• Title/Summary/Keyword: 자연 유기 화합물

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Reactive Ceramic Membrane Incorporated with Iron Oxide Nanoparticle for Fouling Control (산화철 나노입자 부착 반응성 세라믹 멤브레인의 막 오염 제어)

  • Park, Hosik;Choi, Heechul
    • Journal of Korean Society of Environmental Engineers
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    • v.35 no.2
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    • pp.144-150
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    • 2013
  • Hybrid ceramic membrane (HCM) processes that combined ozonation with a ceramic membrane (CM) or a reactive ceramic membrane (RM), an iron oxide nanoparticles (IONs) incorporated-CM were investigated for membrane fouling control. Alumina disc type microfiltration and ultrafiltration membranes doped with IONs by sintering method were tested under varying mass fraction of IONs. Scanning electron microscope (SEM) images showed that IONs were well-doped on the CM surface and doped IONs were approximately 50 nm in size. Change in the pure water permeability of RM was negligible compared to that of CM. These results indicate that IONs incorporation onto CM had little effect on CM performance in terms of the flux. Natural organic matter (NOM) fouling and fouling recovery patterns during HCM processes confirmed that the RM-ozonation process enhanced the destruction of NOM and reduced the extent of fouling more than the CM-ozonation process by hydroxyl radical formation in the presence of IONs on RM. In addition, analyses of NOM in the feed water and the permeate showed that the efficiency of membrane fouling control results from the NOM degradation during HCM processes; leading to removal and transformation of relatively high contents of aromatic, high molecular weight and hydrophobic NOM fractions.

A Study of Intercalations-complexes of Montmorillonite as Model-Systems (Model-system으로서의 몬트모릴로나이트의 층간화합물에 관한 연구 (I))

  • Jo, Seong-Jun;Kim, Jong-Ok
    • The Journal of Natural Sciences
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    • v.5 no.1
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    • pp.77-86
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    • 1992
  • By cation-exchange-reaction long-chain organic cationic tensides can be intercalated in the montmorillonite layer space, and thus intercalations-complexes of montmorillonite with different properties of materials can be obtained. Such intercalations-complexes are finding strong technical appliances in many areas and are also used very often as model-systems for studying behaviors of materials. Therefore in this research intercalations-complexes of montmorillonite with organic cationic tensides ad model-systems were synthesized and their behabiors under various different conditions were studied.

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VOC 흡착 분말활성탄의 폭발특성

  • 김성규;이경덕;김영수;신창섭
    • Proceedings of the Korean Institute of Industrial Safety Conference
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    • 2001.11a
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    • pp.263-268
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    • 2001
  • 휘발성유기화합물(Volatile Organic Compounds, VOC)은 연소배기가스중의 NOx, SOx와 함께 대기환경오염의 주 요인이 되는 물질로서, 제거방법의 하나로 활성탄 흡착법을 주로 사용한다. 흡착제로서 석탄이나 나무에서 제조된 활성탄(Activated Carbon)을 사용하는데, 활성탄 자체는 폭발하지 않으나 어느 정도 유기증기를 흡착하면 분산상태에서 폭발을 일으키는 것으로 알려져 있다 그러나, 국내에서 활성탄에 대한 연구는 자연발화위험성에 대해서만 연구가 진행되었을 뿐, 휘발성유기화합물이 흡착된 활성탄에 대한 연구는 전무한 상태이다.(중략)

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오존을 이용한 폐수처리

  • 한국환경기술인연합회
    • Environmental engineer
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    • s.115
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    • pp.43-45
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    • 1996
  • 강력한 오존 발생기에서 나오는 4.6$\%$의 오존이 액체에 주어졌을 때 처음 반응은 오존이 산소분자와 원자로 분열을 일으키고 산소 발생기로 접어들게 함으로써 산화물을 촉진케 하는 불소를 능가하는 단 하난의 음전성의 산화가능성을 가진 것이기 때문에 오존은 거의 모든 유기성 화합물을 공격할 수 있는 자연이 준 강력한 산화제이며 만능의 처리제인 것이다.

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A Study on the Change of the Adsorption Process of VOCs in the Materials Prepared from the Intercalation Reaction (층간 삽입반응으로 얻어진 화합물을 이용한 휘발성 유기화합물의 흡착과정 변화에 대한 연구)

  • Ahn, Beom-Shu
    • Journal of the Korean Applied Science and Technology
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    • v.34 no.4
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    • pp.799-806
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    • 2017
  • The potential use of modified clays in the adsorption of vapor phase benzene and toluene was investigated. The modified clays OC-CPC, IOC, and Al-PILC were prepared for comparative purposes and were characterized using infrared spectroscopy, thermogravimetric analysis, and X-ray diffraction. It was confirmed the intercalation of the aluminium pillar in IOC and Al-PILC, as well as the introduction of cetylpyridinium. The adsorption studies showed a great affinity of benzene and toluene for OC-CPC due to the hydrophobic character that resulted and also to the increase in the interlaminar distance. IOC showed a lower affinity for the benzene and toluene, followed by Al-PILC. Natual clay had no affinity for benzene and toluene due to its hydrophilic nature. Clay materials having a laminar structure can be chemically modified, changing their physiochemical characteristics, such as interlaminar distance, surface area, pore size, and chemical affinity. In this study, it was focused on obtaining modified clays to be used for the adsorption of volatile organic chemicals.

Study on the estimation of NVOC emission (자연 VOC 배출량 산정에 대한 연구)

  • 김조천;홍지형;장영기;주명칠;전의찬;조규탁;한진석;강창희;김득수
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2001.11a
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    • pp.360-361
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    • 2001
  • VOCs 배출원은 크게 인위적인 배출원과 자연적인 배출원으로 나눌 수 있다. 식물은 자연 발생적 VOCs(NVOCs)의 가장 주요한 배출원이며, 대기 중으로 유입되는 반응성이 강한 탄소의 주요한 배출원이다. 이소프린, terpene, 알콜, 카르보닐화합물, 에스테르 등은 식물에서 발생되는 대표적인 탄화수소화합물들이다. 이러한 물질들은 에어로졸의 형성 등 전지구적 대기화학반응, 광역적 광화학산화제 (특히 오존)의 형성, 탄소순환의 수지균형 비도시지역의 산성침적에 기여하는 유기산의 생성 등에 주요한 영향을 끼친다. (중략)

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Structure Analysis, Biological Activity of a Novel Antibiotics, Cystocin, from Streptomyces sp. GCA0001 and Production of its Derivatives (Streptomyces sp. GCA0001로부터의 신규 항생물질 Cystocin의 구조분석, 생물활성 및 유도체제조)

  • 김자용;이희찬;우진석;송재경
    • Proceedings of the KAIS Fall Conference
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    • 2001.05a
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    • pp.295-297
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    • 2001
  • Cystocin, a derivative of Puromycin, is a new material derived from Streptomyces sp GCA0001, new strain of Actinomycetes spiecies. This compound has outstanding biological activities in anti-bacteria, anti-tumor and anti-virus than former Puromycin compounds. And it is chosen by natural selection processing through extraction, isolation and purification from , so it may replace old Puromycins in most applications.

Detection of Organic Halide by Using cis,cis-1,2,3,4-Tetraphenylbutadiene thin Film (cis,cis-1,2,3,4-Teteraphenylbutadiene 박막 필름을 이용한 유기 할로겐 화합물 감지)

  • Park, Jaehyun
    • Journal of Integrative Natural Science
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    • v.3 no.4
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    • pp.215-218
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    • 2010
  • cis,cis-1,2,3,4-Tetraphenylbutadiene has been synthesized and its optical properties are investigated by using UV-Vis absorption and fluorescence spectroscopy. Thin films of tetraphenylbutadiene prepared from thin layer chromatography(TLC) displays strong luminescence and used for the detection of vapor of organic halide. Tetraphenylbutadiene shows dramatic quenching photoluminescence under exposure of chloroform vapor.

A Study on Characteristics of Natural Organic Matter using XAD and FTIR in Yeongsan River System (XAD 및 FT-IR을 이용한 영산강수계 광주시 유역 자연유기물질의 분포특성 연구)

  • Lee, Dong-Jin;Chon, Kang-Min;Kim, Sang-Don;Jung, Soo-Jung;Lee, Kyung-Hee;Hwang, Tae-Hee;Lim, Byung-Jin;Cho, Jae-Weon
    • Korean Journal of Ecology and Environment
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    • v.44 no.4
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    • pp.358-363
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    • 2011
  • This study investigated the characteristics of natural organic matter(NOM) with tXAD resin and FT-IR in the Yeongsan river system of Gwangju region. NOM fractionation by XAD 8/4 resins was used to classify hydrophobic and hydrophilic substances. FTIR was applied to classify functional groups in the structure of NOM. In the XAD investigation, most of the four site-samples were mainly hydrophilic substances. In March, hydrophobic substances were dominant in the Gwangju 1 site (GJ-1), while hydrophilic substances were dominant for the other sites. In May, samples of all four sites were hydrophilic with a vigorous activity of microorganism due to increasing temperatures. The October results were very similar with those from March. In the FT-IR investigation, most of the broad and large peaks were assigned to the aliphatic group, particularly the OH group, C-H, $C-H_2$, $C-H_3$, and C-O alcohol group. All were related to hydrophilic substances. Other peaks showed the aromatic group, particularly the C=O (Ketone) Group. As a result, there is an identification of NOM in the Yeongsan river system composing mainly of hydrophilic substances and functional groups (OH, C-H etc.) of the aliphatic compound.