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Environmental Contamination and Bioavailability Assessment of Heavy Metals in the Vicinity of the Dogok Au-Ag-Cu Mine (도곡(Au-Ag-Cu)광산 주변지역의 중금속 원소들의 환경오염특성 및 생체흡수도 평가)

  • Lee Sung-Eun;Lee Jin-soo;Chon Hyo-Taek
    • Economic and Environmental Geology
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    • v.38 no.2 s.171
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    • pp.135-142
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    • 2005
  • In order to investigate the contamination level and seasonal variation of heavy metals and evaluate the bioavailability of toxic elements, environmental geochemical survey was undertaken at the Dogok Au-Ag-Cu mine area. The main pollution sources in the area were suggested as tailings, mine waste materials and mine water. Elevated levels of $140{\cal}mg/{\cal}kg{\;}As,{\;}107{\cal}mg/{\cal}kg{\;}Cd,{\;} 3017{\cal}mg/{\cal}kg{\;}Cu,{\;}12926{\cal}mg/{\cal}kg{\;}Pb,{\;}9094{\cal}mg/{\cal}kg$ Zn(before rainy season) were found in mine tailings. Concentrations of heavy metals in farmland soils exceeded normal level in nature soil (Bowen, 1979). The highest level of heavy metals was found in water samples near the mine tailing dumps regarded as a main pollution source of toxic elements in the area. These concentrations decreased to downstream due to the effect of dilution. From the results of sequential extraction analyses for tailings and soils, non-residual forms of heavy metals were found, which indicate the contamination to be progressing by continuing weathering and oxidation. Cadmium and Zn would be of the highest mobility in all samples. The bioavailability of Cd, Cu, Zn and As using SBET analysis from paddy soils was $53.3{\%},{\;}46.5{\%},{\;}41.0{\%}$ and $37.0\%$, respectively. The farmland soil sample(S3) showed the highest total concentration and bioavailability of heavy metals.

Geophysical surveys for delineation of leachate flows from AMD and buried rock wastes in Kwangyang abandoned mine (광양 폐광산의 산성광산배수의 유동경로 및 폐광석 탐지를 위한 지구물리탐사)

  • 김지수;한수형;윤왕중;김대화;이경주;최상훈;이평구
    • Economic and Environmental Geology
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    • v.36 no.2
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    • pp.123-131
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    • 2003
  • Geophysical surveys(electrical resistivity, self-potential, seismic refraction, GPR) were conducted to investigate the physical properties of the subsurface, and to delineate the flow channel of leachate from a AMD(acid mine drainage), buried rock wastes and tailings, and drainage pipes at an abandoned mine(Kwangyang mine). Especially in rainy season the sites appear to be abundant in AMD leachate, characterized by electrical conductivities of 0.98-1.10 ms/S. Electrical resistivity sections indicate that the leachate flows running in two directions at southern part rise up through the narrow fracture zones at the central part and contaminates the surrounding soil and stream. Such schematic features at the anomalous zone are well correlated with negative peaks in self-potential data, the limited penetration depth in GPR data and low velocity zone in seismic refraction data. Shallow high-resistivity zone is associated with the buried rock wastes which cause the diffractions in GPR image. In addition, the events at depth of approximately 1-1.25 m in GPR sections must be the metal pipes through which AMD is drained off to the inner bay.

Experiment of Reactive Media Selection for the Permeable Reactive Barrier Treating Groundwater contaminated by Acid Mine Drainage (산성광산배수로 오염된 지하수 정화용 투수성 반응벽체 반응매질 선정 기초실험)

  • Ji Sang Woo;Cheong Young Wook
    • Economic and Environmental Geology
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    • v.38 no.3 s.172
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    • pp.237-245
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    • 2005
  • The batch tests were performed to evaluate the applicability of the permeable reactive barrier (PRB) to in-situ treatment of groundwater with high concentration of heavy metals. The lead\chates used in this study were collected from waste rock dump of the Imgy mine, and have a low pH and high metal concentration. The acidity loading was 65kg as $CaCO_3/day$, metal loading of Fe+Al+Mn was 11.6kg/day. This type of water could be treated with biological-mediated sulfate reduction using the organic carbon mixture as a reactive media. The batch tests were carried out with five mixtures that were composed with different mixing ratios of mushroom compost, pine-tree bark, and limestone cheep. Results indicated that the PRB could reduce the acidity loading $CaCO_3/day$ to 12.3kg and reduce the metal loading to 3.3kg/day. Considering about the low pH and high metal loading, the contaminated water may be ameliorated by passing it through the buffering PRB composed with inorganic carbonate materials and then through the PRB composed with the organic carbon mixture which can induce sulfate reduction.

Emission Characteristics of Carbonyl Compounds Depending on Different Finishing Materials in a Wooden House (목조주택 내 마감자재에 따른 카르보닐화합물의 방산특성)

  • Lee, Hee-Young;Park, Sang-Bum;Kang, Young-Suk;Lee, Sang-Min;Park, Jong-Young
    • Journal of the Korean Wood Science and Technology
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    • v.37 no.1
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    • pp.12-18
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    • 2009
  • This study was attempted to investigate indoor air quality of a wooden house. Emission characteristics of carbonyl compounds from indoors whose interiors were finished using ecofriendly materials were detected. From the results of the examination, the carbonyl compounds mostly consisted of formaldehyde, acetaldehyde, and hexaldehyde. Especially, formaldehyde accounted for the largest portion of the compounds at 25.6~30.5%. All the rooms except for R2-2 contained formaldehyde less than criteria of indoor air quality of newly-constructed houses. In addition, all the rooms except for room R1-3, contained acetaldehyde more than the level of $48{\mu}g/m^3$ recommended by Japan's Ministry of Health, Labour and Welfare. As a results of the different wall covering, the room R1-1 of Hwangto emitted relatively higher levels of carbonyl compounds than the room R2-1 of phytoncide. In addition, the room R2-2 of the bamboo charcoal panels emitted more carbonyl compounds than the room R1-2. The living room R1-3 of Japanese cypress (Cryptomeria Japonica) emitted lower levels of carbonyl compounds than other rooms.

Experiences with Emergency Percutaneous Cardiopulmonary Support in In-hospital Cardiac Arrest or Cardiogenic Shock due to the Ischemic Heart Disease (허혈성 심질환으로 인해 병원 내에서 발생한 심정지 혹은 심정지 혹은 심인성 쇼크에 있어서의 경피적 심폐 보조장치의 치료 경험)

  • Rhee Il;Kwon Sung-Uk;Cho Sung Woo;Gwon Hyeon-Cheol;Lee Young Tak;Park Pyo Won;Park Kay-Hyun;Lee Sang Hoon;Sung Kiick
    • Journal of Chest Surgery
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    • v.39 no.3 s.260
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    • pp.201-207
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    • 2006
  • Background: Percutaneous cardiopulmonary support (PCPS) provides passive support of gas exchange and perfusion, allowing the use of other methods of care for organ recovery, and saves lives of patients with severe cardiopulmonary failure in a wide variety of clinical settings with a minimal risk of bleeding and need for chest re~ exploration. We summarized a single center's experiences with PCPS in patients with cardiogenic shock or cardiac arrest due to the ischemic heart disease. Material and Method: Among the 20 consecutive patients with cardiogenic shock or cardiac arrest from May 1999 to June 2005, Biopump (Medtronic, Inc, Minneapolis, MN) was used in 7 patients and the self-priming, heparin-coated circuit of EBS (Terumo, Japan) was applied to remaining 13 patients. Most of cannulations were performed percutaneously via femoral arteries and veins. The long venous cannulas of DLP (Medtronic inc. Minneapolis, MN) or the RMI (Edwards's lifescience LLC, Irvine, CA) were used with the arterial cannulae from 17 Fr to 21 Fr and the venous cannula from 21 Fr to 28 Fr. Result: The 20 consecutive patients who were severely compromised and received PCPS for the purpose of resuscitation were comprised of 13 cardiac arrests and 7 cardiogenic shocks in which by-pass surgery was performed in 11 patients and 9 ongoing PCls under the cardiopulmonary support. The mean support time on the PCPS was 38$\pm$42 hours. Of the 20 patients implanted with PCPS, 11 patients ($55\%$) have had the PCPS removed successfully; overall, 8 of these patients ($40\%$) were discharged from the hospital in an average surviving time for 27$\pm$17 days after removing the PCPS and survived well with 31$\pm$30 months of follow-up after the procedure. Conclusion: The use of PCPS appears to provide the hemodynamic restoration, allowing the survival of patients in cardiac arrest or cardiogenic shock who would otherwise not survive, and patients receiving PCPS had a relatively long-term survival.

The Study on the Effects of Hospice Care on the Pain Management of the Terminal Cancer Patients (호스피스간호가 말기암환자의 통증에 미치는 효과에 관한 연구)

  • Yoon, Mae-Ok
    • Journal of Hospice and Palliative Care
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    • v.6 no.1
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    • pp.34-44
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    • 2003
  • Purpose : The purpose of this study was to elucidate the effects of hospice care on pain management of the terminal cancer patients. Method : The subjects of the study were 37 terminal cancer patients hospitalized in the general hospital in JeonJu with the hospice care nit. The data were collected using the questionaire with interviews from July to Nov. in 2000. The severity and interference of pain were examined with the self reported survey based on the Korean version of Brief Pain Inventory (BPI-K). The data were analyzed with the mean, SDs, paired t-test. The hospice care to provide for three weeks. Results : 1) The mean scores of the worst pain for the last 24-hours measured with the pain severity of BPI-K were pre-intervention (6.35) and post (4.76). The pain interference of BPI-K in pre-intervention was enjoy (8.22), work (7.46), walk (7.08) and activity (7.08), while post was of enjoy (6.62), work (6.43), walk (6.11) and activity (5.78), respectively. 2) In pain severity, significant difference was found between the pre-intervention and post in all of followings. - worst pain for last 24 hours (t=4.085, P=.000) - least pain for last 24 hours (t=4.020, P=.000) - average pain for last 24 hours (t=4.254, P=.000) - pain right now (t=4.017, P=.000) 3) In pain interference, significant difference was found between the pre- intervention and the post in all of followings. - activity (t=3.137, P=.003) - mood (t=6.713, P=.000) - walk (t=2.027, P=.050) - work (t=2.132, P=.040) - relate (t=4.143, P=.000) - sleep (t=4.071, P=.000) - enjoy (t=3.881, P=.000) Conclusion : The terminal cancer patients who were offered hospice care had significantly lower hospice care pain and pain interference than those without hospice care. According to these results, hospice care can be regarded as an effective modality in relief of pain in the terminal ill-patients.

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Characterization of Particulates Containing Naturally Occurring Radioactive Materials in Phosphate Processing Facility (인광석 취급 산업체에서 발생하는 천연방사성물질 함유 입자의 특성 평가)

  • Lim, HaYan;Choi, Won Chul;Kim, Kwang Pyo
    • Journal of Radiation Protection and Research
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    • v.39 no.1
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    • pp.7-13
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    • 2014
  • Phosphate rock, phosphogypsum, and products in phosphate processing facility contain naturally occurring radioactive materials (NORM). Therefore, they may give rise to enhanced radiation dose to workers due to inhalation of airborne particulates. Internal dose due to particle inhalation varies depending on particle properties. The objective of the present study was to characterize particle properties at the largest phosphate processing facility in Korea. A cascade impactor was employed to sample airborne particulates at various processing areas in the plant. The collected samples were used for characterization of particle size distribution, particle concentration in the air, and shape analysis. Aerodynamic diameters of airborne particulates ranged 0.03-100 ${\mu}m$ with the highest concentration at the particle size range of 4.7-5.8 ${\mu}m$ (geometric mean = 5.22 ${\mu}m$) or 5.8-9.0 ${\mu}m$ (geometric mean = 7.22 ${\mu}m$). Particle concentrations in the air varied widely by sampling area up to more than two orders of magnitude. The large variation resulted from the variability of mechanical operations and building ventilations. The airborne particulates appeared as spheroids or rough spherical fragments across all sampling areas and sampled size intervals. Average mass densities of phosphate rocks, phosphogypsums, and fertilizers were 3.1-3.4, 2.1-2.6, and 1.7 $gcm^{-3}$, respectively. Radioactivity concentration of uranium series in phosphate rocks varied with country of origin, ranging 94-866 $Bqkg^{-1}$. Among the uranium series, uranium was mostly concentrated on products, including phosphoric acid or fertilizers whereas radium was concentrated on byproducts or phosphogypsum. No significant radioactivity of $^{226}Ra$ and $^{228}Ra$ were found in fertilizer. However, $^{40}K$ concentration in fertilizer was up to 5,000 Bq $g^{-1}$. The database established in this study can be used for the accurate risk assessment of workers due to inhalation of airborne particles containing NORM. In addition, the findings can be used as a basic data for development of safety standard and guide and for practical radiation safety management at the facility.

Vertical Distribution of the Heavy Metal in Paddy Soils of Below Part at Guundong Mine in Milyang, Korea (구운동 폐광산 하류 논토양의 토심별 중금속함량)

  • Yun, Eul-Soo;Park, Sung-Hak;Ko, Jee-Yeon;Jung, Ki-Yeol;Park, Ki-Do;Hwang, Jae-Bok;Park, Chang-Yeong
    • Korean Journal of Soil Science and Fertilizer
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    • v.43 no.5
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    • pp.590-595
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    • 2010
  • This study was conducted to investigate form of pollution brought by residual of mine tailing in agricultural land, and get basic information need for environment restoration. Guundong mine was completely restored region by implementation the soil pollution prevention plan. The districts is soils in Guundong mine vicinity the Mahul-ri, Muan-myeon, Miryang city, Gyeongsangnam-do. The nature of soil studied is the Shinra series andesite and mineral deposits which contain brimstone and heavy metals such as gold, silver, copper, lead, and zinc. The residual mine tailing and around agricultural land of heavy metals analyzed with 0.1N HCI solubility. The chemical properties of surface soil in upper part around mining area were pH 4.3-4.4, organic matter 19-21 g $kg^{-1}$, available $P_2O_5$ 85 mg $kg^{-1}$, exchangeable Ca 0.21-0.25 $cmol_c\;kg^{-1}$, exchangeable Mg 0.04 $cmol_c\;kg^{-1}$. The pH, exchangeable Ca, and Mg were increased with soil depth. The contents of 0.1N HCl extractable Cu, Cd, Pb, Cr, and Ni in soil (siteI) which influenced by outflow water from mine tailing were 97, 0.6, 197, 0.28 및 0.12 mg $kg^{-1}$, respectively. The vertical distribution of heavy metals in soil varied considerably among the metals kind. In case of siteI, The content of Cu, Pb, and Cr in soil was highest at surface soil. However, the content of Cd, Zn, Ni, and Mn was high at middle part of soil profile.