• Title/Summary/Keyword: 전류효율

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TCO 박막의 결정 구조 및 표면 특성에 따른 OLED 소자의 특성

  • Lee, Bong-Geun;Lee, Yu-Rim;Lee, Gyu-Man
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.11a
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    • pp.183-183
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    • 2009
  • OLED소자의 양극재료로써 현재는 산화인듐주석(ITO : indium tin oxide) 박막이 널리 이용되고 있다. 그러나 낮은 전기 비저항과 높은 투과도를 갖는 ITO 박막을 얻기 위해서는 $300^{\circ}C$ 이상의 고온에서 성막되어야 하며, 원료 물질인 인듐의 수급량 부족으로 인한 문제점과 독성, 저온증착의 어려움, 스퍼터링 시 음이온 충격에 의한 막 손상으로 저항의 증가의 문제점이 있고, 또한 유기발광소자의 투명전극으로 쓰일 경우에 유기물과의 계면 부적합성, 액정디스플레이의 투명전극으로 사용될 경우에 $400^{\circ}C$정도의 놓은 온도와 수소 플라즈마 분위기에서 장시간 노출 시 열화로 인한 광학적 특성변화가 문제가 된다. 이러한 문제점을 지닌 ITO 박막을 대체할 수 있는 물질로 산화 인듐아연(lZO) 박막이 많은 각광을 받고 있다. IZO(Indium Zinc Oxide) 박막은 저온 ($100^{\circ}C$ 이상)에서 증착이 가능하고 추가적인 열처리 없이도 가시광 영역에서 90% 이상의 광 투과도와 ${\sim}10^{-4}{\Omega}cm$ 이하의 낳은 전기 비저항을 갖는 것으로 알려져 있다. 이러한 IZO박막은 성막 후 고온의 열처리 과정이 필요 없기 때문에 폴리카보네이트와 같은 유기물 기판을 사용하여 제작 가능한 유연한 평판형 표시 소자의 제작에도 적용될 수 있다. IZO(Indium Zinc Oxide) 박막은 상온 공정에서도 우수한 전기적, 광학적, 표면 특성을 나타낼 뿐만 아니라 양극재료로써 높은 일함수를 가지고 있어 고효율의 유기 발광 소자를 구현하는데 유리한 재료라 판단된다. 본 연구에서는 TCO 박막의 면 저항과 표면 거칠기가 OLED 소자의 성능에 미치는 영향을 조사하였다. R.F Magnetron Sputtering을 이용하여 투명 전도막을 성막 형성 하였으며, 기판온도와 증착과정에서 주입되는 산소, 수소의 유랑 변화가 박막의 구조적, 전기적 특성에 어떠한 영향 미치는 것인가를 자세히 규명하였다 ITO 와 IZO박막은 챔버 내 다양한 가스 분위기(Ar, $Ar+O_2$ and $Ar+H_2$) 에서 R.F Magnetron Sputtering 방법으로 증착했다. TCO박막의 구조적인 이해를 돕기 위해서 X-ray diffraction 과 FESEM으로 분석했다. 광학적 투과도와 박막의 두께는 Ultraviolet Spectrophotometer(Varian, cary-500)와 Surface profile mersurement system으로 각각 측정하였다. 면저항, charge carrier농도, 그리고 TCO박막의 이동성과 길은 전기적특성은 Four-point probe와 Hall Effect Measurement(HMS-3000)로 각각 측정한다. TCO 박막의 표면 거칠기에 따른 OLED소자의 성능분석 측면에서는 TCO 박막의 표면 거칠기 조절을 위해 photo lithography 공정을 사용하여 TCO 박막을 에칭 하였다. 미세사이즈 패턴 마스크가 사용되고 에칭의 깊이는 에칭시간에 따라 조절한다. TCO박막의 표면 형태는 FESEM과 AFM으로 관찰하고 그리고 나서 유기메탈과 음극 전극을 연속적으로 TCO 박막위에 증착한다. 투명전극으로 사용되는 IZO기판 상용화를 위해 IZO기판 위에 $\alpha$-NPB, Alq3, LiF, Al순서로 OLED소자를 제작하였다. 전류밀도와 전압 그리고 발광과 OLED소자의 전압과 같은 전기적 특성은 Spectrometer (minolta CS-1000A) 에 의하여 I-V-L분석을 했다.

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Battery Level Calculation and Failure Prediction Algorithm for ESS Optimization and Stable Operation (ESS 최적화 및 안정적인 운영을 위한 배터리 잔량 산출 및 고장 예측 알고리즘)

  • Joo, Jong-Yul;Lee, Young-Jae;Park, Kyoung-Wook;Oh, Jae-Chul
    • The Journal of the Korea institute of electronic communication sciences
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    • v.15 no.1
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    • pp.71-78
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    • 2020
  • In the case of power generation using renewable energy, power production may not be smooth due to the influence of the weather. The energy storage system (ESS) is used to increase the efficiency of solar and wind power generation. ESS has been continuously fired due to a lack of battery protection systems, operation management, and control system, or careless installation, leading to very big casualties and economic losses. ESS stability and battery protection system operation management technology is indispensable. In this paper, we present a battery level calculation algorithm and a failure prediction algorithm for ESS optimization and stable operation. The proposed algorithm calculates the correct battery level by accumulating the current amount in real-time when the battery is charged and discharged, and calculates the battery failure by using the voltage imbalance between battery cells. The proposed algorithms can predict the exact battery level and failure required to operate the ESS optimally. Therefore, accurate status information on ESS battery can be measured and reliably monitored to prevent large accidents.

Experimental Study on Temperature-Moisture Combined Measurement System for Slope Failure Monitoring (사면붕괴 모니터링에 사용되는 온도-함수비 복합계측시스템 개발에 관한 실험적 연구)

  • Nam, Jin-Won
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.19 no.2
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    • pp.33-39
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    • 2015
  • Recently, the event of slope failure has been occurring frequently due to rapid climate changes and broad development of infrastructures, and the research for establishment of monitoring and prevention system has been an attentive issue. The major influence factors of slope failure mechanism can be considered moisture and temperature in soil, and the slope failure can be monitored and predicted through the trend of moisture-temperature change. Therefore, the combined sensing technology for the continuous measurement of moisture-temperature with different soil depths is needed for the slope monitoring system. The various independent sensors for each item (i.e. temperature and moisture respectively) have been developed, however, the research for development of combined sensing system has been hardly carried out. In this study, the high-fidelity sensor combing temperature-moisture measurement by using the minimized current consuming temperature circuit and the microwave emission moisture sensor is developed and applied on the slope failure monitoring system. The feasibility of developed monitoring system is verified by various experimental approaches such as standard performance test, mockup test and long-term field test. As a result, the developed temperature-moisture combined measurement system is verified to be measuring and monitoring the temperature and moisture in soil accurately.

Electrochemical Characteristics of Supercapacitor Electrode Using MnO2 Electrodeposited Carbon Nanofiber Mats from Lignin-g-PAN Copolymer (이산화망간 전기증착 리그닌 기반 탄소나노섬유 매트를 이용한 슈퍼캐퍼시터용 전극소재의 전기·화학적 특성)

  • Kim, Seok Ju;Youe, Won-Jae;Kim, Yong Sik
    • Journal of the Korean Wood Science and Technology
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    • v.44 no.5
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    • pp.750-759
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    • 2016
  • The $MnO_2$ electrodeposited on the surface of the carbon nanofiber mats ($MnO_2$-LCNFM) were prepared from electrospun lignin-g-PAN copolymer via heat treatments and subsequent $MnO_2$ electrodeposition method. The resulting $MnO_2$-LCNFM was evaluateed for its potential use in a supercapicitor electrode. The increase of $MnO_2$ electric deposition time was revealed to increase diameter of carbon nanofibers as well as $MnO_2$ content on the surface of carbon nanofiber mats as confirmed by scanning electon microscope (SEM) analysis. The electrochemical properties of $MnO_2$-LCNFM electrodes are evaluated through cyclic voltammetry test. It was shown that $MnO_2$-LCNFM electrode exhibited good electrochemical performance with specific capacitance of $168.0mF{\cdot}cm^{-2}$. The $MnO_2$-LCNFM supercapacitor successfully fabricated using the gel electrolyte ($H_3PO_4$/Polyvinyl alcohol) showed to have the capacitance efficiency of ~90%, and stable behavior during 1,000 charging/discharging cycles.

Design of a step-up DC-DC Converter using a 0.18 um CMOS Process (0.18 um CMOS 공정을 이용한 승압형 DC-DC 컨버터 설계)

  • Lee, Ja-kyeong;Song, Han-Jung
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.17 no.6
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    • pp.715-720
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    • 2016
  • This paper proposes a PWM (Pulse Width Modulation) voltage mode DC-DC step-up converter for portable devices. The converter, which is operated with a 1 MHz switching frequency, is capable of reducing the mounting area of passive devices, such as inductor and capacitor, and is suitable for compact mobile products. This step-up converter consists of a power stage and a control block. The circuit elements of the power stage are an inductor, output capacitor, MOS transistors Meanwhile, control block consist of OPAMP (operational amplifier), BGR (band gap reference), soft-start, hysteresis comparator, and non-overlap driver and some protection circuits (OVP, TSD, UVLO). The hysteresis comparator and non-overlapping drivers reduce the output ripple and the effects of noise to improve safety. The proposed step-up converter was designed and verified in Magnachip/Hynix 0.18um 1-poly, 6-metal CMOS process technology. The output voltage was 5 V with a 3.3 V input voltage, output current of 100 mA, output ripple less than 1% of the output voltage, and a switching frequency of 1 MHz. These designed DC-DC step-up converters could be applied to the Personal Digital Assistants(PDA), cellular Phones, Laptop Computer, etc.

Effective Concentration of Procaine Solution for Inotophoresis

  • Lee Jae-Hyoung;Kim Joo-Young;Jekal Seung-Joo
    • The Journal of Korean Physical Therapy
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    • v.10 no.1
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    • pp.1-6
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    • 1998
  • The purpose of this study was to determine the of effective concentration of procaine iontophoresis for durarion of cutaneous local anesthesia. Forty-five healthy students with an age range of 19 to 34 years$(21\pm2.7)$, were participated in this study. The subjects were randomly assigned into 5 groups. Bach 9 subjects received iontophoresis on the flexor surface of dominant forearm with soft cotton pad $(3.5\times3.5cm)$ soaked in 2ml of $2\%$ (pH 5.28), $4\%$ (pH 5.12), $8\%$ (pH 4,98), $16\%$ (pH 4.72), $32\%$ (pH 4.52) procaine hydrochloride solution at 4mA for 10 minutes (total current 40mA min) using anodal direct current. The study was performed in a randomized, double-blind design, After procaine iontophoresis, the duration of anesthesia were evaluated at five minute intervals on five random locations in the iontophoretically area using a 21-gauge sterile hypodermic needle pressed with 1mm invagination unitl sharp pin-pricking pain sensation returned. The data were analyzed with one-way ANOVA to determine significant differences between groups. Duncan post hoc was performed at level .01. The relationship between anesthetic duration and procaine concentration was assessed with Pearson Product-Moment Correlation Coefficients. ANOVA tests showed significant differences in the anesthetic duration between the concentration of procaine solution (p<.001). Procaine iontophoresis with $4\%$ concentration produced cutaneous Socal anesthesia of significantly longer duration(15.56 min) than iontophoresis with $2\%,\;8\%,\;16\%$, and $32\%$ of procaine GCl(p<.01). Whereas the anesthetic duration had no correlation with concentration of procaine solution (r=-0.41, NS). These results support the $4\%$ procaine solution was an effective concentration of iontophoresis for induced cutaneous local anesthesia.

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A Study on the Characteristic Analysis of Blue OLED for the Luminous Traffic Safety Mark (발광형 교통안전표지용 청색 OLED의 특성분석에 관한 연구)

  • Kang, Myung-Goo;Kim, Jung-Yeoun;Oh, Hwan-Sool
    • The Journal of The Korea Institute of Intelligent Transport Systems
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    • v.6 no.2
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    • pp.138-145
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    • 2007
  • Luminous traffic safety mark is restricted to use only the place that has a thick fog, many night traffic accidents, limited field of view due to structure of road. Recently, LEDs are used for luminous traffic safety mark, but we propose an organic LED for a novel luminous traffic safety mark in the near future. The device structure was $ITO/2-TNATA(500{\AA})/{\alpha}-NPD(200{\AA})/DPVBi(300{\AA})/BCP(10{\AA})/Alq_3(200{\AA})/LiF(10{\AA})/Al:Li(1000{\AA})$. The characteristics of the device are most efficient on occasion of using $N_2$ gas plasma treatment. Current density is $240.71mA/cm^2$ luminance $10,550cd/m^2$, and current efficiency 3.53cd/A at an applied voltage of 10V. The maximum EL wavelength of the fabricated blue organic light-emitting device is 456nm. CIE color coordinates are x=0.1449 and y=0.1633, which is similar to NTSC deep-blue color with CIE color coordinates of x=0.14 and y=0.08.

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Ohmic Heating Characteristics of Fermented Soybean Paste and Kochujang (된장 및 고추장의 Ohmic heating 특성)

  • Cho, Won-Il;Kim, Do-Un;Kim, Young-Suk;Pyun, Yu-Ryang
    • Korean Journal of Food Science and Technology
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    • v.26 no.6
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    • pp.791-798
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    • 1994
  • Ohmic heating is a food processing operation in which heat is internally generated within foods by the passage of alternating electric current. The process enables highly viscous paste foods such as Kochujang, and fermented soybean paste to be heated very fast. In order to develope the novel pasteurization process of paste foods, static Ohmic heating system was built, and heating characteristic during Ohmic heating under various conditions were studied. Electric conductivities of Kochujang and fermented soybean paste at room temperature were 1.865 S/m and 2.510 S/m, respectively and increased linearly with increasing temperature. Specific heating rate was highly dependent on the frequency. The highest heating rate was achieved at 5 KHz for Kochujang and 20 KHz for fermented soybean paste. Uniform heating throughout the sample was achieved during Ohmic heating with low frequency electrical currents, however above 5 KHz frequency, surface temperature was several degrees higher than the bulk.

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Role of Electrode Reaction of Electrolyte in Electrokinetic-Fenton Process for Phenanthrene Removal (동전기-펜턴 공정에서 전해질의 전극반응이 처리효율에 미치는 영향)

  • Park Ji-Yeon;Kim Sang-Joon;Lee You-Jin;Yang Ji-Won
    • Journal of Soil and Groundwater Environment
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    • v.11 no.1
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    • pp.7-13
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    • 2006
  • The effects of electrolytes were investigated on the removal efficiency when several different electrolytes were used to change the electrode reaction in an electrokinetic (EK)-Fenton process to remediate phenanthrene-contaminated soil. Electrical potential gradient decreased initially due to the ion entrance into soil and then increased due to the ion extraction from soil under the electric field. Accumulated electroosmotic flow was $NaCl>KH_2PO_4>MgSO_4$ at the same concentration because the ionic strength of $MgSO_4$ was the highest and $Mg(OH)_2$ formed near the cathode reservoir plugged up soil pore to inhibit water flow. When hydrogen peroxide was contained in electrolyte solution, removal efficiency increased by Fenton reaction. When NaCl was used as an electrolyte compound, chlorine ($Cl_2$) was generated at the anode and dissolved to form hypochlorous acid (HClO), which increased phenanthrene removal. Therefore, the electrode reaction of electrolyte in the anode reservoir as well as its transport into soil should be considered to improve removal efficiency of EK-Fenton process.

Vacuum Web-coater with High Speed Surface Modification Equipment for fabrication of 300 mm wide Flexible Copper Clad Laminate (FCCL) (초고속 대면적 표면 처리 장치가 부착된 300 mm 폭 연성 동박적층 필림 제작용 진공 웹 코터)

  • Choi, H.W.;Park, D.H.;Kim, J.H.;Choi, W.K.;Sohn, Y.J.;Song, B.S.;Cho, J.;Kim, Y.S.
    • Journal of the Korean Vacuum Society
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    • v.16 no.2
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    • pp.79-90
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    • 2007
  • Prototype of $800{\ell}$ vacuum web coater (Vic Mama) consisting of ion source with low energy less than 250 eV for high speed surface modification and 4 magnetron sputter cathodes was designed and constructed. Its performance was evaluated through fabricating the adhesiveless flexible copper clad laminate (FCCL). Pumping speed was monitored in both upper noncoating zone pumped down by 2 turbo pumps with 2000 l/sec pumping speed and lower surface modification and sputter zone vacuumed by turbo pumps with 450 1/sec and 1300 1/sec pumping speed respectively. Ion current density, plasma density, and uniformity of ion beam current were measured using Faraday cup and the distribution of magnetic field and erosion efficiency of sputter target were also investigated. With the irradiation of ion beams on polyimide (Kapton-E, $38{\mu}m$) at different fluences, the change of wetting angle of the deionized water to polyimide surface and those of surface chemical bonding were analyzed by wetting anglometer and x-ray photoelectron spectroscopy. After investigating the deposition rate of Ni-Cr tie layer and Cu layer was investigated with the variations of roll speed and input power to sputter cathode. FCCL fabricated by sputter and electrodeposition method and characterized in terms of the peel strength, thermal and chemical stability.