• Title/Summary/Keyword: 전극간격

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Fundamental Mechanisms of Platinum Catalyst for Oxygen Reduction Reaction in Fuel Cell: Density Functional Theory Approach (연료전지 산소환원반응 향상 위한 백금 촉매의 구조적 특성: 밀도범함수이론 연구)

  • Kang, Seok Ho;Lee, Chang-Mi;Lim, Dong-Hee
    • Journal of Korean Society of Environmental Engineers
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    • v.38 no.5
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    • pp.242-248
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    • 2016
  • The overall reaction rate of fuel cell is governed by oxygen reduction reaction (ORR) in the cathode due to its slowest reaction compared to the oxidation of hydrogen in the anode. The ORR efficiency can be readily evaluated by examining the adsorption strength of atomic oxygen on the surface of catalysts (i.e., known as a descriptor) and the adsorption energy can be controlled by transforming the surface geometry of catalysts. In the current study, the effect of the surface geometry of catalysts (i.e., strain effect) on the adsorption strength of atomic oxygen on platinum catalysts was analyzed by using density functional theory (DFT). The optimized lattice constant of Pt ($3.977{\AA}$) was increased and decreased by 1% to apply tensile and compressive strain to the Pt surface. Then the oxygen adsorption strengths on the modified Pt surfaces were compared and the electron charge density of the O-adsorbed Pt surfaces was analyzed. As the interatomic distance increased, the oxygen adsorption strength became stronger and the d-band center of the Pt surface atoms was shifted toward the Fermi level, implying that anti-bonding orbitals were shifted to the conduction band from the valence band (i.e., the anti-bonding between O and Pt was less likely formed). Consequently, enhanced ORR efficiency may be expected if the surface Pt-Pt distance can be reduced by approximately 2~4% compared to the pure Pt owing to the moderately controlled oxygen binding strength for improved ORR.

Derivation of Optimum Operating Conditions for Electrical Resistance Heating to Enhance the Flushing Effect of Heavy Oil Contaminated Soil (중질유 오염토양의 세정효과를 증진시키기 위한 전기저항가열의 최적 운전조건 도출)

  • Lee, Hwan;Jung, Jaeyun;Kang, Doore;Lee, Cheolhyo
    • Journal of Environmental Impact Assessment
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    • v.29 no.3
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    • pp.219-229
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    • 2020
  • This study evaluated the applicability of the convergence technology by deriving the optimum conditions about operating factors of electrical resistance heating to enhance the soil flushing effect on soil contaminated with bunker C oil in the coastal landfill area. As a result of the batch scale experiment, the flushing efficiency of the VG-2020 was higherthan that of the Tween-80, and the flushing efficiency increased by about 1.4 times at 60℃ compared to room temperature. As a result of the electrical resistance heating box experiment, soil temperature rose to 100℃ in about 40~80 minutes in soil with water content of 20~40%, and it was found that the heat transfer efficiency is excellent when the pipe-shaped electrode rod with STS 316 material is located in a triangular arrangement in saturated soil. In addition, it was confirmed that the interval between the electrode rods to maintain the soil temperature above 60℃ under the optimum conditions was 1.5 m, and the soil flushing box experiment accompanying electrical resistance heating showed TPH reduction efficiency of about 55% at 5 Pore Volume, and satisfied the Korean standard for the conservation of soil (less than TPH 2,000 mg/kg) at 10 Pore Volume.

ESTIMATING THE VOLUME OF CONSTRUCTION-WASTE LANDFILL USING GEOPHYSICAL TECHNIQUES (물리탐사 기법을 이용한 건축 폐기물 매립지의 규모 파악)

  • Mun,Yun-Seop;Lee,Tae-Jong;Lee,Chae-Yeong;Yun,Jun-Gi
    • Journal of the Korean Geophysical Society
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    • v.6 no.1
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    • pp.13-23
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    • 2003
  • Dipole-dipole resistivity and ground penetrating radar(GPR) surveys were performed on an abandoned landfill site filled with asbestos containing material. The main purpose of the study was to estimate spatial extension and volume of the landfill for evaluting the cost for developing appropriate remedial alternatives. Assuming that the bedrock is within 10 m depth, dipole spacings of 2, 2.5 and 5m were set for six survey lines for resistivity measurements. For More detailed information, GPR suvey using 225 Mhz antenna was carried out for twelve survey lines for the shallower information. DC resistivity structures showed few tens ~ hundreds ohm-m for the landfill or alluvial laver, and 1,000~ 5,000 ohm-m for the bedrock. The depth to bedrock is found out to be approximately 5m. GPR survey results represented very clear reflection and/or diffraction events from the boundaries as well as from the blocky construction wastes. With high-resolution GPR survey, depth of the bedrock was resolved up to 2m, which in turn, could be a good indicator for estimating the volume of the landfill. Those depths of bedrock were confirmed by backhoe excavation data for 13 sites. The total area and volume of the landfill were to be approximately 3,953 .$m^2$ and 4,033 $m^3$, respectively.

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Electric and Electromagnetic Surveys of the Hongseong Fault Zone (홍성 단층대에서의 전기, 전자 탐사 연구)

  • Kwon, Byung-Doo;Lee, Heui-Soon;Park, Gye-Soon;Oh, Seok-Hoon;Lee, Choon-Ki
    • Journal of the Korean earth science society
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    • v.24 no.4
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    • pp.361-368
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    • 2003
  • We have investigated the electric resistivity structure of the fault zone located in the Hongseong area where a big earthquake with M 5.0 occurred in 1978. Usually, Electric and Electromagnetic methods are broadly operated in the field of engineering works since these methods are effective to understand the distribution of geological weak zones - fault or fracture zones. We have conducted the dipole-dipole array resistivity method and MT(magnetotelluric) method and interpreted the resistivity distribution of the fault zone with the aid of various inversion methods. An MT survey was performed at 18 points along a 2.9 km survey line perpendicular to the fault line and a magnetic dipole source was used to enhance the S/N ratio in the high frequency. A Electric dipole-dipole array resistivity survey with the dipole length of 50 meters was carried out perpendicular to the fault. In view of two survey results, the fault marks the boundary between two opposite resistivity structures, especially the low resistivity zone is exhibited deeply through the prospective fault line. The result that the low resistivity zone is located at the center of the fault zone corresponds with the fact that the fault zone of the Hongseong area is active. We expect these results to provide basic information about the physical properties of fault zones in Korea.

Evaluation of the Sterilization Effect of a Plasma Generator with a Flexible Electrode Structure on Staphylococcus aureus and Pseudomonas aeruginosa (황색포도알균과 녹농균에 대한 유연전극 구조를 갖는 플라즈마 발생기의 멸균효과 평가)

  • Park, Chul;Lee, Hyeok Jae
    • Korean Journal of Clinical Laboratory Science
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    • v.52 no.4
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    • pp.372-380
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    • 2020
  • In this study, the sterilization ability of S. aureus and P. aeruginosa was evaluated using a plasma generator with a flexible electrode structure. Both strains were prepared at a concentration of 1.5×106 CFU/mL and inoculated and spread evenly on two medium plates. The medium were kept at a distance of 3 cm and 9 cm from the plasma generator and were plasma discharged from 30 sec to 10 minutes. The growth of colonies on the media, were subsequently compared with the control group. The mean colonies of S. aureus formed at a 3 cm distance were 9.2×102 (log value 2.96) CFU/mL for the 5 min discharge period and 8.0×10 (1.90) CFU/mL for the 10 min discharge period. When the medium was exposed for 5 min and 10 min at a 9 cm distance, the mean colonies of S. aureus formed were 2.16×103 (3.33) and 2.4×102 (2.38) CFU/mL, respectively. The medium containing P. aeruginosa kept at a 3 cm distance and exposed to 3, 5, 10-minute discharge, did not form any colonies. When kept at a 9 cm distance for 3 minutes, 6.0×102 (2.78) CFU/mL mean colonies were formed but no colonies were formed at exposure periods of 5 and 10 minutes. This enhanced sterilization effect was confirmed in experiments of S. aureus and P. aeruginosa using TiO2.

Fabrication of Combined Probes for Interstitial hyperthermia and Brachyradiotherapy (고 선량율 근접 및 온열치료 병용 삽입관의 제작과 특성)

  • Chu, Sung-Sil;Kim, Sung-Kyu
    • Proceedings of the Korean Society of Medical Physics Conference
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    • 2004.11a
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    • pp.85-87
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    • 2004
  • We fabricated flexible thermoradiotherapy probes to alternated combination with Interstitial hyperthermia and Brachyradiotherapy thermoradiotherapy probe was coated by gold plate on polyethylene brachytherapy probe. When Agar phantom was heated 15 minute with 30 W radiofrequency power, temperature increased as 5oC for polyethylene probe and 20oC for gold coated polyethylene probe. We observed that the 1 cm square array would heat a volume with a 1.25 cm radius circular field cross section to therapeutic temperatures (90% relative SAR using Tm) and the 2 cm square array with a 1.75 cm radius rectangular field with central inhomogeneity. With 2 cm long electrode implants, we observed that the 1 cm square array would heat a 3 cm long sagittal section to therapeutic temperature (90% relative SAR using Tm). The histopathological changes associated with RF heating of normal canine brains have been correlated with thermal distributions. RF needle electrode heating was applied for 50 min to generate tissue temperatures of 43${\circ}$C. We obtained a quarter of the heated tissue material immediately after heating and sacrificed at intervals from 7${\sim}$30 days. The acute stage was demonstrated by liquefactive necrosis, pyknosis of neuronal element in the gray matter. Mild gliosis occurring around the necrosis was demonstrated in the last sacrificed (days30)canine brain.

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Sexual Behavior of Male Rats Following Damage to the Mammillary Bodies (유두체가 손상된 흰쥐 수컷의 성 행동)

  • Kim, Jong-Kyu;Kim, Chul
    • The Korean Journal of Physiology
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    • v.6 no.1
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    • pp.33-37
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    • 1972
  • It was thought desirable to elucidate the influence of the mammillary bodies upon sexual behavior. Twenty male rats were used, of which 9 rats had their mammillary bodies damaged electrolytically through implanted electrodes (mammillary body group) and 11 rats received the same surgery short of electrolytic damage to the mammillary bodies (operated control group). Their sexual behavior was observed 3 weeks after surgery. Observation was discontinued when an ejaculation was followed by a successive intromission. 1. Mounting without intromission occurred significantly less often in the mammillary body group than in the operated control group. 2. No significant group difference existed with regard to the occurrence of mounting with intromission. However, the value tended to rise in the mammillary body group compared with the value of the operated control group. 3. Mountings with and without intromission tended to occure more often in the mammillary body group than in the operated control group, but the difference was nonsignificant. 4. The ejaculatory latency (time interval between the first intromission and the first ejaculation) and the postejaculatory interval (time interval between an ejaculatory act and the next intromission) tended to decrease in the mammillary body group compared with the values of the operated control group. However, again the difference did not reach significancy. 5. There existed no significant group differences with regard to the mounting latency (time interval between the first encounter with female and the first mounting with or without intromission), the intromission latency (time interval between the first encounter and the first intromission), and the interintromission period (mean time interval between two successive intromissions). From the above results, it may be inferred that the mammillary bodies tend to exert slight and nonsignificant inhibitory influence upon sexual behavior of male rats. However, further study is indicated before reaching final conclusion.

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Resistivity Survey on Stylobate of Five-story Stone Pagoda in Tamni-ri, Uiseong (의성 탑리리 오층석탑 기단부 전기비저항 탐사)

  • Oh, Hyundok;Kwon, Moonhee
    • Geophysics and Geophysical Exploration
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    • v.23 no.4
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    • pp.253-260
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    • 2020
  • The five-story stone pagoda in Tamni-ri located in Uiseong County in Gyeongsangbuk-do had an unstable upper structure, and the structural deformation of the foundation stone and the stylobate was severe. In order to repair the base of the pagoda, it must be confirmed if there are support stones inside the base. Resistivity survey was performed to study the inner base stone structure during the repair work. The stylobate was exposed soil and broken stones after removing the walls and the cover of the stylobate. Modified pole-dipole array II was used for the resistivity survey, and compared with the typical pole-dipole array method. And in this study, a physical scale-down model experiment was performed to compare and analyze distortions caused by severe topographical undulations such as right-angled lines. The results show that the stylobate of Five-story Stone Pagoda in Tamni-ri Uiseong has base stones inside the reinforced filling soil and are located beneath the pillar of the body and supporting the pagoda.

a study on the elastic wave delay line (탄성파 지정선에 관한 연구)

  • 김종상
    • Journal of the Korean Institute of Telematics and Electronics
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    • v.11 no.6
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    • pp.1-15
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    • 1974
  • In this paper, the SH mode of elastic surface waves which are used for delay lines of elastic surface wave is the cretically analysed. It is shown that the SH mode has very large electromechanical coupling factor and propagates on the surface with very small decaying coefficient into the medium. In the case of P2T-4, the depth cf piezoelectric medium that contains 80% of energy is 190 wavelengths. An elastic surface wave delay line is discussed from the view point of 2-port network. Center frequency is shifted by the ratio of transducer electrode width to gap between transducer ellcerodes when electromechanical coupling factor is large. Tempera _ore coefficients for bulk waves of LiNbO3 and LiTaO3 are also calculated and the minimum temperature coefficient value of delay time is 5.4X 10-6/$^{\circ}C$ ia the case of transverse wave propagating along Z axis on LiTaO3. Experimental data are in good agreement with theoretical values of the temperature coefficients of delay time for elastic surface waves propagating along X axis of 130$^{\circ}$ and 64$^{\circ}$ rotated Y cut planes of the LiNbO3.

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A study of internal reflectance enhancement for crystalline silicon solar cell adopted with Bragg mirror structure using TCAD simulation

  • Jeong, Sujeong;Kim, Soo Min;Lee, Kyung Dong;Kim, Jae eun;Park, Hyomin;Kang, Yoonmook;Lee, Hae-seok;Kim, Donghwan
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.421.2-421.2
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    • 2016
  • 고효율 태양전지에서 후면 반사 방지막은 장파장대(900nm~1200nm) 빛의 내부 반사를 증가시켜 광흡수도를 개선한다. 태양전지 후면에 박형 절연층 구조를 구성함으로써 특정 파장에서 높은 반사도를 얻을 수 있는 Bragg mirror 구조를 이론적으로 계산할 수 있다. Bragg mirror 구조를 이용하여 태양전지의 후면 반사층(Rear reflector layer)을 형성함으로써 태양전지 내부의 광흡수도를 개선할 수 있다. 후면 반사 방지막(Rear anti-reflection coating)으로 사용되는 Al2O3와 SiOxNy 또는 이러한 두 가지 물질의 겹층 구조를 구성하여 장파장대 빛의 반사도 차이에 의한 광흡수도 개선 정도를 광학 시뮬레이션을 통해 계산하였다. 광학 시뮬레이션은 TCAD를 이용하였으며 두 가지 겹층 구조에서 각 반사 방지막의 두께에 따른 단락 전류(Jsc)의 개선 정도, 후면 반사층 두께의 최적화 조건을 계산하였다. 후면 반사방지막을 제외한 기본적인 태양전지 구조는 n-type PERC 구조를 사용하였으며, 후면 반사방지막만의 광학적 특성을 살펴보기 위해 전극은 광학적으로 투명하다고 가정하였다. 반사방지막 두께의 범위는 Al2O3(5-30nm), SiNx(150-300nm), SiOxNy(150-300nm)에서 수행하였으며, 각각 1nm, 2nm 간격으로 진행하였다. Al2O3/SiOxNy 구조에서는 단락 전류가 32.45-32.87mA/cm2 값을 가진다. Al2O3/SiNx 구조에서는 단락 전류가 32.59-32.87mA/cm2 값을 가진다. 결론적으로, 후면 반사방지막의 겹층 구조를 통해 광흡수도를 증가 시킬 수 있으며, TCAD 시뮬레이션을 통하여 입사되는 태양광 스펙트럼에 최적화된 구조를 설계할 수 있다.

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