• Journal of Conservation Science
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• v.38 no.3
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• pp.217-233
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• 2022

The remains found in Geumcheok-ri, Gyeongju are located in close proximity to the Ancient Tombs in Geumcheok-ri, Gyeongju (Historic Site) which were built between the late 5th and early 6th centuries, and these tombs are known to belong to the powerful rulers of that area. Using metallurgical techniques, this study was conducted on the iron objects obtained from the excavated remains in Geumcheok-ri, Gyeongju which are presumed to have a close relation to the nearby ruins that played an important role in the growth of Silla. To identify differences in manufacturing techniques based on the purpose of the iron objects, eight objects were selected after classifying them by use and the microstructure and non-metallic inclusions were investigated. The analyses results confirmed that the manufacturing process involved forging iron with a high or low carbon content to produce a particular shape, and that the carburization process was applied to iron post forging a shape to increase its strength when necessary. The mechanical properties were improved by selectively applying the steelmaking method and the heat treatment technique considering the functions of the parts, and the low temperature reduction was applied to the smelting process. Furthermore, in comparison with the iron objects excavated from the remains located in the center of Gyeongju and its outskirts, it is confirmed that there is similarity in the smelting and manufacturing techniques between these objects.

• Korean Chemical Engineering Research
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• v.45 no.6
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• pp.677-679
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• 2007

Nearly monodisperse spherical silica particles, 200~300 nm in diameter, were produced via a dry route for the first time through a two-stage hydrolysis of $SiCl_4$ vapor. In the first stage, the $SiCl_4$ was partially hydrolyzed in a batch reactor at $150^{\circ}C$ to form nearly monodisperse silicon oxychloride particles. In the second stage, the oxychlorides were hydrolyzed further in a tubular reactor to have produced silica with the morphology and size nearly conserved.

• KOREAN JOURNAL OF CROP SCIENCE
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• v.30 no.2
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• pp.201-206
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• 1985

This experiment was carried out to get the basic information about long term storage (Temp.: -10${\pm}$1$^{\circ}C$ and -l${\pm}$1$^{\circ}C$, RH; 30${\pm}$6) of rice germplasm by using three Japonica and one Indica x Japonica cultivars based on the storage periods (96, 86, 58 and 20 months). The germination ability, based on the storing periods, was tested under the conditions of 30-32$^{\circ}C$ and 15-17$^{\circ}C$ air temperature. The results obtained are summarized as follows: 1. There were no significant differences between the short and long term storage conditions in the percentage of germination, average germination period, germination coefficient of the four varieties tested under both 15-17$^{\circ}C$ of low and 30-32$^{\circ}C$ of optimum temperature conditions. 2. Eventhough there were no significant differences in germination depending on the storage periods under optimum temperature condition (30-32$^{\circ}C$). Longer storage duration resulted in lower germination percentage, longer average germination period and lower germination coefficient under low temperature condition (15-17$^{\circ}C$). Comparing the varieties, the germination percentage of a Indica/Japonica cultivar "Tongil" was lower than that of Japonica cultivars under the low temperature condition (15-17$^{\circ}C$). 3. The longer period of storage, the more abnormal plants had appeared. 4. The germination ability was lost earlier under the condition of high moisture content in the seed and non-ventilation container.

• Journal of the Korea institute for structural maintenance and inspection
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• v.21 no.4
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• pp.132-139
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• 2017

In this study, in order to prevent the frost damage of the concrete, the characteristics of the form using heating sheet utilizing the chemical reaction of quicklime and the insulation were evaluated through experiments at low temperature. In the case of form at $-10^{\circ}C$, the form with attached heating sheet showed a temperature history of more than $10^{\circ}C$ higher than that of wood form at the early of concreting due to heat of the quicklime in the heating sheet. In the case of the insulated form, the concrete was kept at a high temperature by preserving the hydration heat. When the heating sheet and the isopink(extruded polystyrene) were attached together on the form, the effect was the same as that of the vacuum insulation. The compressive strength of the form with vacuum insulation and form with isopink, heating sheet as measured about 5 MPa at age 3. The experimental in Mongolia, as with the pervious results, the form with the heating sheet and the insulation showed the highest temperature history over $25^{\circ}C$ for 48 hours. Therefore, it was confirmed that the heating sheet and insulation are attached to the form, which helps the concrete strength development at low temperature by heat generation and the insulation effect.

• Korean Journal of Food Science and Technology
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• v.16 no.1
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• pp.66-70
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• 1984

An attempt was made on the development of a commercial scale storage method of garlic by irradiation. Irradiated garlics with 50, 100 and 150 Gy were stored at natural low temperature storage room $(12{\pm}6^{\circ}C,{\;}75-85%{\;}RH)$ and the physicochemical properties during the 10 months storage were investigated. The unirradiated garlic was mostly sprouted after 8 months storage, whereas the sprouting of all irradiated groups was completely inhibited until 10 months storage, The rotting rate and weigh loss of garlic after 10 months storage were reduced by 25 to 54% at 100 Gy irradiation compared with those of an unirradiated group. The moisture content remained relatively constant during the whole storage period. The total sugar content was increased with storage period. Ascorbic acid content was also decreased until 8 months storage but its content was rapidly increased along with sprouting. Garlic was marketable after 10 months storage by 100 Gy irradiation combined with natural low temperature.

• The Journal of the Petrological Society of Korea
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• v.23 no.3
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• pp.239-247
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• 2014

The (U-Th)/He dating utilizes the production of alpha particles ($^4He$ atoms) during natural radioactive decays of $^{238}U$, $^{235}U$ and $^{232}Th$. (U-Th)/He age can be determined from the abundances of the parent nuclides $^{238}U$, $^{235}U$ and $^{232}Th$ and the radiogenic $^4He$. Because helium is one of the noble gases (non-reactive) with a relatively small radius, it diffuses rapidly in many geological materials, even at low temperatures. Therefore, ingrowth of $^4He$ during radioactive decay competes with diffusive loss at elevated temperatures during the geologic time scale, determining the amount of $^4He$ existing today in natural samples. For example, He diffusion in apatite is known to be very rapid compared to that in most other minerals, causing a significant diffusive loss at ${\sim}80^{\circ}C$ or higher. At ${\sim}40^{\circ}C$, He diffusion in apatite becomes slow enough to preserve most $^4He$ in the sample. Thus, an apatite's (U-Th)/He age represents the timing when the sample passed through the temperature range of $80-40^{\circ}C$. The crustal depth corresponding to this temperature range is called a "partial retention zone." Normal closure temperatures for a typical grain size and cooling rate are ${\sim}60-70^{\circ}C$ for apatite and ${\sim}200^{\circ}C$ for zircon and titanite. Because the apatite He closure temperature is lower than that of most other thermochronometers, it can provide critical constraints on relatively recent or shallow-crustal exhumation histories.

• Proceedings of the Korean Vacuum Society Conference
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• 2013.02a
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• pp.258-258
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• 2013

최근 건조 제품의 양질화, 고급화 및 편의화가 요구되어 이를 충족시키기 위한 새로운 건조방법이 계속 개발 되어 왔다. 이러한 방법들 중에서 저온과 진공하에서 건조가 이루어지는 진공 동결 건조는 가장 완벽한 건조 방법으로 최근 실용화 되고 있다. 진공동결건조란 건조의 한 종류로 수분을 함유한 시료를 동결시킨 후 진공펌프를 이용하여 수증기압을 3중점 이하로 낮추어 얼음을 직접 증기로 만드는 승화의 원리에 의해서 얻어진다. 분무진공동결건조의 특징은 (1) 물리적구조의 보존성, (2) 화학적인 안정성, (3) 생물학적인 활동의 보존성, (4) 제품의 높은 복원성 및 재생성이다. 따라서 분무진공동결건조 기술은 크게 진공, 분무, 동결, 건조, 멸균 등과 같은 요소기술의 복합기술이라 할 수 있다. 분말을 제조하기 위해서 진공동결건조 후 분쇄하는 방법을 사용하나 본 방법에서는 정밀화학품 제조를 위해서 분무진공동결건조 방식을 사용한다. 이를 통하여 적당한 크기인 5~10 um의 입경 제조가 가능하고, 공기동력학적인 입경이 기존 방식에 비해 작아서 허파까지의 운반효율이 1.5~2배 우수하다. 화학, 의학 분야에서의 분무동결 건조는 주로 민감한 제품, 즉 생물학적 고유성의 손상 없이 물을 제거하는데 사용되어 영구적으로 저장 가능한 상태로 보관할 수 있으며 물의 첨가로 원상태로 복구할 수 있어서 매우 각광을 받고 있다. 의약용 냉동건조 제품은 항생물질, 박테리아, 혈청, 백신, 검사 약물, 단백질을 포함하는 생물공학 제품들, 세포, 섬유, 화학제품 등이 있으며 주로 vial 또는 ampule 상태로 건조가 이루어진다.본 연구에서는 원료를 $-194^{\circ}C$의 액체질소에 분무시켜 동결된 미립자를 형성한 후 진공 및 저온상태에서얼음의 승화(sublimation)에 기반한 1차 건조와 수증기 탈착(desorption)에 기초한 2차 건조 과정으로 구성된 분무진공동결건조기를 개발하였다. 분무동결 과정의 해석을 통해 2유체식 노즐을 통해 분무된 미세 입경의 액적이 액체 질소 표면까지 도달하는 회수률, 분무 노즐의 위치, 운전 조건 및 용기의 설계의 최적화를 수행하였다. 초기 액적속도, 분무노즐의 높이, 흡입구 추가에 따른 액적 유동 및 회수의 특성을 제시하였으며 이를 통한 분사시스템 고도화 가능성을 제시하였다. 구형의 미세 입자가 적층된 제품의 동결건조 공정의 해석은 흡착승화 모델(sorption sublimation model)을 기반으로 다음과 같은 열전달, 물질전달, 상변화 모델을 고려하여 유도되었다. 분무노즐 및 냉동/진공 배기계 시작품을 개발하여, 표면의 고다공도를 갖춘 입경 3~20 m 정도의 시료를 얻을 수 있으며, 동역학적 입경 5 m 충족함을 확인하였다.

• Journal of Conservation Science
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• v.27 no.4
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• pp.441-450
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• 2011

This study investigated potential damages and conservation methods for the ceramics (without glaze) by examination of physical and chemical effects from the burial environments. For this study, pottery samples excavated from Daejeon Hakha, Asan Eumbong, Hwasung Sogeunsan and Kongju Haengbokdosi were examined with released ions and extraction through desalination. The result showed that the ion inflow into the ceramics was dependent upon the porosity and the absorption of ceramics. The high temperature fired ceramics (over $1,000^{\circ}C$) have low porosity and absorption, therefore almost no salt infiltration during the burial period. However, low temperature fired ceramics (under $800^{\circ}C$) have high porosity and absorption, and most of salts were removed during the desalination. The 40 to 60% of salts were removed in two days and 60 to 80% of slats were released in a week. Furthermore, fertilizer residues such as $K_2SO_4$, in soils were detected in the ceramcis. Also the characteristics of buried soil affected ion infiltration into ceramics. Ceramics buried in sandy soil had relatively less ion contents from buried environments than those in clayey soil. Therefore, low temperature fired ceramics could do not only cleaning but also desalination if it is necessary, and the period could be decided to the condition of ceramics.

• Journal of Embryo Transfer
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• v.16 no.1
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• pp.35-40
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• 2001

Artificial insemination (AI) with frozen or cooled semen is widely used in commercial fields of cattle and pig. Little is known about characteristics of canine sperm after freezing or cooling. For both practical and commercial goal, the canine semen treated with cooling and freezing should be carried out to exam the fundamentals, including sperm motility, survivability and fertilizing capacity. The aim of this study, thus, was to identify the effects of extended exposure to 4$0^{\circ}C$ on canine semen by motility, survivability, acrosomal changes following different duration. Fifteen ejaculates collected by digital manipulation twice per week from 3 dogs (Shih-Tzu) were divided to 16 aliquots after adding Tris-egg yolk (TE) buffer formulated by our laboratory, and cooled from 37 to 4$^{\circ}C$, by ramp rate of 0.6$^{\circ}C$/min. Each sample was evaluated by their motility, survivability and the acrosomal status at 0h (control), 2h, 12h and 1 d~10 d, respectively. The motility of spermatozoa was graded to 6 levels using the modified method of Seager. The survivability of sperm was assessed using an epifluorescence microscope after Fert/Light (Mole-cular Probes Inc.) staining. To estimate the proportion of the spermatozoa of intact acrosome, 200 spermatozoa were assessed in randomly selected fields, using epifluorescence microscope after FITC/PSA (Sigma) staining. At 2 h after cooling, the motility of most spermatozoa were assessed to be grade 0 and 1. At 12 h, high number of sperm were in grade 0 to 1, however, it was significantly (P<0.05) lower than that of 2 h. From 1 d to 4 d, ~50% of sperm was assessed to grade 0 to 1. On day 7, a little sperm were in grade 0 to 1. No sperm showed motility on day 10. Sperm motility was rapidly reduced by the percent of 10% of grade 0 to 1. From 2 h to 6 h, the number of live sperm was 90% and the sperm chilled for 10 days lived>50%. Acrosomal intact of spermatozoa exposed to 4$^{\circ}C$ for 2 h was 51%, supposed the sperm of control was 100%. Our results suggest that 1) this is easy to transfer and preservation for short periods 2) AI can be used by semen chilled for 6-Day.

• Korean Journal of Food Science and Technology
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• v.17 no.6
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• pp.474-481
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• 1985

Radurization effects on fried fish meat paste with Co-60 gamma irradiation at 0-5 kGy and physicochemical aspects of the stored samples at low ($3{\pm}1^{\circ}C$, LT) and room ($10-20^{\circ}C$, RT) temperatures were investigated. The initial microbial loads of the samples were $2.2{\times}10^3/g$ in total bacterial count, $2.8{\times}10^2/g$ in yeasts & molds, and $1.0{\times}10^2/g$ in coliform group, respectively. An irradiation dose of more than 3 kGy was shown to be effective for the radurization of stored samples and there is no apparent difference between air and vacuum packaging groups. The chemical components related to the quality underwent similar changes in the nonirradiated and irradiated groups; however, as the storage time was prolonged the quality of nonirradiated samples rapidly deteriorated. Textural parameters of the samples were little affected by the applied doses, and sensory evaluations showed that 3 kGy irradiation was the optimum dose level to extend the shelf-life of fried fish meat paste up to 2 times at RT and 3 to 4 times at LT, respectively compared with the nonirradiated control.