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절연성 고분자 poly(methyl methacrylate) 박막 층 안에 분산된 $SnO_2$ 나노입자를 사용한 유기 쌍안정성 소자의 안전성

  • Park, Hun-Min;Yu, Chan-Ho;Kim, Tae-Hwan
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.02a
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    • pp.378-378
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    • 2012
  • 나노복합체를 이용하여 제작한 유기 쌍안정성 형태의 비휘발성 메모리 소자는 간단한 공정과 플렉서블 기기에 응용 가능성 때문에 많은 연구가 진행되고 있다. 나노복합체를 사용하여 제작한 비휘발성 메모리 소자의 전기적 성질에 대한 연구는 많이 진행되었으나, poly (methyl methacrylate) (PMMA) 고분자 박막 내부에 분산된 $SnO_2$ 나노입자를 이용하여 제작한 유기 쌍안정성 소자에서 기억 특성의 안정성에 대한 연구는 상대적으로 미흡하다. 본 연구에서는 PMMA 박막층 내부에 분산된 $SnO_2$ 나노입자를 사용한 메모리 소자를 제작하여 전기적 특성 및 안정성에 대하여 관찰하였다. $SnO_2$ 나노입자를 PMMA와 용매인 클로로벤젠에 용해한 후에 초음파 교반기를 사용하여 두 물질을 고르게 섞었다. 전극이 되는 indium-tin-oxide 가 성장된 유리 기판 위에 $SnO_2$ 나노입자와 PMMA가 섞인 용액을 스핀 코팅한 후, 열을 가해 용매를 제거하여 SnO2 나노입자가 PMMA에 분산되어 있는 유기 쌍안정성 형태의 나노복합체 박막을 형성하였다. 형성된 나노복합체 박막 위에 상부 전극으로 Al을 열증착하여 비휘발성 메모리 소자를 제작하였다. 제작된 소자의 전류-전압 측정 결과는 메모리 특성을 나타내는 ON과 OFF의 두 가지 상태가 존재하고 ON/OFF 전류 비율은 20이었다. $SnO_2$ 나노입자를 포함하지 않은 소자와 비교를 통해 $SnO_2$ 나노입자가 비휘발성 메모리 소자에서의 전하 저장 영역으로 하는 역할을 확인하였다. 전류-시간 측정 결과 소자의 ON/OFF 전류 비율이 시간에 따라 큰 변화 없이 1,000회 이상 지속적으로 유지함을 관찰함으로써 소자의 안정성을 확인하였다.

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[6,6]- phenyl-C85 Butyric Acid Methyl Ester 나노입자를 포함한 나노복합체를 사용하여 제작한 비휘발성 메모리의 전기적 성질과 안정성

  • Park, Hun-Min;Lee, Min-Ho;Yun, Dong-Yeol;Kim, Tae-Hwan
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.08a
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    • pp.274-274
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    • 2011
  • 유기물/무기물 나노복합체를 이용하여 제작한 비휘발성 메모리 소자는 저전력 구동과 간단한 공정과 같은 장점 때문에 많은 연구가 진행되고 있다. 무기물 나노 입자를 포함한 고분자 박막을 사용한 비휘발성 메모리 소자에 대한 연구는 많이 진행되었으나, [6,6]- phenyl-C85 butyric acid methyl ester (PCBM) 나노 입자가 고분자 박막에 분산되어 있는 나노복합체를 사용하여 제작한 메모리 소자의 전기적 특성과 안정성에 대한 연구는 미흡하다. 본 연구에서는 PCBM 나노 입자가 poly (methylmethacrylate) (PMMA) 박막 안에 분산되어 있는 나노복합체를 사용한 메모리 소자를 제작하여 전기적 특성 및 안정성에 대하여 관찰하였다. PCBM 나노 입자를 PMMA와 함께 용매인 클로로벤젠에 용해한 후에 초음파 교반기를 사용하여 두 물질을 고르게 섞었다. 전극이 되는 indium-tin-oxide 가 성장된 유리 기판 위에 PCBM과 PMMA가 섞인 용액을 스핀 코팅한 후, 열을 가해 용매를 제거하여 PCBM입자가 PMMA에 분산되어 있는 나노복합체 박막을 형성하였다. 형성된 나노복합체 박막 위에 상부 전극으로 Al을 열증착하여 비휘발성 메모리 소자를 완성하였다. 제작된 소자의 전류-전압 측정 결과는 큰 ON/OFF 전류비율을 보여주었다. PCBM 나노입자를 포함하지 않은 소자에서는 메모리 특성이 나타나지 않았기 때문에 PCBM 나노 입자가 비휘발성 메모리 소자의 기억 특성을 나타내는 저장매체가 됨을 알 수 있었다. 전류-시간 측정 결과는 소자의 ON/OFF 전류 비율이 시간이 지남에 따라 큰 감쇠 현상 없이 104 sec 까지 지속적으로 유지됨을 알 수 있었다. 제작된 각각의 메모리 소자의 ON/OFF 전류 비율 결과는 103 이상의 일정한 값이 측정되어 제작된 소자의 안정성을 보여주었다.

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A Study on Synthetic Method and Material Analysis of Calcium Ammine Chloride as Ammonia Transport Materials for Solid SCR (Solid SCR용 암모니아 저장물질인 Calcium Ammine Chloride의 합성방법 및 물질분석 연구)

  • Shin, Jong Kook;Yoon, Cheon Seog;Kim, Hongsuk
    • Transactions of the Korean Society of Automotive Engineers
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    • v.23 no.2
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    • pp.199-207
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    • 2015
  • Solid materials of ammonia sources with SCR have been considered for the application of lean NOx reduction in automobile industry, to overcome complex problems of liquid urea based SCR. These solid materials produce ammonia gas directly with proper heating and can be packaged by compact size, because of high volumetric ammonia density. Among ammonium salts and metal ammine chlorides, calcium ammine chloride was focused on this paper due to low decomposition temperature. In order to make calcium ammine chloride in lab-scale, simple reactor and glove box was designed and built with ammonium gas tank, regulator, and sensors. Basic test conditions of charging ammonia gas to anhydrous calcium chloride are chosen from equilibrium vapor pressure by Van't Hoff plot based on thermodynamic properties of materials. Synthetic method of calcium ammine chloride were studied for different durations, temperatures, and pressures with proper ammonia gas charged, as a respect of ammonia gas adsorption rate(%) from simple weight calculations which were confirmed by IC. Also, lab-made calcium ammine chloride were analyzed by TGA and DSC to clarify decomposition step in the equations of chemical reaction. To understand material characteristics for lab-made calcium ammine chloride, DA, XRD and FT-IR analysis were performed with published data of literature. From analytical results, water content in lab-made calcium ammine chloride can be discovered and new test procedures of water removal were proposed.

Characteristic of Hydrogen Generation from Solid-State NaBH4 and Fuel Cell Operation for Fuel Cell Aircraft (연료전지 항공기를 위한 고체상태 NaBH4의 수소발생 및 연료전지 구동 특성)

  • Lee, Chung-Jun;Kim, Tae-Gyu
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.39 no.9
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    • pp.858-865
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    • 2011
  • This paper describes the characteristics of hydrogen generation from solid-state $NaBH_4$ and fuel cell operation for fuel cell aircraft. The solid-state $NaBH_4$ was used for a high hydrogen storage density, and was reacted with hydrochloric acid to generate hydrogen. The hydrogen generation rate for the solid-state $NaBH_4$ reaction was measured at various conditions. As a result, the hydrogen generation rate was increased with the feed rate and concentration of hydrochloric acid, while not be affected by the reaction temperature. A fuel cell was connected with the solid-state $NaBH_4$ hydrogen generator. The stable power output was obtained at the gradual and sudden increases of electric loads.

Design and Implementation of Trajectory Riving Tree for Combined Queries in Moving Object Databases (이동체 데이타베이스에서 복합 질의를 위한 궤적 분할 트리의 설계 및 구현)

  • 임덕성;전봉기;홍봉희;조대수
    • Journal of KIISE:Databases
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    • v.31 no.2
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    • pp.150-162
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    • 2004
  • Moving objects have characteristics that they change continuously their positions over time. The movement of moving objects should be stored on trajectories for processing past queries. Moving objects databases need to provide spatio-temporal index for handling moving objects queries like combined queries. Combined queries consist of a range query selecting trajectories within a specific range and a trajectory query extracting to parts of the whole trajectory. Access methods showing good performance in range queries have a shortcoming that the cost of processing trajectory Queries is high. On the other hand, trajectory-based index schemes like the TB-tree are not suitable for range queries because of high overlaps between index nodes. This paper proposes new TR(Trajectory Riving)-tree which is revised for efficiently processing the combined queries. This index scheme has several features like the trajectory preservation, the increase of the capacity of leaf nodes, and the logical trajectory riving in order to reduce dead space and high overlap between bounding boxes of nodes. In our Performance study, the number of node access for combined queries in TR-tree is about 25% less than the STR-tree and the TB-tree.

Study of Characterization for Lean NOx Trap Catalysts Utilizing a Bench-Flow Reactor System (Bench-Flow Reactor System을 이용한 Lean NOx Trap 촉매의 특성 연구)

  • Yoon, Cheon-Seog;Kim, Hak-Yong;Nguyen, Ke
    • Transactions of the Korean Society of Automotive Engineers
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    • v.16 no.5
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    • pp.179-189
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    • 2008
  • The performance of Lean NOx Trap (LNT) based on the catalysts of Pt/K/Ba/$\gamma-Al_2O_3$ with proprietary washcoat formulation is studied using a bench flow reactor system. To investigate the effect of temperature and gas hourly space velocity (GHSV) on the nitrogen oxides (NOx) trapping capacity as well as NOx breakthrough time and final ratio of $NO_2$ to NO of LNT, series of adsorption isotherms are carried out with simulated exhaust gases of the lean burn engines. Since typical operation of LNT requires periodic regeneration with a short rich excursion, where the stored or trapped NOx is released and subsequently reduced to $N_2$, the effect of the duration of lean and rich phase and type of reductants on the NOx conversion is investigated. NOx storage capacity and breakthrough time obtained from adsorption isotherms shows a volcano-type dependence on the temperature with a maximum NOx storage capacity occurring $350^{\circ}C$ and with a maximum breakthrough time occurring $400^{\circ}C$ at all GHSVs investigated in this study. Also, maximum ratio of $NO_2$ to NO is obtained at $400^{\circ}C$ with a GHSV of $75,000\;hr^{-1}$ Lean/rich cycle of 100 s lean and 5 s rich used with a concentration of 1.33% of $H_2$ and 4% of CO in the rich phase is found to be optimum at operating temperature of $350^{\circ}C$ and a GHSV of $50,000\;hr^{-1}$.

Development of Digital Telesounder (디지털 원격 어군탐지기의 개발에 관한 연구)

  • Sin, Hyeon-Ok;Hwang, Seung-Uk
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.34 no.2
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    • pp.135-138
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    • 1998
  • This paper describes the construction and experimetal results of prototype digital telesounder developed to monitor remotely the fish school entered in setnet. The telesounder consists of the sea station and land station. The former consists of an ultrasonic transceiving part of 50 KHz, a hand made 16 bits single board computer (SBC), and a RF MODEM of 9600 bps for data link. The SBC controls the trigger signal to transmit the ultrasonic pulse, maximum detection range, sampling rate in analog to digital converter and data link. The sampling rate of echo data was 80 ${\mu}$s. The later consists of a RF MODEM same as the former one and 486 notebook computer which displays the echogram and saves its raw data. The authors carried out some experiments to confirm the practical use of the telesounder. At results the echogram obtained on the land station is sufficiently good and clear to monitor the behavior of fish school in setnet.

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Realization of 3D Virtual Face Using two Sheets of 2D photographs (두 장의 2D 사진을 이용한 3D 가상 얼굴의 구현)

  • 임낙현;서경호;김태효
    • Journal of the Institute of Convergence Signal Processing
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    • v.2 no.4
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    • pp.16-21
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    • 2001
  • In this paper a virtual form of 3 dimensional face is synthesized from the two sheets of 2 dimensional photographs In this case two sheets of 2D face photographs, the front and the side photographs are used First of all a standard model for a general face is created and from this model the feature points which represents a construction of face are densely defined on part of ears. eyes, a nose and a lip but the other parts. for example, forehead, chin and hair are roughly determined because of flat region or the less individual points. Thereafter the side photograph is connected symmetrically on the left and right sides of the front image and it is gradually synthesized by use of affine transformation method. In order to remove the difference of color and brightness from the junction part, a linear interpolation method is used. As a result it is confirmed that the proposed model which general model of a face can be obtain the 3D virtual image of the individual face.

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Adsorption Characteristics and Moisture Content Prediction Model of Coffee with Water Activity and Temperature (수분활성과 온도변화에 따른 커피의 흡착특성 및 흡착량 예측모델)

  • Youn, Kwang-Seop;Choi, Yong-Hee
    • Korean Journal of Food Science and Technology
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    • v.22 no.6
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    • pp.690-695
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    • 1990
  • The adsorption characteristics of coffee were mvestigated at $5, 15, 25, and 35^{\circ}C$ under various water activities such as 11, 32, 57, 75 and 90% and prediction models were developed by optimization program. The moisture adsorption isotherm curves were similar to the typical sigmoid type. The values of equilibrium moisture content and the monolayer moisture content were highest in the Freeze Dried, which was due to porous structure by the drying method. In the result of adjusting the isotherm models in this paper, Halsey model generally gave the best fit for isotherms of coffee. Prediction model for equilibrium moisture content was established with water activity and temperature. Adsorption prediction models were also developed with water activity, with water activity and time, and with water activity, time and temperature, respectively.

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Real-time 3D Converting System using Stereoscopic Video (스테레오 비디오를 이용한 실시간 3차원 입체 변환 시스템)

  • Seo, Young-Ho;Choi, Hyun-Jun;Kim, Dong-Wook
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.33 no.10C
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    • pp.813-819
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    • 2008
  • In this paper, we implemented a real-time system which displays 3-dimensional (3D) stereoscopic image with stereo camera. The system consists of a set of stereo camera, FPGA board, and 3D stereoscopic LCD. Two CMOS image sensor were used for the stereo camera. FPGA which processes video data was designed with Verilog-HDL, and it can accommodate various resolutional videos. The stereoscopic image is configured by two methods which are side-by-side and up-down image configuration. After the left and right images are converted to the type for the stereoscopic display, they are stored into SDRAM. When the next frame is inputted into FPGA from two CMOS image sensors, the previous video data is output to the DA converter for displaying it. From this pipeline operation, the real-time operation is possible. After the proposed system was implemented into hardware, we verified that it operated exactly.