• Resources Recycling
• /
• v.9 no.1
• /
• pp.63-69
• /
• 2000

Ferromanganese dust is an oxide substance of Mn. If imprities are removed and oxidation degree is controlled, the dust can be recycled for soft ferrite materials. The ferromanganese dust contained about 7 kinds of impurities, expecially about 9000 ppm of $SiO_2$ contents of the ferromanganese dust from 9000 ppm to under 500 ppm by fritting method. The $SiO_2$ in ferromanganese dust can be converted into water soluble compounds by alkali fritting and removed by water leaching. KOH and NaOH were used. The most effective conditions to get rid of $SiO_2$ from the dust are that the weight ratio of alkali to ferromanganese dust is 1.75 and fritting is run at $550^{\circ}C$ for 1 hour.

• Journal of Navigation and Port Research
• /
• v.28 no.6
• /
• pp.503-507
• /
• 2004

We prepared EM wave absorbers by using recycled Sr ferrite for GHz frequency, and investigated the effects of carbon additions and preparation temperatures on their EM wave absorption properties. A Sr ferrite EM wave absorber with the ratio of Sr ferrite: silicon rubber: carbon = 80 : 13.6: 6.4 wt% prepared at 7$0^{\circ}C$ showed -24 dB at 9.4 GHz and -23 dB at 5.5 GHz for 2 mm and 3 mm thickness, respectively.

• Proceedings of the Korean Institute of Navigation and Port Research Conference
• /
• 2004.04a
• /
• pp.17-22
• /
• 2004

We prepared EM wave absorbers by using recycled Ba and Sr ferrites for GHz frequency, and investigated the effects of carbon additions, thickness and preparation temperatures on their EM wave absorption properties. We clarified that it is very important to consider carbon amounts in Ba and Sr ferrites and preparation temperature for Ba and Sr ferrite EM wave absorbers with high quality. In this study, the developed a EM Wave absorber satisfying over 20 dB.

• Resources Recycling
• /
• v.12 no.4
• /
• pp.20-29
• /
• 2003

In order to efficiently recycle the waste solution resulting from shadow mask processing, nano-sized Ni-ferrite powder was fab-ricated through spray pyrolysis process. The average particle size of the powder was below 100nm. In this study, the effects of the reaction temperature. the concentration of raw material solution and the injection speed of solution on the properties of powder were respectively investigated. As the reaction temperature increased from $800^{\circ}C$ to $1100^{\circ}C$, average particle size of the powder significantly Increased and power structure became more solid, whereat its specific surface area was greatly reduced. Formation rate and crystallization of($NiFe_2$$O_4$) phale increased along with the temperature rise. As the concentrations of iron and nickel components in wastere solution increased, particle size of the powder became larger, particle size distribution became more irregular, and specific surface area was reduced. Formation rate and crystallization of $NiFe_2$$O_4$ phase increased significantly along with the increase of the concentration of solution. As the inlet speed of solution increased, particle size of the powder became larger, particle size distribution became wider, specific surface area was reduced and powder structure became less solid. As the inlet speed of solution decreased, formation rate and crystallization of $NiFe_2$$O_4$ phase significantly increased.

• Resources Recycling
• /
• v.17 no.1
• /
• pp.66-72
• /
• 2008

Fundamental studies for the synthesis of Mn-Zn ferrite powder were investigated using a series of leaching and coprecipitation processes from spent alkaline manganese batteries. Zinc and Manganese dissolution rates obtained at the reaction conditions of 100g/L pulp density, 3.0M $H_2SO_4$, $60^{\circ}C$ and 200 rpm with 30 ml $H_2O_2$ as a reducing agent were more than 97.9% and 93.9% and coprecipitation of Mn-Zn ferrite powder was performed according to various reaction conditions such as temperature, time and amount of $O_2$ gas injection using the leaching solution. As a result of coprecipitation, Mn-Zn ferrite could be synthesized directly at low temperature in the reaction condition pH 12, $80^{\circ}C$, $O_2$ 1.3 L/min. and 400 rpm. The synthesized Mn-Zn ferrite powder was spherical powder of $0.143{\mu}m$ particle size and had a saturation magnetization about 80 emu/g.