DOI QR코드

DOI QR Code

Detection of Organic Halide by Using cis,cis-1,2,3,4-Tetraphenylbutadiene thin Film

cis,cis-1,2,3,4-Teteraphenylbutadiene 박막 필름을 이용한 유기 할로겐 화합물 감지

  • Received : 2010.12.06
  • Accepted : 2010.12.23
  • Published : 2010.12.31

Abstract

cis,cis-1,2,3,4-Tetraphenylbutadiene has been synthesized and its optical properties are investigated by using UV-Vis absorption and fluorescence spectroscopy. Thin films of tetraphenylbutadiene prepared from thin layer chromatography(TLC) displays strong luminescence and used for the detection of vapor of organic halide. Tetraphenylbutadiene shows dramatic quenching photoluminescence under exposure of chloroform vapor.

Keywords

References

  1. R. H. Friend, R. W. Gymer, A. B. Holmes, J. H. Burroughes, R. N. Marks, C. Taliani, D. D. C. Bradley, D. A. Dos Santos, J. L. Bredas, M. Logdlund, and W. R. Salaneck, "Electroluminescence in conjugated polymers", Nature, Vol. 397, p. 121, 1999. https://doi.org/10.1038/16393
  2. S. A. Jenekhe and J. A. Osaheni, "Excimers and exciplexes of conjugated polymers", Science, Vol. 265, p. 765, 1994. https://doi.org/10.1126/science.265.5173.765
  3. R. Deans, J. Kim, M. R. Machacek, and T. M. Swager, "A Poly(p-phenyleneethynylene) with a Highly Emissive Aggregated Phase", J. Am. Chem. Soc., Vol. 122, p. 8565, 2000. https://doi.org/10.1021/ja0007298
  4. C. Belton, D. F. O'Brien, W. J. Blau, A. J. Cadby, P. A. Lane, D. D. C. Bradley, H. J. Bryne, R. Stockmann, and H. H. Horhold, "Excited-state quenching of a highly luminescent conjugated polymer", Appl. Phys. Lett., Vol. 78, p. 1059, 2001. https://doi.org/10.1063/1.1345840
  5. W. Holzer, A. Penzkofer, R. Stockmann, H. Meysel, H. Liebegott, and H. H. Horhold, "Photophysical characterization of diphenyl-substituted phenylenevinylene and diphenylenevinylene polymers", Polymer, Vol. 42, p. 3183, 2001. https://doi.org/10.1016/S0032-3861(00)00522-X
  6. J. Luo, Z. Xie, J. W. Y. Lam, L. Cheng, H. Chen, C. Qiu, H. S. Kwok, X. Zhan, Y. Liu, D. Zhu, and B. Z. Tang, "Aggregation-induced emission of 1-methyl-1,2,3,4,5-pentaphenylsilole", Chem. Commun., p. 1740, 2001.
  7. J. Chen, C. C. W. Law, J. W. Y. Lam, Y. Dong, S. M. F. Lo, I. D. Williams, D. Zhu, and B. Z. Tang, "Synthesis, Light Emission, Nanoaggregation, and Restricted Intramolecular Rotation of 1,1-Substituted 2,3,4,5-Tetraphenylsiloles", Chem. Mater. Vol. 15, p. 1535, 2003. https://doi.org/10.1021/cm021715z
  8. B. K. An, S. K. Kwon, S. D. Jung, and S. Y. J. Park, "Enhanced Emission and Its Switching in Fluorescent Organic Nanoparticles", J. Am. Chem. Soc., Vol. 124, p. 14410, 2002. https://doi.org/10.1021/ja0269082
  9. J. Chen, Z. Xie, J. W. Y. Lam, C. C. W. Law, and B. Z. Tang, "Silole-Containing Polyacetylenes. Synthesis, Thermal Stability, Light Emission, Nanodimensional Aggregation, and Restricted Intramolecular Rotation", Macromolecules, Vol. 36, p. 1108, 2003. https://doi.org/10.1021/ma0213504
  10. W. Holzer, A. Penzkofer, R. Stockmann, H. Meysel, H. Liebegott, and H. H. Horhold, "Energy density dependent fluorescence quenching of diphenyl substituted phenylene-vinylene and diphenylene-vinylene polymers by exciton-exciton annihilation", Synth. Met., Vol. 125, p. 343, 2002.
  11. H. Sohn, R. R. Huddleston, D. R. Powell, and R. West, "An electroluminescent polysiole and some dichlorooligo-siloes", J. Am. Chem. Soc., Vol. 121, p. 2935, 1999. https://doi.org/10.1021/ja983350i
  12. S. Yamaguchi, T. Endo, M. Uchida, T. Izumizawa, K. Furukawa, and K. Tamao, "Toward New Materials for Organic Electroluminescent Devices: Synthesis, Structures, and Properties of a Series of 2, 5-Diaryl-3,4-diphenylsiloles", J. Chem. Eur., Vol. 6, p. 1683. 2000. https://doi.org/10.1002/(SICI)1521-3765(20000502)6:9<1683::AID-CHEM1683>3.3.CO;2-D