• Title/Summary/Keyword: 자유에너지

Search Result 710, Processing Time 0.028 seconds

Total temperature investigation in free & wall jet regions (고속 자유/벽 제트 영역에서의 총온도 특성 고찰)

  • Jung Hyungab;Lee Jangwoo;Yu Mansun;Cho Hyunghee;Hwang Kiyoung;Bae Ju chan
    • Proceedings of the Korean Society of Propulsion Engineers Conference
    • /
    • v.y2005m4
    • /
    • pp.329-333
    • /
    • 2005
  • Total temperature distribution in high speed fee & wall jet regions was investigated using the total temperature probe. For the free jet, the distance of probe from the nozzle exit is changed in the range of 1, 2, 4 and 6 times o nozzle exit diameter. Energy separation phenomenon was observed on shear layer between jet and ambient. In wall jet region, impinging plate was fixed at Z/D=2 and total temperature distribution has been measured for various radial distance($R/D=1.25\sim2.0$). Energy separation phenomenon was found at wall jet boundary and near wall, and was compared with measured adiabatic wall temperature value.

  • PDF

Free Vibrations and Strain Energy Anaylsis of Antisymmetric Cross-ply Laminted Plates (역대칭(逆対称) Cross-ply 다층판(多層板)의 자유진동(自由振動) 및 변형 에너지 해석(解釋))

  • Park, Moon Ho;Jin, Yoshimura;Takashi, Mikami;Park, Sung Jin
    • KSCE Journal of Civil and Environmental Engineering Research
    • /
    • v.11 no.4
    • /
    • pp.37-44
    • /
    • 1991
  • A powerful analytical procedure and strain energy analysis to investigate the free vibration of antisymmetric cross-ply laminated plates, having one pair of opposite edges simply supported, are develped on the basis of the Yang, Norris abd Stavsky (YSN) theory. The equation of motion of the plate are solved by the use of collation method. A range of results are presented for plates to show the effects of modulus ratio and number of layers on natural frequency. In addition, an analysis of the strain energy distributions is used as an aid for the better understanding of the vibration characteristics of the plates.

  • PDF

Thermodynamics of Meso substituted Thiacarbocyanines in Solution

  • 손세모
    • Journal of the Korean Graphic Arts Communication Society
    • /
    • v.18 no.2
    • /
    • pp.125-132
    • /
    • 2000
  • To take an information of substitutent effect and thermodynamic of association at thiacarbocyanines, association constant $K_{D}$, free energy of association $\Delta$ $G_{D}$, enthalpies of association $\Delta$ $H_{D}$ were measured by spectrophotometer according to dependence on concentration of dyes and temperature of aqueous MeOH system. With increase of concentration dyes or decrease of temperature of aqueous MeOH system, absorption spectra of dyes exhibited equlilibria shift toward the dimer. Phenyl meso substituted thiacarbicyanine, DyeIII, resulted in higher $K_{D}$ and $\Delta$ $G_{D}$ values than DyeI and DyeII. To easily make an association of thacarbicyanine, meso substutituent group need to be a flat structure, which will make a park as well as lain tiles.tiles.ructure, which will make a park as well as lain tiles.les.

  • PDF

HDM2-p53 상호작용 억제제 개발에서의 탄화수소체인의 역할과 중요성

  • Yeo, Jin-Hui;Im, Hae-Ri;Ham, Si-Hyeon
    • Proceeding of EDISON Challenge
    • /
    • 2017.03a
    • /
    • pp.158-164
    • /
    • 2017
  • 암을 억제시키는 기능을 하는 단백질로 잘 알려진 p53은, 주로 종양세포에서 과도하게 발현되는 단백질인 HDM2와 복합체를 형성하여 비활성화되고 항암기능을 상실하게 됩니다. 때문에 종양세포에서의 p53-HDM2의 상호작용을 억제하기 위해 현재까지 많은 연구가 진행되어왔으며, 다양한 p53-HDM2 억제제가 개발된 바 있습니다. 최근 연구들에 따르면, HDM2와 결합친화도를 높이고 소수성 작용(hydrophobic interaction)에 기여하여 보다 안정한 구조를 만드는 탄화수소체인(staple)을 연결시킨 펩타이드 설계에 대한 관심이 높아지고 있는 추세입니다. 이에, 본 연구에서는 분자동역학 모의실험을 통해서 얻은 탄화수소체인-p53과 비탄화수소체인-p53 및 각각의 HDM2와 결합한 복합체를 기반으로 EDISON의 용매화 자유에너지(Solvation Free Energy) 프로그램을 이용하여 탄화수소체인의 특징 및 역할을 구조적인 측면과 열역학적인 측면으로 분석하여 비교하고자 합니다. 우리 연구에서 비탄화수소체인-p53의 구조는 분자동역학 시뮬레이션을 수행하는 동안 나선구조형태로 풀려 HDM2와 결합 유도 시에 주요결합 아미노산 잔기가 올바른 결합부위와 상호작용하지 못한 결과를 확인한 반면, 탄화수소체인이 형성된 구조는 시뮬레이션 동안에도 펩타이드의 나선구조를 유지시켜 HDM2와 주요 결합을 형성하는 아미노산 잔기들을 올바른 방향으로 배치시켜 HDM2와의 결합친화도를 높였습니다. 이 연구 결과는 탄화수소체인이 펩타이드의 나선성을 유지시키고, HDM2와의 상호작용을 통한 구조적인 안정성 유도 및 용매화 자유에너지에 큰 기여를 통해 p53-HDM2상호작용 억제제에서 긍정적인 역할을 할 가능성을 보여줍니다.

  • PDF

Estimation of Activation Energy for the Free Radical Polymerization by Using Isoconversional Analysis (등전환 분석(Isoconversional Analysis)를 이용한 자유라디칼 중합의 활성화 에너지 계산)

  • Chung, I.
    • Elastomers and Composites
    • /
    • v.39 no.4
    • /
    • pp.281-285
    • /
    • 2004
  • In this paper, the simple way to evaluate the value of the activation energy for the overall rate of free radical polymerization by using DSC thermograms was studied using free radical polymerization or butylacrylate as a model. Activation ehergies were determined at heating rates of 1, 2, 5, and $10^{\circ}C/min$ by applying the multiple scanning-rate methods of Kissinger, Osawa, and half-width methods as well as the single rate method of Barrett. The value of the overall activation energy measured was closely matched with the values calculated from individual data. This work also demonstrated that the use of the isoconversional method was a simple and effective way to estimate the activation energy for the overall free radical polymerization.

Power Conditioning System for Single Phase Linear Generation System of Free Piston Engine (자유 피스톤 엔진용 단상 선형 발전시스템을 위한 전력제어시스템)

  • Kwak, Bongwoo;Kim, Jonghoon;Kim, Myungbok
    • Proceedings of the KIPE Conference
    • /
    • 2017.07a
    • /
    • pp.431-432
    • /
    • 2017
  • 본 논문은 자유 피스톤 엔진에 적용되는 단상 선형발전기용 전력제어시스템에 관한 연구이다. 자유 피스톤 엔진 선형발전시스템은 피스톤의 움직임을 구속하는 기구가 없기 때문에 기계적 마찰 손실이 적고 상사점 도달 시간이 짧아 에너지 효율측면에서 기존의 피스톤 엔진보다 유리한 기술이다. 하지만, 자유 피스톤 엔진의 경우 초기 기동 할 수 있는 동력원이 필요하며, 단상 선형 발전기의 경우 짧은 스트로크 및 낮은 속도로 인해 인덕턴스가 크게 설계 되어, 높은 인덕턴스로 인한 전류의 위상 지연으로 역률이 낮아지게 되고, 응답성이 떨어지는 문제점을 가지고 있다. 이러한 문제점을 해결하기 위해 본 논문에서는 역률 보상 및 응답성을 높일 수 있는 자유피스톤 엔진용 단상선형발진기용 전력제어시스템을 제안한다.

  • PDF

A study on the Gasifier Modeling using a Chemical Equilibrium (화학평형을 이용한 가스화기 모델링에 관한 연구)

  • 정근모;임태훈;오인환;박명호
    • Journal of Energy Engineering
    • /
    • v.2 no.3
    • /
    • pp.276-284
    • /
    • 1993
  • This study is to obtain some basic data which are prerequisite for the conceptual design of gasification process based on entrained-bed type gasifier. The Gibbs free energy minimization method is used to analyze the chemical equilibrium in the gasifier. The modeling results which consider the conventional mass balance and heat balance are compared with the experimental data published by Electric Power Research Institute. The analysis shows that the reaction in a entrained-bed gasifier is influenced mainly by the amount of oxidant, by the temperature of gasifier and by the type of coals.

  • PDF

The Research of Vibration Power Generation with Two Degree of Freedom Using Ocean Wave (파도를 이용한 2자유도 파력진동발전시스템에 대한 연구)

  • Han, Ki-Bong;Lee, Hyoung-Woo
    • Journal of Advanced Marine Engineering and Technology
    • /
    • v.35 no.8
    • /
    • pp.1028-1034
    • /
    • 2011
  • This paper have been studied that ocean wave power vibration generation system with two D.O.F.(degree of freedom) consists of buoy and vibration generation system with two D.O.F. for using efficiency of ocean wave energy. It selected main frequencies ${\omega}_1$, ${\omega}_2$ in frequency with ocean wave and it fitted them to the natural frequencies of vibration system with two D.O.F. in the vibrational power generation system. Then each the relative velocity of between the winding coil and the permanent magnet is faster than the velocity of ocean wave up and down motion by resonance phenomenon. Also the ocean wave power generation with two D.O.F. obtained the more electric energy then the ocean wave power generation with one D.O.F. by coupling effect for two D.O.F. vibration system. Therefore ocean wave power vibration generation system with two degree of freedom that is proposed in this paper has merits which not only using more energy in the ocean wave but also obtaining more electronic energy.