• Korean Chemical Engineering Research
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• v.46 no.5
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• pp.958-964
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• 2008

In this work, micro-sized dextran particles, which have recently been focused as one of the candidate materials for the Drug Delivery System(DDS), were prepared by means of the Supercritical Antisolvent (SAS) process with $CO_2$. With dimethyl sulfoxide(DMSO) as the solvent, effects of the operating variables such as temperature (308.15~323.15 K), pressure(90~130 bar), solute concentration(10~20 mg/ml), and the molecular weight of the solute(Mw=37,500, 450,000) on the size and morphology of the resulting particles were thoroughly observed. The higher solute concentration led to the larger particles, however, the injection velocity of the solution and pressure did not show significant effects on the resulting particle size. With dextran of the lower molecular weight, the smallest particles were obtained at 313.15 K. On the other hand, the size of the particles from the high molecular weight dextran ranged between $0.1{\sim}0.5{\mu}m$ with an incremental effect of the temperature and pressure. For the solute concentration of 5 mg/ml, the lower molecular weight dextran did not form discrete particles while aggregation of the particles appeared when the solute concentration exceeded 15 mg/ml for the higher molecular weight dextran. It is believed that if the solute concentration is too low, the degree of the supersaturation in the recrystallization chamber would not be sufficient for initiation of the nucleation and growth mechanism. Instead, the spinodal decomposition mechanism leads to formation of the island-like phase separation which appears similar to aggregation of the discrete particles. This effect would be more pronounced for the smaller molecular weight polymer system due to the narrower phase-splitting region.

• Journal of the Korea Convergence Society
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• v.7 no.6
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• pp.193-198
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• 2016

The texture of electrodeposits varies with deposition conditions. Texture of electrodeposits is also related to microstructure, surface morphology and mechanical properties. When the electrodeposits annealed, the recrystallization texture may be different from the original deposition texture. The surface morphology, the microstructure and the initial and recrystallization textures of copper electrodeposits vary with deposition conditions. The texture, microstructure, surface morphology and mechanical properties of electrodeposits are known to vary with electrolysis conditions, such as bath composition, over potential, pH, current density, bath temperature, etc. The (111) and (110) textures of copper electrodeposits can be obtained from copper sulfate bath. In this study, copper electrodeposits with (111) and (110) textures are obtained from a copper sulfate bath, and the change from (111) to (110) textures of copper electrodeposits can be explained.

• Korean Journal of Materials Research
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• v.9 no.7
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• pp.740-747
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• 1999

Grain refinement is the only strengthening mechanism that improves both strength and toughness. Controlled rolling and accelerated cooling techniques have been known to be effective method to improve the mechanical properties by controlling the recrystallization and/or grain coarsening during processing. Repeat phase transformation $(\gamma/\alpha)$ by repeat heat treating is another way of grain refinement. In this study, a combined effect of controlled rolling and repeat heat treating was investigated. To study the effects of Mo addition and process parameters, Mo alloyed low carbon steels were prepared and thermomechanical controlled processes were simulated in the Gleeble system. The Mo addition resulted in an increasement of the grain coarsening temperature and suppress austenite recrystallization. The optimum condition for the refinement of austenite was obtained when the controlled rolling was performed twice with the same heat treatment condition, and reduction ratio of second pass was higher than that of first pass.

• Journal of the Korean Chemical Society
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• v.36 no.6
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• pp.857-863
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• 1992

Acid type saturated Weston cells that can be used as the standard of electromotive force unit were constructed and their characteristics in a specially designed enclosure were evaluated. Cadmium sulfate was purified by recrystallization under vaccum. Mercurous sulfate with dispersed mercury and the exact composition of cadmium amalgam were obtained by means of electrolysis. The enclosure was constructed using a commercial circulator. Temperature of the enclosure was only drifted in the range of ${\pm}$5 mK in the case of extreme change of room temperature. The electromotive force of standard cells was measured over the temperature range of 5∼${\sim} 30^{\circ}C$. The standard deviation of the electromotive forces was about 1 ppm.

• Transactions of the Korean Society of Machine Tool Engineers
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• v.10 no.6
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• pp.57-62
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• 2001

Recently, it has increased that the importance of gas pressure weldment of steel bars in large construction bars. But there has hardly been any studies about it. Therefore we need more research. SD40 steel bar (32mm in diameter) which has been practically used at construction sites are tested about tension, bonding, fatigue, a macro structure and micro structure at foil gitudinal section and hardness to fed out the mechanical property and best welding ranges in some cases of mechanical cut and gas cut before gas pressure welded. It is that a gas-pressure welded zone of steel bar where was cleaned of impurities in way of two-upsetted method is more excellent bending and tension property than the regulation of KD D 0244. Also gas cut bars gained hardness from the heat affected zone so. In conclusion, to improve the weldability of steel bars, it is considered best to clean mechanically cut sutra- faces and then weld them by a method of 2 step upset way.

• Proceedings of the Materials Research Society of Korea Conference
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• 2010.05a
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• pp.50.2-50.2
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• 2010

니켈기 초내열합금 Inconel 617은 수소생산용 초고온 가스 냉각로의 열 교환기와 고온 가스관 등의 고온 배관용 후보재료로써, Cr, Mo, 와 W등의 첨가물이 함유된 고용 강화된 합금으로, 우수한 고온 강도, 크립 저항성, 내부식성 및 내산화성을 가지고 있는 것으로 알려져 있다. 본 연구에서는 결정립 미세화가 고온열화에 의해 입계를 따라 형성되는 internal oxide에 미치는 영향에 대해 평가하였고, 이러한 internal oxide가 인장응력 하에서 크렉 형성 및 전파에 미치는 영향을 평가하기 위하여 3-point bending test를 수행하였다. 미세한 결정립을 가지는 Inconel 617은 냉간압연 후 재결정을 통해 확보하였으며, as-received(AR)과 grain-refined(GR) Inconel 617은 $950^{\circ}C$에서 2000시간 동안 He분위기 하에서 열화시험을 수행하였다. AR과 GR에 형성된 internal oxide은 깊이와 분포 등의 뚜렷한 차이를 보였으며, 이러한 차이로 인해 인장응력 하에서 크렉 전파의 큰 차이를 나타내었다.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 1998.04a
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• pp.8-8
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• 1998

Alloy 718은 Fe을 다량 함유하고 있어 가격이 저렴하고 엔진 작동조건에서 내열강도, 내환경성 등이 우수하여, 터빈디스크, 터빈샤프트, 터빈실, 압축기 블레이드 등에 다양하게 이용되고 있다. 이 합금은 고온에서 반복응력을 받는 부위에 대부분 사용되기 때문에 고온인장, 저주기 피로측정 등의 기계적 성질이 동시에 요구되며, 이들 특성은 단조공정변수 및 후열처리 등에 의해 크게 바뀌게 된다. 본 연구에서는 Alloy 718을 이용하여 가스터빈 디스크 제조할 경우 공정변수로서 단조온도, 변형속도 등에 의한 조직이 변화와 이에 따른 기계적 특성의 변화를 다루었다. 특히 이 합금에서 결정립크기는 고온 기계적 성질을 결정하는 중요한 변수로 작용하는데, 2단계 단조공정시 재결정에 의한 조직의 변화를 전산모사 방법에 의해 해석하고 그 결과를 조직 관찰을 통해 검증하였다.

• Transactions of Materials Processing
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• v.13 no.5
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• pp.455-460
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• 2004

The deformation and annealing behaviors of a 1050 Al alloy deformed at cryogenic temperature were investigated, focusing on the evolution of microstructures and mechanical properties. Especially, the effects of annealing temperature, $150~300^{\circ}C$, on microstructures and mechanical properties of the sheets received reduction of 88% at cryogenic temperature were investigated. The significant change in mechanical properties with the annealing temperatures of $200~300^{\circ}C$ would be attributed to the variations in the volume fraction of recrystallized grains and coarse equiaxed grains.

• Journal of the Korean Society for Precision Engineering
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• v.15 no.9
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• pp.75-81
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• 1998

Simulations of warm and hot forming processes need reliable expressions of flow stress at high temperatures. To get flow stress of the materials usually tension, compression and torsion tests are conducted. In this study, hot compression tests were adopted to get flow stress of medium carbon steel. Experiments have been conducted under both isothermal, near constant strain rate in the temperature ranges 650～100$0^{\circ}C$. Phase transformation takes place by temperature changes for steels in hot and warm forging stage. So Constitutive equation are formulated as the function of strain, strain rate and temperature for isothermal conditions and phase transformation.

• Korean Journal of Materials Research
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• v.3 no.1
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• pp.50-57
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• 1993

Abstract The sintering behavior of the mechanically alloyed AI-8wt%Fe power during vacuum hot pressing was investigated and high temperature deformation behavior of the sintered specimen was studied through compression tests at various strain rates in the temperature range between 35$0^{\circ}C$ and 45$0^{\circ}C$. In 'addition, thermal stablity of the sintered specimem was examined by hardness measurement after annealing the spcimem for 60 hours in the temperature range of 30$0^{\circ}C$ ~50$0^{\circ}C$. The compressive stress increased rapidly with strain and reached the maximum point at the strain about 3%. With slight decrement after reaching the maximum point, the flow stress became constant up to the strain of 30% and it was considered to be due to equilibrium between work hardening and dynamic recrystallization. The hardness of the 60 hrs annealed specimens began to decrease rapidly at 40$0^{\circ}C$ .