• Title/Summary/Keyword: 전극재

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Fabrication of Supercapacitors using Silver Nano Paste and Gel Electrolyte (은 나노 페이스트와 젤 전해질을 이용한 슈퍼캐패시터 제작)

  • Yoon, Seong Man;Jang, Hyunjung;Kim, Dae Won;Jang, Yunseok;Jo, Jeongdai;Go, Jeung Sang
    • Clean Technology
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    • v.19 no.4
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    • pp.410-415
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    • 2013
  • The supercapacitors were fabricated using silver (Ag) nano paste and activated carbon paste on the polyimide (PI) film and 5% potassium polyacrylate (PAAK) was used for gel electrolyte. In this paper, the current collector film and the electrode film were fabricated using screen printing. The thickness of printed silver paste was $7.3{\mu}m$ and the sheet resistance has the range of $5-7m{\Omega}/square$. An activated carbon with a surface area of $1,968m^2/g$, an electronic conducting agent (SUPER P, TIMCAL) and poly (4-vinylphenol) were mixed in 2-(2-buthoxyethoxy) ethyl acetate (BCA) with a ratio of 7:1:3 to fabricate the electrode paste. To analyze electrochemical characteristics, cyclic voltammetry was performed to evaluate the stability of the devices under the voltage range of -0.5-0.5 V. The calculated specific capacitances were 44.04 and 8.62 F/g for 10 and 500 mV/s scan rates, respectively.

Capacitively-coupled Resistivity Method - Applicability and Limitation (비접지식 전기비저항 탐사 - 적용성과 한계)

  • Lee Seong Kon;Cho Seong-Jun;Song Yoonho;Chung Seung-Hwan
    • Geophysics and Geophysical Exploration
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    • v.5 no.1
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    • pp.23-32
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    • 2002
  • Capacitively-coupled resistivity (CCR) system is known to be very useful where galvanic contact to earth is impossible, such as the area covered with thick ice, snow, concrete or asphalt. This system injects current non-galvanically, i.e., capacitively to earth through line antenna and measures potential difference in a same manner. We derived geometric factor for two types of antenna configuration and presented the method of processing and converting the data obtained with CCR system suitable to conventional resistivity inversion analysis. The CCR system, however, has limitations on use at conductive area or electrically noisy area since it is very difficult to inject sufficient current to earth with this system as with conventional resistivity system. This causes low SM ratio when acquiring data with CCR system and great care must be taken in acquiring data with this system. Additionally the uniform contact between line antennas and earth is also crucial factor to obtain good S/N ratio data. The CCR method, however, enables one to perform continuous profiling over a survey line by dragging entire system and thus will be useful in rapid investigation of conductivity distribution in shallow subsurface.

Effect of Compensation for Thickness Reduction by Chemical Degradation of PEMFC Membrane on Performance and Durability (PEMFC 고분자막의 화학적인 열화에 의한 두께 감소 보정이 성능 및 내구성에 미치는 영향)

  • Sohyeong Oh;Yoojin Kim;Seungtae Lee;Donggeun Yoo;Kwonpil Park
    • Korean Chemical Engineering Research
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    • v.62 no.1
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    • pp.1-6
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    • 2024
  • As the demand for hydrogen electric vehicles for commercial vehicles increases, the durability of PEMFCs must increase more than five times that of passenger cars, so research and development to improve durability is urgent. When the PEMFC membrane electrode assembly (MEA) undergoes chemical degradation, the MEA thickness decreases and pinholes occur. In this study, changes in the performance and durability of the MEA were measured while increasing the clamping pressure of the unit cell after open circuit voltage (OCV) holding, an accelerated chemical degradation experiment. As the clamping pressure increased, the resistance of the polymer membrane and the membrane/electrode contact resistance decreased, improving the I-V performance and reducing the hydrogen permeability. As the hydrogen permeability decreased, the OCV increased. When the pinhole area was removed and the MEA clamping pressure was increased, the hydrogen permeability decreased sharply, confirming that the local degradation has a large effect on the performance and durability of the entire cell. When the pinhole was removed and re-clamping and OCV holding was evaluated, it was confirmed that the durability improved according to the decrease in membrane resistance and hydrogen permeability.

Effects of Spark Plug Changes on Performance of an SI Engine Fueled by Gaseous Fuel (스파크플러그 변화에 따른 가스 엔진 성능 변화)

  • Lee, Sunyoup
    • Journal of the Korean Institute of Gas
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    • v.17 no.6
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    • pp.27-32
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    • 2013
  • Renewable gas fuels such as biogas and landfill gas are obtained from the biodegradable organic wastes so that they inherently have carbon-neutral nature which can respond global warming. Therefore, attentions are paid to use this renewable gases as a main fuel for internal combustion engines. However, the composition of the fuel varies by its origin or conversion process, it is necessary to make stable combustion and accomplish high efficiency when used in power generating spark ignition (SI) engines. In this study, efforts have been made to investigate the effect of the composition of renewable gas fuel on the engine performance and exhaust emissions. In addition, a new spark plug with a long electrode was tested and compared with a base spark plug as a way to improve engine efficiency and reduce harmful emissions.

Characteristics of an AZO/Ag/AZO Transparent Conducting Electrode Fabricated by Magnetron Sputtering for Application in Cu2ZnSn(S,Se)4 (CZTSSe) Solar Cells (Cu2ZnSn(S,Se)4 (CZTSSe) 박막 태양전지 적용을 위한 마그네트론 스퍼터링으로 증착된 AZO/Ag/AZO 투명전극의 특성)

  • Lee, Dong Min;Jang, Jun Sung;Kim, Jihun;Lee, InJae;Lee, Byeong Hoon;Jo, Eunae;Kim, Jin Hyeok
    • Korean Journal of Materials Research
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    • v.30 no.6
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    • pp.285-291
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    • 2020
  • Recent advances in technology using ultra-thin noble metal film in oxide/metal/oxide structures have attracted attention because this material is a promising alternative to meet the needs of transparent conduction electrodes (TCE). AZO/Ag/AZO multilayer films are prepared by magnetron sputtering for Cu2ZnSn(S,Se)4 (CZTSSe) of kesterite solar cells. It is shown that the electrical and optical properties of the AZO/Ag/AZO multilayer films can be improved by the very low resistivity and surface plasmon effects due to the deposition of different thicknesses of Ag layer between oxide layers fixed at AZO 30 nm. The AZO/Ag/AZO multilayer films of Ag 15 nm show high mobility of 26.4 ㎠/Vs and low resistivity and sheet resistance of 3.5810-5 Ωcm and 5.0 Ω/sq. Also, the AZO/Ag (15 nm)/AZO multilayer film shows relatively high transmittance of more than 65 % in the visible region. Through this, we fabricated CZTSSe thin film solar cells with 7.51 % efficiency by improving the short-circuit current density and fill factor to 27.7 mV/㎠ and 62 %, respectively.

Control of an Artificial Arm using Flex Sensor Signal (굽힘 센서신호를 이용한 인공의수의 제어)

  • Yoo, Jae-Myung;Kim, Young-Tark
    • Journal of the Korean Institute of Intelligent Systems
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    • v.17 no.6
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    • pp.738-743
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    • 2007
  • In this paper, a muscle motion sensing system and an artificial arm control system are studied. The artificial arm is for the people who lost one's forearm. The muscle motion sensing system detect the intention of motion from the upper arm's muscle. In sensing system we use flex sensors which is electrical resistance type sensor. The sensor is attached on the biceps brachii muscle and coracobrachialis muscle of the upper arm. We propose an algorithm to classify the one's intention of motions from the sensor signal. Using this algorithm, we extract the 4 motions which are flexion and extension of the forearm, pronation and supination of the arm. To verify the validity of the proposed algorithms we made experiments with two d.o.f. artificial arm. To reduce the control errors of the artificial arm we also proposed a fuzzy PID control algorithm which based on the errors and error rate.

Increase of Cell Concentration by the Automatic Analysis and Addition of glucose with an On-line Flow Injection Analysis System int he Cultivation of Saccharomyces cerevisiae Using a Korean Paper Digestion Wastewater (한지자숙폐액을 이용한 Saccharomyces cerevisiae의 배양에서 온-라인 FIA시스템에 의한 Glucose의 자동분석 및 첨가에 의한 증균)

  • 이형춘
    • KSBB Journal
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    • v.15 no.4
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    • pp.388-392
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    • 2000
  • An on-line glucose flow injection analysis system was developed and used for the automatic analysis and addition of glucose in the cultivationof a Saccharomyces cerevisiae in a korean paper digestion wastewater in order to increase the cell concentration. The system was composed of a ceramic sampler a sampling valve an injection valve an immobilized glucose oxidase column a debbble a flow cell with platinum electrodes a potentiostat a computer and interface system and tubing pumps. The glucose concentration of the wastewater medium was mainitained at the low concentration of $176{\pm}31 mg/L$ with the on-line FIA system and by adding glucose and $>(NH_4)_2S0_4$ the cell concentration as total cell count can be increased by 3.1times.

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The Determination of Iodine in Human Milk and Cow Milk by Iodide Specific Ion electrode and Neutron Activation Analysis (요오드 전극을 이용한 방법과 중성자방사화 분석에 의한 모유 및 우유내 요오드 함량 분석 방법 비교)

  • 문수재
    • Journal of Nutrition and Health
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    • v.31 no.2
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    • pp.213-219
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    • 1998
  • This study was conducted to compare and evaluate the iodide specific ion electrode method (ISE) and neutron activation analysis method (NAA) for determining iodine in human milk and cow milk. The neutron irradiation and counting operations were carried out at the TRIGA Mark-III reactor facility of the Korea Atomic Energy Research Institute. The mean concentrations of iodine in human milk samples by the ISE and the NAA were 1450$\mu\textrm{g}$/L and 1350$\mu\textrm{g}$/L, respectively. The levels were not significantly different. In cow milk samples , the mean concentrations of iodine by the ISE and the NAA were 250$\mu\textrm{g}$.L and 200$\mu\textrm{g}$/L, respectively. here, the ISE reading was significantly higher than the NAA. reading. The correlations of the two methods were 0.92(p<0.001) for human milk samples and 0.65 for cow milk samples . The coefficient of variation was 8.3% in the ISE and 4.9% in the NAA. Therefore, the iodide specific ion electrode method is sample and fast method, but probably not in processed milk since free sulfhydryl groups in milk are also detected by the iodide electrode. However, these also indicate that the ISE method may be applicable to human milk and pasteurized milk if the conventional pasteurization time-temperature relationship of standards is not exceeded. On the other hand, the NAA method , which is independent of chemical forms and matrix, can be used for determining iodine in all kinds of milk and foods.

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Characterization of Ag Nanowire Transparent Electrode Fabricated on PVDF Film (PVDF 필름 위에 제작된 고전도도 Ag 나노와이어 투명전극 특성 연구)

  • Ra, Yong-Ho;Park, Hyelim;An, Soyeon;Kim, Jin-Ho;Jeon, Dae-Woo;Kim, SunWoog;Lee, Mijai;Hwang, Jonghee;Lim, Tae Young;Lee, YoungJin
    • Journal of Sensor Science and Technology
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    • v.28 no.6
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    • pp.366-370
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    • 2019
  • In this study, we have successfully fabricated a highly conductive transparent electrode using Ag nanowires, based on piezoelectric polyvinylidene difluoride (PVDF) film, that can be applied as transparent and flexible speakers. The structural morphology of the Ag nanowires was confirmed by a detailed scanning electron microscopy. Ultraviolet-visible spectroscopy demonstrated that the transparent electrode fabricated by the Ag nanowires exhibited a transmittance of above 70%. The transparent electrode also showed very low sheet resistance with high flexibility. We have further developed an anti-oxidation coating layer by using a tetraethyl orthosilicate-poly trimethyloxyphenylsilane (TEOS-PTMS) slurry technique. It was confirmed that the transmittance and sheet resistance of the antioxidant film depends critically on the humidity of the film surface. We believe such Ag nanowire electrodes are a very promising next-generation transparent electrode technology that can be used in future flexible and transparent devices.

A Study on the MIM diode for LCD Device (LCD소자용 MIM 다이오드의 특성연구)

  • 최광남;이명재;곽성관;정관수;김동식
    • Journal of the Korean Vacuum Society
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    • v.12 no.1
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    • pp.40-45
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    • 2003
  • High quality $Ta_2O_5$ thin films have been obtained from the anodization of deposited tantalum (Ta). The as-deposited amorphous films of 750 $\AA$ thickness have excellent electrical properties. These properties include refractive indices 2.1~2.2 dielectric constants ~25, and leakage currents $10^{-8}$ /A$\textrm{cm}^{-2}$ at 1 MV$\textrm{cm}^{-1}$. We fabricated a MIM element with the $Ta_2O_5$ films. They have perfect current-voltage symmetry characteristics. A high performance MIM device was formed by newly developed processes based on our unique anodization and annealing treatment. The effects of various processing conditions (top-electrode metals, annealing conditions) on the MIM device performances will be extensively discussed throughout this work.