sodium hydroxide etc. was generated at electrolysis process, and we have toward sterilizing power. Derelicts such as chlorine, phosphorus, sulfur etc. are gathered from a negative ion, and we make acid ion water to + electrode direction in electrolysis. We used a diaphragm in order to disconnect too acid water and alkaline water. We implemented so that the acid water which it came down to three kinds of PWM voltage to PWM (pulse width modulation) control, and implementation method of ph intensity change authorized ph intensity between weak acidity to electrode in strong acidity as we used Microprocessor, and intensity was adjusted successively by PWM control was generated.

Regeneration of PCB Etchants and Copper Recovery in a Batch-type Electrolytic Cell (회분식 전해조에서 PCB 식각폐수의 재생 및 구리의 회수)

  • Nam, Sang Cheol;Nam, Chong Woo;Tak, Yongsug;Oh, Seung Mo
    • Applied Chemistry for Engineering
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    • v.8 no.2
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    • pp.161-171
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    • 1997
  • Anodic regeneration of PCB enchant and cathodic deposition of copper using electrochemical method has been studied. Cu(I)/Cu(II) concentration ratio as a function of Cu(I) oxidation at the anode was measured from the potential difference between platinum and Ag/AgCl/4M KCl electrodes. Chlorine gas evolution was minimized by maintaining Cu(I) concentration above a specific concentration and using non-porous graphite electrode. Dendritic copper deposition was observed at the cathode and the optimum conditions for Cu deposition was identified as the current density of $360mA/cm^2$, and copper concentration of 12 g/l. Titanium was the most effective cathode material which showed a higher current efficiency and copper recovery. The current efficiency decreased with increasing temperature, but the highest power efficiency was achieved at $50^{\circ}C$.

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