• Title/Summary/Keyword: 전이층

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Clinical Presentation of Paraganglioma in Orthopaedics - Report of Two Cases - (정형외과 영역에서의 부신경절종의 임상 양상 - 2례 보고 -)

  • Lee, Sang-Lim;Oh, Joo-Han;Lee, Sang-Hoon;Kim, Han-Soo;Kim, Hyung-Ho;Kim, June-Hyuk
    • The Journal of the Korean bone and joint tumor society
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    • v.11 no.1
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    • pp.94-99
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    • 2005
  • Paraganglioma is a neoplasm consisting of sympathetic neuroendocrine cells, which arise from neural ectoderm of extra-adrenal paraganglia. It often occurs in thyroid, carotid body, mediastinum, lung, duodenum, the retroperitoneal area and periaortic area. Malignant paraganglioma is defined not by the histological diagnosis, but by spread to regional lymph nodes or distant metastasis. Rare bone metastasis mostly occurs in the base of skull or spine, and even it rarely metastasizes to pelvis or femur. We would like to report two cases of paraganglioma; one in the subcutaneous fat layer that was mistaken for a vascular tumor, and the other in the retroperitoneal space with early bone metastasis.

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VOCs Oxidation Characteristics of Transition $Metals/\gamma-Al_2O_3$ Catalyst (전이금속/$\gamma-Al_2O_3$ 촉매의 VOCs 산화특성)

  • Kim, Bong-Soo;Park, Yeong-Seong
    • Journal of Korean Society of Environmental Engineers
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    • v.29 no.4
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    • pp.444-451
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    • 2007
  • Catalytic oxidation characteristics of benzene as a VOC was investigated using a fixed bed reactor system over transition $metals/\gamma-Al_2O_3$ catalysts. As transition metals, eight metals including copper, nickel, manganese, iron etc. were adopted. The parametric tests were conducted at the reaction temperature range of $200\sim500^{\circ}C$, benzene concentration of $1,000\sim3,000$ ppm, and space velocity range of $5,000\sim60,000\;hr^{-l}$. The property analyses such as BET, SEM, XRD and the conversions of catalytic oxidation of VOC were examined. The experimental results showed that the conversion was increased with decreasing VOC concentration and space velocity. It was also found that $Cu/\gamma-Al_2O_3$ catalyst calcinated at $500^{\circ}C$ showed the highest activity for the oxidation of benzene and 15% metal loading was the optimum impregnation level.

Effect of Pressure on Minimum Fluidization Velocity and Transition Velocity to Fast Fluidization of Oxygen Carrier for Chemical Looping Combustor (케미컬루핑 연소를 위한 산소전달입자의 최소유동화속도 및 고속유동층 전이유속에 미치는 압력의 영향)

  • KIM, JUNGHWAN;BAE, DAL-HEE;BAEK, JEOM-IN;PARK, YEONG-SEONG;RYU, HO-JUNG
    • Transactions of the Korean hydrogen and new energy society
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    • v.28 no.1
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    • pp.85-91
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    • 2017
  • To develop a pressurized chemical looping combustor, effect of pressure on minimum fluidization velocity and transition velocity to fast fluidization was investigated in a two-interconnected pressurized fluidized bed system using oxygen carrier particle. The minimum fluidization velocity was measured by bed pressure drop measurement with variation of gas velocity. The measured minimum fluidization velocity decreased as the pressure increased. The transition velocity to fast fluidization was measured by emptying time method and decreased as the pressure increased. Gas velocity in the fuel reactor should be greater than the minimum fluidization velocity and gas velocity in the air reactor should be greater than the transition velocity to fast fluidization to ensure proper operation of two interconnected fluidized bed system.

Metal Catalyst Encapsulated in Nitrogen-doped Carbon Shell for Fuel Cell Application: Theoretical and Experimental Study (연료전지용 질소 도핑 탄소촉매의 표면 반응에 관한 이론적 연구와 실험적 입증)

  • No, Seung-Hyo;Seo, Min-Ho;Gang, Jun-Hui;;Han, Byeong-Chan
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2017.05a
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    • pp.86-86
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    • 2017
  • 고효율의 에너지 변환 및 친환경적인 이점들을 이유로, 고분자전해질 연료전지(PEMFC)는 차세대 에너지 장치로 이목을 끌어왔다. 반면, 값비싼 백금 촉매의 이용은 연료전지의 상업적 이용에 주요한 결점으로 작용했다. 최근, Zelenay와 연구팀은 폴리아닐린-철-탄소 복합체구조에서 산소환원활성이 백금과 견주어 비슷한 성능을 낼 수 있음을 보고 하였다. Dodelet은 이러한 높은 성능이 전이금속의 영향에 의한 것일 수 있다는 주장을 하였다. 본 연구팀은 지난 연구에서 제일원리전산모사를 통해 니켈, 코발트, 구리등과 같은 전이금속이 질소가 도핑된 탄소 그래핀층에 미치는 거동을 밝혔다. 결론적으로, 금속들은 질소가 도핑된 그래핀의 전자구조를 바꿀 수 있고, 이러한 전자구조의 변화는 산소 환원반응에서 긍정적으로 작용할 수 있음을 확인하였다. 이러한 이론적 연구에 기반하여, 탄소층으로 감싼 금속은 내구성과 활성을 동시에 보유한 향후 전망있는 촉매 물질로 예상되어진다. 특히, 질소가 도핑된 탄소층으로 코팅된 철-코발트 합금은 계산을 통해 산소환원반응에서 우수할 것으로 예측되었다. 본 연구팀은 FeCo@N-C 나노입자를 직접 합성하였고, 이 촉매의 우수한 활성을 전기화학적, 구조적 관점에서 1) 질소의 도핑 효과, 2) 탄소의 두께 효과, 3) 합금효과에 집중하여 분석하였다.

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Mineralogical and Geochemical Properties and Origin of Clay-silt Sediments, Suwon, Korea (경기도 수원시에서 산출되는 적갈색 점토-실트 퇴적물의 광물 및 지화학 특성과 기원)

  • Jeong, Gi Young
    • Korean Journal of Mineralogy and Petrology
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    • v.33 no.3
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    • pp.153-163
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    • 2020
  • Mineral and geochemical analysis were conducted on two sections (~3.5 m) of red-brown claysilt sediments covering the gneiss and granite weathering zones in Suwon-si for establishing Quaternary paleoenvironmental changes in Korea. The sections were divided into four sedimentary layers (Unit 1-4) by vertical changes in mineral composition and chemical composition. The lowermost unit 1 was a sandy sediment with a high K-feldspar content with a significant contribution of weathered bedrock. Unit 2 was a transition layer showing intermediate characteristics. Unit 3 was a reddish brown clay-silt sediment, with a total clay content of 58% on average, and the main clay minerals were illite-smectite mixed layer minerals and hydroxy-interlayered vermiculite/smectite. Unit 3 contained almost no plagioclase, while the content of kaolin minerals derived by the plagioclase weathering was higher than in the other layers. Unit 4 had similar mineral composition and chemical properties to Unit 3, but had a higher content of plagioclase and chlorite and lower content of kaolin minerals. The chemical compositions of the sections were compared with those in other regions of Korea, suggesting the eolian origin of Units 3 and 4. The paleoenvironmental change in the sedimentary section of this region was interpreted as follows. Weathered products of gneiss and granite, which are bedrocks of this region, were eroded and deposited as sandy sediments in the periphery to form the lower layers (Unit 1, 2), followed by the deposition of the claysilty rich eolian sediments (Unit 3) during the glacial. Unit 3 was chemically weathered during the warm humid climate during the last interglacial, developing a reddish brown color. After that, a eolian sediment layer (Unit 4) was deposited during the last glacial.

The comparisons of layers and the effect of additional firings on flexural strength and translucency of 5Y-ZP (Translucent zirconia의 layer 간 비교 및 추가적인 소성이 굽힘강도, 투과도에 미치는 영향)

  • Kim, Hyung-Joon;Shin, Soo-Yeon
    • Journal of Dental Rehabilitation and Applied Science
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    • v.37 no.3
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    • pp.111-122
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    • 2021
  • Purpose: The purpose of this in vitro study was to investigate the flexural strength and translucency of three layers in 5Y-ZP and to assess the effect of additional firings on these properties. Materials and Methods: Sintered zirconia blocks were sectioned according to three layers : incisal, transition, and body. Disc-shaped specimens were fabricated from each layer. The diameter of specimens was 15.0 mm and each thickness of specimens for biaxial flexural strength test and translucency was 1.2 mm and 1.0 mm. The specimens were classified into subgroups according to the number of firing (0, 1, and 3 times; n = 10/subgroup) and the additional firings were performed under 900℃ using a furnace. Biaxial flexural strength and translucency was measured using universal testing machine and uv-vis spectrophotometer. X-ray diffraction (XRD) analysis was used for measurement of the phase identification. One-way ANOVA, Tukey HSD test were performed (α = 0.05). Results: There was no significant difference in flexural strength between the three layers (P > 0.05), while there was significant difference in translucency between different layers (P < 0.05). The flexural strength of incisal and transition layer was decreased by the single additional firing, and the three additional firings significantly decreased the flexural strength of three layers. The translucency of layer was decreased by additional firings except the body layer. The XRD patterns of all groups were similar. Conclusion: Three layers of 5Y-ZP were different only in translucency. Additional firings affected the flexural strength and translucency differently depending on the layers but crystalline phases were not changed.

Electrochemical Properties of Photoelectrode using NiO-$TiO_2$ (NiO-$TiO_2$ 광전극을 이용한 염료감응형태양전지의 전기화학적 특성)

  • Park, Kyunghee;Jin, Enmei;Zhao, Xingguan;Park, Areum;Jiao, Wang;Gu, Halbon
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.06a
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    • pp.68.1-68.1
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    • 2010
  • 염료감응형 태양전지에서 가능한 광전자의 이동경로에 대해 살펴보면 빛 에너지를 흡수한 루테늄계 염료는 기저상태에서 여기상태로 전이한 후 광전자의 반도체 전도띠로 전자주입이 이루어진다. 이러한 전자 중 일부는 반도체산화물의 트랩으로의 전이와 트랩에서 염료 기저상태로의 전이가 일어나고 일부 전자는 전해질의 이온종 또는 산화된 염료와 재결합하는 현상이 일어난다. 본 연구에서는 이러한 전자의 재결합을 막고자 p형 반도체인 NiO paste를 제작하여 $TiO_2$ 광전극 층 위에 코팅하였다. 코팅된 NiO 층은 홀수용체로서 염료에 전자를 제공해 주는 역할과 동시에 $TiO_2$ 가전도대로 이동되었던 전자들이 염료의 기저상태의 홀이나 전해질로의 전자 유입이 이루어지는 전자의 재결합을 막는 방벽의 역할을 동시에 하게 된다. 제작된 염료감응형 태양전지 셀의 에너지 변환효율 특성을 알아보기 위하여 1000 W Xe Arc Lamp와 Air Mass 1.5, filter가 장착된 Thermo-Preal (USA) Solar simulator system을 사용하여 개방전압 (Voc), 광전류 (Isc), fill factor (FF), 에너지변환 효율 (${\eta}$)을 조사하였으며 광학현미경을 통해 염료의 흡착 정도를 비교해 보았다. NiO의 코팅 두께나 NiO 나노입자 크기에 따라 염료감응형태양전지에서 에너지변환효율에 미치는 영향을 조사하였다. NiO가 코팅되지 않은 $TiO_2$ 광전극과 비교해 볼 때 NiO 코팅시 Voc와 Isc의 증가로 인해 에너지변환효율이 20% 이상 향상되는 것을 볼 수 있었다.

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Efficient Analysis of Shear Wall with Piloti (필로티가 있는 전단벽의 효율적인 해석)

  • 김현수;이동근
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.16 no.4
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    • pp.387-399
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    • 2003
  • The box system that consists only of reinforced concrete walls and slabs we adopted in many high-rise apartment buildings recently constructed in Korea. Recently, many of the box system buildings with pilotis has been constructed to meet the architectural design requirements. This structure has abrupt change in the structural properties between the upper and lower parts divided by transfer girders. For an accurate analysis of a structure with pilotis, it is necessary to have the buildings modeled into a finer mesh. But it would cost tremendous amount of computational time and memory. In this study, an efficient method is proposed for an efficient analysis of buildings those have pilotis with drastically reduced time and memory. In the proposed analysis method, transfer gilders are modeled using super elements developed by the matrix condensation technique and fictitious beams are introduced to enforce the compatibility conditions at the boundary of each element. The analyses of example structures demonstrated that the proposed method used for the analysis of a structure with pilotis will provide analysis results with accuracy for the design of box system buildings.

A Bubble Detection Method for Conformal Coated PCB Using Transfer Learning based CNN (전이학습 기반의 CNN을 이용한 컨포멀 코팅 PCB에 발생한 기포 검출 방법)

  • Lee, Dong Hee;Cho, SungRyung;Jung, Kyeong-Hoon;Kang, Dong Wook
    • Journal of Broadcast Engineering
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    • v.26 no.6
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    • pp.809-812
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    • 2021
  • Air bubbles which may be generated during the PCB coating process can be a major cause of malfunction. so it is necessary to detect the bubbles in advance. In previous studies, candidates for bubbles were extracted using the brightness characteristics of bubbles, and the candidates were verified using CNN(Convolutional Neural Networks). In this paper, we propose a bubble detection method using a transfer learning-based CNN model. The VGGNet is adopted and sigmoid is used as a classification layer, and the last convolutional layer and classification layer are trained together when transfer learning is applied. The performance of the proposed method is F1-score 0.9044, which shows an improvement of about 0.17 compared to the previous study.

Malaria Cell Image Recognition Based On VGG19 Using Transfer Learning (전이 학습을 이용한 VGG19 기반 말라리아셀 이미지 인식)

  • Peng, Xiangshen;Kim, Kangchul
    • The Journal of the Korea institute of electronic communication sciences
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    • v.17 no.3
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    • pp.483-490
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    • 2022
  • Malaria is a disease caused by a parasite and it is prevalent in all over the world. The usual method used to recognize malaria cells is a thick and thin blood smears examination methods, but this method requires a lot of manual calculation, so the efficiency and accuracy are very low as well as the lack of pathologists in impoverished country has led to high malaria mortality rates. In this paper, a malaria cell image recognition model using transfer learning is proposed, which consists in the feature extractor, the residual structure and the fully connected layers. When the pre-training parameters of the VGG-19 model are imported to the proposed model, the parameters of some convolutional layers model are frozen and the fine-tuning method is used to fit the data for the model. Also we implement another malaria cell recognition model without residual structure to compare with the proposed model. The simulation results shows that the model using the residual structure gets better performance than the other model without residual structure and the proposed model has the best accuracy of 97.33% compared to other recent papers.