• Korean Chemical Engineering Research
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• v.61 no.1
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• pp.52-57
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• 2023

This study is a basic research for the development of high performance flexible electrode material. To enhance its electrochemical property, CuO nanoparticles (CuO NPs) were introduced and dispersed on surface of CNT fiber through electrochemical deposition method. The CNT fiber/CuO NPs electrode was fabricated and applied to electrochemical non-enzymatic glucose sensor. Surface morphology and elemental composition of the CNT fiber/CuO NPs electrode was characterized by scanning electron microscope (SEM) with energy dispersive X-ray spectrometry (EDS). And its electrochemical characteristics were investigated by cyclic voltammetry, electrochemical impedance spectroscopy and chronoamperometry. The CNT fiber/CuO NPs electrode exhibited the good sensing performance for glucose detection such as high sensitivity, wide linear range, low detection limit and good selectivity due to synergetic effect of CNT fiber and CuO NPs. Based on the unique property of CNT fiber, CuO NPs were provide large surface area, enhanced electrocatalytic activity, efficient electron transport property. Therefore, it is expected to develop high performance flexible electrode materials using various nanomaterials.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.2 no.2
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• pp.49-56
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• 2001

The possibility of a noise reduction of piezoelectric single Panels is experimentally studied. Piezoelectric single panel is basically a plate structure on which piezoelectric patch with shunt circuit is mounted. The use of piezoelectric shunt damping can reduce the transmission at resonance frequencies of the panel structure. Piezo-damping is implemented by using a newly proposed tuning method. This method is based on electrical impedance model and maximizing the dissipated energy at the shunt circuit. By measuring the electrical impedance at the piezoelectric patch bonded on a structure, an equivalent electrical model is constructed near the system resonance frequency. Resonant shunt circuit for piezoelectric shunt damping is composed of register and inductor in series, and they are determined by maximizing the dissipated energy throughout the circuit. The transmitted noise reduction performance of single Panel is tested on an acoustic tunnel. The tunnel is a tube with a square cross section and a loud speaker is mounted at one side of the tube as a sound source. Panels are mounted in the middle of the tunnel and the transmitted sound pressure across Panels is measured. By enabling the piezoelectric shunt damping noise reduction is achieved at the resonance frequencies as well. Piezoelectric single panel with piezoelectric shunt damping is a promising technology for noise reduction in a broadband frequency.

• Analytical Science and Technology
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• v.11 no.5
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• pp.360-365
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• 1998

We have studied structural characterization, electrical charge and discharge, and impedence properties for the $LiMn_2O_4$ synthesized by solid state reaction. From the X-ray diffraction results, diffraction patterns for compounds of the four kinds of $LiMn_2O_4$ compounds were observed to peaks of (111), (311), (004) and (400). Also, Small similar peaks (110), (222) and (313) were observed for sample C1 and C2. Concerning to new peaks of (113) and (331) for the sample C4, we can found that structural transitions were accompanied from C1 and C2 to C4 via C3 structure. A electrical charge and discharge data showed that efficiency of C1 was very poor state and efficiencies of C2 and C3 were about 60-70% of theoretical capacity. But, the C4 showed good charge and discharge properties of more than 70% of theoretical capacity. From the impedence properties for finding the effect of ions and electrons transfer of battery, C2 and C3 of high frequency of real number showed good electrical impedence properties.

• Journal of the Korean Electrochemical Society
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• v.23 no.3
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• pp.57-65
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• 2020

It is crucial to investigate the thermal degradation of lithium-ion batteries (LIBs) to understand the possible malfunction at high temperature. Herein, we investigated the effects of surface film formation on the thermal degradation of lithium cobalt oxide (LiCoO₂, LCO) cathode that is one of representative cathode materials. Cycling test at 60℃ exhibited poorer cycleability compared with the cycling at 25℃. Cathodes after the initial 5 cycles at 60℃ (60-LCO) exhibited higher impedance compared to the cathode after initial 5 cycles at 25℃ (25-LCO), resulting in the lower rate capability upon subsequent cycling at 25℃, although the capacity values were similar at the lowest C-rate of 0.1C. In order to understand degradation of the LCO cathode at the high temperature, we analyzed the cathodes surface using X-ray photoelectron spectroscopy (XPS). Among various peaks, intensity of lithium hydroxide (LiOH) increased substantially after the operation at 60℃, and the C-C signal that represents the conductive agent was distinctly lower on 60-LCO compared to 25-LCO. These results pointed to an excessive formation of cathode-electrolyte interphase including LiOH at 60℃, leading to the increase in the resistance and the resultant degradation in the electrochemical performances.

• Journal of the Korean Electrochemical Society
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• v.8 no.2
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• pp.88-93
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• 2005

Anode-supported solid oxide fuel cell (SOFC) was investigated to increase the cell power density at intermediate temperature through control of the cathode structure. The anode-supported SOFC cell were fabricated by wet process, in which the electrolyte of $8mol\%\;Y_2O_3-stabilized\;ZrO_2 (YSZ)$ was coated on the surface of anode support of Ni/YSA and then the cathode was coated. The cathode has two- or three- layered structure composed of $(La_{0.85}Sr_{0.15})_{0.9}MnO_{3-x}(LSM),\;LSM/YS$ composite (LY), and $La_{0.6}Sr_{0.4}Co_{0.2}Fe_{0.8}O_3{LSCF)$ with different thickness. Their single cells with different cathode structures were characterized by measuring the cell performance and ac impedance in the temperature range of 600 to $800^{\circ}C$ in humidified hydrogen with $3\%$ water and air. The cell with $LY\;9{\mu}m/LSM\;9{\mu}m/LSCF\;17{\mu}m$ showed best performance of $590mW/cm^2$, which was attributed to low polarization resistance due to LY and to low interfacial resistance due to LSCF.

• Membrane Journal
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• v.13 no.3
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• pp.162-173
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• 2003

The pseudo n-type polyaniline was prepared by doping of camphorsulfonic acid(CSA) and dodecylbenzenesulfonic acid(DBSA) as the dopants in solvent of N-methyl-2-pyrrolidinone(NMP). The dopants in polymer structure was qualitatively analyzed using FT-IR. The influence on electrochemical properties with dopant concentration of PANI film were investigated. The electrochemical characteristics of the n-type PANI electrode that coated on ITO were evaluated by cyclic voltammetry(CV) and AC impedance method. The prepared PANI were confirmed as n-type PANI from FT-IR and CV. The charge transfer resistance of film on PANI/CSA electrode were measured as 1.14{\sim}1.09k{\mu}$by AC impedance. The charge transfer resistance of PANI/DBSA electrode decreased with increasing the mole ratio of DBSA as 27.73{\sim}8.37 k{\mu}$. The double layer capacitance of PANI/CSA electrode was showed almost constant value as $13.47{\sim}14.59 {\mu}F$ and that of PANI/DBSA electrode increased with increasing mole ratio of DBSA from 0.49 to $1.20 {\mu}F$.

• Geophysics and Geophysical Exploration
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• v.11 no.3
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• pp.184-196
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• 2008

We perform MT soundings in Bendigo, the northern part of Victoria, Australia, to investigate the deep subsurface geologic structure. The primary purpose of this survey is to figure out whether the discontinuity such as faults extends northward. The time series of MT signal were measured over 11 days at 71 measurement stations together with at remote reference, which help enhance the quality of impedance estimation and its interpretation. The impedances are estimated by robust processing using remote reference technique and then inverted with 2D MT 2D inversion. We can see that known faults are clearly imaged in MT 2D inversion. Comparing resistivity images from MT 2D inversion with interpreted boundary from reflection seismic exploration, two interpretations match well each other.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.16 no.7
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• pp.4849-4854
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• 2015

It has been often occurred for the outside components(BU, SVaC, DB) of UM71c AF track circuits to be broken down caused by some pieces of falling ice in the winter time or by infrastructure repairing equipments while facility maintenance works since 2004, opening of Kyeongbu High Speed Rail Express. In this paper, we proposed that we could move the outside components of UM71c track circuit out of wayside from present place. Then we can assure that the life time of those components would be extended. So we simulated the electrical characteristics by changing cable length using MATLAB Simulinks and we designed the compensation capacitor. Also, we obtained the same results as those of simulation by field demonstration test on site. The design specifications obtained from this field verification test could be applied in the absent section of track circuit, if only have a little more intensified research to compensate changed electrical characteristics and to redesign inner impedance of the track circuit.

• Journal of the Institute of Electronics Engineers of Korea TC
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• v.48 no.1
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• pp.102-107
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• 2011

The current blood control system is using barcode and scanning one by one to manage blood bags. To have better management and accuracy, an RFID BIS (blood information system) is implemented with an UHF RFID tag antenna using a reflecter for a blood bag has been used.. The UHF RFID tag for blood bag, attached on the high permittivity blood, is designed and fabricated. The tag antenna is optimized and fabricated with the simulation tests such as the existence and nonexistence of the reflector, various distance between the reflector and the dipole tag, the different widths of the reflector and the existence and nonexistence of the T-matching structure. The characteristics and the reading range patterns of the tag antennas are measured. The BIS is implemented with the new tag design.

• Journal of Advanced Marine Engineering and Technology
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• v.23 no.6
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• pp.761-769
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• 1999

In this paper the effect of aging heat treatment to the Corrosion behavior for the Nimonic 80A superalloy was studied by AC Impedance methods. Tested solution was 3.5% with tempera-ture $25^{\circ}C$ Electro-chemical corrosion test were carried out for the Nimonic 80A super-alloy which solution heat treated at $1080^{\circ}C$ for 8 hours followed by aging heat treated at $650^{\circ}C,\;700^{\circ}C,\;750^{\circ}C\;800^{\circ}C$ and $850^{\circ}C$ with 16hours under vacuum environment. The obtained results were as follows; 1. Base metal and solution-treated materials were exhibited similar corrosion tendency as Ran-dle equivalent cell. The value of passive film resistance was 579 ohms for the base metal and 124,770 ohms for the solutionized metal such a difference was arose by the ${{\gamma}_^'}$ precipitate on the metal surface during heat treatment. 2. The measure value of $R_p$ for heat-treated at $650^{\circ}C,\;700^{\circ}C,\;800^{\circ}C$and $850^{\circ}C$ were 97,943, 93, 111, 26,961, 15,798 and 11,780ohm respectively. Which indicated that the passive film resistance Rp was reduced as aging temperature increased due to the growth of grain size and sensitization at the grain boundary. 3. The similar tendency was exhibited for corrosion behavior of the electro-chemical corrosion polarization method and AC impedance method and confirmed that AC impedance method was useful tool for corrosion research.