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Biodegradation of 4-t-Octylphenol by Basidioradulum molare and Schizopora paradoxa and Estrogenecity Reduction of its Metabolites (옥틸페놀(4-t-Octylphenol)의 Basidioradulum molare와 Schizopora paradoxa에 의한 분해 및 에스트로겐성 저감효과)

  • Lee, Soo-Min;Ku, Bon-Wook;Lee, Jae-Won;Choi, Don-Ha;Jeung, Eui-Bae;Choi, In-Gyu
    • Journal of the Korean Wood Science and Technology
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    • v.32 no.4
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    • pp.27-35
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    • 2004
  • Recalcitrant 4-t-Octylphenol used as a surfactant was subjected to the biodegradation with wood rot fungi, Basidioradulum molare and Schizopora paradoxa. Two fungi were grown in the culture medium containing various concentrations of 4-t-Octylphenol in order to investigate their resistance against 4-t-octylphenol Schizopora paradoxa was reached to the full growth within 14 incubation days in the concentration of more than 200 ppm of 4-t-Octylphenol, while Basidioradulum molare showed the inhibitory mycelium growth as the concentration was increased Schizopora paradoxa and Basidioradulum molare biodegraded 95% and 36% of initial concentration of 4-t-Octylphenol at first incubation day, respectively. However, the biodegradation capability reached to more than 95% after 3 incubation days. During the biodegradation of 4-t-Octylphenol, the activity of manganese dependent peroxidase was induced by the addition of 4-t-Octylphenol in the culture medium of Schizopora paradoxa, but that of laccase was maximal before the addition. The reduction of estrogenecity was assayed by MCF-7 cell proliferation test and measurement of pS2 mRNA expression. The level of pS2 mRNA was decreased down to the level of baseline at first incubation day. Also, estrogenecity of 4-t-Ocrylphenol completely disappeared after treatment with supernatant by Schizopora paradoxa and Basidioradulum molare from first incubation day of culture down to the levels of vehicle.

Carrageenan-Based Liquid Bioadhesives for Paper and Their Physical Properties (카라기난 기반 액상형 바이오 종이 접착제의 제조 및 물성에 관한 연구)

  • Oh, Seung-Jun;Han, Won-Sik;Wi, Koang-Chul
    • Journal of Conservation Science
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    • v.36 no.6
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    • pp.541-548
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    • 2020
  • There is a growing demand for natural materials to replace adhesives based on volatile organic compounds (VOCs). However, the exclusion of VOCs from the manufacturing process leads to difficulties in manufacturing, and reduction in productivity and preservability. In this paper, we report the manufacture of natural bioadhesives using the carrageenan component of seaweed. λ-carrageenan, isolated from the extracted total carrageenan, was used to prepare a highly stable adhesive for paper. The resulting composition was 52.0 ± 1.0% λ-carrageenan, 30.5 ± 0.5% Polyvinylpyrrolidone, 1.0 ± 0.05% ethylhexylglycerin, 1.5 ± 0.05% glycerin, 13.5 ± 0.5% dextrine, and 0.6 ± 0.05% food-grade antifoam emulsion. The viscosity was found to be 1.13 ± 0.07 × 105 cP (25℃), UV degradation occurred at pH6.22, drying rate was 15min, △b* was -10.79, and △E* ab was 8.18. The bioadhesive showed an excellent adhesion strength of 44.63 kgf/cm2. Thus this adhesive showed excellent fungal resistance and good adhesive persistence, without the presence of total volatile organic compounds (TVOC), formaldehyde (HCHO), and heavy metals.

Experimental Study on the Shearing and Crushing Characteristics of Subaqueous Gravels in Gravel Bed River (수중 자갈의 전단 및 파쇄 특성에 관한 실험적 연구)

  • Kim, So-Ra;Jeong, Sueng-Won;Lee, Gwang-Soo;Yoo, Dong-Geun
    • Journal of the Korean earth science society
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    • v.42 no.2
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    • pp.164-174
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    • 2021
  • The study examines the shearing and crushing characteristics of land-derived subaqueous granular materials in a gravel-bed river. A series of large-sized ring shear tests were performed to examine the effect of shear time and shear velocity on the shear stress characteristics of aquarium gravels with a 6-mm mean grain size. Three different shear velocities (i.e., 0.01, 0.1, and 1 mm/sec) were applied to measure the shear stress under the drained (long-term shearing) and undrained (short-term shearing) conditions. Different initial shear velocities, i.e., 0.01→0.1→1 mm/sec and 0.1→0.01→1 mm/sec, were considered in this study. The test results show that the grain crushing effect is significant regardless of drainage conditions. The shear stress of coarse-grained materials is influenced by initial shear velocities, regardless of the drainage conditions. In particular, particle breakage increases as grain size increases. The shearing time and initial shear velocity are the primary influencing factors determining the shear stress of gravels. The granular materials may be broken easily into particles through frictional resistance, such as abrasion, interlocking and fracture due to the particle-particle interaction, resulting in the high mobility of granular materials in a subaqueous environment.

Compressional and Shear Wave Properties of Cement Grout Including Carbon Fiber (탄소섬유를 포함한 시멘트 그라우트의 압축파 및 전단파 특성)

  • Choi, Hyojun;Cho, Wanjei;Yune, Chanyoung
    • Journal of the Korean GEO-environmental Society
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    • v.22 no.12
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    • pp.15-24
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    • 2021
  • In Korea, which is mostly mountainous, the proportion of tunnel and underground space development are increasing. Although the ground is reinforced by applying the ground improvement method during underground space development, accidents still occur frequently in Korea. In the grouting method, a representative ground reinforcement method, the effect was judged by comparing the total amount of injection material with the amount of injection material used during the actual grouting construction. However, it is difficult to determine whether the ground reinforcement is properly performed during construction or within the target ground. In order to solve this problem, it is necessary to study a new method for quality control during or after construction by measuring electrical resistivity after performing grouting by mixing carbon fiber, which is a conductive material, and microcement, which is a grout material. In this study, as a basic study, a cement specimen mix ed with 0%, 3%, 5%, 7% of carbon fiber was prepared to evaluate the performance of the grout material mixed with carbon fiber, which is a conductive material. The prepared specimens were wet curing for 3 days, 7 days, and 28 days under 99% humidity, and then compression wave velocity and shear wave velocity were measured. As a result of the compression wave velocity and shear wave velocity measurement, it showed a tendency to increase with the increase in the compounding ratio of carbon fibers and the number of days of age, and it was confirmed that the elastic modulus and shear modulus, which are the stiffness of the material, also increased.

Characteristics of the Lateral Resistance of Pile according to the Lateral Loading Rate in Dense Sand (조밀한 모래지반에서 수평재하속도에 따른 말뚝의 수평저항 특성)

  • Gichun Kang;Hyejeong Park;Seong-kyu Yun;Jiseong Kim
    • Journal of the Korean Geosynthetics Society
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    • v.22 no.3
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    • pp.97-103
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    • 2023
  • Recently, research on the lateral resistance of pile foundations has been actively conducted. In experimental studies on the lateral resistance of pile foundations, displacement control or load control methods are used. However, in the case of the displacement control method, the lateral resistance of the pile varies depending on the rate of the load applied to the pile. Therefore, this study seeks to determine the change in lateral resistance of pile foundations according to lateral loading rate through model experiments. The experimental results showed that the lateral resistance of the pile tended to decrease as the lateral loading rate applied to the pile head increased. In order to confirm this, a model experiment of the side change of the ground and pile according to the loading rate was additionally conducted. Through inverse analysis, the change in the depth of the rotation point according to the lateral loading rate was identified. Through the change in the lateral resistance of the pile foundation and the depth of the rotating point according to the lateral loading rate, it was proposed to test the loading rate within 1.5 mm/min during the lateral loading test of the pile.

Geotechnical Engineering Characteristics of Ulleung Basin Sediment, East Sea (동해, 울릉 분지 심해토의 지반공학특성)

  • Lee, Chang-Ho;Yun, Tae-Sup;J.C., Santamarina;Bahk, Jang-Jun;Lee, Jong-Sub
    • Journal of the Korean Geotechnical Society
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    • v.25 no.6
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    • pp.17-29
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    • 2009
  • There has been an increase in the investigation of deep sea sediments with a consequent increase in the amount of energy required to undertake these investigations. The geotechnical characteristics of Ulleung Basin sediment are explored by using depressurized specimens following methane production tests carried out on pressured core samples obtained at 2,100 m water depth and 110 m below sea floor. Geotechnical index tests, X-ray diffraction, and scanning electron microscope are conducted to identify the geotechnical index parameters, clay mineralogy, chemical composition, and microstructure of the sediments. Compressibility, and elastic and electromagnetic wave parameters are investigated for two samples by using a multi sensing instrumented oedometer cell. The strength chatracteristics are obtained by the direct shear tests. The dominant clay minerals are mostly kaolinite, illite, chlorite, and calcite. The SEM shows a well-developed flocculated structure of the microfossil. Void ratio, electrical resistivity, real permittivity, conductivity, and shear wave velocity show bi-linear behavior with the effective vertical stress: as the vertical effective stress increases. The friction angle obtained by the direct shear test is about $21^{\circ}$, which is similar to the value observed in the Ulleung Basin sediments. This study shows that the understanding of the behavior acting on the diatomaceous marine sediment is important because it often maintains the useful energy resources such as gas hydrate and so will be the new engineering field in the next generation.

Evaluation of Steel Tube Connection in Precast Concrete Double Wall System (프리캐스트 콘크리트 더블월 시스템의 각형 강관 연결부 성능평가 )

  • Yujae Seo;Hyunjin Ju
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.27 no.2
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    • pp.25-32
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    • 2023
  • In this study, a double wall system is introduced, which was invented to simplify the complicated manufacturing process of the existing precast concrete (PC) double wall systems and to remove defects such as laitance that may occur during the production of concrete panels. An experimental study was conducted to investigate the tensile resisting capacity of the steel tube which is embedded in the precast concrete panel to keep the spacing between PC panels and to prevent damage of the PC panels during transportation and casting concrete onsite. The experiment was planned to determine the detail of effective steel tube connection considering the steel plate treatment method according to the formation of the opening, the presence of embedded concrete, and the reinforcement welding for additional dowel action as key variables. As a result, the ultimate tensile strength increased by 20-30% compared to the control specimen (ST) except for the steel tube specimen (ST_CP) which has steel plates bent inward at the end part of the steel tube. Since the specimen (ST_CON) filled with concrete inside the control specimen has no additional process and cost for the steel tube connections compared to the control specimen during the production of the developed double wall system, it is determined to be the appropriate detail of steel tube connection.

Development and Applicability Evaluation of High Performance Poly-urea for RC Construction Reinforcement (RC 구조물 보강을 위한 고성능 폴리우레아의 개발 및 적용성 평가)

  • Kim, Sung Bae;Kim, Jang-Ho Jay;Choi, Hong-Shick;Heo, Gweon
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.30 no.2A
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    • pp.169-176
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    • 2010
  • Generally, poly-urea is widely used as waterproof coating material due to its superior adhesiveness, elongation capacity, and permeability resistance. In addition, it can be quickly and easily applied on structure surfaces using spray application. Since it hardens in about 30 seconds after application, its construction efficiency is very high and its usage as a special functional material is also excellent. However, currently, poly-urea is mostly used as waterproof coating material and the researches on its usage as a retrofitting material is lacking at best. Therefore, basic studies on the use of poly-urea as a general structural retrofitting material are needed urgently. The objective of this study is to develop most optimum poly-urea composition for structure retrofitting purpose. Moreover, the structural strengthening capacity of the developed poly-urea is evaluated through flexural capacity experiments on RC beams and RC slabs. From the results of the flexural test of poly-urea strengthened RC beam and slab specimens, the poly-urea and concrete specimen showed monolithic behavior where ductility and ultimate strength of the poly-urea strengthened specimen showed slight increase. However, the doubly reinforced specimens with FRP sheet and poly-urea showed lower capacity than that of the specimen reinforced only with FRP sheet.

Corrosion Behavior and Ultrasonic Velocity in RC Beams with Various Cover Depth (다양한 피복두께를 가진 RC 보의 부식 거동 및 초음파 속도)

  • Jin-Won Nam;Hyun-Min Yang;Seung-Jun Kwon
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.11 no.3
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    • pp.184-191
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    • 2023
  • With increasing corrosion in RC (Reinforced Concrete) structures, cracks occurred due to corrosion products and bearing load resistance decreased. In this study, corrosion was induced through an accelerated corrosion test (ICM: Impressed Current Method) with 140 hours of duration, and changes in USV (Ultra-Sonic Velocity), flexural failure load, and corrosion weight were evaluated before and after corrosion test. Three levels of cover depth (20 mm, 30 mm, and 40 mm) were considered, and the initial cracking period increased and the rust around steel decreased with increasing cover depth. In addition, the USV linearly decreased with decreasing cover depth and increasing amount of corrosion. In the flexural loading test, the bending capacity decreased by more than 10% due to corrosion, but a clear correlation could not be obtained since the corrosion ratio was small, so that the effect of slip was greater than that of reduced cross-sectional area of steel due to corrosion. As cover depth increased, the produced corrosion amount and USV changed with a clear linear relationship, and the cracking period due to corrosion could be estimated by the gradient of the measured corrosion current.

Field Application of Waterworks Automatic Meter Reading and Analysis of Household Water Use (상수도 원격검침시스템의 현장 적용성 평가 및 가정용수 사용량 분석)

  • Joo, Jin Chul;Ahn, Hosang;Ahn, Chang Hyuck;Ko, Kyung-Rok;Oh, Hyun Je
    • Journal of Korean Society of Environmental Engineers
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    • v.34 no.10
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    • pp.656-663
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    • 2012
  • After the construction of waterworks automatic meter reading with 15 mm diameter digital water mater with magnetoresistance sensor developed in this study at 96 households of apartment complexes located in Incheon-City B-Gu S-Dong, the feasibility of field application of waterworks automatic meter reading was evaluated. The field application of waterworks automatic meter reading was performed from July to December in 2011, and average reception rate was as low as 84.6% due to the instable wibro networks, the existence of communication blackout and temporary malfunction of router. After the extraction of 10 households with one to five residents out of 96 households by using stratified random sampling method and analysis of domestic water use, it was found that domestic water use was significant at August and showed a decreasing trend at September, followed by increase in domestic water use at November and decrease in domestic water use at December. This phenomenon should be attributed to weather factors (temperature, humidity, etc.), which significantly affected domestic water use. Similar trend in domestic water use in terms of weather factors was obtained in case of Liter per capita day of water use after the extraction of 30 households out of 96 households by using stratified random sampling method. After analysis of Liter per capita day for 96 households, single residents increases resulted in reduction of domestic water usage by about 14% of Liter per capita day. These results might be due to the fact that domestic water usage such as laundry, beverages, catering, cleaning, etc. should be required for even the household with one resident, whereas domestic water usage for those common utilization can be significantly saved for the household with more than one resident.