• Title/Summary/Keyword: 전위성

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Synthesis and Electrochemical Properties of LiFePO4 Cathode Material obtained by Electrospinning Method (전기방사법을 이용한 LiFePO4 양극 활물질의 합성 및 전기화학적 특성)

  • Lee, Seung-Byung;Cho, Seung-Hyun;Park, Sun-Il;Lee, Wan-Jin;Lee, Yun-Sung
    • Journal of the Korean Electrochemical Society
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    • v.11 no.4
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    • pp.268-272
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    • 2008
  • $LiFePO_4$ material was synthesized by electrospinning method to obtain optimal particle size($50{\sim}100\;nm$) without carbon coating or ball milling. This material showed an orthorthombic structure with Pnma space group without any impurities, such as FeP or $Fe_2P$, in the XRD pattern. The particle morphology and particle shape were observed by SEM analysis. Li/$LiFePO_4$ cell showed a high initial discharge capacity of 135 mAh/g, at current density of $0.1\;mA/cm^2$ with a cut-off voltage of 2.8 to 4.0V. This cell exhibited a perfect cycle performance over 99.9% cycle retention rate up to 50 cycles.

A Study on the Kinetics of Copper Ions Reduction and Deposition Morphology with the Rotating Disk Electrode (RDE를 이용한 구리이온의 환원속도 및 전착형태에 관한 고찰)

  • Nam, Sang Cheol;Um, Sung Hyun;Lee, Choong Young;Tak, Yongsug;Nam, Chong Woo
    • Applied Chemistry for Engineering
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    • v.8 no.4
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    • pp.645-652
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    • 1997
  • Electrochemical characteristics and kinetic parameters of copper ion reduction were investigated with a platinum rotating disk electrode (RDE) in a diffusion controlled region. Reduction of Cu(II) in sulfate had one-step two-xelectron process, while the reduction of Cu(II) in chloride solution was involved two one-electron processes. The transfer coefficient of Cu(II) in sulfate solution was lowest, and the transfer coefficient of Cu(I) in halide solutions had the value of nearly one. In chloride solutions, electrodeposition rate of Cu(II) was about one hundred times faster than Cu(I). Diffusion coefficient increased in the order of Cu(II) in chloride solution, Cu(I) in the iodide, bromide, chloride solution, Cu(II) in sulfate solution. The calculated ionic radii and activation energy for diffusion decreased in the same order as above. Morphological study on the copper electrodeposition indicated that the electrode surface became rougher as both concentration and reduction potential increases, and the roughness of the surface was analyzed with UV/VIS spectrophotometer.

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Semi-continuous Emulsion Polymerization of n-Butyl acrylate/Methyl metacrylate using Environmental-Friendly LE-Type Nonionic Surfactant (환경친화적 LE-형 비이온계면활성제를 사용한 반연속식 말브틸-아크릴레이트/메틸메타-아크릴레이트 유화중합에 관한 연구)

  • Kim, Chul-Ung
    • Clean Technology
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    • v.11 no.1
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    • pp.41-50
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    • 2005
  • In this study, semibatch emulsion copolymerization of n-BA as adhesive component and MMA as coagulant component were carried out for the stable acrylic polymer latex in aqueous phase for polymer cement using LE-type nonionic surfactant as environmental friendly surfactant. The stable polymer emulsion was obtained with the increases of chain length(n) of this surfactant. The effect on the amount of LE-50 as nonionic surfactant were showed that the concentration of polymer latex were increased by increasing the amount of LE-50, whereas the average particle size were decreased by increasing the amount. The addition of functional monomer in initial reactor charge showed a significant effect on the final polymer concentration and the latex particle size. The single polymerization of each n-BA or MMA showed a very low concentration of polymer latex and very big particle size due to coagulation. In the polymerization composed of mixed monomer with MMA and n-BA, the larger the ratio of MMA to n-BA in the copolymers, the greater the amount of coagulum produced. It was found that a stable copolymers were obtained in the range of 15-35 % of n-BA. Moreover, incorporation of some functional monomers in addition to of main monomers became more stable polymer latex. Through DSC and IR analysis, the final polymer latex was composed by MMA/n-BA/AA/AM with a single Tg depending on the reaction conditions. As a result, the conditions of this acrylic polymerization could also be effectively controlled to get the desired final products.

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A review on Cognitive Information Processing and Emotional Changes of Athletes by Overtraining: P300, EEG Cerebral Hemispheric Asymmetry (과훈련에 따른 선수의 인지정보처리와 정서변화에 대한 문헌 고찰: P300, EEG 대뇌반구비대칭 연구를 중심으로)

  • Ha, Tae-Ho;Kim, Jin-Gu;Kim, Sung-Woon
    • Journal of Digital Convergence
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    • v.15 no.8
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    • pp.501-509
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    • 2017
  • The purpose of this study was to review the effects of the physical fatigue induced by overtraining on cognitive information processing and emotional change of athletes by neurophysiologic study. And to provide basic data for the athletes and coaches in the sports field to improve understanding of the overtraining symptoms from the brain physiological point of view. We reviewed the domestic and international academic materials and research reports published in the last 20 years using electronic databases and examined the literature that is consistent with the purpose of this study among the retrieved documents. Based on the reviewed literature, we examined the cognitive information processing and emotional change of the athlete according to the training, and overtraining can accumulate the fatigue of the body, which can cause severe side effects in terms of cognitive ability and emotional ability of athletes as well as deterioration of performance. The study using P300 and EEG cerebral hemispheric asymmetry difference indices also confirmed the possibility of a new approach to understand psychological and physiological effects of overtraining on information processing and emotional changes.

Geological Structure of the Jirisan Metamorphic Complex of the Yeongnam Massif in the Hwagae Area, Korea (화개지역에서 영남육괴 지리산 변성암복합체의 지질구조)

  • Lee, Deok-Seon;Kang, Ji-Hoon
    • The Journal of the Petrological Society of Korea
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    • v.22 no.4
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    • pp.251-261
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    • 2013
  • Hwagae area, which is situated in the southeastern part of the Jirisan province, Yeongnam massif, Korea, is mainly composed of Precambrian Jirisan metamorphic rock complex (JMRC). Lithofacies distribution of the Precambrian constituent rocks mainly shows NS-trending tight fold and EW-trending open fold. This paper researched deformational phased structural characteristics of JMRC based on the geometric and kinematic features and the forming sequence of multi-deformed rock structures, and suggests that the geological structure of this area was formed through at least three phases of ductile deformation. (1) Most of structural elements related to the $D_1$ deformation were recognized as $S_{0-1-2}$ composite foliation which was transposed by the $D_2$ deformation. (2) The $D_2$ deformation occurred under the EW-directed tectonic compression, and formed the NS-trending $F_2$ fold and $D_2$ ductile shear zone which is (sub)parallel to the axial plane of $F_2$ fold. (3) The $D_3$ deformation occurred under the NS-directed tectonic compression, and partially reoriented the pre-$D_3$ structural elements into ENE or WNW direction. It indicates that the distribution of Precambrian lithofacies showing NS and EW-trending folds in the Hwagae area is closely associated with the $D_2$ and $D_3$ deformations, respectively.

Influence of Rice-Duck Farming System on Yield and Quality of Rice (벼논오리 방사가 쌀 수량 및 품질에 미치는 영향)

  • 강양순;김정일;박정화
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.40 no.4
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    • pp.437-443
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    • 1995
  • Concerns on use of excess amount of chemical fertilizier and pesticide in current farming system turns both of the producer and consumer of agricultural products to an organic farming which use a less chemicals and more natural manure. Rice-duck farming system is one of the strategy to meet the purpose and this experiment was carried out to find the effect of the rice-duck farming system on the quality and yields of rice. 20day-old rice seedling were mechanically transplanted in sandy-loam paddy field and 21 day-old ducks were raised from 3 weeks after transplanting with population of 30 heads per 10a. The plots were consists of reduce fertilizer(70%) with and without duck-raising. The conventional fertilizer treatment without duck-raising was used as check. The results obtained are summarized as follows. The weeds population of test plots which were raised with duck for 3 consecutive years was less than that of test plots without duck-raising, though a speciffic population of Echinochola crusgallis were increased. The weed control effect was higer in duck-raising than in check at the maximum tillering stage but, not at later stages of rice plant. It was found that the small animals and insects inhibiting in the rice field were reduced by duck-treatment, however, there were also damages of grass leaf roller at booting stage in the plots of duck-raising. In rice-duck plot, dark green leaf color were found: 41.8 of SPAD value than 38.6 of SPAD in check plot. Higher root activity and surface soil oxidation were also observed in rice-duck plot than check plot. 3% of the increase in yield was observed by duck-treatment. However, the expected increase of the palatability wsa not observed. This may be due to the unfavorable weather conditions during the rice growing in this expriment.

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Effect of Redox Processes and Solubility Equilibria on the Behavior of Dissolved Iron and Manganese in Groundwater from a Riverine Alluvial Aquifer (만경강 하천변 충적 지하수의 용존 Fe와 Mn 거동에 대한 산화-환원 과정과 용해 평형의 효과)

  • Choi, Beom-Kyu;Koh, Dong-Chan;Ha, Kyoo-Chul;Cheon, Su-Hyun
    • Economic and Environmental Geology
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    • v.40 no.1 s.182
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    • pp.29-45
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    • 2007
  • Biogeochemical characteristics involving redox processes in groundwater from a riverine alluvial aquifer was investigated using multi-level monitoring wells (up to 30m in depth). Anaerobic conditions were predominant and high Fe ($14{\sim}37mg/L$) and Mn ($1{\sim}4mg/L$) concentrations were observed at 10 to 20 m in depth. Below 20 m depth, dissolved sulfide was detected. Presumably, these high Fe and Mn concentrations were derived from the reduction of Fe- and Mn-oxides because dissolved oxygen and nitrate were nearly absent and Fe and Mn contents were considerable in the sediments. The depth range of high Mn concentration is wider than that of high Fe concentration. Dissolved organics may be derived from the upper layers. Sulfate reduction is more active than Fe and Mn reduction below 20 m in depth. Disparity of calculated redox potential from the various redox couples indicates that redox states are in disequilibrium condition in groundwater. Carbonate minerals such as siderite and rhodochrosite may control the dissolved concentrations of Fe(II) and Mn(II), and iron sulfide minerals control for Fe(II) where sulfide is detected because these minerals are near saturation from the calculation of solubility equilibria.

Cellular Flavonoid Transport Mechanisms in Animal and Plant Cells (플라보노이드 세포 수송 기전)

  • Han, Yoo-Li;Lee, So-Young;Lee, Ji Hae;Lee, Sung-Joon
    • Korean Journal of Food Science and Technology
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    • v.45 no.2
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    • pp.137-141
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    • 2013
  • Flavonoids have various biological activities; however, their cellular uptake mechanism is beginning to be understood only recently. This review focuses on cellular flavonoids transport mechanisms in both plants and animals. In plants, flavonoids exist in various cellular compartments, providing a specialized transport system. Newly synthesized flavonoids can be transported from the endoplasmic reticulum to the vacuoles or extracellular space via cellular trafficking pathway. Among membrane transporters, ATP binding cassette, multidrug and toxic extrusion, bilitranslocase homologue transporters play roles in both the influx and efflux of cellular flavonoids across the cell membrane. In recent years, extensive researches have provided a better understanding on the cellular flavonoid transport in mammalian cells. Bilitranslocase transports flavonoids in various tissues, including the liver, intestine and kidneys. However, other transport mechanisms are largely unknown and thus, further investigation should provide detailed mechanisms, which can potentially lead to an improved bioavailability and cellular function of flavonoids in humans.

The Electrical Characteristics of the Grain Boundary in a $BaTiO_{3}$ PTC Thermistor ($BaTiO_{3}$ PTC 서미스터 입계의 전기적인 특성)

  • Kwon, Hyuk-Joo;Lee, Jae-Sung;Lee, Yong-Soo;Lee, Dong-Kee;Lee, Yong-Hyun
    • Journal of Sensor Science and Technology
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    • v.1 no.1
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    • pp.67-75
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    • 1992
  • PTC thermistor has been fabricated with as-received $BaTiO_{3}$ powder and its electrical properties were investigated. The resistivity of the PTC thermistor was measured at $20^{\circ}C$ intervals from $20^{\circ}C$ to $200^{\circ}C$. The electrical characteristics of the PTC thermistor are determined by the ac complex impedance analysis. The average grain size measured with a scanning electron microscope increased from $3.8{\mu}m$ to $8.8{\mu}m$ with increasing sintering temperature between $1280^{\circ}C$ and $1400^{\circ}C$. The maximum resistivity jump was $4{\times}10^{5}$. The bulk resistivity of the thermistor sintered above $1340^{\circ}C$ decreased with increasing temperature of the measurement. The grain boundary resistance increased exponentially, the grain boundary capacitance decreased, and the built-in potential at the grain boundary increased with increasing temperature of the measurement. The charge densiy at the grain boundary increased with increasing temperature up to $110^{\circ}C$, which leveled off with further increase in measuring temperature.

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Electrochemical Properties of Kaolinite in Aqueous Suspension (수용액중(水溶液中)에서의 Kaolinite 입자(粒子)의 전기화학적(電氣化學的) 성질(性質))

  • Lim, Hyung-Sik;Baham, J.;Volk, V.V.
    • Korean Journal of Soil Science and Fertilizer
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    • v.16 no.4
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    • pp.318-324
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    • 1983
  • Electrochemical properties of Georgia kaolinite in aqueous suspension were studied by ion adsorption, potentiometric titration, and electrophoretic mobility measurements. Kaolinite in 0.001 M and 0.1 M NaCl solution showed qualitatively both pH independent and pH depender negative and positive charges through pH range 2.5-11.0 when dissolved aluminum ions from kaolinite were considered as well as $Na^+$ and $Cl^-$ as index ions. Electrophoretic mobilities (EM) of 0.02 wt. % kaolinite suspension in distilled water and 0.001 M NaCl solution were approximately constant against mobility measuring time consumed in the electrophoresis cell at different pH values, and isoelectric points(IEP) were around pH 4.7. EM values in 0.1 M NaCl solution were positive and constant against mobility measuring time below pH 4; but above pH 4, EM values were negative for the first 10 seconds followed by positive values which became approximately constant through stepped changes after 10 minutes. Hydrated cations may bind to the six- member oxygen ring sites having multiple partial negative charges on the exterior tetrahedral layer surface by both electrostatic and hydrogen bonding force while hydrated anions bind to the partially positively charged hydrogen atoms on the exterior octahedral layer surface. Parts of the aluminol groups on the exterior octahedral layer surface as well as edge faces may be involved in complex reactions and have both anion and cation exchange capacities in the electrolyte solution above pH 4.

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