• Title/Summary/Keyword: 전기 삼투

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Studies on the Transport of Acetic Acid by Electrodialysis (전기투석에 의한 초산의 이동특성 연구)

  • 최동민;구윤모
    • KSBB Journal
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    • v.11 no.3
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    • pp.360-366
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    • 1996
  • Electrodialysis of acetic acid was studied to find out the trend of the transport of organic acids through ultrafiltration and ion exchange membranes. The net transport rate of acetic acid was determined from the electro-migration velocity relative to the electro-osmotic flow rate through the membrane. Electro-osmosis flows through ultrafiltration membranes were from the anodic side to the cathodic side in the presence of electric field. The surface of ultrafiltration membrane was measured by the electro-osmotic flow to be charged negatively. Different transport behaviors of acetic acid were found with the ultrafiltration membranes of different materials. In general, regenerated cellulose membranes (YM series) were more effective than polysulfone membranes (PM series) for the transport of acetic acid. The transport of acetic acid was affected by electric strength, distance between the electrodes, surface area of electrode, temperature, and pore size of membrane. The transport rate through the ion exchange membrane was 1.5 to 3 times of those through the ultrafiltration membranes at the constant current of 150 mA in the experimental ranges. The transport rate of acetic acid through the ion exchange membrane increased by 10% with a pulse electric field of 10 sec/hr.

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Effect of ionic Strength of Electrolyte on Phenanthrene Removal in Electrokinetic-Fenton Process (동전기-펜턴 공정에서 phenanthrene 제거에 대한 전해질 이온세기의 영향)

  • Park Ji-Yeon;Kim Sang-Joon;Lee You-Jin;Yang Ji-Won
    • Journal of Soil and Groundwater Environment
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    • v.10 no.4
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    • pp.18-25
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    • 2005
  • Characteristics of phenanthrene removal in an electrokinetic (EK)-Fenton process were investigated in a viewpoint of concentration and ionic strength of electrolytes. When three kinds of electrolytes (NaCl, $KH_2PO_4,\;and\;MgSO_4$) were used, the increase in electrolyte concentration caused the decrease of electrical potential gradient. The increase of electrical conductivity was due to the increase of ionic concentration in soil. The decrease of accumulated electroosmotic flow (EOF) with increase in electrolyte concentration was due to the decrease of zeta potential. The removal efficiency was in proportion to accumulated EOF which depended on ionic strength. Total energy expenditure without electrolyte was 10-30 times higher than its with 0.5 M electrolyte. The lower removal efficiency was caused by the lower energy expenditure with 0.5 M one. An effective EK-Fenton process was determined from considering the removal efficiency and the energy expenditure, simultaneously.

Electrokinetic Strengthening of Soft Marine Clays in E/K Cell (Electrokinetic cell을 이용한 해성점토지반의 개량효과 연구)

  • Lee, Seung-Won;Lee, Yeong-Nam
    • Geotechnical Engineering
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    • v.14 no.4
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    • pp.77-90
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    • 1998
  • To study the improvement of soft marine clay from southern coast of Korea under theelectroosmosis and electrophoresis conditions, several electrokinetic tests were carried out in electrokinetic(E/K) cell. In electroosmosis tests, various treatment times and current densities were used to investigate the strengthening effect under different conditions. From these tests results, it may be noted that electroosmotic strengthening of soft marine clay was effective in proportion to unit power consumption, current density and treatment time. However, electrophoresis method was not effective for thin soil.

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Electrokinetic-Fenton Process for Removal of Phenanthrene (동전기-펜턴 공정을 이용한 phenanthrene 오염토양의 정화)

  • 양지원;박지연;김상준;이유진;기대정
    • Journal of Soil and Groundwater Environment
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    • v.9 no.1
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    • pp.47-53
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    • 2004
  • Feasibility of electrokinetic process combined with Fenton-like reaction was investigated for the removal of phenanthrene from contaminated soil. Transport of hydrogen peroxide by electroosmosis and decomposition of phenanthrene by Fenton-like reaction were observed in a model system. Electrical potential gradient and electroosmotic flow (EOF) at 10 mA were higher than those at 5 mA. High accumulated EOF resulted in high removal efficiency of phenanthrene because the large amount of hydrogen peroxide was transfered through the soil. Removal efficiency of phenanthrene by water washing was 8.5% for 7 days. The highest removal efficiency including phenanthrene decomposition was 95.6% for 14 days. After the operation, soil samples with removal efficiency of 95.6% showed low concentrations of phenanthrene and its intermediates. From this result, it was presumed that phenanthrene was decomposed to small molecules or mineralized to water and carbon dioxide due to continuous supply of hydrogen peroxide by electroosmotic flow.

Study on the Effect of the Mg2+ Ion on the Behavior of Anionic Surfactants in Electrophoresis (전기 이동에서 Mg2+ 이온이 음이온 계면활성제의 거동에 미치는 영향)

  • Jeong, Hyuk
    • Analytical Science and Technology
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    • v.18 no.1
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    • pp.35-42
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    • 2005
  • This study reports the effect of $Mg^{2+}$ ions on the behavior of the anionic surfactant in electrophoresis. Intractions of $Mg^{2+}$ ions with carboxylates and sulfonates resulted large changes in their apparent mobilities. A comprehensive analysis of the electroosmotic and electrophoretic mobilities reveals that major cause for the variation of the apparent mobilities of anions arises from the electroosmotic mobilities.

Removal of Phenanthrene by Electrokinetic-Fenton Process in a 2-dimensional Soil System (동전기-펜턴 공정을 이용한 2차원 토양 정화장치에서의 phenanthrene 제거)

  • Park Ji-Yeon;Kim Sang-Joon;Lee You-Jin;Yang Ji-Won
    • Journal of Soil and Groundwater Environment
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    • v.10 no.5
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    • pp.11-17
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    • 2005
  • Characteristics of phenanthrene removal in the Electrokinetic (EK)-Fenton process were investigated in a 2-dimensional test cell in a viewpoint of the effect of gravity and electrosmotic flow (EOF). When the constant voltage of 100 V was applied to this system, the current decreased from 1,000 to 290 mA after 28 days, because soil resistance increased due to the exhaustion of ions in soil by electroosmosis and electromigration. Accumulated EOF in two cathode reservoirs was 10.3 L and the EOF rate was kept constant for 28 days. At the end of operation, the concentration of phenanthrene was observed to be very low near the anode and increased in the cathode region because hydrogen peroxide was supplied from anode to cathode region following the direction of EOP. Additionally, the concentration of phenanthrene decreased at the bottom of the test cell because the electrolyte solution containing hydrogen peroxide was largely transported toward the bottom due to a low capillary action in the soil with high porosity. Average removal efficiency of phenanthrene by EK-Fenton process was 81.4% for 28 days. In-situ EK-Fenton process would overcome the limitations of conventional remediation technologies and effectively remediate the contaminated sites.

Bacterial Behavior in Soil under Electric Field and its Effect on Electrokientic Bioremediation (전기장하 토양내에서 미생물 이동특성과 동전기 생물학적복원의 효과)

  • Kim, Sang-Joon;Park, Ji-Yeon;Lee, You-Jin;Yang, Ji-Won
    • KSBB Journal
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    • v.21 no.3
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    • pp.175-180
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    • 2006
  • In this study, it could be found that the microbial movement in soil under electric field mainly occurred by electrophoresis and electroosmosis. The contribution of electrophoresis on the microbial mobility and flux was generally higher than that of electroosmosis. In the electrokinetic(EK) bioremediation of a pentadecane-contaminated soil, the microbial population increased simultaneously at anode and cathode regions of the soil specimen because both electrophoresis and electroosmosis affected on the microbial movement. After initial operation, the microbial population was high in order of anode, middle, and cathode regions due to their negatively-charged surface and oxygen generation at anode. However, the uniform contaminant removal was achieved by the microbial movement with two-directionality.

Development of Osmotic Infusion Pump (삼투압 약물주입 펌프의 개발)

  • Kim, Dong Sun;Choi, Seong Wook
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.39 no.6
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    • pp.471-475
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    • 2015
  • Because of increasing demand, a small portable drug injector that uses osmotic pressure for its operation force is developed, and its performance is evaluated. The osmotic drug injector can be small and lightweight because it does not require heavy batteries and an actuator, unlike previous electromechanical drug injectors. Moreover, its injection pressure can be sustained longer than that of previous elastic drug injectors. The new device is composed of a drug sac, osmotic pressure chamber, semipermeable membrane, and solvent chamber. To evaluate its performance, an in-vitro experiment was designed to measure the outflow and the injection pressure with respect to time. The experimental results show that the new drug infuser can continuously deliver 20 ml drug over a period of 20 h. The maximum injecting pressure was over 400 mmHg. Which prevents backflow caused by changes in the outlet pressure resulting from changes to the position of the device and the patient's posture.

A STUDY ON CHARACTERISTICS OF EECTRO-OSMOTIC FLOWS UNDER THE LOCAL VARIATION OF THE ELECTRIC FIELD (전기장의 국소변화에 따른 전기삼투 유동 및 혼합 특성해석)

  • Heo H. S.;Jeong J. H.;Sub Y. K.
    • 한국전산유체공학회:학술대회논문집
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    • 2005.10a
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    • pp.27-30
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    • 2005
  • In a microfluidic chips pressure driven flow or electro-osmotic flow has been usually employed to deliver bio-samples. Flow in the chips is usually slow and the mixing performance is poor. A micro-mixer with a rapid mixing is important for practical applications. In this study a newly designed and electro-osmotic driven micro-mixer is proposed. This design is comprised of a channel and a series of metal electrodes periodically attached on the side surface. In this configuration electro-osmotic flows and the stirring effects are simulated three-dimensionally using a commercial code, CFD-ACE. Focus is given the effect on the electro-osmotic flow characteristics under the local variation of the electric field.

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An Theoretical Analysis of Electro-osmotic Flow in 2-dimensional slit with Electrical Double Layers in Interaction (전기 이중층의 상호작용을 고려한 2차원 슬릿 내의 전기삼투 유동에 관한 이론적 해석)

  • Lee, Dae-Keun
    • 유체기계공업학회:학술대회논문집
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    • 2006.08a
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    • pp.497-500
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    • 2006
  • An theoretical analysis on the electro-osmotic flow in a 2-dimensional slit, that is induced by an external electric field acting on the electrical double layers near the slit wall, was performed. Especially, although there were many studies on the interacting electrical double layers, it was found in this study that they have several physical or mathematical fallacies. To resolve these, the general solution on the charge-regulating slit with the height as a parameter was obtained. The results of this work can provide the electrokinetic solution of nanoscale slit with the electrical double layer interaction as well as that of microscale slit without the interaction and can be used as the benchmark of a numerical analysis and the reference of electrokinetic flow path design.

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