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Formulation and Application of UV-Cured Anti-cigar burning Coating Compounds for PVC Tile (PVC 바닥상재용 광경화형 내열 코팅액의 제조 및 응용에 관한 연구)

  • Park, Bo-Ram;Ha, Jin-Wook
    • Proceedings of the KAIS Fall Conference
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    • 2009.12a
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    • pp.84-87
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    • 2009
  • 본 연구는 건축용 바닥재로 널리 이용되는 PVC 상재의 표면을 열에 의한 손상으로부터 보호하기 위하여 기존에 사용하는 광경화형 우레탄-아크릴 수지에 내열성(anti-cigar burning)을 향상시킨 광경화형 수성도료 개발에 관한 것이다. PVC 바닥상재용으로 사용되는 내열기능성이 없는 우레탄-아크릴 수지에 인계화합물을 주원료로 합성한 내열재, 구아니딘을 주원료로 합성한 내열재, 일시적 방염제로 사용되는 제 2인산암모늄을 수지의 양 대비 함량(wt%)을 10, 20, 30%로 변화하여 첨가한 후 배합하여 수지의 내열성을 향상시킨 코팅액을 제조하였다. 제조한 코팅액은 코팅층의 두께조절이 가능한 Bar-coating을 사용하여 PVC 바닥상재에 코팅한 후, 내열성, 부착력, 내화학성, 코팅두께 등의 코팅층 표면물성을 평가하였다. 연구결과, 수지에 인계화합물을 주원료로 합성한 내열재 30%를 혼합하여 제조한 코팅액을 Bar-coater No.12로 코팅한 코팅표면이 열에 의한 손상이 가장 적고, 부착력 100%, 내화학성 양호로 가장 좋은 물성을 보였다. 전반적으로 내열재 함량이 높고 코팅 두께가 두꺼울수록 내열성이 우수한 것으로 나타났다.

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Synthesis of Water Soluble Anti-Static Composition and It’s Application for PVC Floor (수용성 대전방지제의 합성 및 이를 이용한 PVC 바닥재 코팅)

  • 이도현;하진욱
    • Proceedings of the KAIS Fall Conference
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    • 2001.05a
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    • pp.73-75
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    • 2001
  • 본 연구에서는 무용제 타입의 알킬(alkyl)기를 가진 친수성 4차 암모늄염인 대전방지제(Ultramer 5530)를 합성, 유/무광 수용성 수지와 배합하여 PVC 바닥재에 열경화 코팅을 행하였다. 대전방지 코팅액은 Ultramer 5530을 광택조절이 가능한 유/무광 수용성 수지에 무게 기준으로 5-20 wt%(이하 ‘part’로 표기)범위로 첨가, 배합하여 제조하였다. 대전방지 코팅 처리전 PVC 바닥재의 표면저항은 10/sup 12/Ω이었으나 코팅 후 표면저항은 유광 수지의 경우 최대 10/sup 8/Ω, 무광 수지의 경우 최대 10/sup 6/Ω까지 감소하였다. 유/무광 수지 모두 경화조건에 관계없이 일반적으로 Ultramer 5530의 첨가량이 증가할수록 코팅된 PVC 바닥재의 표면저항은 현저히 감소하였다. 경화온도 l00℃에서 1분간 경화한 콜이도막은 Ultramer 5530의 첨가량이 증가함에 따라 전기저항이 현저하게 감소하였으나 경도 및 부착률 등의 코팅도막 물성이 현저히 저하됨을 알 수 있었다. 이러한 물성 저하는 경화온도를 80℃로 낮추고 경화시간을 20분으로 늘리면 해결할 수 있었다. 본 연구결과, PVC 바닥재의 표면에 형성된 코팅도막의 물성은 Ultramer 5530의 첨가량을 8 part로 하고 120℃에서 1분간 열경화를 시켰을 때 가장 좋았다.

재도전 소상공인의 역량모델링에 관한 연구

  • Im, Jin-Hyeok;Park, Seong-Hui;Chae, Yeon-Hui
    • 한국벤처창업학회:학술대회논문집
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    • 2022.11a
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    • pp.59-65
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    • 2022
  • 본 연구는 코로나 팬데믹과 같은 외부 환경의 영향뿐만 아니라 경쟁 환경 및 시장변화에 적절하게 대응하지 못하는 등 역량부족의 문제로 사업 실패률이 높아진 소상공인들의 성공적인 재기를 돕고자 이들에게 요구되는 역량을 모델링하는데 목적이 있다. 이를 위해 1977년부터 2022년까지 발행된 관련 문헌을 분석하였고 7인의 재도전 소상공인을 대상으로 행동사건인터뷰(BEI)를 진행하였으며, 역량개발 및 HRD 전문가를 섭외하여 세 차례에 걸처 초점집단인터뷰(FGI)를 실시하는 과정을 통해 역량초안을 도출하였다. 이를 바탕으로 12명의 관련분야(창업, 소상공인, 심리/역량) 전문가를 섭외하여 3회에 걸친 델파이기법(Delphi Analysis)을 통해 재도전 소상공인의 성공적인 재기에 도움이 되는 역량을 2개의 역량군(소상공인, 실패회복), 8개의 세부역량(사업기회포착, 사업기획, 사업차별화, 운영관리, 판로개척, 제품과 서비스 연구개발, 긍정적 자기조절, 실패경험 극복 및 대처), 22개의 역량요소, 72개의 지식·기술·태도(KSA)가 표시된 행동지표로 도출하였다. 이와 같이 진행된 본 연구는 국내 최초로 재도전 소상공인에게 요구되는 역량을 구체화했다는데 학술적 의미가 있다. 또한 본 연구 결과는 재도전 소상공인 대상 역량기반 교육프로그램을 개발하거나 지원 프로그램에 적합한 대상자 선별하는 등에서 활용될 수 있으며 소상공인 스스로 사업 성공을 위해 역량을 진단하며 자기개발을 촉진하는데 활용할 수 있을 것으로 보인다.

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Effects of Shading Rate and Method of Inside Air Temperature Change in Greenhouse (차광율 및 차광방법이 온실내부의 온도변화에 미치는 영향)

  • 이석건;이현우;김길동;이종원
    • Journal of Bio-Environment Control
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    • v.10 no.2
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    • pp.80-87
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    • 2001
  • This study was conducted to provide basic data for the design of shading facility of greenhouse. The proper distance between external shading screen and roof surface, transmissivity of shading materials, and shading effects of external and internal shadings were analyzed. About a distance of 10 cm between inclined external shading screen and roof surface was enough to guarantee the external shading effect in the greenhouse without roof vent. The inside temperature of greenhouse installed with 85% internal shading screen was lower the maximum of 4$^{\circ}C$ and mean of 2$^{\circ}C$ than that with 55% internal shading screen in both natural ventilation and no ventilation condition. The difference of soil temperature between shading and no shading greenhouse was great, but the difference by shading rate or shading method was small. The performance of external shading for controlling inside temperature down was superior to that of the internal shading. The externally inclined shading screen parallel to the roof surface of greenhouse was more effective than the externally horizontal shading screen in controlling inside temperature of greenhouse without roof vent.

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Construction of Transgenic Silkworms Expressing Human Stem Cell Factor (hSCF) (인간 유래 Stem Cell Factor (hSCF) 재조합단백질이 발현되는 누에형질전환체 제작)

  • Kim, Sung-Wan;Yun, Eun-Young;Kim, Seong-Ryul;Park, Seung-Won;Kang, Seok-Woo;Kwon, O-Yu;Goo, Tae-Won
    • Journal of Life Science
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    • v.21 no.12
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    • pp.1726-1731
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    • 2011
  • Human Stem Cell Factor (hSCF) is a cytokine that binds to the c-Kit receptor and plays an important role in hematopoiesis, spermatogenesis, and melanogenesis. To produce the human Stem Cell Factor (hSCF) recombinant protein, we constructed a germline transgenic silkworm using the piggyback vector. The expression of the hSCF gene was driven by the Drosophila heat shock protein 70 (dHsp70) promoter. 3XP3 promotor-driven EGFP was used as a marker which allowed us to rapidly distinguish the transgenic silkworm. A mixture of the donor and helper vector was micro-injected into 1,020 eggs of bivoltin silkworms, Keomokjam. We obtained approximately 22 G1 broods that were EGFP-positive. The expression of the hSCF gene in the transgenic silkworm was analyzed by SDS-PAGE and immunoblotting. Also, analysis of insertion sites into the silkworm genome using inverse PCR showed that exogenous DNA was inserted into the transgenic silkworm genome. These results show that successfully constructed transgenic silkworm expresses the hSCF recombinant protein.

Preparation and Characterization of Polyurethane Waterproof Coatings Containing Fly Ash

  • Lee, Sung-Il;Kim, Duk-Bae;Yang, Go-Su;Kim, Wan-Young;Byoun, Youn-Seop;Lee, Youn-Sik
    • Elastomers and Composites
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    • v.38 no.3
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    • pp.243-250
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    • 2003
  • Polyurethane waterproof (PW) coatings are increasingly demanded in Korea for repairing cracks on old building roofs and construction of many sporting facilities. Calcium carbonate, a common filler, is incorporated in PW compositions. In this study, PW coatings were prepared by substituting a part of calcium carbonate with fly ash. The maximum amounts of calcium carbonate which can be substituted by fly ash obtained in the cyclone and bag filter dust collectors were 20 and 10%, respectively. It was found that the curing rate of PWs ran be controlled by varying the amount of Pb-octoate catalyst. The elongations at break as well as tensile strength and tear strength of PW coatings containing fly ash could also be adjusted such that their values were comparable to those of a standard PW coating by varying relative amounts of some components. However, the amount of cadmium, mercury, and lead leached from PW coatings containing fly ash obtained from the bag filter collector exceeded the respective allowed upper limits, mainly due to the initial high contents of them in the fly ash. On the other hand, PW coatings containing fly ash obtained from the cyclone collector exhibited better mechanical properties and did not release any significant amounts of the heavy metals. Thus, it was concluded that PW coatings containing fly ash can be utilized for practical applications as long as an appropriate fly ash is used.

The Effect of Physical Environment of Family Restaurant upon Customers' Emotions, Satisfaction and Revisit Intent - Focused on the Moderating Roles of Gender and Age - (패밀리 레스토랑의 물리적인 환경이 고객의 감정, 만족도 및 재방문 의도에 미치는 영향 - 성별과 연령의 조절 효과를 중심으로 -)

  • Jung, Hyo-Sun;Yoon, Hye-Hyun
    • Culinary science and hospitality research
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    • v.16 no.4
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    • pp.190-205
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    • 2010
  • The purpose of this study is to understand the effect of physical environment of family restaurant upon customers' emotions, satisfaction and revisit intent. Based on total 438 samples obtained from the empirical research, this study reviewed the reliability and fitness of the research model using Amos program. The hypothesized relationships in the model were tested simultaneously by using a structural equation model (SEM). The proposed model provided an adequate fit to the data, $x^2$ 592.898(p<0.001), df=239, CMIN/DF 2.481, RMR 0.103, GFI 0.900, NFI 0.952, CFI 0.970, RMSEA 0.058. SEM resulted that the physical environment showed a significant effect on customers' positive emotions($\beta$=0.388, p<0.001) and negative emotions($\beta$=-0.148, p<0.001). Also, customers' positive emotion($\beta$=0.828, p<0.001) bad a positive significant effect on customer satisfaction, and customer satisfaction($\beta$=0.771, p<0.001) bad a positive significant effect on revisit intent. Limitations and future research directions are also discussed.

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A Cell Loss Constraint Method of Bandwidth Renegotiation for Prioritized MPEG Video Data Transmission in ATM Networks (ATM망에서 우선 순위가 주어진 MPEG 비디오 데이터 전송시 대역폭 재협상을 통한 셀 손실 방지 기법)

  • Yun, Byoung-An;Kim, Eun-Hwan;Jun, Moon-Seog
    • The Transactions of the Korea Information Processing Society
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    • v.4 no.7
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    • pp.1770-1780
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    • 1997
  • Our problem is improvement of image quality because it is inevitable cell loss of image data when traffic congestion occurs. If cells are discarded indiscriminately in transmission of MPEG video data, it occurs severe degradation in quality of service(QOS). In this paper, to solve this problem, we propose two method. The first, we analyze the traffic characteristics of an MPEG encoder and generate high priority and low priority data stream. During network congestion, only the least low priority cells are dropped, and this ensures that the high priority cells are successfully transmitted, which, in turn, guarantees satisfactory QoS. In this case, the prioritization scheme for the encoder assigns components of the data stream to each priority level based on the value of a parameter ${\beta}$. The second, Number of high priority cells are increased when value of ${\beta}$ is large. It occurs the loss of high priority cell in the congestion. To prevent it, this paper is regulated to data stream rate as buffer occupancy with UPC controller. Therefore, encoder's bandwidth can be calculated renegotiation of the encoder and networks. In this paper, the encoder's bandwidth requirements are characterized by a usage parameter control (UPC) set consisting of peak rate, burstness, and sustained rate. An adaptive encoder rate control algorithm at the Networks Interface Card(NIC) computes the necessary UPC parameter to maintain the user specified quality of service. Simulation results are given for a rate-controlled VBR video encoder operating through an ATM network interface which supports dynamic UPC. These results show that dynamic bandwidth renegotiation of prioritized data stream could provided bandwidth saving and significant quality gains which guarantee high priority data stream.

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Separation of Cerium Hydroxide from Wasted Cerium Polishing Powders by the Aeration and Acidity-Controlling Method (폐세륨연마재 건조분말로부터 공기산화 및 산도조절에 의한 수산화세륨의 분리회수)

  • Yoon Ho-Sung;Kim Chul-Joo;Eom Hyoung-Choon;Kim Joon-Soo
    • Resources Recycling
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    • v.14 no.6 s.68
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    • pp.3-9
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    • 2005
  • In this study, the separation and recovery of cerium hydroxide was investigated from the wasted cerium polishing powders. Waste cerium polishing powder contains $64.5\;wt\%$ of rare earth oxide and the content of cerium oxide is $36.5\;wt\%$. Since cerium oxide, $56.3\%$ of rare earths, is the most stable state in rare earth, the dissolution of cerium oxide in acid solution is not easy. Therefore the process of rare earth oxide by sulfation and water leaching was examined in order to increase the recovery of rare earth. Rare earth elements were recovered in the form of $\Re{\cdot}Na(SO_{4})_{2}$ by the addition of sodium sulfate to leached solution. The slurry of rare earth hydroxide was prepared by the addition of $\Re{\cdot}Na(SO_{4})_{2}$ to sodium hydroxide solution. After the oxidation of cerous hydroxide($CE(OH)_{3}$) to ceric hydroxide($CE(OH)_{3}$) by aeration, ceric hydroxide was separated from other rare earth hydroxides by controlling the acidity of solution.

Control of relative humidity in the static bag emission test method by adding water and its effect on formaldehyde emission intensity (백을 이용한 정적 방출시험 방법에서 수분공급을 통한 상대습도조절과 포름알데하이드의 방출강도에 미치는 영향)

  • Park, Cheol-Soon;Yoo, Ji-Ho;Kim, Man-Goo
    • Analytical Science and Technology
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    • v.24 no.4
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    • pp.282-289
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    • 2011
  • Rapid screening method for the determination of the emissions of pollutants from vehicle interior parts and materials have been developed as ISO 12219-2 which is using bag and based on a static condition. The method was not controlled humidity in the test bag, so it is not suitable test method for formaldehyde emission test which is highly related to humidity condition. In this study, possibility of control humidity in the static test bag by adding extra water and the effect of humidity condition for formaldehyde emissions have been investigated. The relative humidity in the test bag was affected not only amount of water added also material of test bag and test specimen. The emission intensity of formaldehyde was increased according to increasing relative humidity in test bag. But excessively supplied water was condensed on the inner surface of test bag and surface of sample specimen that were sorption formaldehyde and were reduced its emission intensity.