• Title/Summary/Keyword: 전자포획

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Multi-residue Analysis of Pesticides using GC-TOF/MS, ECD, NPD with QuEChERS Sample Preparation (QuEChERS 전처리법과 GC-TOF/MS, ECD, NPD를 이용한 잔류농약 다성분분석)

  • Park, Jungwook;Kim, Aekyung;Kim, Jongpil;Lee, Hyanghee;Park, Duckwoong;Moon, Sujin;Ha, Dongryong;Kim, Eunsun;Seo, Kyewon
    • The Korean Journal of Pesticide Science
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    • v.18 no.4
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    • pp.278-295
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    • 2014
  • Fast and accurate multi-residue pesticides inspecting method needs in Agro-Fishery Products Inspection Center. So, We tried to seek the optimum method using GC-TOF/MS, GC-ECD, GC-NPD after QuEChERS sample preparation. In GC-TOF/MS, 138 kinds of pesticide were spiked at 0.3 and $0.5{\mu}g/g$for the identification and quantification in lettuce sample. Recoveries of 77 pesticides were between 70 and 130% with RSD (relative standard deviation lower than 20% at $0.3{\mu}g/g$. In GC-ECD, NPD, 146 kinds of pesticide were spiked for the identification and quantification in lettuce. Recoveries of 61 species were between 70 and 130% with lower than 20%. These results indicated that GC-TOF/MS, GC-ECD, NPD analysis with the QuEChERS sample preparation can be partly applied to multi-residue pesticides in vegetables.

Space Radiation Effect on Si Solar Cells (우주 방사능에 의한 실리콘 태양 전지의 특성 변화)

  • Lee, Jae-Jin;Kwak, Young-Sil;Hwang, Jung-A;Bong, Su-Chang;Cho, Kyung-Seok;Jeong, Seong-In;Kim, Kyung-Hee;Choi, Han-Woo;Han, Young-Hwan;Choi, Yong-Woon;Seong, Baek-Il
    • Journal of Astronomy and Space Sciences
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    • v.25 no.4
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    • pp.435-444
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    • 2008
  • High energy charged particles are trapped by geomagnetic field in the region named Van Allen Belt. These particles can move to low altitude along magnetic field and threaten even low altitude spacecraft. Space Radiation can cause equipment failures and on occasions can even destroy operations of satellites in orbit. Sun sensors aboard Science and Technology Satellite (STSAT-l) was designed to detect sun light with silicon solar cells which performance was degraded during satellite operation. In this study, we try to identify which particle contribute to the solar cell degradation with ground based radiation facilities. We measured the short circuit current after bombarding electrons and protons on the solar cells same as STSAT-1 sun sensors. Also we estimated particle flux on the STSAT-l orbit with analyzing NOAA POES particle data. Our result clearly shows STSAT-l solar cell degradation was caused by energetic protons which energy is about 700keV to 1.5MeV. Our result can be applied to estimate solar cell conditions of other satellites.

지질시대 및 지구조별 국내대리석 석재자원의 분류와 물성

  • 윤현수;홍세선;박덕원;이병대;김주용
    • Proceedings of the Mineralogical Society of Korea Conference
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    • 2002.10a
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    • pp.153-169
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    • 2002
  • 국내 대리석류 석재자원은 지질시대 및 지구조별로 선캠브리아기의 경기육괴와 영남육괴, 시대미상의 옥천대 남서부, 캠브리아-오오도비스기의 옥천대 북동부 그리고 일부 기하시대의 옥천대 북동부 등으로 분류될 수 있다. 전자는 변성퇴적암류내에 협재된 결정질 석회암, 화강암질 편마암내 포획된 결정질 석회암 등s으로 경기육괴의 포천, 김포, 온수리, 목계와 신림도폭 그리고 영남육괴의 춘양, 현동, 울진, 중평동 장기리와 장계도폭 등이 해당된다. 시대미상암류는 옥천대 남서부로서 목계 충주 괴산, 강경, 남원과 송정도폭, 그리고 캠브리아기는 풍촌석회암으로 임계, 호명, 서벽리도폭 등이 해당된다. 오오도비스기는 정선석회암이 분포하는 석병산, 평창, 정선과 임계도폭, 화천리층이 분포하는 문경도폭, 그리고 황강리도폭 등이 해당한다. 기타시대는 시대미상의 각력질 석회암과 상부석탄기의 홍점층군내 협재하는 결정질 석회암으로 이들은 각각 정선도폭과 석병산도폭에 위치한다. 선캠브리아기, 시대미상, 캠브리아기 및 오오도비스기 대리석류의 물성 중에서 흡수율과 공극율은 선캠브리아기, 오오도비스기 시대미상과 캠브리아기의 순으로 점차 감소한다 이들의 공극율은 비중에 대하여 대체로 불규칙하며, 흡수율은 공극율에 대하여 거의가 뚜렷한 정의 상관관계를 이룬다. 압축강도는 공극율에 대하여 다소 불규칙한, 그리고 인장강도에 대하여 정의 상관관계를 이룬다. 그리고 마모경도는 압축강도와 인장강도에 대하여 대체로 뚜렷한 정의 경향을 각각 보인다. 이들 대리석류는 선캠브리아기 중경암-경암, 시대미상 중경암-경암, 캠브리아기 거의가 중경암-경암, 그리고 오오도비스기는 경암에 각각 해당한다.역할을 충실히 담당하고 있는 것으로 분석되었다. 그러나 과학기술의 급격한 발달, 소비패턴의 변화, 생활환경과 삶의 질을 중시하는 새로운 가치관의 확산 등으로 광업의 역할도 새로운 변화의 전기를 맞이하고 있음을 볼 수 있다. 국내광업이 21C 급변하는 산업환경에 적응하여 생존하기 위해서는 각종 첨단산업에서 요구하는 소량 다품종의 원료광물을 적기에 공급 할 수 있는 전문화된 기술력을 하루속히 확보해야 하며, 이를 위해 고품위의 원료광물 확보를 위한 탐사 및 개발을 적극 추진하고 가공기술의 선진화를 위해 선진국과의 기술제휴 등 자원산업 글로벌화 정책이 절실히 요구되고 있음을 알 수 있다. 또한 삶의 질을 향상시키려는 현대인의 가치관에 부합하기 위해서는 각종 소비제품의 원료를 제공하는 광업의 본래 목적 이외에도 자연환경 훼손을 최소화하며 개발 할 수밖에 없는 구조적인 어려움에 직면할 수밖에 없다. 이처럼 국내광업이 안고 있는 여러 가지 난제들을 극복하기 위해서는 업계와 정부가 합심하여 국내광업 육성의 중요성을 재인식하고 새로운 마음가짐으로 관련 정책을 수립 일관성 있게 추진해 나가야 할 것으로 보인다.의 연구 결과를 요약하면 다음과 같다. 첫째, 브랜드 이미지와 서비스 품질과의 관계에서 브랜드이미지는 서비스 품질의 선행변수가 될 수 있음을 증명하였으며 4개 요인의 이미지 중 사풍이미지를 제외한 영업 이미지, 제품 이미지, 마케팅 이미지가 서비스 품질에 영향을 미치고 있음을 알 수 있다. 둘째, 지각된 서비스 품질과 가격 수용성과의 관계에서, 서비스 품질은 최소 가격에 신뢰서비스 요인에서 정의 영향을 미치고 있으나 부가서비스, 환경서비스에서는 역의 영향을

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Neutron Capture Resonance Energy Identification of Indium by Time-of-Flight Method (중성자 비행시간법을 이용한 인듐의 공명에너지 동정에 관한 연구)

  • Lee, Sam-Yol
    • Journal of the Korean Society of Radiology
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    • v.6 no.5
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    • pp.403-408
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    • 2012
  • Prompt gamma ray from the natural Indium sample was measured by using an assembly of BGO($Bi_4Ge_3O_{12}$) scintillation detectors in the neutron energy region from 1 to 300 eV. The assembly was composed of pieces of BGO. The spectrometer was composed geometrically as total energy absorption detector. 46-MeV electron linear accelerator which is located at Research Reactor Institute, Kyoto University used for neutron sources from photonuclear reaction. The measurement of the neutron capture resonances was performed to below neutron energy 1 keV, because of strong X-ray effect from photonuclear reaction in Ta target and short distance from the target to an assembly of detector. The distance of neutron flight path is $12.7{\pm}0.02m$. The large neutron capture resonances were measured from 1 to 400 eV. The energy in the capture resonance was compared with the evaluated values. The large resonances were seen in the present measurement. General agreement can be seen between the present measurement and the previous evaluated data in relevant energy region. In the present study, we measured the continues resonance structure above 1 keV neutron energy region. 91.49 eV new neutron capture resonance was found in present measurement.

Occurrence and petrochemistry of the granites in the Pocheon-Euijeongbu area (포천-의정부 일대에 분포하는 화강암류의 산상과 암석화학)

  • 윤현수
    • The Journal of the Petrological Society of Korea
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    • v.4 no.2
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    • pp.91-103
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    • 1995
  • The study area is located at the middle part of Daebo granitic batholith in the Gyeonggi massif. The geology of the area is mostly composed of Precambrian gneiss complex, coarse- grained middle Jurassic and fine-grained early Cretaceous biotite granites, and Cretaceous small stocks and dykes. The gneiss complex consists mainly of banded gneiss, granitc gneiss, some schist and quartzite. The coarse-grained granite can be divided into greyish granite(Gg1 in the margin and slightly pinkish granite(Gp) in the center. The former is hornblende biotite granite characterized by basic clot and xenolith. The latter is generally garnet biotite granite containing only poor basic clot. The fine-grained granite intruded the coarse-grained granite. The K/Ar biotite ages from the granites belong to middle Jurassic and early Cretaceous. The K/Ar biotite ages and geochemical compositions indicate that Gg and Gp were differenciated from a single magmatic body. The granites are calc-alkali and metaluminous-peraluminous. They are S-type(i1menite series) and partly I-type granitedmagnetite series) formed by melting of relatively fixed source composition. Their tectonic settings belong to the compressional suits and VAG of continental margin.

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Experimental Evaluation of an Analytical Method for Chlorofluorocarbons (CFSs) in Air and Water Using Gas Chromatography (가스 크로마토그래피를 이용한 대기와 물시료의 CFCs(chlorofluorocarbons) 분석법의 실험적 평가)

  • Koh, Dong-Chan;Choi, Beom-Kyu;Kim, Yong-Je
    • Economic and Environmental Geology
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    • v.40 no.1 s.182
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    • pp.129-140
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    • 2007
  • CFC(CFC-12, CFC-11 and CFC-113) analytical system for air and water was constructed using a customized purge and trap extraction device and a gas chromatograph with an electron capture detector. Sampling methods of air and water for CFCs were also established. The analytical system was experimentally optimized to result in reproducibilities of triplicates less than 2% for current air samples and less than 5% for groundwater samples with CFC-12 concentration of 160 to 180 pg/kg, and verified with respect to the CFC system in USGS, which showed analytical results were in agreement within 10%. CFCs in air were monitored at three sites over 19-month period in the central part of South Korea, and the result indicates no significant local sources of CFCs in those areas. For groundwater in Jeju Island, CFCs were measured over a year with a two-month interval. The time-series data showed seasonal fluctuations which could be interpreted by the effect of recharge pulse derived from large amount of rainfall during monsoon period with a few month delay, which indicates high permeability of basaltic rocks in Jeju Island.

Cellular Imaging of Gold Nanoparticles Using a Compact Soft X-Ray Microscope (연 X-선 현미경을 이용한 금 나노입자 세포영상)

  • Kwon, Young-Man;Kim, Han-Kyong;Kim, Kyong-Woo;Kim, Sun-Hee;Yin, Hong-Hua;Chon, Kwon-Su;Kang, Sung-Hoon;Park, Seong-Hoon;Juhng, Seon-Kwan;Yoon, Kwon-Ha
    • Applied Microscopy
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    • v.38 no.3
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    • pp.235-243
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    • 2008
  • A compact soft x-ray microscope operated in the 'water window' wavelength region ($2.3{\sim}4.4nm$) was used for observing cells with nano-scale spatial resolution. To obtain cellular imaging captured with colloidal gold nanoparticles using a compact soft x-ray microscope. The colloidal gold nanoparticles showed higher contrast and lower transmission more than 7 times than that of cellular protein on the soft x-ray wavelength region. The structure and thickness of the cell membrane of the Coscinodiscus oculoides (diatome) and red blood cells were seen clearly. The gold nanoparticles within the HT1080 and MDA-MB 231 cells were seen clearly on the soft x-ray microscopy. The gold nanoparticles were aggregated within vesicles by endocytosis.

Geochemical Origins and Occurrences of Natural Radioactive Materials in Borehole Groundwater in the Goesan Area (괴산지역 시추공 지하수의 자연방사성물질 산출특성과 지화학적 기원)

  • Kim, Moon Su;Yang, Jae Ha;Jeong, Chan Ho;Kim, Hyun Koo;Kim, Dong Wook;Jo, Byung Uk
    • The Journal of Engineering Geology
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    • v.24 no.4
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    • pp.535-550
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    • 2014
  • The origins and varieties of natural radioactive materials, including uranium and radon-222, were examined in a drilled borehole extending to a depth of 120 m below the surface in the Goesan area. In addition to core samples, eight groundwater samples were collected at different depths, using a double packer system and bailer, and their geochemical characteristics were determined. Most of the rock samples from the drilled core consisted of granite porphyry, with sedimentary rocks (slate, carbonate, or lime-silicates) and pegmatite occurring in certain sections. The pH of samples varied from 7.8 to 8.4, and the groundwater was of a Na-$HCO_3$type. Uranium and thorium concentrations in the core were < 0.2-14.8 ppm and 0.56-45.0 ppm, respectively. Observations by microscope and an electron probe microanalyzer (EPMA) showed that the mineral containing the natural radioactive materials was monazite contained in biotite crystals. The uranium, which substituted for major elements in the monazite, appeared to have dissolved and been released into the groundwater in a shear zone. Concentrations of Radon-222 in the borehole showed no close relationship with levels of uranium. The isotopes of noble gases, such as helium and neon, would be useful for analyzing the origins and characteristics of the natural radioactive materials.

Morphological Differentiation of the Trap in Aquatic and Terrestrial Utricularia Species (서식환경에 따른 통발속(Utricularia) 포충낭의 형태 분화)

  • Lee, Kyoung-Lan;Kim, In-Sun
    • Applied Microscopy
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    • v.40 no.4
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    • pp.237-244
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    • 2010
  • Utricularia forms small, but complex carnivorous trap along the stem either in water or in soil depending upon species. The shapes and sizes of the traps, appendages, and trichomes are known to differ among aquatic, terrestrial and epiphytic species. In the present study, the morphology and microstructure of the trap in aquatic Utricularia japonica and terrestrial U. livida were examined using light and electron microscopy. The aim of this study was to compare the characteristics of trap features between the aquatic and terrestrial species. The trap was found to be comprised of a thin walled bladder with numerous capitate trichomes, two-armed bifid and four-armed quadrifid glands in both species; however, the traps of the two species were different in size, and number and morphology of the trichomes and glands. Aquatic Utricularia was chlorenchymatous with chloroplasts distributed throughout the body, whereas the terrestrial species was translucent without plastids due to an adaptation to underground habitats. Furthermore, the former differed considerably in that the traps developed antenna and appendages around the entrance area. A peculiar trap entrance was also noted in U. livida, which exhibited radiating rows of various trichomes within funnel-shaped tissue. A large number of glandular trichomes covered the entrance area and door surface with four trigger hairs each in the aquatic form but only two in the terrestrial form. The glandular trichomes near the door secreted a large amount of mucilage that temporarily composed the velum in the U. japonica, however, it was not observed in the terrestrial species. All of the aforementioned features were highly related in their structure and function during carnivorous mechanism in Utricularia. The current findings provide important data for further comparison of the different life forms within Utricularia.

Fine Structure of the Silk Spigots in the Spider Dolomedes sulfureus (Araneae: Pisauridae) (닷거미과의 황닷거미(Dolomedes sulfureus)의 실크 분비장치의 미세구조)

  • Moon, Myung-Jin
    • Applied Microscopy
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    • v.38 no.2
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    • pp.89-96
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    • 2008
  • Dolomedes spiders of the family Pisauridae are one of free wandering spiders with semi-aquatic habitation. They do not build web for prey-hunting but build a nursery web for spiderlings. This paper describes the fine structure of the silkspinning spigots of the fishing spider Dolomedes sulfureus revealed by the field emission scanning electron microscope (FESEM). The fishing spider Dolomedes sulfureus possesses only three types of silk glands which connected through the typical spinning tubes on the spinnerets. The silk spigots of this spider were identified as three groups: ampullates, pyriforms and aciniforms. Two pairs of major ampullate glands send secretory ductules to the anterior spinnerets, and another two pairs (or $1{\sim}2$ pairs in males) of minor ampullate glands supply the middle spinnerets. In addition, the pyriform glands feed silk into the anterior spinnerets ($62{\sim}68$ pairs in females and $45{\sim}50$ pairs in males), and the aciniforms send ductules to the middle ($33{\sim}40$ pairs in females and $18{\sim}25$ pairs in males) and the posterior spinnerets ($42{\sim}50$ pairs in females and $24{\sim}28$ pairs in males). Among these, the ampullate one is the most predominate gland in both sexes.