• Clean Technology
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• v.23 no.2
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• pp.163-171
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• 2017

Currently, researches on recycling and reuse of waste energetic materials have recently gained a great attention from advanced countries due to ever tightening environmental regulations. In this study, as a part of a recycling technology, the experiments and dynamic simulation of simulated moving bed (SMB) process were performed to efficiently separate TNT and RDX from their mixture, which are main components of ammunition. In order to determine the operation zone of SMB process, the retention times of TNT and RDX were measured using HPLC at different flow rates and the adsorption equilibrium of each component was obtained by using a moment method. According to the adsorption equilibrium and the triangle theory of SMB process, four operation points were determined and separation experiments were carried out by the SMB process using the solvent consisting of acetonitrile and water. Two different mixing ratios (6:4 and 1:1) of acetonitrile and water were chosen for the experiment due to the great impact of mixing ratio of the solvent on separation. The performance of SMB process was evaluated by purity, recovery, productivity and solvent consumption. Pure TNT and RDX were successfully obtained from the SMB process and the dynamic simulation for the SMB process agreed well with the experimental results. Therefore, the dynamic model could be applied for predicting the dynamic behavior of the SMB process and designing a large scale SMB process.

• Proceedings of the Korea Water Resources Association Conference
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• 2019.05a
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• pp.197-197
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• 2019

총인처리시설에서는 응집제를 주입하여 인이나 오염물질을 침전시켜 처리하고 있으며 PAC(poly aluminum chloride)나 $FeCl_3$, $Al_2(SO_4)_3$, 등 다양한 종류의 응집제가 사용되어지고 있다. 하지만 기존에 사용되어 지고 있는 알루미늄계열의 응집제는 처리수에 잔류이온이 존재하게 되어 인체에 축적돼 알츠하이머 병 등 신체질환을 유발할 수 있는 단점이 있다. 따라서 이러한 단점을 사전에 예방하기 위해 $TiCl_4$와 같은 티타늄계열 응집제에 대한 연구가 진행되고 있다. $TiCl_4$ 응집제는 인 제거에 효과적으로 적용할 수 있으며 수중에 잔류이온을 유발하지 않으며 Ti이온은 치과임플란트나 의료장비로 사용될 만큼 인체에 무해하다고 알려져 있다. 응집제 사용에 따라 생성된 응집슬러지의 처리방안에 있어서 기존 응집제의 경우 생성된 슬러지의 대부분은 하수슬러지 위탁처리업체를 통해 소각 및 매립, 재활용 되고 있으나, $TiCl_4$를 응집제로 사용할 경우 생성된 슬러지를 인발하여 건조 및 소성을 통해 이산화티타늄으로 재활용할 수 있어 슬러지를 친환경적으로 처리가 가능해 기존 슬러지 처리방안의 경제적, 환경적 부담을 줄일 수 있는 장점이 있다. 따라서 본 연구에서는 $TiCl_4$를 하수처리장 방류수에 주입하여 수중의 총인(T-P)을 처리한 후 생성된 슬러지를 인발하여 건조와 소성과정을 거쳐 이산화티타늄을 제조하였다. 방류수를 취수해 2.5mg/L의 초기 총인 농도를 가진 원수를 제조하였으며 제조된 원수에 $TiCl_4$를 0.6mL 주입하였을 때 99.93%의 총인제거효율을 얻을 수 있었다. 응집 실험 후 생성된 슬러지를 인발하여 건조 후 $300{\sim}1000^{\circ}C$의 각각 다른 온도조건에서 소성하여 이산화티타늄을 제조하였으며, SEM과 XRD를 통해 제조된 이산화티타늄의 표면특성과 결정성 분석을 실시하였다. 제조된 이산화티타늄은 $500{\sim}800^{\circ}C$에서는 아나타제, $900{\sim}1000^{\circ}C$에서는 루타일 결정구조가 나타났다. 또한, $TiCl_4$ 주입량에 따른 이산화티타늄의 최종 생산량과 제조 시 사용되는 건조로 및 소성로의 경제적 비용 등을 고려하여 이산화티타늄 1Ton을 제조하기 위해 필요한 단가를 산출하였다. 본 연구에서 제조된 이산화티타늄 1kg의 생산단가는 약 5,400원으로 나타났으며, 가장 많이 사용되는 P-25 광촉매 보다 저렴한 가격으로 제조 및 판매를 기대할 수 있다. 따라서 하수처리장에 적용 시 기존 응집제 보다 비싼 $TiCl_4$ 비용을 보완하고 친환경적인 슬러지 처리로 제조된 이산화티타늄의 유통 및 현장적용을 통해 경제적, 환경적으로 우수하다고 판단된다.

• Membrane Journal
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• v.31 no.3
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• pp.228-240
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• 2021

The organic solvent robust polybenzimidazole (PBI) membranes were prepared as organic solvent nanofiltration (OSN) membrane for the recycling of alcoholic solvents using non-solvent induced phase separation with different dope solution concentration and coagulant composition of water/ethanol mixtures to control the membrane morphology and permeation performance. Investigation on crosslinking of polybenzimidazole indicated that the membrane crosslinked with dibromoxylene (DBX) had enough mechanical strength and solvent resistance to be applied as a OSN membranes. The crosslinked PBI membrane prepared by more than 20wt% dope concentration coagulated in water showed a rejection of > 90% to Congo Red (MW of 696.66 g/mol) while pure ethanol permeances was more than 22.5 LMH/bar at 5 bar. Investigation on coagulant composition indicated that ethanol permeance through crosslinked PBI OSN membrane increased with increasing of ethanol concentration in water/ethanol mixture coagulants.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.14 no.4
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• pp.343-356
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• 2016

The Korea Radioactive Waste Agency (KORAD) has developed a dual-purpose metal cask for the dry storage of spent nuclear fuel that has been generated by domestic light-water reactors. The metal cask was designed in compliance with international and domestic technology standards, and safety was the most important consideration in developing the design. It was designed to maintain its integrity for 50 years in terms of major safety factors. The metal cask ensures the minimization of waste generated by maintenance activities during the storage period as well as the safe management of the waste. An activation evaluation of the main body, which includes internal and external components of metal casks whose design lifetime has expired, provides quantitative data on their radioactive inventory. The radioactive inventory of the main body and the components of the metal cask were calculated by applying the MCNP5 ORIGEN-2 evaluation system and by considering each component's chemical composition, neutron flux distribution, and reaction rate, as well as the duration of neutron irradiation during the storage period. The evaluation results revealed that 10 years after the end of the cask's design life, $^{60}Co$ had greater radioactivity than other nuclides among the metal materials. In the case of the neutron shield, nuclides that emit high-energy gamma rays such as $^{28}Al$ and $^{24}Na$ had greater radioactivity immediately after the design lifetime. However, their radioactivity level became negligible after six months due to their short half-life. The surface exposure dose rates of the canister and the main body of the metal cask from which the spent nuclear fuel had been removed with expiration of the design lifetime were determined to be at very low levels, and the radiation exposure doses to which radiation workers were subjected during the decommissioning process appeared to be at insignificant levels. The evaluations of this study strongly suggest that the nuclide inventory of a spent nuclear fuel metal cask can be utilized as basic data when decommissioning of a metal cask is planned, for example, for the development of a decommissioning plan, the determination of a decommissioning method, the estimation of radiation exposure to workers engaged in decommissioning operations, the management/reuse of radioactive wastes, etc.

• Korean journal of food and cookery science
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• v.20 no.6 s.84
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• pp.607-613
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• 2004

The purpose of this study was to investigate the quality characteristics of functional cookies made with potato peels (cortex layer) containing high amounts of glycoalkaloid. Cookies were processed by mixing ratios of 10, 15 and $20\%$ potato peel relatively to flour. The spread ratio of the cookies was increased with increasing potato peel addition. Texture measurement for the cookies on substituting $10\%$ of flour for potato peel showed a decreased hardness, but the cohesiveness and springiness were increased compared to the control and other ratios. The glycoalkaloid contents of the cookies on substituting 10, 15 and $20\%$ of the flour forpotato peel were 6.27, 9.40 and 12.54mg, respectively, which according to the USAD guidelines are safe amounts for the human body, and also enough for making functional cookies. In the sensory evaluations, the cookies with $10\%$ of the flour substituted for potato peel had the highest scores in flavor, taste, appearance and texture.

• Journal of Radiation Protection and Research
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• v.38 no.4
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• pp.228-233
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• 2013

It has been continuously generated the requirement for the replacement of the main components such as a steam generator due to the deterioration of the nuclear power plant all around the world. Also, a large amount of radioactive metal was generated during the decommissioning in a short period. It is required to make an accurate measurement of the residual radioactivity for recycling the metal waste for releasing from regulatory control. In planning the measurement procedures, the influence of geometry, self-absorption, density and other relevant factors on the representativeness of the measurements should be considered for the decommissioning metal waste. In this study, the method for measurement procedures, the source term evaluation, the ways to secure representative samples, the measurement device for wide area and the self-absorption correction factors for different density were evaluated. The metal samples for measurement were prepared for securing the simple geometry and representative by melting process. The developed correction method for measuring the radioactivity a variety density of metal waste could improve the reliability of the evaluation results for clearance.

• Journal of the Korean BIBLIA Society for library and Information Science
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• v.25 no.4
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• pp.79-108
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• 2014

The purpose of this study was to research instances of green library construction and recognition in order to increase awareness of green libraries. To this end, we investigated the green library's outline and green building, evaluated cases of G-SEED certified libraries, and surveyed the employees at the 16 different G-SEED certified libraries. Results showed that the employees' knowledge of green libraries and the green certification system was low, whereas their interest and needs regarding the green library concept were very high. Second, the respondents were able to recognize as a whole the factors of green library construction based on the evaluation items for G-SEED and place particular emphasis on 'recyclable resources & recycling bins.' However, only a few recognized 'water reclamation/reuse system establishment' as a green library factor. Third, the respondents largely agreed upon an evaluation of items on the suitability of G-SEED, and their ranked reasons for build a green library were preventing environmental pollution, energy-saving, environment, ecology, and indoor environmental factors. Fourth, a lack of 'awareness about the concept of the green library' was thought to most affect the awareness of difficulties in green library construction, and the respondents agreed with the need for 'library image enhancement' to better manage expectations of the green library.

• International Journal of Highway Engineering
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• v.6 no.4 s.22
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• pp.1-12
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• 2004

This study evaluated the asphalt binder characteristics for the hot-recycled asphalt mixture in which RAP was added in ambient temperature for surface course as well as for base course. RAPs were collected from four sources and their physical properties were evaluated. Mix designs were performed using 10 and 20% RAP contents for surface courses and 10, 20 and 30% for base courses. A virgin asphalt with the penetration grade of 60-80 was used for mixing recycled mixtures. Physical properties of recycled binders, including penetration, absolute viscosity, GPC, BBR and penetration after TFO were measured. From the results, regression analysis of absolute viscosity versus LMS in GPC showed $R^2$ being over 0.95, showing that GPC results estimate the absolute viscosity with relative accuracy. In BBR test, the resistance of recycled mixtures at low service temperature was inferior to the control, because the low temperature PG of recycled binder was one grade higher than that of the control binder.

• Journal of Digital Contents Society
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• v.10 no.4
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• pp.659-667
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• 2009

ADL SCORM(Sharable Content Object Reference Model) has been widely accepted as a global reference model for standardizing e-learning technology, and SCORM 2004 4th Edition, a stable version of SCORM, gives content developers the efficient way to build interoperable and reusable e-learning contents. Recently, a number of research efforts have been taken to build on-line SCORM contents based on some traditional training or learning styles. However, they have lacked for supporting more sophisticated learning style such as game based learning, and especially they do not consider employing the specific components of SCORM model for developing game based learning contents in practice. In this work, we elicit some SCORM data elements that is useful for representing game run-time data, and apply those elements to SCORM sequencing of game based learning SCOs(Sharable Content Objects). We thus present the whole procedure of developing SCORM game based learning contents with a sample contents.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2017.05a
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• pp.136-136
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• 2017

화학제염 기술은 산화제, 환원제, 금속이온, 무기산등이 혼합되어 있는 화학용액을 사용하여 원전기기 계통 내부에 생성된 고방사능 준위의 산화막과 오염물질을 제거하는 기술이다. 원전의 해체 및 유지보수에 있어 방사능 피복저감을 위한 필수적인 기술이다. 현재 원전 해체 산업은 잠재성이 높은 고부가가치 창출 산업으로 주목을 받고 있다. 원전 보유국의 경우, 기존 상용 제염기술과는 차별성 있는 제염기술을 확보하고자 노력하고 있다. 기존의 공정과 비교하여 공정비용 및 시간을 감소시킬 수 있어야 할 뿐만 아니라, 화학용액에 의한 원전 계통 금속 부품의 부식 및 손상을 최소화해야 한다. 금속 부품이 화학약품에 의한 부식손상을 받는다면 금속 부품의 수명 및 재활용 가치가 감소하기 때문에, 화학제염 기술 적용에 있어 용액에 대한 재료의 건전성 평가가 사전에 필히 이루어져야 한다. 본 연구에서는 원전 냉각재 펌프용 재료로 주로 사용되는 Stainless 304강을 시험편으로 선정하여, 화학제염 시험공정 3가지에 대한 부식손상 특성을 규명하였다. 산화공정은 과망간산($HMnO_4$) 용액을 공통으로 사용하였으며, 산화공정 종료 후 환원공정은 각 시험공정에 따라 시험공정 1은 옥살산($H_2C_2O_4$) 2000ppm, 시험공정 2는 옥살산($H_2C_2O_4$)1500ppm + 시트르산($H_8C_6O_7$)500ppm, 그리고 시험공정 3은 옥살산($H_2C_2O_4$) 3000ppm 용액을 각각 투입하여 수행하였다. 산화, 환원공정을 1Cycle로 하여, 각 시험공정 별로 총 5Cycle을 실시하였다. 각 시험공정 Cycle종료 후 시험편을 취외하여 무게감량측정, SEM(Scanning electron microscope) 분석, 3D현미경분석 그리고 타펠분극 실험을 실시하였다. 각 분석결과를 토대로 하여, Stainless 304강에 대한 화학제염 시 모델별 시험공정에 따른 부식특성을 규명하였다.