• Journal of the Korean Applied Science and Technology
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• v.29 no.2
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• pp.268-277
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• 2012

The thermal decomposition characteristic of waste PVC wires has been studied by using TGA and fixed-bed reactor. The experimental conditions of decomposition temperatures, air flow rates and weight ratio of CaO/PVC were considered in this work. To verify the effectiveness of CaO addition to remove HCl and toxic gases generated from thermal decomposition of PVC wire, the gaseous products obtained from the thermal decomposition of PVC were analyzed by GC/MS(Gas Chromatograph and Mass Spectrometry). To investigate the effect of CaO in thermal decomposition of PVC, liquid products were also analyzed by GC/MS. And the effect of decomposition temperature, air flow rate and CaO/ PVC weight ratio on the yield of liquid, gas and residue fraction have been also studied. From this work, it was found that the removal amount of HCl generated from thermal decomposition of PVC increased with increase of CaO addition.

• Journal of the Korean Magnetics Society
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• v.3 no.3
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• pp.229-233
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• 1993

The effects of differential partial pressures of oxygen during sputtering on the magnetic and recording characteristics of magneto-optical disks were investigated. Different flows of oxygen were deliberately introduced into the sputtering chamber to have a variety of partial pressures of oxygen during sputtering. A residual gas analyzer was employed to monitor the oxygen peak before, during, and after sputtering and to estimate the reacted oxygen amount. Most of the oxygen introduced into the chamaber was reacted during sputtering. As the partial pressure of oxygen increased, the oxygen content of the TbFeCoCr film increased also. The oxygen appeared to be bound as Tb-O, effectively decreasing the magnetically active Tb content of the film The coercivity decreased but the squareness of the Kerr hysteresis loops was still excellent. The perpendicular anisotropy was not significantly affected by oxygen amount. The carrier-to-noise ratio, includi!1g the write power sensitivity and bias field sensitivity did not change too much with oxygen content in the film The disks sputtered with oxygen showed better bias field sensitivity with lower write power threshold than the disk sputtered without oxygen, due to high demagnetization during domain formation. No significant degradation of coercivity for the disk sputtered oxygen was observed during an accelerated aging test.

• Journal of the Institute of Electronics and Information Engineers
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• v.50 no.7
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• pp.269-274
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• 2013

We are used with the alkaline ion water which an application field does to object for drinking water compare with the alkaline ion water which asked ion acid electrolysis so as to be very different. This is used with sterilization disinfection use by residual chlorine in case of strong acidity according to ph intensity, and in case of middle acidity use by washing and face washing, and mix with meal materials in case of weak acidity widely usable in cooking. Acid ion water generates as we electrolyze water. Chlorine gas and sodium hydroxide etc. was generated at electrolysis process, and we have toward sterilizing power. Derelicts such as chlorine, phosphorus, sulfur etc. are gathered from a negative ion, and we make acid ion water to + electrode direction in electrolysis. We used a diaphragm in order to disconnect too acid water and alkaline water. We implemented so that the acid water which it came down to three kinds of PWM voltage to PWM (pulse width modulation) control, and implementation method of ph intensity change authorized ph intensity between weak acidity to electrode in strong acidity as we used Microprocessor, and intensity was adjusted successively by PWM control was generated.

• Korean Chemical Engineering Research
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• v.46 no.3
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• pp.540-544
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• 2008

Pyrolytic characteristics of mixed plastics containing 22 wt.% HDPE, 17 wt.% LDPE, 27 wt.% PP, 12 wt.% PS, 16 wt.% ABS, 6 wt.% PVC have been studied in the batch-type microreactor of stainless steel. Thermal degradation experiments were performed at temperature of $410{\sim}450^{\circ}C$. The yield of each pyrolytic products were obtained by the weight measurement and molecular weight distribution of pyrolytic liquid products determined by the GC-SIMDIS method. It was shown that the yield and molecular weight of pyrolytic liquid product were decreased with the increase of reaction temperature and time. It was know that 20wt% of PVC composing of the mixed plastics was converted to the gas products of chloride during the pyrolysis process. The chain-end scission rate parameter was determined to be 50.2 kcal/mole of mixed plastics by the Arrhenius plot.

• Journal of Soil and Groundwater Environment
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• v.16 no.5
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• pp.42-52
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• 2011

In this laboratory study, the changes in gas-exposed perchloroethene (PCE) saturation in sand during a PCE removal process were measured using gaseous tracers. The flux of fresh air through a glass column packed with PCEcontaminated, partially water-saturated sand drove the removal of PCE from the column. During the removal of PCE, methane, n-pentane, difluoromethane and chloroform were used as the non-reactive, PCE-partitioning, water-partitioning, and PCE and water-partitioning tracers, respectively. N-pentane was used to detect the PCE fraction exposed to the mobile gas. At water saturation of 0.11, only 65% of the PCE was found to be exposed to the mobile gas prior to the removal of PCE, as calculated from the n-pentane retardation factor. More PCE than that detected by n-pentane was depleted from the column due to volatilization through the aqueous phase. However, the ratio of gas-exposed to total PCE decreased on the removal of PCE, implying gas-exposed PCE was preferentially removed by vaporization. These results suggest that the water-insoluble, PCE-partitioning tracer (n-pentane in this study), along with other tracers, can be used to investigate the changes in fluid (including nonaqueous phase liquid) saturation and the removal mechanism during the remediation process.

• Transactions of the Korean hydrogen and new energy society
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• v.22 no.4
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• pp.534-545
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• 2011

This paper describes the evaluation of kinetic parameters for pyrolysis and carbon char oxidation of residual oil. The non-isothermal pyrolysis of residual oil was carried out with TGA (Thermo-Gravimetric Analyzer) at heating rate of 2, 5, 10 and $20^{\circ}C/min$ up to $800^{\circ}C$ under N2 atmosphere. The first order and nth order pyrolysis models were used to fit the experimental data, and the nth order model was turned out to follow the experimental data more precisely than the first order model. For carbon char oxidation experiment, TGA and four heating rates used in pyrolysis experiment were also adapted. The kinetic parameters for the residual carbon char particle were obtained with three char oxidation model, that is, volume reaction, grain and random pore model. Among them, the random pore model described the char oxidation behaviour quite well, compared to other two models. The non-linear regression method was used to obtain kinetic parameters for both pyrolysis and carbon char oxidation of residual oil.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.34 no.9
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• pp.1227-1233
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• 2010

In the hot section of a gas turbine, the turbine blades were protected from high temperature by providing a thermal barrier coating (TBC) as well as by cooling air flowing through internal passages within the blades. The cooling air then passed through discrete holes on the blade surface, creating a film of cooling air that further protects the surface from the hot mainstream flow. The holes are subjected to stresses resulting from the lateral growth of thermally grown oxide, the thermal expansion misfit between the constituent layers, and the centrifugal force due to high-speed revolution; these stresses often result in cracking. In this study, the deformation and cracks occurring near a hole on a heat-resistant alloy subjected to thermo-mechanical cycling were investigated. The experiment showed that cracks formed around the hole depending on the applied stress level and the number of cycles. These results could be explained by our analytic solution.

• Journal of the Korean Vacuum Society
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• v.13 no.3
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• pp.120-126
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• 2004

A damage-reduced trench was investigated in view of the defect distribution along trench sidewall and bottom using high resolution transmission electron microscopy, which was formed by HBr plasma and additive gases in magnetically enhanced reactive ion etching system. Adding $O_2$ and other additive gases into HBr plasma makes it possible to eliminate sidewall undercut and lower surface roughness by forming the passivation layer of lateral etching. To reduce the RIE induced damage and obtain the fine shape trench corner rounding, we investigated the hydrogen annealing effect after trench formation. Silicon atomic migration on trench surfaces using high temperature hydrogen annealing was observed with atomic scale view. Migrated atoms on crystal surfaces formed specific crystal planes such as (111), (113) low index planes, instead of fully rounded comers to reduce the overall surface energy. We could observe the buildup of migrated atoms against the oxide mask, which originated from the surface migration of silicon atoms. Using this hydrogen annealing, more uniform thermal oxide could be grown on trench surfaces, suitable for the improvement of oxide breakdown.

• Proceedings of the KWS Conference
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• 2009.11a
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• pp.116-116
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• 2009

마그네슘 합금은 구조용으로 사용 가능한 금속 재료 중 가장 가벼운 소재이며, 동시에 비강도 및 비강성과 같은 기계적 특성이 우수하여 알루미늄 합금의 뒤를 이을 차세대 경량 재료로써 주목을 받고 있다. 더욱이 석유자원의 대부분을 소비하고 있는 운송기기 분야에서는 경량화를 통한 연비향상과 배출가스 저감이 가장 큰 과제이며, 이 문제를 해결하기 위한 노력의 일환으로 최경량 소재인 마그네슘 합금의 사용량은 더욱 증가할 것으로 기대된다. 한편 기존의 마그네슘 합금 관련 연구는 새로운 합금의 개발에 치우쳐 있었으며, 상대적으로 이들 합금을 활용하기 위한 가공기술, 특히 용접에 대한 연구는 아직까지 많이 부족한 실정이다. 이는 철강재와 비교하여 마그네슘 합금의 고유물성이 용접의 관점에서는 상당히 열악하기 때문으로, 마그네슘은 융점 및 비점은 낮은 반면, 증기압과 열전도율은 높고 표면장력 및 점성은 낮은 특성을 가지고 있다. 그러므로 타 공법에 비해 상대적으로 입열이 적고 고속용접이 가능한 레이저의 적용이 최적으로 판단된다. 따라서 본 연구에서는 Nd:YAG 레이저를 사용하여 압연판재로 상용화되어 있는 AZ31B 마그네슘 합금의 맞대기 용접성을 조사하였으며, 용접부의 미세조직과 용접조건에 따른 용접부의 기계적 특성을 비교 및 검토하였다. 용접부의 기계적 특성은 인장 및 경도시험을 통해 평가하였다. 그 결과 레이저 출력 1.2kW를 적용한 경우에 안정적인 강도를 얻을 수 있었으며 레이저 출력 1.5kW, 용접속도 80mm/sec의 조건에서 모재 인장강도 대비 103% 그리고 연신율 대비 47.1%의 최적의 결과가 얻어졌다. 또한 용접부의 경도는 모재와 동등하거나 다소 높은 수준이었다. 이는 용접시 용접부내 잔류하는 알루미늄에 의한 고용 강화 효과와 금속간화합물의 석출 빈도 증가, 그리고 레이저 용접의 특징인 급열급랭 공정에 기인한 결정립 미세화의 영향 때문으로 사료된다. 한편 용접부 미세조직을 관찰한 결과, 열영향부의 존재는 두드러지지 않았으며 용융경계부에서는 주상정이, 그리고 용접부 가운데에서는 등축정이 관찰되었다.

• Applied Chemistry for Engineering
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• v.23 no.5
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• pp.456-461
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• 2012

To verify the utilization of biomass as energy, the combustion characteristic has been studied by an experimental combustion furnace under an isothermal and non-isothermal combustion. The wood pellet, rice straw and rice husk were used as biomass samples in this work. The characteristics of emission gases, dusts and residues from biomass combustion have been analyzed and compared with those of reuse derived fuel (RDF). From isothermal combustion experiments, it was found that the incomplete combustion of rice straw was greater that that of rice husk, wood pellet and RDF. This is due to the fact that the combustion reaction rate of the rice straw was faster than that of other samples, and the oxygen concentration in rice straw combustion was rapidly decreasing. It was also found that $NO_{X}$ concentration of emission gas from wood pellet combustion was the lowest. From non-isothermal combustion experiments, it was found that all samples were burned before $900^{\circ}C$. Also, the temperature range of $NO_{X}$ emission was similar to that of CO emission, on the other hand, $SO_{2}$ was emitted at a higher temperature than that of CO emission.