• Journal of the Korean Chemical Society
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• v.50 no.3
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• pp.208-215
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• 2006

A simply prepared graphite, pencil-type working electrode was utilized to monitor fenitrothion concentrations, using the cyclic voltammetry (CV) and square-wave (SW) stripping voltammetry methods. The optimum conditions for analysis were sought. A very low detection limit was obtained compared to that obtained when other common voltammetry methods are used. The optimal parameters of the pencil-type electrode were found to be as follows: a pH of 3.7, a frequency of 500 Hz, an SW amplitude of 0.1 V, an increment potential of 0.005 V, an initial potential of -0.9V, and a deposition time of 500 sec. The analytical detection limit was determined to be 6.0 ngL-1 (2.16410-11 molL-1) fenitrothion at SW anodic and CV, and the relative standard deviation at the fenitrothion concentration of SW anodic 10 ugL-1 was 0.30% (n = 15) under the optimum conditions. Analysis was directly conducted through in-vivo real-time assay.

• Applied Chemistry for Engineering
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• v.32 no.4
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• pp.461-466
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• 2021

In this article, a portable and cost-effective voltammetric biosensor with nanoparticles was developed for the measurements of heterogeneous nuclear ribonucleoprotein A1 protein (hnRNP A1) biomarker which can potentially be used for lung cancer diagnosis. Gold nanoparticles were first electrodeposited onto screen printed carbon electrode (SPCE) followed by immobilizing a single stranded DNA aptamer specific to hnRNP A1 onto the electrode surface. Ethanolamine was also used when immobilizing DNA aptamer on the surface to prevent signals from non-specific adsorption events. Sequential injection of hnRNP A1 biomarker and anti-hnRNP A1 conjugated with alkaline phosphatase (ALP) onto the aptamer chip surface allows to form the sandwich complex of DNA aptamer/hnRNP A1/ALP-anti-hnRNP A1 on the electrode surface which further reacted with 4-aminophenyl phosphate (APP). The electrocatalytic reaction of the enzyme, ALP, and the substrate, APP, resulting in the oxidative current response changes at -0.05 and -0.17 V (vs. Ag/AgCl) against the hnRNP A1 concentration was measured using cyclic and differential pulse voltammetry, respectively. The Au nanoparticles-integrated voltammetric biosensor was applied to analyze human normal serum solutions possibly suggesting potential applicability for lung cancer diagnosis.

• Proceedings of the IEEK Conference
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• 1998.06a
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• pp.371-374
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• 1998

본 논문에서는 muller법과 regular falsi법에 의한 CMOS 반전 증폭 회로를 해석하는 방법을 제안한다. Muller법과 regular falsi법을 이용하여 회로의 절점전압과 branch 전류를 예측하였고 회로의 출력 절점에서 KCL을 만족하도록 하였다. CMOS 반전 증폭 회로의 모의실험을 수행한 결과 MEDICI에 사용된 결합법에 비해 전압특성과 전류특성은 각각 5%와 5.4%의 최대상대오차를 보였다.

• 전기의세계
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• v.20 no.2
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• pp.32-34
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• 1971

전파방정식과 그 증명을 이해한 후, 이것의 응용법을 알기 전에 전기공학도는 송전선에 따른 전압, 전류의 변동현상에 친숙해야 하는데, 이를 위해서는 그래프법이 있으면 매우 좋다. 왜냐하면 그래프법에의해 송전선의 동작을 통일적, 시각적으로 통찰할 수 있기 때문이다. 이러한 방법의 하나가 1943년에 출판된 고 F.Esclangon교수의 한 논문에 제시되었다. 불행하게도 이 논문은 주목을 받지 못했는데, 여기에는 두가지 이유가 있을 수 있다. 첫째, 이 논문이 2차대전중에 발행되어서 여러 사람의 손에 들어가지 않았고, 둘째 저자가 자기의 방법의 중요한 이점을 분명히 나타내지 못했다. 본 고는 그래프법을 알려줌으로서 송전선에 대한 흥미를 일깨워주고자 한다.

• Journal of the Korean Applied Science and Technology
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• v.29 no.3
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• pp.421-428
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• 2012

We investigated an electrochemical properties for Langmuir-Blodgett (LB) nano-films of polyimide and phospholipid mixture. LB films of polyamic acid and phospholipid monolayer were deposited by the Langmuir-Blodgett method on the indium tin oxide(ITO) glass. The electrochemical properties measured by cyclic voltammetry with three-electrode system(an Ag/AgCl reference electrode, a platinum wire counter electrode and LB film-coated ITO working electrode) in $KClO_4$ solution. The current of reduction and oxidation range was measured from 1650 mV to -1350 mV, continuously. The scan rates were 50, 100, 150, 200 and 250 mV/s, respectively. As a result, monolayer LB films of polyamic acid and phospholipid mixture was appeared on irreversible process caused by the reduction current from the cyclic voltammogram. Diffusion coefficient (D) effect in the polyamic acid and phospholipid mixture was used in the LAPC with LLPC fewer than the diffusion coefficient values.

• Journal of the Korean Applied Science and Technology
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• v.29 no.2
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• pp.311-316
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• 2012

We are investigated to an electrochemical characteristic for Langmuir-Blodgett (LB) films by cyclic voltammetry method. The phospholipid compound was deposited by using the LB method on the Indium tin oxide(ITO) glass. We tried to measure the electrochemical by using cyclic voltammetry with three-electrode system(an Ag/AgCl reference electrode, a platinum wire counter electrode and LB film-coated ITO working electrode) in 0.5, 1.0, 1.5 and 2.0 N $NaClO_4$ solution. A measuring range was reduced from initial potential -1350 mV, continuously oxidized to 1650 mV. As a result, LB films of the phospholipid compounds are appeared irreversible process caused by only the oxidation current from the cyclic voltammogram. The diffusivity(D) effect of LB films decreased with increasing of phospholipid compound amount.

• Journal of the Korean Applied Science and Technology
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• v.31 no.3
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• pp.352-358
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• 2014

We were investigated the stability through the electrochemical characteristics of saturated fatty acid(C12, C14, C16, C18) monolayer LB films by cyclic voltammetry. Saturated fatty acid monolayer LB films was deposited on the indium tin oxide(ITO) glass by the LB method. The electrochemical properties were measured by cyclic voltammetry with a three-electrode system in 0.1 N $NaClO_4$ solution. The measuring range was continuously oxidized to 1650 mV, with an initial potential of -1350 mV was reduced. Scanning rates of 50, 100, 150, 200, and 250 mV/s were set. As a result, LB monolayer films of saturated fatty acid were appeared on irreversible processes by the oxidation current from the cyclic voltammogram. Diffusion coefficient(D) of saturated fatty acid(C12, C14, C16, and C18) was calculated 22.231, 2.461, 7.114 and 2.371 ($cm^2s^{-1}{\times}10^{-4}$) in 0.1 N $NaClO_4$ solution, respectively.

• Journal of the Korean Magnetics Society
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• v.9 no.1
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• pp.64-70
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• 1999

The inrush current of transformer can flow when the overvoltage caused by surge or external faults is applied. In this paper, an algorithm for the calculation of this inruch current is proposed. The capacitances of windings are precalculated by using 3 dimensional FEM and are appended to circuit of the transformer. And transient characteristics of the transformer are analyzed by axisymmetric FEM which is coupled magnetic field of transformer and circuit of transformer. When a transformer encounters abnormal voltage, using the proposed method, internal magnetic field of transformer, voltages and currents of windings are calculated.

• Korean Chemical Engineering Research
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• v.50 no.5
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• pp.933-937
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• 2012

In the present study, we evaluate the sensitivity and optimal stripping voltammetry (SV) conditions of copper (Cu), which is one of the main trace heavy metals inducing the environmental contamination, using carbon nanotube (CNT) electrode. In addition, the reaction mechanism of stripping reaction of Cu is investigated. The electrochemical analyses such as squarewave stripping voltammetry (SWSV) and linear scan voltammetry (LSV) are used for the evaluations. As a result of that, the best SWSV conditions like squarewave amplitude of 15 mV, frequency of 60 Hz, deposition potential of -1.0V vs. Ag/AgCl and deposition time of 200s are determined with the measured Cu sensitivity of $1.824{\mu}A/{\mu}M$. As a driving force affecting the stripping reaction of Cu, surface reaction is more dominant one than diffusion. These results are compared with other reference results and it is confirmed that our suggested CNT electrode gives rise to better Cu sensitivity result than other references.

• 전기의세계
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• v.27 no.6
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• pp.9-13
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• 1978

유도기의 사용환경이나 기기응용범위의 확대에 따라 수요자의 요구사양이 다양화하며 전용화하는 경우가 뚜렷하여 지고 있다. 그로인하여 극수변환을 하는 유도전동기에 있어서도 동일철심에 극수가 다른 두개 이상의 권선을 삽입하는 경우가 많다. 이때 운전중인 한쪽 권선에 의한 자속이 다른 권선에 쇄교되어 전압이 유기될 경우가 있다. 이 유기전압은 두 코일의 권선극수비에 따라 권선재에서 상살되던가 아니면 상살하고자 권선내에 순환전류가 흐른다. 이 순환전류의 흐름을 판별하려면 개개의 코일유기전압을 vector합성하여 검토하여 보면 알 수 있다. 이 vector합성 결과에 따르면 유기전압 상살여부는 권선의 종류가 정하여 지면 일반적으로 극수비에 따라 일의적으로 정하여 지는 성질을 가지고 있다. 그러므로 극수변환유도전동기를 다각도로 분석검토하여 각종권선에 따른 순환전류의 문제를 이론적으로 해석한 결과로 순환전류판별법을 설명하고자 한다.