• Korean Journal of Materials Research
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• v.4 no.1
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• pp.55-62
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• 1994

Co(A $I_{1- X}$C $u_{X}$ ) (0$\leq$0.40)합금계의 결정구조 및 자기적 특성을 X-선 회절분석기, 주사전자현미경 그리고 진동 시료형 자력계를 이용하여 조사하였다. X-선 결정구조 및 상분석 결과, 전조성 범위에서 주상은 격자상수가 약 2.86$\AA$인 규칙화한 B2(CsCI)구조를 가지고 있었으며, x $\geq$0.10범위에서는Cu함량이 많은 제 2상이 존재하였고 격자상수가 약 3.63$\AA$인 FCC 구조이었다. 자화측정결과 x $\geq$0.25범위에서는 강자성, x$\leq$0.10에서는 상자성 그리고 x=0.15, 0.20에서는 초상자성의 특성을 나타내었다. Cu함량(x)이 증가함에 따라 자화값은 증가하는 현상을 보여주었다. 본 합금계의 측정한 분자당 스핀자기 모멘트 값은 국부환경모델을 이용하여 각 조성에서 계산된 Co원소에 대한 스핀자기 모멘트 값과 잘 일치함을 보여주었다.다.

• Korean Journal of Materials Research
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• v.7 no.1
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• pp.69-75
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• 1997

Thin films of $Si0_2(1000{\AA})/CoNiCr(400{\AA})/Cr$ were fabricated as a function of Cr thickness by KF magnetron sputtering. The saturation magnetization, coercive force and squareness with annealing temperature for these films were investigated. The values of saturation magnetization of $SiO_2/CoNiCr/Cr$ thin films decreased as the thickness of Cr underlayer increased, whereas coercive force increased as the thickness of Cr underlayer increased. The value of Ms was 600 emu/cc and the maximum value of Hc was 550 Oe. Especially, the value of saturation magnetization was rapidly decreased $SiO_2/CoNiCr/Cr(1700{\AA})$ thin films as the annealing temperature increased And the coercive force increased as the annealing temperature increased When annealing temperature was $650^{\circ}C$, the Ms was reduced to 90 % of the as-deposited film. And the Hc was showed maximum 1600 Oe. It was thought that Cr diffusion into CoNiCr layer reduced the magnetic moment of CoKiCr layer. In addition. Hc might he increased due to grain growth perpendicular to the film plane.

• Korean Journal of Materials Research
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• v.6 no.5
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• pp.470-474
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• 1996

증착법을 이용해 증착시 기판의 온도를 변화시키면서 MnSbPt 합금 박막을 만들고 이를 열처리 한 후 나타나는 자기 및 자기광학적 성질을 조사하였다. Mn45Sb45Pt10조성의 박막에서 0.85$^{\circ}$의 높은 Kerr Rotation Angle값을 나타내고, 또한 광원의 입사파장이 단파장으로 이동하여도 우수한 Kerr Rotation Angle 값을 유지함으로써 자기광 재료로서의 기록밀도 향상가능성이 기대된다. 이 재료가 갖고 있는 열악한 자기적성질도 열처리를 통하여 포화자화값과 보자력의 향상 효과를 얻었지만, 자기광 재료가 갖추어야할 수직자화를 얻기에는 미흡하여 이에 대한 보완이 필요하다.

• Journal of the Korean Magnetics Society
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• v.18 no.2
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• pp.63-66
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• 2008

In order to the magnetization and magnetic entropy change for superparamagnetic ferrite nanoparticles, ultrafine cobalt ferrite particles were synthesized using a mircoemulsion method. The peak of X-ray diffraction pattern corresponds to a cubic spinel structure with the lattice constant 8.40 $\AA$. The average particle size, determined from X-ray diffraction line-broadening using Scherrer's, is 7.9 nm. The maximal magnetizations measured at 5 and 300 K are 24.3 emu/g and 17.2 emu/g, respectively. Superparamagnetic behavior of the sample is confirmed by the coincidence of the M vs. H/T plots at various temperatures. According to the thermodynamic theory, magnetic entropy change decreases with increasing temperature.

• Journal of the Korean Magnetics Society
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• v.7 no.4
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• pp.191-195
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• 1997

$Co_{84}Hf_{16}$ (1300$\AA$, 2150$\AA$) thin films were prepared by dc magnetron sputtering method. To investigate the uniaxial anisotrpy of the sample, the saturation and effective magnetization of the thin films were measured by VSM and FMR, respectively. The spectroscopic splitting g factor were estimated from the ferromagnetic resonance curves. For 1300$\AA$, 2150$\AA$, the effective magnetization was measured at the temperatures from T=77K to T=300K. The results were analyzed in terms of Bloch's law $M_s(T)=M_s(0)(1BT^{3/2}CT^{5/2}$. The Bloch coefficient B and C were determined by fitting. $M_{eff}(0)$ was obtained by extrapolating $M_{eff}$ to 0 K. From this result, the spinwave stiffness constants D was also determined and the exchange stiffness constants $A_{eff}$ were calculated by Kittel's resonance conditions.

• Progress in Medical Physics
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• v.19 no.4
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• pp.269-275
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• 2008

Although MR imaging is generally applicable to depict knee joint deterioration it, is sometimes occurred to mis-read and mis-diagnose the common knee joint diseases. In this study, we employed magnetization transfer ratio (MTR) method to improve the diagnosis of the various knee joint diseases. Spin-echo (SE) T2-weighted images (TR/TE 3,400-3,500/90-100 ms) were obtained in seven cases of knee joint deterioration, FSE T2-weighted images (TR/TE 4,500-5,000/100-108 ms) were obtained in seven cases of knee joint deterioration, gradient-echo (GRE) T2-weighted images (TR/TE 9/4.56/$50^{\circ}$ flip angle, NEX 1) were obtained in 3 cases of knee joint deterioration, In six cases of knee joint deterioration, fat suppression was performed using a T2-weighted short T1/tau inverse recovery (STIR) sequence (TR/TE =2,894-3,215 ms/70 ms, NEX 3, ETL 9). Calculation of MTR for individual pixels was performed on registration of unsaturated and saturated images. After processing to make MTR images, the images were displayed in gray color. For improving diagnosis, three-dimensional isotropic volume images, the MR tristimulus color mapping and the MTR map was employed. MTR images showed diagnostic images quality to assess the patients' pathologies. The intensity difference between MTR images and conventional MRI was seen on the color bar. The profile graph on MTR imaging effect showed a quantitative measure of the relative decrease in signal intensity due to the MT pulse. To diagnose the pathologies of the knee joint, the profile graph data was shown on the image as a small cross. The present study indicated that MTR images in the knee joint were feasible. Investigation of physical change on MTR imaging enables to provide us more insight in the physical and technical basis of MTR imaging. MTR images could be useful for rapid assessment of diseases that we examine unambiguous contrast in MT images of knee disorder patients.

• Journal of the Korean Magnetics Society
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• v.9 no.4
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• pp.177-183
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• 1999

Ultrafine $CoFe_{1.9}Bi_{0.1}O_4$ particles were fabricated by using a sol-gel method and their magnetic and structural properties were investigated with an x-ray diffractometer (XRD), a vibrating sample magnetometer (VSM), and a M$\"{o}$ssbauer spectrometer. The result of x-ray diffraction and M$\"{o}$ssbauer spectroscopy showed that the powders fired at and above 523 K had only cubic spinel structures. M$\"{o}$ssbauer spectra measurements showed that the powders annealed at 523,723 and 823 K possessed ferrimagnetic nature and paramagnetic nature due to superparamagnetism, simultaneously at room temperature and the powders annealed at and above 923 K behaved ferrimagnetically. In the case of the powder annealed at 923 K, the lattice constant was $a_0=8.398$\pm$0.005{\AA}$ and the hyperfine fields were $H_{hf}(A)=479kOe,\; H_{hf}(B)=502kOe$. The isomer shifts indicate that the iron ions are ferric at tetrahedral[A] and octahedral sites [B], respectively. The magnetization as a function of annealing temperature increased as increasing annealing temperature. The largest coercivity values were $H_C=1368\;Oe$ AT 923 K annealing temperature. In the case of the powder annealed at 1123 K, the magnetization value was $M_S=75\;emu/g$ and this value was similler to that of $CoFe_2O_4$.Fe_2O_4$.

• 전기의세계
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• v.42 no.9
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• pp.20-27
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• 1993

1. 철근출막은 결정자기이방성의 영향이 작기 때문에, 자기특성이 막의 기하학적구조에 의해 거의 결정되고 그것에 의하여 자성막의 설계가 가능하다. 2. 코발트 근출막은 결정자기이방성이 자기특성에 영향은 크기때문에 코발트 결정의 자화용역축(C축)의 배향에 의하여 자기특성은 크게 변한다. 따라서 이 C축의 배향성을 변화시켜 석출입자의 형태를 바꾸지 않고 작은 포아직경에서도 항자력의 제어가 가능하였다. 3. 코발트-철합금신출막은 조성변화에 의하여 자기특성을 제어할 수 있다. 또 ㅈ포화자화, 항자력도 철을 석출한 자성막에 비해서 높은 값을 나타냄을 물론, 우수한 각형화(Mr/Ms)로 얻어지는 큰 자기에너지적으로 수직 자기기록방식의 고정밀의 로타리 엔코다에의 응용이 유망하다.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2017.05a
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• pp.161.2-161.2
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• 2017

희토류계 영구자석은 대부분의 전기, 전자 제품의 핵심부품이며 높은 보자력, $BH_{max}$를 가지고 있어 자기기록저장매체, MEMS(엑츄에이터), 소형센서, 소형모터 등의 응용 분야에 적용시키기 위해 다양한 연구들이 진행되고 있다. 그러나 영구자석에 들어가는 희토류계 원소의 수급의 어려움 및 가격의 문제점으로 친환경 자석으로의 전환 및 희토류나 중희토류를 사용하지 않는 비희토류계 영구자석을 제조 및 개발하는데 많은 연구가 이루어지고 있다. 이 중 Fe-N 계 자성물질인 $Fe_{16}N_2$는 포화 자화 값이 현재까지의 비희토류계 자성물질 중 가장 높은 값(240emu/g)을 나타내며 상대적으로 높은 결정자기이방성 상수를 가지고 있어 비희토류계 영구자석 물질 중 하나로 주목받으며 연구되어지고 있다. 본 연구에서는 $Fe_{16}N_2$ 박막을 얻기 위해 DC Magnetron Sputtering 방법을 이용하여 Si wafer 위에 박막을 증착하고 증착시간에 따라 두께를 제어하여 제조한 후 박막의 미세구조, 상 분석, 자성 특성을 관찰을 통해 최적의 공정 조건을 찾고자 하였다. 증착 시간에 따른 박막의 성장 속도는 일정하게 증가하였으며, 증착 시간의 증가에 따라 박막 내 $Fe_{16}N_2$의 상대적인 분율은 감소하였다. 모든 공정 조건에서 $Fe_3N$, $Fe_4N$, $Fe_{16}N_2$ 상들이 섞여 성장하였으며 XRD를 통한 상분석과 더불어 VSM을 통한 자성 특성을 분석해본 결과 $Fe_{16}N_2$의 분율을 가장 높게 성장된 공정 조건은 증착 시간이 10분이며 박막의 두께가 ${\sim}1{\mu}m$ 일 때, 최적의 조건을 얻을 수 있었으며, 이 때의 자성 특성을 분석한 결과 ~2.45T의 포화 자화 값과 ~1.41T의 잔류 자화 값을 얻을 수 있었다.

• Journal of the Korean Magnetics Society
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• v.19 no.6
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• pp.209-215
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• 2009

M-type barium ferrite (BaFe12O19) powders were synthesized through the co-precipitation method. Starting material composition $Fe^{3+}:\;Ba^{2+}$ mole ratio was fixed as 8 and the relative amount of $Fe^{3+}$ and $Ba^{2+}$ was controlled. Structure and magnetic properties and powder morphology were investigated using XRD, SEM, VSM. Powder showing high coercivity and small magnetization was obtained at pH8 and $Fe_{3+}:\;Ba_{2+}$ of 12 : 1.5. Small magnetization value was originated from the existence of ${\alpha}-Fe_2O_3$. Single-phase Mtype barium ferrite were obtained regardless of the heat treatment condition and the amount of $Fe_{3+}\;and\;Ba_{2+}$ at pH$\approx$10. The largest value of magnetization (55.7 emu/g) under investigation were obtained when $Fe_{3+}:\;Ba_{2+}$ of 13.6 : 1.7 and furnace cooled powder in $O_2$. Particle size of powder was in the range of 50~200 nm.