• Title/Summary/Keyword: 자외선 흡수도

Search Result 293, Processing Time 0.027 seconds

Effect of UV-Absorber Treatment on the Mechanical Properties of Cotton Fabrics (자외선 차단 가공에 의한 면직물의 역학적 특성 변화)

  • Kwon, Young-Ah;Kang, Mi-Jung;Cho, Hyun-Hok
    • Journal of the Korean Society of Clothing and Textiles
    • /
    • v.26 no.12
    • /
    • pp.1701-1708
    • /
    • 2002
  • 본 연구의 목적은 자외선 차단 가공 처리 및 자외선 조사처리에 의해 면직물의 역학적 특성 변화를 조사하고 가공제 처리조건에 따른 차이점을 분석하는 것이다. 시료로는 100% 면직물을, 자외선 흡수제로 2,2'-dihydroxy-4,4'-dimethoxy benzophenone을, 첨가제로 Triton X-100, polyethylene glycol 400, MgCl$_2$.6$H_2O$를 사용하였다. 자외선 흡수제 처리는 Atlas Launder-O-meter로 75$^{\circ}C$에서 60분간 흡진법으로 하였다. 미처리 시료 및 처리시료는 모두 xenon 램프에 80시간 동안 노출되었으며, 자외선 조사 전후 시료의 역학적 특성은 KES-F시스템을 사용하여 측정하였다. 본 연구의 결과는 다음과 같이 요약할 수 있다. 자외선 흡수제 처리는 처리 농도에 상관없이 면직물의 선형인장성(LT), 인장레질리언스(RT), 굽힘강성(B), 굽힘이력(2HB), 전단강성(G), 전단이력(2HG5), 표면마찰계수(MIU)등을 증가시켰으며 표면거칠기(SMD)는 감소시켰다. 압축특성은 처리농도의 영향을 받아서 고농도의 자외선 흡수제 처리는 압축특성을 감소시켰으며, 저농도의 처리는 압축특성을 증가시켰다. 자외 선 흡수제 처리는 처리농도에 상관없이 면직물의 fullness/softness를 유의하게 증가시키는 반면 stiffness, crispness및 anti-drape stiffness를 감소시켜서 가공포의 종합태(THV)는 가공 전에 비하여 저하하였다. 자외선 조사는 가공 전 면직물의 경우 B, 2HB, G, 2HG, 2HG5, LC를 감소시켰다. 자외선 조사는 처리농도와 상관없이 가공포의 WT, 굽힘특성 , 전단특성을 감소시켰으며, 저농도의 흡수제 처리포의 경우 SMD를 증가시켰으며, 고농도의 흡수제 처리포의 경우 SMD를 감소시켰다. 자외선 조사는 처리농도와 상관없이 가공포의fullness/softness, stiffness, anti-drape stiffness를 유의하게 감소시켜서 자외선 조사 전 보다 THV가 37% 저하하였고 미 가공포의 THV를 저하율보다는 저하가 낮았다. 자외선 흡수제 처리에 의해 면직물의 태는 가공 전보다 감소하지만, 자외선 흡수제 처리는 자외선 조사에 의한 태 감소율을 낮추는 데 유의 한 효과가 있다.

UV Blocking Coatings by Combination of Organic-inorganic Hybrid materials and UV absorbers (유-무기 하이브리드 재료와 자외선 흡수제의 배합에 의한 자외선 차단 코팅)

  • Yu, Dong-Sik;Lee, Ji-Ho;Do, Young-Woong;Park, Seong-Ae;Ha, Jin-Wook
    • Proceedings of the KAIS Fall Conference
    • /
    • 2006.11a
    • /
    • pp.313-316
    • /
    • 2006
  • 눈은 자외선과 가시광선에 노출되어 있다. 눈은 자외선 노출에 해로우므로 모든 자외선으로부터 눈을 보호해야 한다. 본 연구에서는 자외선 차단을 위해 투명 플라스틱에 유-무기 하이브리드 재료와 자외선 흡수제의 배합에 의한 자외선 차단 코팅하였고, PMMA, CR 39 및 PC기재에 적용하여 자외선 차단 효과를 조사하였다. 자외선 흡수제의 양이 증가할수록 자외선의 투과도는 낮았다. PMMA의 경우 자외선 투과도를 현저히 감소시켰으며 CR 39에서도 자외선 차단 효과가 있는 것으로 나타났다. 한편, PC자체에서는 자외선 차단효과가 있는 것으로 평가되었다. CR 39 렌즈의 부착력, 내약품성, 내온수성은 우수하였고, 연필 경도의 경우 4H였으며 내마모성은 좋지 않았다.

  • PDF

The effect and stability of plant extract ingredient as uv absorber (자외선 흡수제로서의 식물추출성분의 안정성과 효과)

  • 김경동;이용두;박성순;윤성화;이석현
    • Journal of the Society of Cosmetic Scientists of Korea
    • /
    • v.26 no.1
    • /
    • pp.41-58
    • /
    • 2000
  • Recently the harmfulness of W radiation is in creasing due to encironmental pollution. Environmental population may also play a role in global decrease of ozone layer, A major consequence of ozone depletion is increase in solar ultra violet radiation received at the earth's surface excessive exposure to W radiation cause a lot of problems in our skin. Plant extract that possess antioxidative activities has been reported to retard the oxidation process in product to which they have been added. Plant are alived under solar light. So it is expect the plants have so many protection mechanisms and UV absorbent ingredients against ultra violet radiation such as UVB, UVA. Plant extract which were flavonoids, alkaloids and others could be transformed into UV absorber by chemical modification. Therefore with the aim of finding alternative natural absorber that can safely be used in cosmetic, we have screened various extract for their UV absorbent effect. Thus, the cosmetic safety against human skin, antimicrobial effects and others could be improved by using the silicon.

  • PDF

UV Blocking Coatings by Combination of Organic-inorganic Hybrid Materials and UV absorbers (유-무기 하이브리드 재료와 자외선 흡수제의 배합에 의한 자외선 차단 코팅)

  • Yu, Dong-Sik;Lee, Ji-Ho;Ha, Jin-Wook
    • Journal of the Korea Academia-Industrial cooperation Society
    • /
    • v.7 no.6
    • /
    • pp.1296-1301
    • /
    • 2006
  • The human eye is exposed to UV and visible light. UV light exposure becomes harmful to the eye. Protection for eyes should block all ultraviolet rays. In our study, organic-inorganic hybrid materials have been applied to UV blocking coatings with UV absorbing materials on transparent plastics. The optical properties of UV blocking coatings were investigated in PMMA, CR 39 and PC substrates. In case of all UV absorbers, the transmission of UV light decreases with an increased amount of absorber. Our findings indicate that PMMA significantly reduced the transmission of UV radiation, CR 39 showed moderate decrease, while UV-uncoated PC had some UV blocking properties. Adhesion, hot water resistance and chemical resistance of the UV-coated CR 39 lenses were good. Pencil hardness were 4H. Abrasion resistance were poor.

  • PDF

국내산 해조류 중의 자외선 흡수 물질의 분포

  • 박진희;박병직;한태준;구재근;조만기
    • Proceedings of the Korean Society of Fisheries Technology Conference
    • /
    • 2000.10a
    • /
    • pp.187-188
    • /
    • 2000
  • 최근 자외선 차단제의 사용이 증가하면서 자외선 차단제 도포로 인한 자극성 피부염, 접촉 피부염, 광알레르기성 또는 광독성 피부염 등의 보고가 증가하고 있어 피부에 자극이나 알레르기 반응, 독성을 나타내지 않는 적절한 천연소재 자외선 차단제의 개발에 대한 필요성이 증대되고 있다. 이에 본 연구에서는 새로운 자외선 차단제 개발을 위한 기초 자료를 확보하기 위하여, 국내산 해조류 중의 자외선 흡수 물질의 분포를 조사하였다. (중략)

  • PDF

New Photochemistry of UV-Absorbing Chemicals in Phase-Controlled Polymer Microspheres (상구조가 조절된 고분자 미립구에서 자외선 흡수제의 거동에 대한 연구)

  • Lee Jong-Suk;Kim Jin-Woong;Kim Junoh;Han Sang-Hoon;Chang Ih-Seop
    • Journal of the Society of Cosmetic Scientists of Korea
    • /
    • v.30 no.3 s.47
    • /
    • pp.361-367
    • /
    • 2004
  • In this study, a different UV (ultra-violet) ray absorption system is presented in which butyl methoxydiben-zoylmethane (BMDM, a model UV-A absorbent, 320$\~$400 nm) is stabilized in phase-controlled poly(methyl methacrylate) (PMMA) microspheres. The photochemistry of BMDM in the microspheres was investigated considering its phase characteristics therein. The analysis of a differential scanning calorimeter and X-ray diffractometer showed that the BMDM in the microspheres was present with a non-crystalline state. The phase control of BMDM in the polymer microsphere has an excellent ability to protect UV-A with maintaining its photo- and thermal stability. The results obtained in this study illustrate well that the phase control of the UV absorbents in the polymer microspheres is another key factor that de-termines its photochemistry and photostability in the final formulations.

Research and Application for Natural Extract That Contain Ultraviolet Rays Absorbent Ingredient (자외선 흡수 활성 성분을 함유한 천연추출물에 대한 연구와 응용)

  • 김경동
    • Journal of the Society of Cosmetic Scientists of Korea
    • /
    • v.30 no.1
    • /
    • pp.117-122
    • /
    • 2004
  • Exessive UV radiation causes a lot of problems in our skin. In order to find out the alternative UV absorber that can safely be used in cosmetics, we have screened various natural extracts in terms of their UV absorbing effect. Some natural extracts, which possess antioxidative activities, have also been found to retard the oxidation process in our experiment. Natural compound such as 7-hydroxycymopol, baicalein, etc. could be transformed into adjuvant UV absorber by chemical modification. In cosmetics, its chemical stability against UV radiation, exposure to oxygen and other factors could be improved by using the silicone or W/S type emulsion. The values of MED (minimal erythema dose) were improved to 0.10 ${\pm}$ 0.02∼0.11 ${\pm}$ 0.02 by adding this natural extract into the cosmetic formulations. In conclusion, the results of the present study show that natural extracts could be used as an adjuvant UV absorber, if they are stabilized.

Stability and Sun Protection Efficacy of Sunscreens Based on the Solubility and a Combination of Organic UV Absorbers (유기 자외선 흡수제의 조합과 용해도에 따른 자외선 차단 효율의 비교 및 안정성에 관한 연구)

  • Yeon, Jae Young;Hong, Seung Deok;Choi, Se Bum;Kim, Ta Gon;Lee, Cheong Hee;Lee, Sang Gil;Pyo, Hyeong Bae
    • Journal of the Society of Cosmetic Scientists of Korea
    • /
    • v.41 no.3
    • /
    • pp.189-199
    • /
    • 2015
  • In this study, we have investigated the stability of sunscreens based on the solubility of organic UV absorbers in the oil and sun protection efficacy of the products composed of a combination of organic UV absorbers to develop more stable and efficient sunscreen products. Results showed that the solubility of the organic UV absorber and stability were varied depending on the type, storage conditions and concentration of oil. It was also observed from the products in the emulsion type. Various UV absorbances were determined to the products composed of the combination of organic UV absorbers. In some combinations, a synergistic effect was observed to make an increase in absorbance compared to a single component. In other cases, specific synergistic effect was displayed only when combined with the particular component. In addition, the storage condition also affected the sunscreen efficacy. In conclusion, this study confirmed that there are various factors which could affect the UV-blocking efficiency of sunscreen products.

UV Absorbent-added Polymerization and its Application as Ophthalmological Material (자외선 흡수제를 첨가한 고분자 중합 및 안 의료용 소재로의 적용)

  • Sung, A-Young;Kim, Tae-Hun;Ye, Ki-Hun
    • Journal of the Korean Chemical Society
    • /
    • v.55 no.1
    • /
    • pp.98-103
    • /
    • 2011
  • This study was done for the preparation of macromolecular material with UV-blocking features by adding the benzophenone group that is commonly used as a UV-absorbent and $TiO_2$ which is known to be a very stable material in chemical and physical aspects. Also, we compared the level of UV absorbency of the polymer produced from polymerization with previous materials and measured basic properties such as water content, refractive index and optical transmittance of produced contact lenses. The results of the measurement showed that the refractive index and water content of the contact lens with added UV-absorbent was 1.430~1.440 and 35.0~45.0% respectively, which was similar to that of previous contact lenses. Also, for optical transmittances of each wave length, contact lenses without the UV-absorbent was 89%, 88% and 89% respectively for UV-A, UV-B and visible light, indicating that the UV transmittance is very high though contrary with cases of contact lenses with added 2-hydroxy-4-methoxy-benzophenone and 2,4-dihydroxy-benzophenone which showed transmittances of 0% and 6% respectively for UV-A and UV-B showing a UV-blocking effect. Meanwhile, contact lenses with added $TiO_2$ showed transmittance of 6% and 51% respectively for UV-A and UV-B also showing a UV-blocking effect. The visible transmittance was 77~89% showing that it satisfies the visible transmittance required for ophthalmological materials.

Improving the Sensitivity of an Ultraviolet Optical Sensor Based on a Fiber Bragg Grating by Coating With a Photoresponsive Material (광반응 재료가 코팅된 단주기 광섬유격자 기반 자외선센서의 광민감도 향상 연구)

  • Kim, Woo Young;Kim, Chan-Young;Kim, Hyun-Kyoung;Ahn, Tae-Jung
    • Korean Journal of Optics and Photonics
    • /
    • v.26 no.2
    • /
    • pp.83-87
    • /
    • 2015
  • This study was focused on developing an optical sensor that monitors ultraviolet (UV) light. Recently, we proposed and demonstrated a novel, highly sensitive UV sensor based on a fiber Bragg grating (FBG). To ensure that the incident UV light is focused on the FBG surface, the sensor was coated with an azobenzene polymer material that acts as a UV-induced stretchable functional material, in combination with a cylindrical focal lens. In this study we have improved the sensitivity of the sensor by employing a cylindrical focal mirror as a curved reflector, to refocus the UV light passing through the FBG. We considered the performance of several different types of reflectors and chose the optimal radius of curvature for the reflector. Compared to the UV sensor without an auxiliary device, the sensitivity of the FBG sensor with a focal lens and a curved reflector was 15 times as high.