• Applied Chemistry for Engineering
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• v.35 no.2
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• pp.128-133
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• 2024

Although antisolvent-assisted crystallization is one of the promising processes to produce high-quality perovskite films, general antisolvents such as chlorobenzene (CB) have toxic and volatile properties. In addition, CB is not suitable to control the crystallization of perovskite in the atmospheric air. In this work, isopropyl acetate (IA) is used as an eco-friendly antisolvent to demonstrate air-processed perovskite solar cells, and ethyl-4-cyanocinnamate (E4CN) with a cyano group, carbonyl group, and aromatic ring is introduced in IA to improve the performance and stability of devices. Defects at the surface and grain boundaries of the perovskite layer, such as un-coordinated Pb²⁺ and iodine, can be decreased resulting from the interaction of E4CN and perovskite, and thus reduced recombination and enhanced carrier transport can be expected. As a result, the perovskite device with E4CN achieves a high maximum power conversion efficiency (PCE) of 18.89% and outstanding stability, maintaining 60% of the initial efficiency for 300 h in the air without any encapsulation.

• Korean Journal of Soil Science and Fertilizer
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• v.17 no.2
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• pp.147-154
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• 1984

Two Fe-hydrous oxide A,B and one Al-hydroxide minerals were synthesized precipitating Fe $Cl_3$ and $AlCl_3$ with alkali solution(NaOH) at pH 6.0, 12.0 and 4.5 respectively, for precise understanding of physico-chemical and surface charge characteristics of soils in which these minerals are dominant. Identification of these final products, effect of free and amorphous materials on X-ray diffraction analysis, particle size distribution and surface change characterics of these minerals were performed. Fe-hydroxide A and B were identified as great deal of X-ray amorphous material and as goethite with large amount of X-ray amorphous material, respectively. Dehydration by oven at $105^{\circ}C$ of these minerals exhibited akaganeite peaks with low X-ray amorphous hump and pure goethite peaks for Fe-hydroxide A and B, respectively. Both minerals, however, turned into hematite upon firing at $550^{\circ}C$. On the other hand, Al-hydroxide identified as mixture of gibbsite and bayerite of around 7:3 ratio. Application of sodium dithionite and ammonium oxalate solutions for removal of free or amorphous Fe and Al from these minerals revealed that only peak intensities of Al-hydroxide system were enhanced upon Al-extraction by oxalate solution even though dithionite solution was much powerful to extract Fe from Fe-hydrous oxide systems. Original(wet) Fe-hydrous oxide A has the highest specific surface and surface charge development(negative and positive), and the greatest amount of less than $2{\mu}m$ sized particles. Specific surface and clay sized particles(less than $2{\mu}m$) of Fe-hydrous oxide A, however, were drastically reduced upon dehydration($P_2O_5$ and oven drying) compare to the rest minerals. The Z.P.C. of these synthetic minerals were 8.0-8.5, 7.5-8.0 and 5.5-6.0 for Fe-hydrous oxide A, B and Al-hydroxide, respectively.

• MISULJARYO - National Museum of Korea Art Journal
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• v.96
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• pp.155-180
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• 2019

Samsaebulhoedo(三世佛會圖) at Yongjusa Temple(龍珠寺), regarded as a monumental masterpiece consisting of different elements such as Confucian and Buddhist ideas, palace academy garden and Buddhist artist styles, unique traditional and western painting styles, is one of the representative works that symbolically illustrate the development and innovation of painting in the late Joseon dynasty. However, the absence of painting inscriptions raised persistent controversy over the past half century among researchers as to the matters of estimating its production period, identifying the original author and analyzing style characteristics. In the end, the work failed to gain recognitions commensurate with its historical significance and value. It is the particularly vital issue in that estimating the production period of the existing masterpiece is the beginning of all other discussions. However, this issue has caused the ensuing debates since all details are difficult to be interpreted to a concise form due to a number of different records on painters and mixture of traditional buddhist painting styles used by buddhist painters and innovative western styles used by ordinary painters. Contrary to other ordinary Buddhist paintings, this painting, Samsaebulhoedo, has a praying letter for the royal establishment at the center of the main altar. It should be noted that regarding this painting, its original version-His Royal Highness King, Her Majesty, His Royal Crown Prince主上殿下, 王妃殿下, 世子邸下-was erased and instead added Her Love Majesty慈宮邸下 in front of Her Majesty. This praying letter can be assumed as one of the significant and objective evidence for estimating its production period. The new argument of the late 19th century production focused on this praying letter, and proposed that King Sunjo was then the first-born son when Yongjusa Temple was built in 1790 and it was not until January 1, 1800 that he was ascended to the Crown Prince. In this light, the existing praying letter with the eulogistic title-Crown Prince世子-should be considered revised after his ascension to the throne. Styles and icons bore some resemblance to Samsaebulhoedo at Cheongryongsa Temple or Bongeunsa Temple portrayed by Buddhist painters in the late 19th century. Therefore, the remaining Samsaebulhoedo should be depicted by them in the same period as western styles were introduced in Buddhist painting in later days. Following extensive investigations, praying letters in Buddhist paintings in the late 19th century show that it was usual to record specification such as class, birth date and family name of people during the dynasty at the point of producing Buddhist paintings. It is easy to find that those who passed away decades ago cannot be revised to use eulogistic titles as seen by the praying letters in Samsaebulhoedo at Yongju Temple. As "His Royal Highness King, Her Majesty, His Royal Crown Prince" was generally used around 1790 regardless of the presence of first-born son or Crown Prince, it was rather natural to write the eulogistic title "His Royal Crown Prince" in the praying letter of Samsaebulhoedo. Contrary to ordinary royal hierarchy, Her Love Majesty was placed in front of Her Majesty. Based on this, the praying letter was assumed to be revised since King Jeongjo placed royal status of Hyegyeonggung before the Queen, which was an exceptional case during King Jeongjo's reign, due to unusual relationships among King Jeongjo, Hyegyeonggung and the Queen arising from the death of Crown Prince(思悼世子). At that time, there was a special case of originally writing a formal tripod praying letter, as can be seen from ordinary praying letter in Buddhist paintings, erasing it and adding a special eulogistic title: Her Love Majesty. This indicates that King Jeongjo identified that Hyegyeonggung was erased, and commanded to add it; nevertheless, ceremony leaders of Yongju Temple, built as a palace for holding ceremonies of Hyeonryungwon(顯隆園) are Jeongjo, the son of his father and his wife Hyegyeonggung (Her Love Majesty)(惠慶宮(慈宮)). This revision is believed to be ordered by King Jeongjo on January 17, 1791 when the King paid his first visit to the Hyeonryungwon since the establishment of Hyeonryungwon and Yongju Temple, stopped by Yongju Temple on his way to palace and saw Samsaebulhoedo for the first and last time. As shown above, this letter consisting of special contents and forms can be seen an obvious, objective testament to the original of Samsebulhoedo painted in 1790 when Yongju Temple was built.

• The Korean Journal of Mycology
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• v.17 no.3
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• pp.105-113
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• 1989

For selective purification of proteins in Pleurotus cornucopiae, affinity chromatography was performed by p-aminoanilinylsuccinyl-AH-Sepharose 4B gel synthesized by treating p-phenylene diamine with succinyl-AH-Sepharose 4B, which was prepared by treating AH-Sepharose 4B with succinic anhydride. The capacity of p-aminoanilinyl ligand group was 6.1 micromole per milliliter of gel. Total apparent molecular weight of the affinity proteins eluted from the synthesized gel was 167 KD, which were a protein complex of 130 KD and 37 KD. The contents of the nonpolar, polar, positively and/or negatively charged amino acids in the affinity protein were 44.57%, 24.75%, 21.25%, and 9.43%, respectively. Total apparent molecular weight of the affinity proteins eluted from the AH-Sepharose 4B gel was 95.2 KD, which were a protein complex of 61 KD, 31 KD and 3.2 KD. The contents of the nonpolar, positively and/or negatively charged amino acids in the affinity protein by AH-Sepharose 4B gel were 44.05%, 29.13%, and 12.91% respectively.

• The Safety technology
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• no.166
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• pp.12-14
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• 2011

불과 2년 전 한적한 시골 농경지였던 충청남도 서천군 마서면 일대. 푸른 들판과 초록의 나무만 가득했던 이곳이 환경보존의 중요성을 알리는 '생태원'으로 변하고 있다. 무려 99만8,000$m^2$의 사업부지에 생태연구센터, 생태교육센터, 생태체험관, 야외생태체험공간 등이 내년 말 완공을 목표로 한창 조성되고 있는 것. 각 시설 모두가 세간의 큰 관심을 받고 있지만 그중에서도 삼성물산 건설부문이 시공 중에 있는 '국립 생태체험관'은 아직 완공 전임에도 국내를 넘어 세계적으로 유명세를 떨치고 있다. 열대관, 아열대관, 지중해관, 온대관 극지관 등 지구의 5대 생태계를 재현하는 '국립 생태체험관'은 전 세계 각지의 유명 생태관들의 모든 장점에다 국내만의 독창성을 더해 현존 최고 생태체험관의 탄생을 예고하고 있다. 때문에 시공사의 자긍심이 남다른 것은 당연한 일. 최신 친환경 공법을 바탕으로 건물의 가치를 높이는데 혼연의 힘을 다하고 있다. 특히 시공 과정에서 가장 많은 신경을 쓰는 것이 바로 '안전'이다. 후세에 환경보전과 보호의 필요성을 전하는 의미 깊은 장소이니 만큼 안전사고로 그 취지를 얼룩지게 할 수 없다는 것이 이곳 임직원의 각오. 안전으로 역사에 기록될 건축물을 만들고 있는 삼성물산 건설부문의 '국립 생태체험관' 신축현장을 찾아가 봤다.

• Proceedings of the Korean Vacuum Society Conference
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• 2012.08a
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• pp.234-234
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• 2012

고효율 저전력 고휘도를 장점으로 가지고 있는 OLED의 개선을 위하여 수많은 재료와 기술이 연구되어 왔다. 전기적 손실의 방지를 위하여 다양한 재료가 연구되고 있지만 그 중에서도 가장 각광받는 것은 그래핀이다. 그래핀(graphene)은 탄소원자가 육각형 벌집 모양 배열의 격자구조를 가지는 원자 단층 두께의 물질이다. 그래핀은 에너지와 역격자의 k 벡터가 선형적으로 비례하며 전도띠(conduction band)와 가전자띠(valence band)가 한 점에서 만나는 구조를 가지는 특징으로 인해 매우 빠른 전하 이동도(Mobility)를 가지고 있다. 이와 같은 그래핀의 특성을 이용하여 전극 층으로 이용함으로써 소자 특성의 개선이 가능할 것으로 예상되었다. $1{\times}1$ inch Glass에 ITO 대신에 그래핀을 증착한 후 Spin coater를 사용하여 PEDOT을 각각 1,000 rpm, 2,000 rpm으로 도포 하였다. 그 후 HTL (Hole transport latey), ETL (Electron-transport layer), EML (Emissive layer), EIL (Electron injection layer)를 순차적으로 증착 하여 소자를 제작하였다. 발광층에는 유기물질 Alq3를 사용하여 녹색광을 방출하도록 하였다. Spin coater의 rpm에 따라 전도성 고분자의 두께가 결정이 되는데, rpm이 높을수록 두께가 얇으며, 얇을수록 소비전력 효율이 낮다. 하지만 전류밀도 특성이 균일하지 못한 것을 확인하였다. 휘도 효율 특성은 PEDOT의 두께가 얇을수록 동일한 전압에서 휘도가 낮은것을 확인 하였다. 또한 ITO를 이용한 동일 공정의 OLED와 비교하였을 때 상대적으로 낮은 휘도와 전류 효율특성을 보였지만, 전류밀도는 상대적으로 그래핀이 높은 것으로 확인되었다. 본 연구를 바탕으로 그래핀 소자의 개선이 이루어진다면 더욱 높은 효율과 휘도를 낼 수 있을 것으로 판단된다.

• Applied Chemistry for Engineering
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• v.26 no.1
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• pp.116-119
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• 2015

Field-effect transistor (FET)-based ion or biosensors have been intensively studied so far. Among many measurement methods, the variation of the drain current can be induced when ions or biomolecules are interacted with sensing membranes located on the gate insulator of FET. One of typical FET-type sensors is an ion-sensitive field-effect transistor (ISFET) utilized in this study. In ISFET, the voltage is usually applied to the reference electrode instead of the gate voltage. Firstly, the voltage applied to the reference electrode versus the drain current was observed, and the steepest slope in this graph was found. Using this point, the optimized condition was established for the larger variation of the drain current in the saturated region in response to the variation of the input in the dynamic range.

• Magazine of the Korea Concrete Institute
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• v.6 no.2
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• pp.159-168
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• 1994

The present study proposes a realistic method to analyze the prestressed concrete members subjected to torsion. For this end, this study devises a method to realistically take into account the tensile stiffness of concrete after cracking. The effects of biaxial compressive and tensile loadings on the compressive and tensile strengths of concrete are also taken into account in the present model. The comparison of the present theory with experimental data indicates that the proposed model dipicts reasonably well the actual behavior of prestressed concrete members subjected to torsion. The present model can predict not only the service load behavior, but also up to the behavior of ultimate load stages.

• 한국신재생에너지학회:학술대회논문집
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• 2009.06a
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• pp.168-168
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• 2009

고효율 실리콘 이종접합 태양전지 제작을 위한 요소기술 중 a-Si:H/c-Si 간의 계면 안정화는 태양전지 효율에 중요한 역할을 한다. 본 연구에서는 n-type 결정질 실리콘 기판을 사용하여, 소수전하들의 재결합을 방지하고, 계면 안정화를 실행하는 방안으로 실리콘 기판 습식 세정을 수행하였다. 반도체 공정에서 일반적으로 알려진 RCA 세정기법에 HF 세정을 마지막공정으로 추가하여 자연 산화막과 기타 불순물을 더욱 효과적으로 제거할 수 있도록 실험을 진행하였다. 마지막 공정으로 추가된 HF 세정에 의한 a-Si:H/c-Si 계면 안정화 효과를 관찰하기 위하여 HF농도와 HF 세정시간에 따른 소수반송자 수명을 측정하였다. 또한 HF 세정 이후 공정의 영향을 확인하기 위하여 PE-CVD법으로 a-Si:H 박막 증착 이전 실리콘 기판의 온도와 상온에서 머무는 시간에 따른 a-Si:H/c-Si 계면안정화 특성을 분석하였다. 본 실험을 통해 HF세정공정이 계면특성에 미치는 영향을 확인하였으며 실리콘 기판 습식 세정이 이종접합태양전지 특성에 미치는 영향을 분석하였다.

• Proceedings of the Korean Vacuum Society Conference
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• 2013.02a
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• pp.372-372
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• 2013

기존의 MOSFET 구조의 소자는 비례 축소에 의한 단 채널효과, 누설전류, 신뢰성 문제 같은 어려움에 직면해 있다. 이로 인해 20 nm 이하 소자 크기에서 기존의 MOSFET을 대체할 여러가지 차세대 소자에 대한 연구가 활발히 진행 되고 있다. 그 중에서 FinFET 소자는 비례 축소에 용이하고 누설전류 문제에 대한 장점으로 인해 활발한 연구가 진행되고 있다. 기존의 FinFET 소자에 대한 연구는 FinFET 구조를 이용한 메모리 소자의 전기적 특성의 향상, fin의 크기에 따른 소자의 특성 변화와 FinFET 구조의 물질 변화에 따른 전기적 특성 변화에 대한 연구가 많이 이루어져 왔다. 실제 공정에서의 fin의 형태 변화에 따른 전기적 특성변화에 대한 연구가 필요하다. 본 연구에서는 fin의 모서리의 모양의 변화에 따른 FinFET 소자의 전기적 특성 변화를 관찰하였고 전하 수송 메커니즘을 규명하였다. 실제 FinFET 소자의 공정에서 fin의 형태는 이상적인 직육면체 모양이 아니라 옆면이 기울고 모서리가 곡선이 되게 된다. 이로 인한 전자의 이동도 변화로 인해 소자의 성능이 변화하게 된다. FinFET의 경우 채널을 구성하는 fin의 각 면의 Si의 orientation이 다르다. 또한 fin의 모서리의 모양이 변화 함에 따라 채널영역의 orientation이 변화 하게 된다. 이에 따라 fin의 모서리 모양의 변화에 따른 소자의 전기적 특성 변화를 multi-orientation mobility model을 포함한 three-dimensional TCAD 시뮬레이션을 통해 계산하였다. 옆면과 윗면이 만나는 모서리의 모양의 곡률의 크기를 증가하여 다양한 fin의 형태에서 전기적 특성을 관찰하였다. Fin의 옆면과 윗면이 만나는 모서리의 곡률이 증가함에 따라 depletion 영역의 크기 변화와 채널에서의 전자의 밀도와 이동도의 변화를 관찰하였고 이를 토대로 fin의 형태 변화가 FinFET 소자의 전기적 특성에 미치는 영향을 조사하였다.