• Title/Summary/Keyword: 재료정수

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Deposition Characteristics of Lead Titanate Films on $RuO_2$ and Pt Substrates Fabricated by Chemical Vapor Deposition ($RuO_2$ 및 Pt 기판에서 $PbTiO_3$박막의 화학기상 증착특성에 관한 연구)

  • Jeong, Su-Ok;Lee, Won-Jong
    • Korean Journal of Materials Research
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    • v.10 no.4
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    • pp.282-289
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    • 2000
  • $PbTiO_3$ films were fabricated by electron cyclotron resonance plasma enhanced chemical vapor deposition(ECR-PECVD). Deposition characteristics of $PbTiO_3$films on $RuO_2$ and Pt substrates were investigated with varying the flow rate of metalorganic source and substrate temperature. The residence time of Pb-oxide molecules in much longer on $RuO_2$ than on Pt substrate, while the perovskite nucleation is more difficult on $RuO_2$ than on Pt substrate. Therefore, the process conditions to obtain the single perovskite $PbTiO_3$ phase are more restricted on $RuO_2$ than on Pt substrates. An introduction of Ti-oxide seed layer increases perovskite nucleation density and thus enlarges the process window to obtain the single perovkite phase. The introduction of Ti-oxide seed layer make the PZT film that Ti-components of $PbTiO_3$ are partially substituted with Zr atoms have single perovskite phase for the wide range of Zr/(Zr+Ti) concentration ratios.

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A-site Non-stoichiometric Effects of Bi0.5(Na0.78K0.22)0.5TiO3 Ceramics on the Dielectric and Electrical Properties (Bi0.5(Na0.78K0.22)0.5TiO3 세라믹스의 A-site 비화학양론이 유전 및 전기적 특성에 미치는 영향)

  • Park, Jung Soo;Lee, Ku Tak;Yun, Ji Sun;Cho, Jeong Ho;Jeong, Young Hun;Paik, Jong Hoo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.27 no.12
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    • pp.803-808
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    • 2014
  • $Bi_{0.5+x}(Na_{0.78}K_{0.22})_{0.5-3x}TiO_3$ ceramics with an excess $Bi^{3+}$ and a deficiency of $Na^+$ and $K^+$ were synthesized by a conventional solid state reaction method. The structure and morphology of $Bi_{0.5+x}(Na_{0.78}K_{0.22})_{0.5-3x}TiO_3$ ceramics were characterized by X-ray diffraction and field emission scanning electron microscopy. The electric polarization and mechanical strain induced by external electric field, and the temperature dependence of dielectric constant were investigated. These results demonstrated that an ergodic relaxor phase can be induced by controls of the mole ratio of $Bi^{3+}$, $Na^+$ and $K^+$. A phase boundary between non-ergodic and ergodic relaxor phases can be observed at ambient temperature. The ergodic relaxor phase can be transferred to the ferroelectric phase by application of the electric field. The stability of the induced ferroelectric phases strongly depends on the mole ratio of $Bi^{3+}$, $Na^+$ and $K^+$. The maximum strain of 0.31% was observed in $Bi_{0.51}(Na_{0.78}K_{0.22})_{0.47}TiO_3$ ceramics sintered at $1,150^{\circ}C$ for 2 h.

MXene Based Composite Membrane for Water Purification and Power Generation: A Review (정수 및 발전을 위한 맥신(MXene) 복합막에 관한 고찰)

  • Seohyun Kim;Rajkumar Patel
    • Membrane Journal
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    • v.33 no.4
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    • pp.181-190
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    • 2023
  • Wastewater purification is one of the most important techniques for controlling environmental pollution and fulfilling the demand for freshwater supply. Various technologies, such as different types of distillations and reverse osmosis processes, need higher energy input. Capacitive deionization (CDI) is an alternative method in which power consumption is deficient and works on the supercapacitor principle. Research is going on to improve the electrode materials to improve the efficiency of the process. A reverse electrodialysis (RED) is the most commonly used desalination technology and osmotic power generator. Among many studies conducted to enhance the efficiency of RED, MXene, as an ion exchange membrane (IEM) and 2D nanofluidic channels in IEM, is rising as a promising way to improve the physical and electrochemical properties of RED. It is used alone and other polymeric materials are mixed with MXene to enhance the performance of the membrane further. The maximum desalination performances of MXene with preconditioning, Ti3C2Tx, Nafion, and hetero-structures were respectively measured, proving the potential of MXene for a promising material in the desalination industry. In terms of osmotic power generating via RED, adopting MXene as asymmetric nanofluidic ion channels in IEM significantly improved the maximum osmotic output power density, most of them surpassing the commercialization benchmark, 5 Wm-2. By connecting the number of unit cells, the output voltage reaches the point where it can directly power the electronic devices without any intermediate aid. The studies around MXene have significantly increased in recent years, yet there is more to be revealed about the application of MXene in the membrane and osmotic power-generating industry. This review discusses the electrodialysis process based on MXene composite membrane.

A Feasibility Study on the Use of Liner and Cover Materials Using Sewage Sludge (하수슬러지의 차수재 및 복토재로의 이용타당성에 관한 연구)

  • 유남재;김영길;박병수;정하익
    • Journal of the Korean Geotechnical Society
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    • v.15 no.2
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    • pp.43-71
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    • 1999
  • This research is an experimental work of developing a construction material using municipal wastewater sludge as liner and cover materials for waste disposal landfill. Weathered granite soil and flyash, produced as a by-product in the power plant, were used as the primary additives to improve geotechnical engineering properties of sludge. For secondary additives, bentonite and cement were mixed with sludge to decrease the permeability and to increase the shear strength, respectively. Various laboratory test required to evaluate the design criteria for liner and cover materials, were carried out by changing the mixing ratio of sludge with the additives. Basic soil properties such as specific gravity, grain size distribution, liquid and plastic limits were measured to analyze their effects on permeability, compaction, compressibility and shear strength properties of mixtures. Laboratory compaction tests were conducted to find the maximum dry densities and the optimum moisture contents of mixtures, and their effectiveness of compaction in field was consequently evaluated. Permeability tests of variable heads with compacted samples, and the stress-controlled consolidation tests with measuring permeabilities of samples during consolidation process were performed to obtain permeability, and to find the compressibility as well as consolidational coefficients of mixtures, respectively. To evaluate the long term stability of sludges, creep tests were also conducted in parallel with permeability tests of variable heads. On the other hand, for the compacted sludge decomposed for a month, permeability tests were carried out to investigate the effect of decomposition of organic matters in sludges on its permeability. Direct shear tests were performed to evaluate the shear strength parameters of mixed sludge with weathered granite, flyash and bentonite. For the mixture of sludge with cement, unconfined compression tests were carried out to find their strength with varying mixing ratio and curing time. On the other hand, CBR tests for compacted specimen were also conducted to evaluate the trafficability of mixtures. Various test results with mixtures were assessed to evaluate whether their properties meet the requirements as liner and cover materials in waste disposal landfill.

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Recovery of BTEX-aromatics from Post-consumer Polypropylene Fraction by Pyrolysis Using a Fluidized Bed (유동층(流動層) 급속열분해(急速熱分解)에 의한 폐(廢) Polypropylene fraction으로부터 BTEX-aromatics의 회수(回收))

  • Cho, Min-Hwan;Jeong, Soo-Hwa;Kim, Joo-Sik
    • Resources Recycling
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    • v.17 no.6
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    • pp.50-56
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    • 2008
  • A polypropylene fraction collected from the stream of post-consumer plastics was pyrolyzed. The aim of this study is to observe the dependence of yield of BTEX-aromatics normally used as solvent on the reaction temperature. To reach the goal, three experiments were carried out at different temperature between 650 and $700^{\circ}C$, using a fluidized bed reactor that shows an excellent heat transfer. In the experiments, product gases were used as a fluidizing medium to maximize the amount of BTEX-aromatics at fixed flow rate and feed rate during the pyrolysis. Oil, gas and char were obtained as product fractions. Product gases were analyzed with GCs(TCD, FID) and with a GC-MS system for qualitative analysis. For an accurate analysis of product oil, the product oil was distilled under vacuum, and separated the distillation residues from oil fractions that were actually analyzed with a GC-MS system. As the reaction temperature went higher, the content of BTEX-aromatics increased. The maximal yield of BTEX-aromatics was obtained at $695^{\circ}C$ with a value of about 30%. The main compounds of product gas were $CH_4$, $C_2H_4$, $C_2H_6$, $C_3H_6$, $C_4H_{10}$ and the product gas had an higher heating value about 45MJ/kg. It could be used as a heat source for a pyrolysis plant or for other fuel applications.

Cadmium Accumulation and Tolerance of Iris pseudacorus and Acorus calamus as Aquatic Plants Native to Korea (자생 수생식물 노랑꽃창포와 창포의 카드뮴 축적 및 내성)

  • Lee, Sung-Chun;Kim, Wan-Soon
    • Horticultural Science & Technology
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    • v.29 no.5
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    • pp.413-419
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    • 2011
  • This study was conducted to find out the cadmium (Cd) accumulation and tolerance of Iris pseudacorus and Acorus calamus as aquatic plants native to Korea for Cd removal in water. In the range of Cd concentration from $10{\mu}M$ to $130{\mu}M$, the Cd lethal dose 50 ($LD_{50}$) was $78.5{\mu}M$ in I. pseudacorus and $47.6{\mu}M$ in A. calamus. In I. pseudacorus, superoxide dismutase and peroxidase as antioxidants were relatively effective against oxidative stress caused by Cd, while catalase, superoxide dismutase, and polyphenolics were effective in A. calamus. The polyphenolics known as typical antioxidants were not detected in I. pseudacorus. In both species, the Cd accumulation in plants increased with the higher Cd concentration and the longer processing period. Also, the absorbed Cd was accumulated mainly in the roots. The amount of Cd accumulated in the shoot part was maximally $548.1mg{\cdot}kg^{-1}$ (82.1% to Cd accumulated in the root part) in I. pseudacorus and $121.4mg{\cdot}kg^{-1}$ (13.7%) in A. calamus, which implied that both species all were enough evaluated as Cd hyper-accumulators based on 0.01% or more Cd accumulation in the shoot. Especially I. pseudacorus showed outstanding ability to move well Cd into the shoots from the roots and high tolerance to Cd stress.

Dasan's Conceptual Thoughts on the Garden in 「Jaehwangsangyuincheop」 (「제황상유인첩(題黃裳幽人帖)」에 나타난 다산(茶山)의 정원상(庭園想))

  • Jung, Soo-Jin
    • Journal of the Korean Institute of Landscape Architecture
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    • v.46 no.5
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    • pp.22-35
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    • 2018
  • The purpose of this study is to understand the idea of the ideal garden, pursued by Dasan, by analyzing the production process of his writing and the location of his dwelling, and the characteristics of the garden in the writings of Dasan (茶山) Jeong Yag-Yong (丁若鏞)'s "Jaehwangsangyuincheop (題黃裳幽人帖)" is concerned with his writings on an imaginary garden (意園). This paper assumed that "Jaehwangsangyuincheop" served as a blueprint for his ideal dwelling. The main research subjects are the external scenes described in the "Jaehwangsangyuincheop", and the garden elements and spatial construction that were visualized as a Korean Ink Painting (水墨畵) through the analysis of related works. The results are as follows. First, Hwang Sang was Dasan's favorite pupil, and "Jaehwangsangyuincheop" was written by Dasan while at Boeunsanbang in the winter of 1805 as an answer to a question that Hwang Sang posed about the residence of a hermit. By referring to this response, Hwang Sang established Ilsoksanbang (一粟山房) under Mt. Cheongae in Daegu-myeon, Gangjin. Secondly, the residence in "Jaehwangsangyuincheop" has mountains behind it and water in front of it (背山臨水). The residence was used as a place to combine life and leisure. It was an ideal residence that secluded the scholar(隱士). Thirdly, Dasan's ideal garden was shown as operation of natural geography in a residential location, practically using various plant materials, expanding physical boundaries of garden, pursuing synesthetic aesthetics while enjoying garden elements, and having an active experience of the taste for the arts in the extended garden. "Jaehwangsangyuincheop" depicted the life of a scholar with the taste of elegance (雅趣), who live in reclusiveness (隱逸), which was wanted by Dasan after exile. It was realized as Ilsoksanbang. "Jaehwangsangyuincheop" was interpreted as the ideal of a feasible dwelling that faithfully reflects Dasan's conceptual thoughts on the garden.

Power Loss and Electro-Magnetic Characteristics of Ni-Cu-Zn Ferrites (Ni-Cu-Zn페라이트의 損失과 磁性 特性)

  • Otsuki, E.;Kim, Jeong-Su
    • Resources Recycling
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    • v.13 no.6
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    • pp.37-42
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    • 2004
  • The power loss analysis was carried out for Ni-Cu-Zn ferrite sample with different content of NiO and ZnO. The power loss, Pcv decreases monotonically with increasing temperature and attains to a certain value at around 100~120 degrees Celsius. The frequency dependence of Pcv can be explained by Pcv~f$^n$, and n is independent of the frequency, f up to 1 MHz. The Pcv decreases with an increase in ZnO/NiO. The Pcv was separated to hysteresis loss(Ph) and residual loss(Pcv-Ph). The temperature characteristics and compositional dependence of Pcv can be attributed to the Ph, while Pcv-Ph is not affected by both temperature and ZnO/NiO. By analyzing temperature and composition dependence of Ph and initial permeability, ${\mu}_i$ like following equations could be formularized. ${\mu}_i{\mu}_0=I_s^2/(K_I+b{\sigma}_0{\lambda}_s)$ Wh=13.5(I$_s^2/{\mu}_i{\mu}_0)$ Where ${\mu}_0$ is permeability of vacuum, I$_s$ is saturation magnetization, K$_I$ is anisotropy constant, $s_0$ is internal heterogeneous stress, ${\lambda}_s$ is magnetostriction constant, b is unknown constant, and Wh is hysteresis loss per one cycle of excitation (Ph=Wh${\times}$f). Steinmetz constant of Ni-Cu-Zn ferrite, m=1.64~2.2 is smaller than that of Mn-Zn ferrites, which suggests the difference of loss mechanisms between these materials.

Determinants of R&D Performance of Government-supported Research Institutes in the Field of Science and Technology - A Case Study of the Korea Institute of Science and Technology (KIST) - (과학기술계 정부출연연구기관의 연구개발성과 결정요인 - 한국과학기술연구원 (KIST) 사례연구 -)

  • Choi, Ho-Young;Choi, Chi-Ho;Kim, Jung-Soo
    • Journal of Korea Technology Innovation Society
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    • v.14 no.4
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    • pp.791-812
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    • 2011
  • The aim of this paper is to address the factors that influence R&D performance of the Korea Institute of Science and Technology (KIST), the representative government-supported research institute in Korea, through an empirical case study. Using the KIST R&D project data from 2004 to 2008, we investigate the determinants of R&D performance through a logistic regression analysis, and compare the results with the survey data we collected from researchers. Our results indicate that total budget, high rate of temporary researchers, and the outcome of the research director's past publications affect publishing performance, while the size of equipment, materials expenditure, and whether the research is outsourced or not affect patent registration performance and technology transfer performance. Contrary to expectations, major factors of publishing performance and that of patent performance are different respectively, and even the results of the survey data we collected from researchers show the difference. Accordingly, the findings of our study suggest the need for research institutes to consider facilitating communication with researchers and enhancing research policy analysis for improving R&D performance.

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Development of Eggs, Larvae and Juveniles of Bluegill, Lepomis macrochirus RAFINESQUE (Bluegill의 난발생과 자치어)

  • KIM Yong Uk;PARK Yang Sung
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.20 no.1
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    • pp.24-32
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    • 1987
  • Bluegill, Lepomis macrochirus RAFINESQUE, has bred widely in the various districts of Korea since the Office of Fishery transplanted it into our country from Japan in December, 1969. On August 17, 24 in 1985, bluegill were caught in the reservoir of Habuk-Myon, Yangsan-Gun, $Ky\breve{o}ngsangam-Do$, Korea. They spawned in the rearing aquarium on July 13 and August 2 in 1986. The eggs of this species are adhesive and demersal. The size of the egg diameters were varied from 1.18 to 1.30 mm. Hatching took place in 40 hours after fertilization at the water temperature of $24.3-25.4^{\circ}C$. The newly botched larvae were 3.75-4.05 mm in total length possessing yolk sac, and 29-30 mytomes. Many melanophores were evenly distributed on the entire body. Ten days after hatching, the postlarvae attained 6.05-6.35 mm in total length. The yolk sac was completely absorbed and the width of the pectoral finfold had reached the maximum size. One month fifteen days after hatching, the juvenile attained 25.20 mm in total length.

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