• Proceedings of the Korean Vacuum Society Conference
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• 2010.02a
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• pp.78-78
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• 2010

그래핀(Graphene)은 탄소원자가 육각형 벌집(honeycomb)구조로 빼곡히 채워진 2차원의 단원자 층으로 역학적 강도와 우수한 화학적/열적 안정성 및 흥미로운 전기 전도 특성을 가지고 있다. 이러한 그래핀의 우수한 특성으로 인하여 현재 기초연구뿐만 아니라 응용연구 등 많은 연구들이 진행되고 있다. 일반적으로 그래핀의 우수한 물리적 특성들은 그래핀의 층수, 모서리(edge)구조, 결함(defect), 불순물 등에 의해 크게 좌우되는 것으로 알려져 있다. 따라서 그래핀의 구조 및 결함정도를 자유로이 제어하고 그에 따르는 특성 변화를 관찰하는 것은 기초연구의 측면에서 뿐만 아니라 향후 그래핀 응용에 있어서도 매우 중요하다고 할 수 있다. 본 연구에서는 그래핀의 내산화 특성을 연구하기 위하여, 그래핀을 열 및 플라즈마 산화 분위기에 노출시킨 후, Raman 분광법을 이용하여 광학적, 구조적 변화를 분석함으로써 그래핀의 내산화 특성에 대하여 조사하였다. 그래핀은 실리콘 웨이퍼에 전자빔증착법으로 니켈박막을 증착한 후 열화학증기증착법으로 합성하였으며, 메탄가스를 원료가스로 $900^{\circ}C$ 전후에서 합성하였다. 합성한 그래핀은 산화반응 시 기판의 영향을 제거하기 위하여 트렌치 구조의 기판 위에 전사(transfer)함으로써 공중에 떠있는 구조를 구현하였다. 열 산화의 경우, 합성한 그래핀을 대기분위기의 고온($500^{\circ}C$) 챔버에 넣고 처리시간에 따른 특성변화를 살펴보았다. 플라즈마 산화의 경우는 공기를 이용하여 직류플라즈마를 발생시킨 후 0.4 W의 낮은 플라즈마 파워를 이용하여 플라즈마 산화처리와 특성평가를 매회 반복하였다. 그래핀의 특성분석은 Raman분광기와 광학현미경, 원자힘현미경(AFM) 등을 이용하여 분석하였으며, 상기 결과들은 향후 산화환경에서의 그래핀 응용소자 개발에 유용할 것으로 예상된다.

• Economic and Environmental Geology
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• v.56 no.2
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• pp.167-183
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• 2023

Gases originated from the final SNF (spent nuclear fuel) disposal site are very mobile in the barrier and they may also affect the migration of radioactive nuclides generated from the SNF. Mechanisms of gas-nuclide migration in the multi-barrier and their influences on the safety of the disposal site should be understood before the construction of the final SNF disposal site. However, researches related to gas-nuclide coupled movement in the multi-barrier medium have been very little both at home and abroad. In this study, properties of gas generation and migration in the SNF disposal environment were reviewed through previous researches and their main mechanisms were summarized on the hydrogeological evolution stage of the SNF disposal site. Gas generation in the SNF disposal site was categorized into five origins such as the continuous nuclear fission of the SNS, the Cu-canister corrosion, the oxidation-reduction reaction, the microbial activity, and the inflow from the natural barriers. Migration scenarios of gas in porous medium of the multi-barrier in the SNF repository site were investigated through reviews for previous studies and several gas migration types including ① the free gas phase flow including visco-capillary two-phase flow, ② the advection and diffusion of dissolved gas in pore water, ③ dilatant two-phase flow, and ④ tensile fracture flow, were presented. Reviewed results in this study can support information to design the further research for the gas-nuclide migration in the repository site and to evaluate the safety of the Korean SNF disposal site in view points of gas migration in the multi-barrier.

• Journal of the Korean Institute of Gas
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• v.4 no.1 s.9
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• pp.1-8
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• 2000

Third party damage is one of the causes intrimiting the safety of a buried pipelines and it is very important to detect third party damage on pipelines as soon as possible. The purpose of this study is whether third-party damage can be detected by accelerometer sensor and how far the third-party damage signal can propagate. And a pilot experiment was carried out in order to find third-party damage location. As a result, the detected signal's spectum is high frequency at short distances, as the distance is far, the signals in high frequency range are attenuated and those in low frequency range remain. It was also proved that third-party damage within 5.3km distance can be detected by monitoring vibration signals.

• Journal of Korean Society of Environmental Engineers
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• v.32 no.3
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• pp.241-247
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• 2010

The Effects of operating parameters such as initial pH, gaseous ozone concentration, supplied gas flow rate on dissolved ozone concentration and phenol degradation in ozone contact reactor were investigated. Dissolved ozone concentrations were saturated to constant values after a certain ozone contact time. The saturation values were influenced by experimental parameters. Dissolved ozone concentration decreased with the increase of initial pH because the ozone is unstable in high pH regions. The gaseous ozone concentration in a constant gas supply affected the saturation concentration of dissolved ozone and the injection rate of gas with a constant ozone concentration determined the rate to reach dissolved ozone saturation. Effects of operating parameters on phenol degradation were closely related with those of parameters on dissolved ozone concentration. Phenol degradation was enhanced by the increase of initial pH, because the degradation of dissolved ozone gave birth to free radicals which have much higher reactivity with phenol. Increase of gaseous ozone concentration and gas flow rate promoted the phenol degradation through the generation of dissolved ozone which plays the role in phenol degradation. The injection of methanol deteriorated the phenol degradation through the scavenging effect on OH radicals.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.39 no.10
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• pp.1029-1037
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• 2015

Recently, the importance of rotordynamic stability has been increased because of the tendency to employ ultra-high speeds in rotating machinery. In particular, the dynamic characteristics of gas bearings for high-speed rotating machinery need to be identified at various excitation frequencies to predict the rotor's behavior. In this study, we perform dynamic loading tests for gas-foil bearings (GFBs) to determine the bump foil structure and an air-film combined bump-foil structure for varying excitation frequencies. We calculate the dynamic characteristics from the measured force and displacement data. The air film is generated by a pressurized air supply. Based on the results, the stiffness coefficients of the bump structure and the air-film combined bump structure increased, while the damping coefficients decreased at increasing excitation frequencies. Further, the stiffness and damping coefficients of the air-film combined structure show lower values than those of the bump structure. Consequently, we identify the frequency-dependent dynamic characteristics of the bump structure and the effect of gas film on the dynamic characteristics of GFBs. Furthermore, to reveal the effectiveness of the proposed method, we perform experiments and discuss two methods of extracting the dynamic characteristics from the measured data.

• Plant Journal
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• v.9 no.3
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• pp.38-42
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• 2013

Submarine gas fields have focused because of the increasing fuel cost, the environmental regulations, and the safety & NIMBY problems. LNG-FPSO which is available for acid gas removal, recovery of the condensate & LPG and Liquefaction in topside process is one of high technology offshore structures. On the other hands, it is necessary to verify the pre-treatment efficiency by the ship motion and to apply to the design for LNG-FPSO. This study is to develop the pre-treatment technology for LNG-FPSO as taking account to the process efficiency by ship motion effects and the area optimization. Based on the simulation results, it founds that hybrid process shows the low circulate rate, the low heat duty and the small size of column dimensions compared to typical amine process. It will be verified the process efficiency in the various conditions by sea states as performing the 6-DOF motion test and CFD simulation.

• Proceedings of the KSME Conference
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• 2001.06e
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• pp.323-328
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• 2001

Supersonic coaxial, axisymmetric, jets issuing from various kinds of dual coaxial nozzles were experimentally investigated. Four different kinds of coaxial, dual nozzles were employed to characterize the major features of the supersonic, coaxial, dual jets. Two convergent-divergent supersonic nozzles with an impinging angle in the jet axis of the annular jets were designed to have the Mach number 2.0 and used to compare the coaxial jet flows with those discharging from two sonic nozzles. The primary pressure ratio was changed in the range from 4.0 to 10.0 and the assistant jet ratio from 1.0 to 4.0. The results obtained show that the assistant jets from the annular nozzle affect the coaxial jet flows and an increase of both the primary jet pressure ratio and assistant jet pressure ratio produces longer supersonic length of the dual, coaxial jet.

• Proceedings of the KIEE Conference
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• 2006.11a
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• pp.108-110
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• 2006

계량기의 시장이 독점 시장에서 자유 시장으로 천이 되면서 시장은 계량기의 상호운용능력과 계량기의 지능, 관리능력 그리고 보안등의 부가적인 기능들을 요구 하게 되었다. 이러한 시장의 요구에 맞추어 DLMS 프로토콜을 표준으로 하고 COSEM 오브젝트 모델링 기법을 사용하는 계량기 표준인 IEC 62056이 제정되었다. 본 논문에서는 IEC 62056에서 정의한 프로토콜 및 서비스에 적합한 DLMS/COSEM 계량기의 S/W 아키텍처 및 그 설계 방법을 제안한다. 계량기 S/W는 크게 MCS와 MOM으로 구성되며, MCS는 계량기의 모델링 스크립트로 COSEM 오브젝트와 계량기의 구체적인 기능을 명시하고, MOM은 MCS를 읽어 계량기를 구동 시키는 모듈로 MCS에서 선언된 기능 및 동작을 해석하여 계량기를 전기, 가스, 수도 등의 기능을 갖는 계량기로 동작시키는 역할을 한다.

• Proceedings of the Korean Society of Precision Engineering Conference
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• 1996.11a
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• pp.538-541
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• 1996

The flow of the molten drop in the GMAW was observed to explain the mechanism of its formation and break-up process. Fluid flew analysis was made with the assumption that the electrode wire acts like fluid, and it is shown how the convection of the drop inside affects its flow, from the formation to the break-up of the drop. In later part, the process of the spray mode development at high current is shown, as well as the one of the globular mode, by the fluid flow analysis.

• Proceedings of the KIEE Conference
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• 1998.07b
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• pp.781-786
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• 1998

Since a gas turbine is still a significant contributor to peak time, it is very important to tune the gains of P. I. D to get a maximum power and stability within permissible limits. In the gas turbine, the main control loop must adjust the fuel flow to ensure the correct output power and frequency. but it is not easy, because the control loop is composed of many subsystems. In this paper we acquire a transfer function based on the operations data of Gun-san gas turbine and study to apply a loop compensation type 2-DOF PID controller tuning by neural-network to control loop of gas turbine to reduce phenomena caused by integral and derivative actions through simulation. We obtained satisfactory results to disturbances of subcontrol loop such as, fuel flow, air flow, turbine extraction temperature.